RAPTOR HARDENER

Safety Data Sheet

according to the Hazardous Products Regulation (February 11, 2015)
Issue date: 08-26-2021 Revision date: 05-03-2023 Supersedes: 08-26-2021 Version: 1.1

SECTION 1: Identification
1.1. Product identifier
Product form : Mixture
Trade name : RAPTOR HARDENER
UP Number UP8435, UP8436
Product group : 2K Hardener
Other means of identification : UP8405, UP8406 and UP8407
1.2. Recommended use and restrictions on use
Recommended use : Hardener

1.3. Supplier

Distributor
U-POL Canada Limited
P.O. Box P.O. BOX 48600
BC V7X 1T2 Vancouver - Canada
T 1-800-424-9300
technicalsupport@u-pol.com - www.u-pol.com

1.4. Emergency telephone number

Emergency number : 1-800-424-9300 (CHEMTREC)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture
Classification (GHS CA)
Flammable liquids Category 2 H225
Serious eye damage/eye irritation Category 2 H319
Skin sensitization, Category 1 H317
Specific target organ toxicity – Single exposure, Category 3, Narcosis H336
Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation H335
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS CA labeling
Hazard pictograms (GHS CA) :

Signal word (GHS CA) : Danger

Hazard statements (GHS CA) : H225 - Highly flammable liquid and vapor
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
H336 - May cause drowsiness or dizziness
Precautionary statements (GHS CA) : P101 - If medical advice is needed, have product container or label at hand.
P102 - Keep out of reach of children.
P103 - Read label before use.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 - Keep container tightly closed.
P261 - Avoid breathing fume, spray, vapors.
P264 - Wash hands thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear eye protection, face protection, protective clothing, protective gloves.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove

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Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

contact lenses, if present and easy to do. Continue rinsing.

P312 - Call a doctor if you feel unwell.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P363 - Wash contaminated clothing before reuse.
P370+P378 - In case of fire: Use dry sand, extinguishing powder, foam to extinguish.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P403+P235 - Store in a well-ventilated place. Keep cool
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.

2.3. Other hazards

2.4. Unknown acute toxicity (GHS CA)

SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Chemical name / Synonyms Product identifier % Classification (GHS CA)
methyl acetate methyl acetate (CAS-No.) 79-20-9 45 – 60 Flam. Liq. 2, H225
acetate of methyl / acetic acid methyl Eye Irrit. 2, H319
ester / acetic acid, methyl ester / STOT SE 3, H336
devoton / ethyl ester of monoacetil
acid / methyl acetate / methyl
acetate, anhydrous / methyl acetic
ester / methyl ester acetic acid /
methyl ethanoate / tereton
hexamethylene diisocyanate (CAS-No.) 28182-81-2 < 45 Acute Tox. 4 (Inhalation), H332
oligomers Skin Sens. 1, H317
STOT SE 3, H335
n-butyl acetate n-butyl acetate (CAS-No.) 123-86-4 <3 Flam. Liq. 3, H226
1-acetoxybutane / 1-butyl acetate / STOT SE 3, H336
acetate of butyl / acetic acid n-butyl
ester / acetic acid normal-butyl ester
/ acetic acid, butyl ester / BUAC /
BuAc (=butyl acetate) /
butanolacetate / butyl acetate / butyl
ethanoate / n-BuAc / n-butyl acetate
/ normal-butylacetate / normal-
butylethanoate
solvent naphtha (petroleum), light solvent naphtha (petroleum), light (CAS-No.) 64742-95-6 <3 Flam. Liq. 3, H226
aromatic arom. / solvent naphtha (petroleum), STOT SE 3, H336
light aromatic STOT SE 3, H335
Asp. Tox. 1, H304
Aquatic Chronic 2, H411

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison
center/doctor/physician if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. If skin
irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Call a poison center/doctor/physician if you feel unwell.
First-aid measures general : Call a poison center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects : May cause drowsiness or dizziness.
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : May cause an allergic skin reaction.
Symptoms/effects after eye contact : Eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Other medical advice or treatment : Treat symptomatically.

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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.

5.2. Unsuitable extinguishing media

5.3. Specific hazards arising from the hazardous product

Fire hazard : Highly flammable liquid and vapor.

5.4. Special protective equipment and precautions for fire-fighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Methods and materials for containment and cleaning up

Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public
waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.3. Reference to other sections
For further information refer to section 8: "Exposure controls/personal protection"

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Flammable vapors may accumulate in the
container. Use explosion-proof equipment. Wear personal protective equipment. Use only
outdoors or in a well-ventilated area. Avoid breathing vapors, spray, fume. Avoid contact with
skin and eyes.
Hygiene measures : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated
clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands
after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Ground/bond container and receiving equipment.
Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

hexamethylene-di-isocyanate (822-06-0)
Canada (Quebec) VEMP (OEL TWA) 0.034 mg/m³
Canada (Quebec) VEMP (OEL TWA) [ppm] 0.005 ppm
Canada (Quebec) Notations and remarks EM, S
Canada (Quebec) Regulatory reference S-2.1, r. 13 - Regulation respecting occupational
health and safety
Alberta OEL TWA 0.03 mg/m³
Alberta OEL TWA [ppm] 0.005 ppm
Alberta Regulatory reference Alberta Regulation 87/2009 (Alberta Regulation
150/2020)
British Columbia OEL STEL [ppm] 0.01 ppm
British Columbia OEL TWA [ppm] 0.005 ppm
British Columbia Notations and remarks S(R) (respiratory sensitization)
British Columbia Regulatory reference OHS Guidelines Part 5: Chemical Agents and
Biological Agents (WorkSafe BC)
Manitoba OEL TWA [ppm] 0.005 ppm (IFV - Inhalable fraction and vapor)
Manitoba Notations and remarks TLV® Basis: URT irr; resp sens. Notations: BEI
Manitoba Regulatory reference ACGIH
New Brunswick OEL TWA [ppm] 0.005 ppm

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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

hexamethylene-di-isocyanate (822-06-0)
New Brunswick Notations and remarks URT irr; resp sens
Newfoundland & Labrador OEL TWA [ppm] 0.005 ppm (IFV - Inhalable fraction and vapor)
Newfoundland & Labrador Notations and remarks TLV® Basis: URT irr; resp sens. Notations: BEI
Newfoundland & Labrador Regulatory reference ACGIH
Nova Scotia OEL TWA [ppm] 0.005 ppm (IFV - Inhalable fraction and vapor)
Nova Scotia Notations and remarks TLV® Basis: URT irr; resp sens. Notations: BEI
Nova Scotia Regulatory reference ACGIH
Nunavut OEL STEL [ppm] 0.015 ppm
Nunavut OEL TWA [ppm] 0.005 ppm
Nunavut Regulatory reference Occupational Health and Safety Regulations, Nu Reg
003-2016
Northwest Territories OEL STEL [ppm] 0.015 ppm
Northwest Territories OEL TWA [ppm] 0.005 ppm
Northwest Territories Regulatory reference Occupation Health and Safety Regulations R-039-
2015 (R-013-2020)
Ontario OEL Ceiling [ppm] 0.02 ppm
Ontario OEL TWA [ppm] 0.005 ppm
Ontario Regulatory reference Ontario Occuational Exposure Limits under Regulation
833
Prince Edward Island OEL TWA [ppm] 0.005 ppm (IFV - Inhalable fraction and vapor)
Prince Edward Island Notations and remarks TLV® Basis: URT irr; resp sens. Notations: BEI
Prince Edward Island Regulatory reference ACGIH
Saskatchewan OEL STEL [ppm] 0.015 ppm
Saskatchewan OEL TWA [ppm] 0.005 ppm
Saskatchewan Regulatory reference The Occupational Health and Safety Regulations,
1996. Chapter O-1.1 Reg 1
n-butyl acetate (123-86-4)
Canada (Quebec) VECD (OEL STEL) [ppm] 150 ppm
Canada (Quebec) VEMP (OEL TWA) [ppm] 50 ppm
Canada (Quebec) Regulatory reference S-2.1, r. 13 - Regulation respecting occupational
health and safety
Alberta OEL STEL 950 mg/m³
Alberta OEL STEL [ppm] 200 ppm
Alberta OEL TWA 713 mg/m³
Alberta OEL TWA [ppm] 150 ppm
Alberta Notations and remarks Occupational exposure limit is based on irritation
effects and its adjustment to compensate for unusual
work schedules is not required.
Alberta Regulatory reference Alberta Regulation 87/2009 (Alberta Regulation
150/2020)
British Columbia OEL STEL [ppm] 150 ppm
British Columbia OEL TWA [ppm] 50 ppm
British Columbia Regulatory reference OHS Guidelines Part 5: Chemical Agents and
Biological Agents (WorkSafe BC)
Manitoba OEL STEL [ppm] 150 ppm
Manitoba OEL TWA [ppm] 50 ppm
Manitoba Notations and remarks TLV® Basis: Eye & URT irr
Manitoba Regulatory reference ACGIH
Newfoundland & Labrador OEL STEL [ppm] 150 ppm
Newfoundland & Labrador OEL TWA [ppm] 50 ppm
Newfoundland & Labrador Notations and remarks TLV® Basis: Eye & URT irr
Newfoundland & Labrador Regulatory reference ACGIH
Nova Scotia OEL STEL [ppm] 150 ppm

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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

n-butyl acetate (123-86-4)

Nova Scotia OEL TWA [ppm] 50 ppm
Nova Scotia Notations and remarks TLV® Basis: Eye & URT irr
Nova Scotia Regulatory reference ACGIH
Nunavut OEL STEL [ppm] 200 ppm
Nunavut OEL TWA [ppm] 150 ppm
Nunavut Regulatory reference Occupational Health and Safety Regulations, Nu Reg
003-2016
Northwest Territories OEL STEL [ppm] 200 ppm
Northwest Territories OEL TWA [ppm] 150 ppm
Northwest Territories Regulatory reference Occupation Health and Safety Regulations R-039-
2015 (R-013-2020)
Ontario OEL STEL [ppm] 200 ppm
Ontario OEL TWA [ppm] 150 ppm
Ontario Regulatory reference Ontario Occuational Exposure Limits under Regulation
833
Prince Edward Island OEL STEL [ppm] 150 ppm
Prince Edward Island OEL TWA [ppm] 50 ppm
Prince Edward Island Notations and remarks TLV® Basis: Eye & URT irr
Prince Edward Island Regulatory reference ACGIH
Saskatchewan OEL STEL [ppm] 200 ppm
Saskatchewan OEL TWA [ppm] 150 ppm
Saskatchewan Regulatory reference The Occupational Health and Safety Regulations,
1996. Chapter O-1.1 Reg 1
methyl acetate (79-20-9)
Canada (Quebec) VECD (OEL STEL) 757 mg/m³
Canada (Quebec) VECD (OEL STEL) [ppm] 250 ppm
Canada (Quebec) VEMP (OEL TWA) 606 mg/m³
Canada (Quebec) VEMP (OEL TWA) [ppm] 200 ppm
Canada (Quebec) Regulatory reference S-2.1, r. 13 - Regulation respecting occupational
health and safety
Alberta OEL STEL 757 mg/m³
Alberta OEL STEL [ppm] 250 ppm
Alberta OEL TWA 606 mg/m³
Alberta OEL TWA [ppm] 200 ppm
Alberta Regulatory reference Alberta Regulation 87/2009 (Alberta Regulation
150/2020)
British Columbia OEL STEL [ppm] 250 ppm
British Columbia OEL TWA [ppm] 200 ppm
British Columbia Regulatory reference OHS Guidelines Part 5: Chemical Agents and
Biological Agents (WorkSafe BC)
Manitoba OEL STEL [ppm] 250 ppm
Manitoba OEL TWA [ppm] 200 ppm
Manitoba Notations and remarks TLV® Basis: Headache; dizziness; nausea; eye dam
(degeneration of ganglion cells in the retina)
Manitoba Regulatory reference ACGIH
New Brunswick OEL STEL [ppm] 250 ppm
New Brunswick OEL TWA [ppm] 200 ppm
New Brunswick Notations and remarks eye & URT irr
Newfoundland & Labrador OEL STEL [ppm] 250 ppm
Newfoundland & Labrador OEL TWA [ppm] 200 ppm
Newfoundland & Labrador Notations and remarks TLV® Basis: Headache; dizziness; nausea; eye dam
(degeneration of ganglion cells in the retina)
Newfoundland & Labrador Regulatory reference ACGIH
Nova Scotia OEL STEL [ppm] 250 ppm
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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

methyl acetate (79-20-9)

Nova Scotia OEL TWA [ppm] 200 ppm
Nova Scotia Notations and remarks TLV® Basis: Headache; dizziness; nausea; eye dam
(degeneration of ganglion cells in the retina)
Nova Scotia Regulatory reference ACGIH
Nunavut OEL STEL [ppm] 250 ppm
Nunavut OEL TWA [ppm] 200 ppm
Nunavut Regulatory reference Occupational Health and Safety Regulations, Nu Reg
003-2016
Northwest Territories OEL STEL [ppm] 250 ppm
Northwest Territories OEL TWA [ppm] 200 ppm
Northwest Territories Regulatory reference Occupation Health and Safety Regulations R-039-
2015 (R-013-2020)
Ontario OEL STEL [ppm] 250 ppm
Ontario OEL TWA [ppm] 200 ppm
Ontario Regulatory reference Ontario Occuational Exposure Limits under Regulation
833
Prince Edward Island OEL STEL [ppm] 250 ppm
Prince Edward Island OEL TWA [ppm] 200 ppm
Prince Edward Island Notations and remarks TLV® Basis: Headache; dizziness; nausea; eye dam
(degeneration of ganglion cells in the retina)
Prince Edward Island Regulatory reference ACGIH
Saskatchewan OEL STEL [ppm] 250 ppm
Saskatchewan OEL TWA [ppm] 200 ppm
Saskatchewan Regulatory reference The Occupational Health and Safety Regulations,
1996. Chapter O-1.1 Reg 1
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure good ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment

Hand protection:
Protective gloves

Eye protection:
Safety glasses

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment

Personal protective equipment symbol(s):

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Color : Colorless
Odor : characteristic
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available

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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

Relative evaporation rate (ether=1) : No data available

Melting point : Not applicable
Freezing point : No data available
Boiling point : 57 °C
Flash point : -13 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability : Not applicable
Vapor pressure : No data available
Vapor pressure at 50°C : No data available
Relative density : No data available
Density : 1.02 g/cm³
Solubility : No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Explosion limits : No data available

9.2. Other information

As Packaged Regulatory VOC : 113 g/l (0.9 lbs/gal)
As Packaged Actual VOC : 50.8 g/l (0.4 lbs/gal)
Water Content 0 wt%
Exempt Compounds by volume : 55.02 vol %
Exempt Compounds by weight : 50.25 wt%
Volatiles : 55.23 wt%
% EPA HAPS : 0.07 wt%
Percent Solids : 44.78 wt%

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity : Highly flammable liquid and vapor.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reactions : No dangerous reactions known under normal conditions of use.
Conditions to avoid : Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be
produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

n-butyl acetate (123-86-4)

LD50 oral rat 10760 – 12789 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female,
Experimental value, Oral, 14 day(s))
LD50 dermal rabbit > 14112 mg/kg body weight (Equivalent or similar to OECD 402, Rabbit, Male / female,
Experimental value, Dermal, 14 day(s))
LC50 Inhalation - Rat 23.4 mg/l (OECD 403: Acute Inhalation Toxicity, 4 h, Rat, Male / female, Inhalation (mixture of
vapour and aerosol), 14 day(s))
LC50 Inhalation - Rat [ppm] 390 ppm/4h
LC50 Inhalation - Rat (Vapours) > 21 mg/l/4h (4 h, OECD Test Guideline 403, rat, vapours)
ATE CA (oral) 10760 mg/kg body weight
ATE CA (Gases) 390 ppmV/4h
ATE CA (vapors) 23.4 mg/l/4h
ATE CA (dust,mist) 23.4 mg/l/4h
solvent naphtha (petroleum), light aromatic (64742-95-6)
LD50 oral rat > 5000 mg/kg body weight Animal: rat, Guideline: OECD Guideline 401 (Acute Oral Toxicity)
LD50 dermal rabbit > 3160 mg/kg (OECD Test Guideline 402)
LC50 Inhalation - Rat (Vapours) > 6.193 mg/l/4h (4 h, OECD Test Guideline 403, vapours)

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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

hexamethylene diisocyanate oligomers (28182-81-2)

LD50 oral rat > 2500 mg/kg (OECD Test Guideline 423, rat, female)
LD50 dermal rat > 2000 mg/kg (OECD Test Guideline 402, rat, male/female)
LC50 Inhalation - Rat (Dust/Mist) 0.39 mg/l/4h (OECD Test Guideline 403, rat, female, inhalation, dust/mist)
ATE CA (Gases) 4500 ppmV/4h
ATE CA (vapors) 11 mg/l/4h
ATE CA (dust,mist) 0.39 mg/l/4h
methyl acetate (79-20-9)
LD50 oral rat 6482 mg/kg body weight Animal: rat, Animal sex: male, Guideline: OECD Guideline 401
(Acute Oral Toxicity)
LD50 dermal rat > 2000 mg/kg body weight Animal: rat, Guideline: EU Method B.3 (Acute Toxicity (Dermal)),
Guideline: OECD Guideline 402 (Acute Dermal Toxicity)
LC50 Inhalation - Rat 49 mg/l
ATE CA (oral) 6482 mg/kg body weight
ATE CA (vapors) 49 mg/l/4h
ATE CA (dust,mist) 49 mg/l/4h
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : May cause drowsiness or dizziness. May cause respiratory irritation.

n-butyl acetate (123-86-4)

STOT-single exposure May cause drowsiness or dizziness.

solvent naphtha (petroleum), light aromatic (64742-95-6)

STOT-single exposure May cause drowsiness or dizziness. May cause respiratory irritation.

hexamethylene diisocyanate oligomers (28182-81-2)

STOT-single exposure May cause respiratory irritation.

methyl acetate (79-20-9)

STOT-single exposure May cause drowsiness or dizziness.

: Not classified
STOT-repeated exposure

methyl acetate (79-20-9)

LOAEC (inhalation,rat,vapor,90 days) 2000 mg/l
NOAEC (inhalation,rat,vapor,90 days) 1057 mg/m³
Aspiration hazard : Not classified

Symptoms/effects : May cause drowsiness or dizziness.

Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : May cause an allergic skin reaction.
Symptoms/effects after eye contact : Eye irritation.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Hazardous to the aquatic environment, short– : Not classified
term (acute)
Hazardous to the aquatic environment, long– : Not classified
term (chronic)

n-butyl acetate (123-86-4)

LC50 - Fish [1] 18 mg/l Test organisms (species): Pimephales promelas

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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

n-butyl acetate (123-86-4)

LC50 - Fish [2] 62 mg/l (Leuciscus idus, static system)
EC50 - Crustacea [1] 44 mg/l Test organisms (species): Daphnia sp.
ErC50 algae 397 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Read-across, GLP)
NOEC (chronic) 23 mg/l Test organisms (species): Daphnia magna Duration: '21 d'
NOEC chronic crustacea 23 mg/l
Partition coefficient n-octanol/water (Log Pow) 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 25
°C)
Organic Carbon Normalized Adsorption 1.268 – 1.844 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Coefficient (Log Koc)

solvent naphtha (petroleum), light aromatic (64742-95-6)

Partition coefficient n-octanol/water (Log Pow) 2.1 – 6

methyl acetate (79-20-9)

LC50 - Fish [1] 250 – 350 mg/l Test organisms (species): Danio rerio (previous name: Brachydanio rerio)
EC50 - Crustacea [1] 1026.7 mg/l Test organisms (species): Daphnia magna
EC50 72h - Algae [1] > 120 mg/l Test organisms (species): Desmodesmus subspicatus (previous name:
Scenedesmus subspicatus)
BCF - Fish [1] < 1 (Pisces, Literature study)
Partition coefficient n-octanol/water (Log Pow) 0.18 (Experimental value, 20 °C)
Organic Carbon Normalized Adsorption 0.18 (log Koc, OECD 121: Estimation of the Adsorption Coefficient (Koc) on Soil and on
Coefficient (Log Koc) Sewage Sludge using High Performance Liquid Chromatography (HPLC), Experimental value,
GLP)
12.2. Persistence and degradability
n-butyl acetate (123-86-4)
Persistence and degradability Readily biodegradable in water.
ThOD 2.21 g O₂/g substance

solvent naphtha (petroleum), light aromatic (64742-95-6)

Persistence and degradability May cause long-term adverse effects in the environment.
methyl acetate (79-20-9)
Persistence and degradability Readily biodegradable in water.
12.3. Bioaccumulative potential
n-butyl acetate (123-86-4)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
Partition coefficient n-octanol/water (Log Pow) 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 25
°C)
Organic Carbon Normalized Adsorption 1.268 – 1.844 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Coefficient (Log Koc)
solvent naphtha (petroleum), light aromatic (64742-95-6)
Bioaccumulative potential Not established.
Partition coefficient n-octanol/water (Log Pow) 2.1 – 6
methyl acetate (79-20-9)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
BCF - Fish [1] < 1 (Pisces, Literature study)
Partition coefficient n-octanol/water (Log Pow) 0.18 (Experimental value, 20 °C)
Organic Carbon Normalized Adsorption 0.18 (log Koc, OECD 121: Estimation of the Adsorption Coefficient (Koc) on Soil and on
Coefficient (Log Koc) Sewage Sludge using High Performance Liquid Chromatography (HPLC), Experimental value,
GLP)
12.4. Mobility in soil
n-butyl acetate (123-86-4)
Surface tension 61.3 mN/m (20 °C, 0.1 %, OECD 115: Surface Tension of Aqueous Solutions)
Ecology - soil Highly mobile in soil. Not toxic to plants.
Organic Carbon Normalized Adsorption 1.268 – 1.844 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Coefficient (Log Koc)
Partition coefficient n-octanol/water (Log Pow) 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 25
°C)
solvent naphtha (petroleum), light aromatic (64742-95-6)
Partition coefficient n-octanol/water (Log Pow) 2.1 – 6

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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

methyl acetate (79-20-9)

Surface tension 24 mN/m (20 °C)
Ecology - soil Highly mobile in soil.
Organic Carbon Normalized Adsorption 0.18 (log Koc, OECD 121: Estimation of the Adsorption Coefficient (Koc) on Soil and on
Coefficient (Log Koc) Sewage Sludge using High Performance Liquid Chromatography (HPLC), Experimental value,
GLP)
Partition coefficient n-octanol/water (Log Pow) 0.18 (Experimental value, 20 °C)

12.5. Other adverse effects

Ozone : Not classified

SECTION 13: Disposal considerations

13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Additional information : Flammable vapors may accumulate in the container.

SECTION 14: Transport information

14.1. Basic shipping description
In accordance with TDG
Transportation of Dangerous Goods
UN-No. (TDG) : UN1263
Packing group (TDG) : II - Medium Danger
TDG Primary Hazard Classes : 3 - Class 3 - Flammable Liquids
Transport document description (TDG) : UN1263 PAINT RELATED MATERIAL, 3, II
Proper Shipping Name (TDG) : PAINT RELATED MATERIAL

Hazard labels (TDG) : 3 - Flammable Liquids

TDG Special Provisions : 59 - Substances that are listed by name in Schedule 1 must not be transported under this
shipping name. Substances transported under this shipping name may contain not more than
20% nitrocellulose if the nitrocellulose contains not more than 12.6% nitrogen (by dry mass).
142 - The following shipping names may be used to meet the requirements of Part 3
(Documentation) and Part 4 (Dangerous Goods Safety Marks) when these dangerous goods
are offered for transport in the same means of containment:
(a) “PAINT RELATED MATERIAL” may be used for a means of containment containing both
paint and paint related material;
(b) “PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE” may be used for a means of
containment containing both paint, corrosive, flammable, and paint related material, corrosive,
flammable;
(c) “PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE” may be used for a means of
containment containing both paint, flammable, corrosive, and paint related material, flammable,
corrosive; and
(d) “PRINTING INK RELATED MATERIAL” may be used for a means of containment
containing both printing ink and printing ink related material.
Explosive Limit and Limited Quantity Index : 5L
Excepted quantities (TDG) : E2
Passenger Carrying Road Vehicle or Passenger : 5 L
Carrying Railway Vehicle Index

14.2. Transport information/DOT

Department of Transport
DOT NA No : UN1263
UN-No.(DOT) : 1263
Packing group (DOT) : II - Medium Danger
Transport document description (DOT) : UN1263 Paint related material, 3, II
Proper Shipping Name (DOT) : Paint related material
Contains Statement Field Selection (DOT) :

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Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120

Division (DOT) : 3
Hazard labels (DOT) : 3 - Flammable liquid

Marine pollutant : NO
Dangerous for the environment : No
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to
5 L (1.3 gallons).
367 - For the purposes of documentation and package marking: a. The proper shipping name
“Paint related material” may be used for consignments of packages containing “Paint” and
“Paint related material” in the same package; b. The proper shipping name “Paint related
material, corrosive, flammable” may be used for consignments of packages containing “Paint,
corrosive, flammable” and “Paint related material, corrosive, flammable” in the same package;
c. The proper shipping name “Paint related material, flammable, corrosive” may be used for
consignments of packages containing “Paint, flammable, corrosive” and “Paint related material,
flammable, corrosive” in the same package; and d. The proper shipping name “Printing ink
related material” may be used for consignments of packages containing “Printing ink” and
“Printing ink related material” in the same package.
383 - Packages containing toy plastic or paper caps for toy pistols described as “UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S” or “NA0337, Toy caps, 1.4S” are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in §173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
B131 - When transported by highway, rail, or cargo vessel, waste Paint and Paint related
material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than
26.5 L (7 gallons), are excepted from the marking requirements in §172.301(a) and (c) and the
labeling requirements in §172.400(a), when further packed in the following specification and
non-specification bulk outer packagings and under the following conditions:

a. Primary receptacles must conform to the general packaging requirements of subpart B of

part 173 of this subchapter and may not leak. If they do leak, they must be overpacked in
packagings conforming to the specification requirements of part 178 of this subchapter or in
salvage packagings conforming to the requirements in §173.12 of this subchapter.

b. Primary receptacles must be further packed in non-specification bulk outer packagings such
as cubic yard boxes, plastic rigid-wall bulk containers, dump trailers, and roll-off containers.
Bulk outer packagings must be liquid tight through design or by the use of lining materials.

c. Primary receptacles may also be further packed in specification bulk outer packagings.
Authorized specification bulk outer packagings are UN11G fiberboard intermediate bulk
containers (IBC) and UN13H4 woven plastic, coated and with liner flexible intermediate bulk
containers (FIBCs) meeting the Packing Group II performance level and lined with a plastic
liner of at least 6 mil thickness.

d. All inner packagings placed inside bulk outer packagings must be blocked and braced to
prevent movement during transportation that could cause the container to open or fall over.
Specification IBCs and FIBCs are to be secured to a pallet.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used
provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous
material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the
MAWP.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail : 5L
(49 CFR 173.27)

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Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

DOT Quantity Limitations Cargo aircraft only (49 : 60 L

CFR 175.75)
DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 128

Other information : No supplementary information available.

14.3. Air and sea transport

IMDG
UN-No. (IMDG) : 1263
Proper Shipping Name (IMDG) : PAINT RELATED MATERIAL
Transport document description (IMDG) : UN 1263 PAINT RELATED MATERIAL, 3, II
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger

IATA
UN-No. (IATA) : 1263
Proper Shipping Name (IATA) : Paint
Transport document description (IATA) : UN 1263 Paint, 3, II
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger

SECTION 15: Regulatory information

15.1. National regulations
n-butyl acetate (123-86-4)
Listed on the Canadian DSL (Domestic Substances List)
solvent naphtha (petroleum), light aromatic (64742-95-6)
Listed on the Canadian DSL (Domestic Substances List)
hexamethylene diisocyanate oligomers (28182-81-2)
Listed on the Canadian DSL (Domestic Substances List)
methyl acetate (79-20-9)
Listed on the Canadian DSL (Domestic Substances List)

15.2. International regulations

n-butyl acetate (123-86-4)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
solvent naphtha (petroleum), light aromatic (64742-95-6)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
hexamethylene diisocyanate oligomers (28182-81-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl acetate (79-20-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory

SECTION 16: Other information

Issue date : 08-26-2021
Revision date : 05-03-2023
Supersedes : 08-26-2021

Full text of H-phrases:

------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H317 May cause an allergic skin reaction
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H335 May cause respiratory irritation

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RAPTOR HARDENER
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

------ H336 May cause drowsiness or dizziness

------ H411 Toxic to aquatic life with long lasting effects

SDS Canada U-POL

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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