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    2021-2022 SPRING TERM Chem 352 Physical Chemistry Ii 4/3/2022 Problem Set I

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    2021-2022 SPRING TERM Chem 352 Physical Chemistry Ii 4/3/2022 Problem Set I

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    2021-2022 SPRING TERM Chem 352 Physical Chemistry Ii 4/3/2022 Problem Set I

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    2021-2022 SPRING TERM

    CHEM 352 PHYSICAL CHEMISTRY II 4/3/2022

    PROBLEM SET I

    1- 3.00 moles of an ideal gas at 27.0ºC expands isothermally from an initial volume of 20.0 dm 3 to a
    final volume of 60.0 dm3. Calculate w for this process a) for expansion against a constant external
    pressure of 1.00 x 105 Pa, and b) for a reversible expansion.

    2- For one mole of an ideal gas, Pexternal = 200 x 103 Pa. The temperature is changed from 100ºC to
    25.0ºC at constant pressure. CV,m = 3/2 R. Calculate q, w, ΔU, and ΔH.

    3- (Atkins Ed.8 2.3b) A sample consisting of 2.00 mol He is expanded isothermally at 22°C from 22.8
    dm3 to 31.7 dm3 (a) reversibly, (b) against a constant external pressure equal to the final pressure
    of the gas, and (c) freely (against zero external pressure). For the three processes calculate q, w,
    ΔU, and ΔH.

    4- A sample containing 2.00 mol of an ideal gas undergoes isothermal expansion along three different
    paths:
    (1) reversible expansion from Pi = 25.0 bar and Vi = 4.50 L to Pf=4.50 bar,
    (2) a single-step irreversible expansion against a constant external pressure of 4.50 bar, and
    (3) a two-step irreversible expansion consisting initially of an expansion against a constant pressure
    of 11.0 bar until P=Pext, followed by an expansion against a constant external pressure of 4.50 bar
    until P=Pext.
    Calculate the work for each of these processes. For which of the irreversible processes is the
    magnitude of the work greater?

    5- (Atkins Ed.8 2.3b) The constant-pressure heat capacity of a sample of a perfect gas was found to
    vary with temperature according to the expression Cp/(J K−1) =20.17 + 0.4001(T/K). Calculate q, w,
    ΔU, and ΔH when the temperature is raised from 0°C to 100°C (a) at constant pressure, (b) at
    constant volume.

    𝑜
    6- At 298K, Δ𝐻𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 =131.28 kJ/mol for the reaction C(graphite) + H2O →CO(g) + H2(g).
    CP,m = 8.53, 33.58, 29.12, and 28.82 J/mol.K for graphite, H2O(g), CO(g), and H2(g),
    respectively. Calculate reaction ΔHo at 125ºC from this information. Assume that the heat
    capacities are independent of temperature.

    7- From the following data at 25C


    𝑜
    ½ H2(g) + ½ O2(g) → OH(g) Δ𝐻𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 = 38.95 kJ/mol
    𝑜
    H2(g) + ½ O2(g) → H2O(g) Δ𝐻𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 = –241.814 kJ/mol
    𝑜
    H2(g) → 2H(g) Δ𝐻𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 = 435.994 kJ/mol
    𝑜
    O2(g) → 2O (g) Δ𝐻𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 = 498.34 kJ/mol

    𝑜
    Calculate , Δ𝐻𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 for
    a) OH (g) → H(g) + O(g)
    b) H2O(g) → 2H(g) + O(g)
    c) H2O(g) → H(g) + OH(g)
    𝑜 𝑜
    Assuming ideal gas behavior, calculate Δ𝐻𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 and Δ𝑈𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 for all three reactions.

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