Acetic Acid - 2019
Acetic Acid - 2019
Acetic Acid - 2019
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Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
STRUCTURAL FORMULA
O
HO CH3
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Used in the manufacture of Chemicals such as Vinyl Acetate Monomer, Acetic Anhydride, Acetate esters and Chloroacetic acid. Used as a
solvent in the manufacture of terephthalic acid and other applications. Used in the Textile, Pharmaceutical, Photographic, Dyestuff, Pesticide
and Rubber industry. Used to make specialty chemicals such as Sorbic acid.
GHS-US classification
Skin corrosion: Category 1B
Metal corrosive: Category1
Flammable Liquid: Category 3
Serious eye damage: Category 1
Acute Toxicity Inhalation: Category 4
Harmful to aquatic Life: Category 3
HAZARDS STATEMENTS
H314: Causes severe skin burns and eye damage.
H290: May be corrosive to metals.
H226: Flammable liquid and vapour.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H412: Harmful to aquatic life with long lasting effects.
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Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
PRECAUTIONARY STATEMENTS
P 273: Avoid to the release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash hands thoroughly after handling.
P261: Avoid breathing fume/mist/vapors/spray.
P271: Use only outdoors or in a well-ventilated area.
P234: Keep only in original container.
P210: Keep away from heat/ sparks/open flames/hot surfaces. No smoking.
P233: Keep container tightly closed.
P240: Ground/ bond container and receiving equipment.
P241: Use explosion proof electrical/ventilating/lighting equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P301+P330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (OR HAIR): Remove/Take off immediately all contaminated clothing .Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P321: Specific treatment reference to supplemental first aid instruction, if immediate specific measures are required.
P312: Call a POISON CENTER or doctor/physician.
P390: Absorb spillage to prevent material damage.
P370+P378: In case of fire use Manufacture /supplier to specific appropriate media for extinction.
P405: Store locked up.
P406: Store in a corrosive resistant/container with a resistant inner liner.
P403+P235: Store in a well-ventilated place. Keep cool.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
Page 3 of 10
Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Control parameters
Exposure Limits Values
Exposure Limits: 1ppm=2.494 mg/m3
Page 4 of 10
Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Exposure Controls
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational
exposure limits. Local ventilation is usually preferred. Ensure that eyewash stations and safety showers are close to the workstation location
Personal Protection:
Hands: Compatible gloves. (Butyl rubber gloves)
Eyes: Safety goggles/ Chemical Safety glasses and Face shield.
Clothing: Boots and clothing to prevent contact.
Respirator: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European
Standard EN 149 approved respirator when necessary.
1-10 times OEL: Use use air-purifying respirator with full facepiece and organic vapor cartridge(s) or air-purifying full facepiece respirator with
an organic vapor canister or a full facepiece powered air-purifying respirator fitted with organic vapor cartridge(s). The air purifying element
must have an end of service life indicator, or a documented change out schedule must be established. Otherwise, use supplied air if in doubt.
For concentrations more than 10 times the occupational exposure level and less than the lower of either 100 times the occupational exposure
level or the IDLH: Use Type C full face piece supplied-air respirator operated in positive-pressure or continuous flow mode.
For concentrations > 100 times the occupational exposure level or greater than the IDLH level or unknown concentrations (such as in
emergencies): Use self-contained breathing apparatus with full face piece in positive-pressure mode or Type C positive-pressure full face
piece supplied-air respirator with an auxiliary positive-pressure self-contained breathing apparatus (SCBA) escape system.
Escape respirators are designed to be used only in an emergency; and only to escape from a dangerous area to a safe area, typically
designed for one-time use for a short period, typically 15 minutes to 1 hour.
Protective Material
Material Grade
BUTYL; NEOPRENE; NITRILE+PVC; PE;
SARANEX-23; TEFLON; PE/EVAL/PE; PVC A
NATURAL RUBBER; NITRILE; BUTYL/NEOPRENE
B
NATURAL + NEOPRENE
NAT+NEOPR+NITRILE C
A: Best Selection;
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
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Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Page 6 of 10
Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
f) Carcinogenicity:
Not listed by NTP, IARC and OSHA.
Not present on the EU CMR list
According to information presently available acetic acid has been tested and not found to be carcinogenic.
g) Reproductive Toxicity:
According to present information acetic acid is not believed to possess a Reproductive Hazard. (NJ Hazardous Substance Fact Sheet RTK
004 Rev. 1998)
h) Aspiration hazard:
No information available
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Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
a) Toxicity
Ecotoxicity:Fish
Bluegill 96hr LC50: 75 mg/l
Pimephalus Promelas (Fathead Minnow )
o LC50: (1;24;48;72;96 hr): (>315; 122; 92, 88; 88 mg/l)
Crustacea
Daphnia Magna (pH 7)
o 24 Hr (EC0; EC50; EC100): 950; 6000; 7145 mg/l)
Daphnia Magna 24Hr LC50: 47 mg/l
Artemia Salina 48 Hr LC50: 32 mg/l
Harmful to aquatic organisms (IPCS 1999)
High concentrations will produce pH levels toxic to oxidizing bacteria, inhibiting oxygen demand. (Environment Canada 1981,
HSDB HSN 40 20050624)
EC50 Tobacco fumigation 41 mg/cu m/2 hr, effect: leaf injury (95% confidence interval 4-79) [Verschueren, K. Handbook of
Environmental Data on Organic Chemicals. Volumes 1-2. 4th ed. John Wiley & Sons., York, NY. 2001, p. 102]
b) Persistence and Degradability
Photochemical degradation: OH rate constant: 7.4X10-13 cm3/molecule-sec. Half life is about 22 days in air.
Biological oxygen demand after 10 days (BOD10) at 20 deg C is: 82% biological oxidation in fresh water and 88% biological
oxidation in sea water [Verschueren, K. Handbook of Environmental Data of Organic Chemicals. 3rd ed. New York, NY: Van
Nostrand Reinhold Co., 1996, p 106].
Readily biodegradable.
Inoculum: Activated sludge, not adapted.
Concentration: 100mg/l
Conditions: Aerobic, pH=7
Result: 100% degradation after 140 hours.
Ref: IUCLID dataset, 2000
Soil
Using a modified OECD protocol, 75% and > 90% degradation of acetic acid was observed after 14 days using garden
soil and sediment from the RhineRiver as inocula, respectively. (HSDB, 40, 2005)
c) Bioaccumulation
BCF = 3.162
Log Kow = -0.17 Low potential to bio accumulate.
Based on the Log Kow and Bio concentration factor value it is expected to have low potential to concentrate in fatty tissue of fish and aquatic
organisms.
d) Mobility
If released in air based on its vapor pressure of 1.5 kPa @20 degrees acetic acid should exist mostly in the air, where it will
photodegrdare with a half life of 22 days approximately.
Henry's Law constant = 1X10-7 atm-cu m/mol at 25 deg C, pH 4.indicates a tendency to stay in water rather than volatilize.
Similarly Koc values ranging from 1 to 228 suggest that acetic acid is expected to have very high to moderate mobility in soil.
e) Environmental Fate
Based on the environmental modeling, this material has a low potential to get moderate absorbed in the organic matter of soil and is
slightly volatile from water bodies and based on the Log Kow and Bio concentration factor value it is expected to have low potential
to concentrate in fatty tissue of fish and aquatic organisms.. Since this is an estimated result it is recommended that the material
should not be disposed into the environment. The material should never be disposed into the sewage.
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Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Packing
S.No Agency UN Number Proper Shipping name Hazard Class
Group
Class 8,
Land Transport UN2789 Acetic acid
DOT Sub risk 3 II
Maritime Class 8,
IMDG UN2789 ACETIC ACID II
Transport Sub risk 3
Class 8,
Air Transport IATA UN2789 Acetic acid II
Sub risk 3
Hazard Class 8
(Corrosive),
Hazard Label Sub risk Class 3
(Flammable)
Environmental hazards
It is expected that this chemical is a marine pollutant and is Harmful to the Aquatic environment
Page 9 of 10
Acetic acid
Safety Data Sheet
According to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
b) A key or legend to aberrations and acronyms used in the safety data sheet
PBT =Persistent Bioaccumulative and Toxic.
vPvB= Very Persistent and Very Bioaccumulative.
SCBA= Self Contained Breathing Apparatus.
NIOSH REL= National Institute for Occupational Safety and Health Recommended Exposure Limit.
OSHA PEL=Occupational Safety and Health Administration Permissible Exposure Limit.
OELTWA= Occupational Exposure Limit Time Weighted Averages.
IDLH= Immediately Dangerous to Life or Health.
UEL= Upper Explosive Limit.
LEL= Lower Explosive Limit.
RTECS= Registry of Toxic Effects of Chemical Substances.
NTP=National Toxicology Program.
IARC= International Agency for Research on Cancer.
EPA=Environmental Protection Agency.
TSCA= Toxic Substances Control Act.
CERCLA= Comprehensive Environmental Response, Compensation, and Liability Act.
SARA= Superfund Amendments and Reauthorization Act.
NFPA= National Fire Protection Association.
WHIMS= Workplace Hazardous Materials Information System.
DSL/NDSL= Domestic/Non-Domestic Substances List.
CSR=Chemical Safety Report.
BCF = Bio Concentration Factor.
DNEL = Derived No Effect Level.
PNEC = Predicted No Effect Concentration.
TLV = Threshold Limit Value.
ACGIH = American Conference of Governmental Industrial Hygienists.
REACH = Registration, Evaluation Authorization and Restriction of Chemicals.
CLP = Classification, Labelling and Packaging.
LD / LC = Lethal Doses / Lethal Concentration.
GHS = Globally Harmonized System.
ADR = Accord European relative au transport international de merchandises.
IMDG-Code = International Maritime Code for Dangerous Goods.
EmS = Emergency measures on Sea.
ICAO = International Civil Aviation Organization.
IATA/DGR= International Air Transport Association/Dangerous Goods Regulation.
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