Master JEE CLASSES

Kukatpally, Hyderabad.

JEE-ADVANCE-2014-P1-Model
Max. Marks: 180

IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS. Darken
the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as:
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
 JEE-ADVANCE-2014-P1-Model
Time: 07:30 AM to 10:30 AM IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 11 – 20) Questions with Integer Answer Type 3 0 10 30

Total 20 60
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Multiple Correct Choice 3 0 10 30

Sec – II(Q.N : 31 – 40) Questions with Integer Answer Type 3 0 10 30

Total 20 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Multiple Correct Choice 3 0 10 30

Sec – II(Q.N : 51 – 60) Questions with Integer Answer Type 3 0 10 30

Total 20 60
Space for rough work Page 2
PHYSICS Max Marks: 60
SECTION-1
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
1. The equation of a transverse wave travelling in a rope is given by

y  A cos  kx  t    where A  0.6m, k  0.005cm1,   8.0s 1 and  is a non-
2
vanishing constant. Then for this wave,
A) the wavelength of the wave is   8m
B) the maximum velocity vm of a particle of the rope will be ; vm  7.54m / s
C) magnitudes of velocity and slope of y-x graph for an element of rope are inversely
proportional to each other .
D) magnitudes of velocity and slope of y-x graph for an element of rope are directly
proportional to each other.

2. A wire of 9.8  103 kg / m passes over a frictionless light pulley fixed on the top of a
frictionless inclined plane which makes an angle of 30º with the horizontal. Masses m
and M are tied at the two ends of wire such that ' m ' rests on the plane and M hangs

Space for rough work Page 3

 freely vertically downwards. The entire system is in equilibrium and a transverse
wave propagates along the wire with a velocity of 100 m/s.
m 1 m
A) m  20kg B) M  5kg C)  D) 2
M 2 M
0.8
3. y  x, t   represents a moving pulse, where x and y are in the metres
 2 
4 x  5t   5
 
and t is in seconds, then
A) pulse is moving in  x direction
B) in 2s it will travel a distance of 2.5 m
C) its maximum displacement is 0.16 m
D) it is a symmetric pulse
4. A transverse wave travelling on a taut string is represented by Y  0.01sin 2 10t  x 
Y and x are in meters and t in seconds. Then,
A) the speed of the wave is 10m/s.
B) closest points on the string which differ in phase by 600 are (1/6)m apart.
C) maximum particle velocity is  / 4 m / s .
D) the phase of a certain point on the string changes by 120º in (1/20) seconds.
Space for rough work Page 4
5. Two identical point particles A and B are placed in front of a concave mirror of focal
length 20 cm, at distances 10 cm and 30 cm respectively. The particles oscillate
perpendicular to the principal axis, such that the displacement equation for both the
particles is given by YA  YB  0.1sin  t  . The correct statement (s) is/are

A) displacement equation of the image of particle A is YA'  0.2sin  t   / 2 

B) displacement equation of the image of particle B is YB'  0.2sin  t   

C) time period of oscillation of both the images is 2s.
D) relative vertical displacement of image of A with respect to image of B is
'
YAB  0.4sin  t 

6. A long, heavy, flexible rope with mass per unit length ‘  ’ is stretched by a constant
force F. A sudden movement causes a circular loop of radius R to form at one end of
the rope. The loop rolls along the rope with speed ‘v’ as shown in the figure. Then

F F
Space for rough work Page 5
 F
A) v 

F
B) v 
2
C) the kinetic energy carried by the loop is 2  RF

D) the kinetic energy carried by the loop is  R  v2

7. Which of the following functions of x and t represent a progressive wave?
1 1
A) y  sin  4t  3 x  B) y  2
C) y  D) y  3x 2  4t
4   4t  3 x  4t  3x

8. One end of a string of length ‘L’ is tied to ceiling of a lift accelerating upwards with
an acceleration ‘2g’. The other end of the string is free. The linear mass density of the
string varies linearly from 0 to ‘  ’ from bottom to top. A transverse pulse is generated
near the bottom of string.
3g
A) Acceleration of the pulse w.r.t. ground is .
4
B) Relative to string, acceleration of the pulse on the string will be 3g/4 every where.
C) The time taken by a pulse to reach from bottom to top will be 8 L / 3 g .
D) The time taken by a pulse to reach from bottom to top will be 4 L / 3 g .
Space for rough work Page 6
9. y-x curve at an instant for a transverse wave travelling along x axis on a string is
shown. Angle made by tangent with horizontal at the point A on the curve is 530 , as
shown.

A) Transverse velocity of the particle at point A is parallel to positive y direction if the

wave is travelling along positive x-axis.
B) Transverse velocity of the particle at point A is parallel to positive y direction if the
wave is travelling along negative x-direction.
C) Magnitude of transverse velocity of the particle at point A is greater than the wave
speed
D) Magnitude of transverse velocity of the particle at point A is less than the wave
speed

Space for rough work Page 7

10. A plane progressive transverse wave is passing through a medium along the positive
x-axis. At the given instant of time, the nature of the displacement(y), position(x)
graph is shown in figure. Which of the following statements are correct? (Consider A,
B, C are three particles of the vibrating string).

A) Elastic potential energy per unit length of the string at the point B is more than that
at points A and C
B) Elastic potential energy per unit length of the string at the point C is more than that
at points A and B
C) Velocity of the particle at A is along negative y direction.
D) Velocity of the particle at C is along positive y direction.

Space for rough work Page 8

 SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
11. The speed of a transverse wave, going on a wire having a length 50cm and mass 5g is

80 m/s. the area of cross section of the wire is 1.0 mm2 and its Young’s modulus is

8 10 11 N / m 2 . Find the extension (in 102 mm ) of the wire over its natural length.

12. A uniform rope of mass 0.1kg and length 2.45m hangs from a ceiling. The speed of a

transverse wave in the rope at a point 0.5m distant from the lower end is 2.45  n

where n =

13. A 4.0 kg block is suspended from the ceiling of an elevator through a string having a

linear density of 19.2  103 kg/m. The speed (with respect to the string) with which a

wave pulse can proceed on the string if the elevator accelerates up at the rate of

2.0m / s 2 is 12.5n . What is the value of n ? Take  g  10m / s 2 and mstring << 4 kg.

Space for rough work Page 9

14. An ant with mass ‘ m ’ is standing peacefully on top of a horizontal, stretched rope.
The rope has mass per unit length ‘  ’ and is under tension F. Without warning, a
student starts a sinusoidal transverse wave of wavelength ‘  ’ propagating along the
rope. The wave is in vertical plane. What minimum wave amplitude (in mm) can
make that ant feel weightless momentarily? Assume m is so small that the presence of
the ant has no effect on the propagation of the wave. [Given:   0.5m ,   0.1 kg / m ,
F  3.125 N , take g   2 ]

15. Two small pulses are created on the rope at points A & B respectively as shown in the
diagram.

A B
The rope is rotating on horizontal plane with constant angular velocity about end A
where as end B is free. S A & S B are the distances covered by pulse A & pulse B
SA
respectively in rope frame before they cross each other. If k  , find the value of
SB

 k  12 .
Space for rough work Page 10
16. As shown in figure, string PQR is stretched by force F = (3 –10 Kt) N, where K is a
constant and t is time in seconds. At time t = 0, a small pulse is generated at the fixed
end P of the string. Find the value of K (in N/s) if the value of force becomes zero as
the pulse reaches point Q. (Given mass per unit length of string is 0.03 kg/m)

17. Two small blocks each having a mass of 3.2 kg are connected by wire CD and the
system is suspended from the ceiling by another vertical wire AB with AB wire
connected(fixed) to the mid point of wire CD. The linear mass density of the wire AB
is 10 g/m and that of CD is 80 g/m. If the ratio of speeds of transverse pulse in AB to
CD is 4/n find n.
18. The speed of a transverse wave, going on a uniform wire having a length 50 cm and
mass 5.0 g, is 80 m/s. The area of cross-section of the wire is 1.0 mm2 and its Young’s
modulus is 16 × 109 N/m2. Find the extension (in mm) of the wire over its natural
length.
Space for rough work Page 11
19. An ant sitting on a string can pull the string with a maximum force up to three times
10
of its own weight. A sine wave of amplitude A  in vertical plane is generated in
2
the string. Find the least time period of oscillations of string elements so that ant will
not fall from the string. (Neglect the variation of tension in the string due to weight of
the ant g  10m / s2 ).
20. A simple harmonic wave of amplitude 2mm is travelling along positive x-axis. At a
given instant, displacements for two different particles on the wave are 1 mm and
2 mm along positive Y direction. If wavelength of the wave is 48 mm then find

minimum separation between mean positions of the particles (in mm).

Space for rough work Page 12

CHEMISTRY Max Marks: 60
SECTION-1
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
21. Which of the following compounds when reacts with PhMgBr (excess) followed by

acidification will yield 30 alcohol?

O O

A) CH 3  C  Cl B) CH 3  O  C  C2 H 5

C) D) CH 3  C  O  H

Space for rough work Page 13

 O
O
 3
 3

i CH MgBr
  A ; 
i CH MgBr
 ii  H 
  B
ii  H 
H 3C CH 3
H CH 3

22. Which of the following reagent can be used to differentiate between A and B?

A) Victor-Mayer test B) Sodium metal

C) Lucas reagent D) K2Cr2O7 / H 

23. Which reaction can convert phenol to hydroquinone
CHO

OH
( )
(i) H 2 O 2 /OH

 (ii)H 
(i) NaOH
+ CO 2 

(ii) H 
A) B) OH

N 2 Cl OH OH

(i) K 2 S2 O8
( )

(ii) H 

OH
C) D)

Space for rough work Page 14

24. In which of the following reactions, a phenolic compound is formed as product ?

CH 2 CH CH2
O

(i )O 2 / 
 
(ii) dil.H 2SO 4

A) B)
SO 3H Cl

(i) fused NaOH (i)fused KOH

  (ii) H 

(ii) H 
C) D)
25. Which of the following changes are involved in the formation of most stable product
X under given condition?
OH

H+
X
( most stable)

A) Delocalisation of charge
B) 1, 2 shift of Ethyl group
C) Aromatisation of ring in which ethyl substituent is present
D) Aromatisation of ring in which ethyl substituent is absent
Space for rough work Page 15
 Cl

OH CH2-C-Cl
NaOH (1 eq.) NaOH (1 eq.) LiAlH4
26. P O Q R S
OH

select the correct statement(s)

O O

A) ‘Q’ is O B) ‘S’ is

O
Cl
O

C) ‘Q’ is OH D) ‘R’ is
27. In the reaction the products are
HBr
OCH3

Br OCH3 and H2 Br and CH3Br

A) B)

Br and CH3OH OH and CH3Br

C) D)
Space for rough work Page 16
28. Which of the following will result in the formation of an ether as major product?
 
  
A)  CH3 3 CO N a + CH3 CH2Br   B) (CH 3)3CBr + C 2 H5 O N a

 
C) C6H5ONa + CH3 Br D) C6H5Br + CH 3 O N a

29. Select incorrect reaction(s):

A) B)

O O

NH
NH
NaBH4

O OH
C) D)

Space for rough work Page 17

30. Diethyl ether is prepared through
A) The reaction between ethanol and conc. H 2 SO4 at 1400 C
B) The reaction between ethyl bromide and sodium ethoxide
C) heating of ethyl bromide with dry silver oxide
D) Heating ethanol with conc. H 2 SO4 at 1700 C
SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
31. At room temperature how many of the following compounds can decompose NaHCO3
to liberate CO2 ?

A) B) C) D)

Space for rough work Page 18

 OH

NO2
O

CH2  C  OH

E) F) G) H) OH
32. How many of the following compounds give Reimer-Tiemann reaction?
CH 2OH

(a) (b) (c)

OH OH

CH3 OH
(d) (e) (f)

Space for rough work Page 19

 O O

O O

1. AlCl3 / CS 2
 product mixture
+ 2. H 2O

33.
How many compounds are exist in the product mixture?

34. The diazonium ions give diazo-coupling with phenol in the presence of dilute NaOH.

How many of the following are more reactive than Benzene diazonium chloride?

Space for rough work Page 20

35. Number of bromine atoms in A are X, therefore X is

36. How many of the following ethers cannot be prepared by Williamson’s synthesis?

C6 H 5OC2 H 5 , C6 H 5OCH 3 , C6 H 5CH 2OC6 H 5 , C6 H 5OC6 H 5 ,

 CH 3 3 C  O  C  CH 3 3,  CH 3 3 C  O  CH 3
OH OH
CHO
2
Fe

H 2 O2
  CH C l3
KOH
 (i) alkaline H 2 O 2
 (ii)H 
X
37.

The number of hydroxyl groups present in the product X is/are

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38.
Number of moles of HI consumed per mole of (A) is X. Identify the value of X
Zn C 2 H 5Cl
39. Phenol X Y (Monoalkylated product); the number of structural
Dust Anhydrous AlCl3

benzenoid isomers of Y (including Y) are

40.
Five membered ring is major product then the sum of degrees of alcoholic groups
present in P is

Space for rough work Page 22

MATHS Max Marks: 60
SECTION-1
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
41. ‘P’ is a point which moves in XY-plane such that the point ‘P’ is nearer to the centre
of a square than any of the sides. The four vertices of the square are  a,  a  . The

region in which ‘P’ will move is bounded by parts of parabola/parabolas having

possible equations is/are
A) x 2  a 2  2ay B) y 2  2ax  a 2 C) y 2  a 2  2ax D) x 2  a 2  ay
42. Let y 2  4ax be a parabola and x 2  y 2  2bx  0 be a circle. If parabola and circle touch
each other externally then
A) a  0, b  0 B) a  0, b  0 C) a  0, b  0 D) a  0, b  0
43. TP and TQ are tangents to parabola y 2  4 x and normal’s at P and Q intersects at a
point R on the curve. The locus of the centre of the circle circumscribing triangle TPQ
is a parabola whose:
7
A) Vertex is 1, 0  B) foot of directrix  , 0 
8 
1 9
C) Length of latus rectum D) focus is  , 0 
4 8 
Space for rough work Page 23
44. Variable chords of the parabola y 2  4ax subtend a right angle at the vertex. Then:
A) Locus of feet of the perpendicular from the vertex on these chords is a circle
B) Locus of the middle points of the chords is a parabola
C) Variable chords passes through a fixed point on the axis of the parabola
D) None
45. A parabola which touches x-axis at 1, 0  and y-axis at  0, 2  . Then
16 2 16 2
A) Vertex is  ,  B) Vertex is  , 
 25 25   5 5
4 2 4 2
C) Focus is  ,  D) Focus is  , 
5 5
   25 25 

46. Equation of chord joining at A t1  , B  t3  on y 2  4ax subtends a right angle at C  t2 

and D  t4  on the same parabola. Then

t2  t4 t2  t4 1
A) 1 B) t2t4  t1t3  0 C)  D) t2t4  t1t3  4
t1  t3 t1  t3 2

47. If two distinct chords of a parabola y 2  4ax passing through the point  a, 2a  are

bisected by the line x  y  1 , then the length of the latus rectum cannot be
A) 5 B) 6 C) 9 D) 11
Space for rough work Page 24
48. The tangent PT and normal PN to the parabola y 2  4ax at a point P on it meet its axis
at points T and N respectively. The locus of the centroid of the triangle PTN is a
parabola whose  a  0 
2a
A) Vertex is  , 0  B) focus is  2a, 0 
 3 
4a a
C) Length of latus rectum is D) directrix is x 
3 3

49. Normal’s drawn at points P,Q and R lying on the parabola y 2  4 x intersect at  3,0  .
Then
3 5
A) Centroid of  le PQR =  , 0  B) Circumcentre of  le PQR =  , 0 
2  3 
5
C) Area of  le PQR =2 D) Radius of circumcircle of  le PQR is
2
50. Through a point P  2,0  , tangents PQ and PR are drawn to the parabola y 2  8 x . Two
circles each passing through the focus of the parabola and one touching parabola at
Q and other at R are drawn. Which of the following points(s) with respect to the
triangle PQR lie (s) on the common chord of the two circles?
A) Centroid B) orthocenter C) incentre D) Circumcentre

Space for rough work Page 25

 SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
51. The radius of circle passing through the focus of parabola x 2  4 y and touches it at

 6, 9  is equal to  10 then   ........

52. Abscissa of two points P and Q on the parabola y 2  8 x are roots of

equation x 2  17 x  11  0 . Tangents at P and Q meet at point T. Distance of T from the
focus of the parabola.
53. A line ‘L’ with slope 2 cuts parabola y 2  8 x to form a chord. If the midpoint of chord
k
lies on x  4 then the equation of L is y=2x+k. Then  .........
3
54. Let L1 : x  y  0 and L2 : x  y  0 are tangent to a parabola whose focus is S 1, 2  . If the
m
length of latus-rectums of the parabola can be expressed as (m and n are co
n
prime). Then the value of m  n  4 is….....
55. A pair of variable straight lines 5x 2  3 y 2   xy  0   R  , cut y 2  4 x at two points P
and Q. If the locus of the point of intersection of tangents to the given parabola at P
and Q is Kx  12  K  N  . Then K  ........

Space for rough work Page 26

56. m1 , m2 , m3 are the slope of normal’s  m1  m2  m3  drawn through the point  9, 6  to the

parabola y 2  4 x; and A   aij  is square matrix of order 3 such that

1 if i  j
aij   Then A  ..........
 mi if i  j

57. A tangent is drawn to the parabola y 2  4 x at the point ‘P’ whose abscissa lies in the
interval 1, 4 . The maximum possible area of the triangle formed by the tangent at ‘P’,

ordinate of the point ‘P; and the x-axis is equal to K. Then the value of K is ..........
58. If the co-ordinate of the point on the parabola y  x 2  7 x  2 , which is nearest to the
K1  K 2
straight line y  3 x  3 is represented as  K1 , K 2  . Then the value of  ..........
2
59. If the lengths of two perpendicular tangents from a point to a parabola are of 3 and 4
units and the length of latus rectum of the parabola is K units. Then  K   ......

. denotes G.I .F 

60. Let S be the focus of the parabola y 2  8 x and PQ be the common chord of the circle
x 2  y 2  2 x  4 y  0 and the given parabola. The area of triangle PQS is…….

Space for rough work Page 27

 Master JEE CLASSES
Kukatpally, Hyderabad.
JEE-ADVANCE-2014-P1-Model
Max.Marks:180
KEY SHEET

PHYSICS
1 ABD 2 AD 3 BCD 4 AB 5 BCD

6 AC 7 AB 8 BC 9 BC 10 BCD

11 4 12 2 13 4 14 2 15 2

16 2 17 1 18 2 19 1 20 2

CHEMISTRY
21 ABC 22 ACD 23 BD 24 ABCD 25 ABC

26 BCD 27 D 28 C 29 ABC 30 ABC

31 3 32 4 33 4 34 2 35 1

36 2 37 2 38 0 39 4 40 4

MATHS
41 ABC 42 AC 43 ABD 44 ABC 45 AC

46 AD 47 ABCD 48 ACD 49 CD 50 ABCD

51 5 52 7 53 2 54 7 55 5

56 8 57 4 58 5 59 4 60 4
 SOLTUIONS
PHYSICS
1. Conceptual
T T
2. v  104   T  98
 9.8 103

T = Mg  M = 10 , T  mg sin 300
 m  20
m
 2
M
3. Conceptual
4. Conceptual
5. Displacement of image of particle A is in phase with the displacement of particle A
hence the displacement equation of particle A’ s image is
Y ' A  0.2 sin  t  ..... 1

Displacement of image of particle B is out of phase with the displacement of particle

B therefore the displacement of equation of particle B ' s image is
YA '  0.2sin  t    ...  2 

Relative vertical displacement of A.w.r.t. to B is

YAB '  YA ' YB '

 0.2sin   t   0.2sin  t   

 0.4sin   t  ...  3

F
6. V


1 1
E  MV 2  IC  2
2 2
7. Conceptual
8. Conceptual
9. Conceptual
10. Conceptual
TL
11. V
m

Page 2
 FL
 Extension e 
AY
Mx
12. T  g
L
T Mgx
So, v    gx
 M 
L 
 L 

hence x  0.5 n  2

4 10  2 
13. 12.5  n  n  4
19.2 103
14. Conceptual
15. At any distance

m L  x m 2 2
T
L
 L  x  2
2

2L
L x  
But T  v2 in rope frame

2 2 2
 v2 
2
L x
 
AB
pulse will be meeting at a distance from A.
2
AB
2 1
k    2 1
AB 2 1
AB 
2

  k  12  2

3  (10K)t dx
16. v 
3  102 dt
L t0
10 3
dx  3
 3  10kt  dt where t 0 
10K
0 0

TAB 64
17. v AB    6400  80m / s
 AB 10 103

T 32
vCD  CD 
 DC 80 103
v AB 80
  4 :1
vCD 20
Page 3
18. The linear mass density is
5  10 3
 2
 1.0  10 2 kg/m
50  10

T
The wave speed is v


Thus, the tension is T  v 2  (1.0  102 )  6400  64 N

T/A
The Young’s modulus is given by Y
L / L
TL 64  0.50
The extension is, therefore, L   2 mm.
AY 1.0  106 16  109

19. At the highest point

mg  3mg  m  amax 
 4mg  m 2 A
4g
   2
A
2
T 

y t X
 sin 2   
A  T ; 
y1 1, A  2,
20.
t x  1 
2   1   sin 1    rad
T   2 6
y1  2, A  2,

t x   1  
2   2   sin 1    rad
T    2  4
t x1 1
 
T  12
t x2 1
 
T  8
x1 x2 1
substract  
  24

 x1  x2  
24
CHEMISTRY
21. Conceptual
22. Conceptual
23. Conceptual

Page 4
24. Conceptual

25.
O
O O O O O

+ Cl

O Cl O
26. OH Cl

OH
LiAlH4

O CH2 CH2OH

27. Conceptual
28. Conceptual

29.
30. Conceptual
OH

31. A) PKa 9.31 B)

Page 5
 OH

NO2

C) PKa 7.15 D) NO2 PKA 3.96

E) PKA 0.38 F) PKA 18

G) PKa 7.12 H) PKa 3.83

32. Conceptual
33. Conceptual
34. Electron withdrawing groups will increase the dizocupling
35. Conceptual
36. Conceptual
37. Conceptual
38. Conceptual

39.
+
O O H
+ OH CH2OH CH2OH
CH2 H CH2 H2O
H 
H3C CH3 H3C CH3 H3C CH3
+ OH

H3C CH3
H3C CH3
40.

Page 6
 MATHS
41. Let ‘O’ be the centre of square ABCD and
Let P   x, y 

By the given data x 2  y 2  a  x , x2  y 2  a  x , x 2  y 2  a  b and x2  y2  a  y

42. For externally touching a and b must have same sign

43. Locus of centre of triangle circumscribing triangle TPQ is
1
y2   x  1
2
Vertex  V  1, 0 
1
L.L.R  4a 
2
44. Conceptual
45. Conceptual
46. A   at12 , 2 at1  B   at22 , 2at2  , P   at12 , 2 at 

4
APB  900   1  1
 t1  t  t  t3 
Let t2 , t3 be the roots of (1)
 t2  t4    t1  t3 

t2  t4
1 and t2t4  t1t3  4
t1  t3
 t2t4  t1t3  4

47. Given point P   a, 2a  let other entity be Q   at 2 , 2at 

 a  at 2 
Midpoint of PQ   , a 1  t   lies as x  y  1
 2 

a  at 2
  a 1  t   1
2
 at 2  2at   3a  2   0

0  a   0,1
Here
 4a   0, 4 

48. Let G   h, k 

at 2   at 2   2a  at 2 2at
h , k
3 3
Page 7
 2
 3k 
 3h  2a  a  
 2a 

9k 2
 3h  2 a   9k 2  4a  3h  2 a 
4a
4a  2a 
Returns y 2  x 
3  3 

x  2a a a
V   , 0  directs x   x
3  3 3 3

49. Normal at ‘t’ is y  xt  2at  at 3

3
(3,0) lies on it t  t  0  t  0,1, 1
 P  1, 2  , Q   0, 0  , R  1, 2 

1
 Area   1 4  0
2

2  5  5
Centroid   , 0   S   , 0   R 
3  2  2

50. Conceptual
51. Tangent at  6, 9  is 3 x  y  9  0

Equation of circle is  x  6 2   y  9 2    3x  y  9   0

 0,1 lies on it    10

 circle is r  5 10    5

52. Use result ST  SP.SQ

53.  4, y  be the mid point
 equation of chord is S1  S11

 yy1  4 x  y12  16

Given slope =2  y1  2
54. Feet of the perpendicular from focus upon any tangent to parabola lies on the tangent
at the vertex.
Equation of SN1 is x  y  k  1

1, 2  lies on it 1  x  y  3

Page 8
 3 3
Solve x  y  3 and x  y  N1   , 
2 2  

Equation of SN 2 is x  y  t  2

1, 2  lies on it  2  y  x  1
1 1 
Solve y  x  1 and x  y  0  N 2   , 
 2 2

 Equation of tangent at vertex = equation of N1 N 2

 2x  4 y  3  0

L.L.R = 4(distance from S(1,2) to tangent at vertex)

2 8  3 43 6
L.L.R = 4   
4  16 2 5 5

55. Equation of a chord of contact is S1  0

yy1  2 x
i.e. yy1  2  x  x1   1 1
2 x1

Horizontal curve y 2  4 x with 1

 yy  2 x 
y2  4x  1 0
 2 x1 

 y 2 x1  2 y1 xy  4 x 2  0

 4 x 2  2 y1 xy  y 2 x1  0  1

Equation of 5 x 2  2 xy  3 y 2  0  2
4 2 y1 x1
1&2 are identical  
5  3
12
x1   5 x1  12  5 x  12
5
56. Equation is y  mx  2m  m3
 9, 6  lies on it m3  7m  6  0

Roots are -1,-2,3

 2 1 1 
 
 A   1 1 1   A  8
 1 1 3
 

1
57. Area of triangle PTQ    2t 2    2t   2 t 3
2

Page 9
 Given t 2  1, 4  t   2, 1  1, 2
 max  16 for t  2

 K  16  k  16  4
3
7 1 41 
58. Parabola is  x    4   y  
 2  4  4

Slope of tangent parallel to given live =m=3

 7 41 
P.C   2am  , am 2     2, 8   k1 , k2 
 2 4

k1  k2
 5
2
2 2
2 2  t 1  2 2  t 1 
59.  a  at   t2   9 and  a  at   t 2   16
   
9 4  144
t 2   4a    4a   4
16 125
60. x  2t 2 ; y  4t , substitute in circle

 4t 4  16t 2  4t 2  16t  0  t  0 or 1

 P   0, 0  ; Q  2, 4  ; S   2, 0 

1
Area  0  8  4units
2

Page 10