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CLM-8589-1.2_SDS+-+CLM-8589-S (1)

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AMMELIDE (RING-13C3, 99%) 100 UG/ML IN

WATER/DIETHYLAMINE (80/20, V/V)


Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 /
Rules and Regulations
Date of issue: 14/04/2015 Revision date: : Version: 1.0

CLM-8589-S

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Product form : Mixtures
Product name. : AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)
Product code : CLM-8589-S
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : For professional use only.

1.2.2. Uses advised against


No additional information available
1.3. Details of the supplier of the safety data sheet
Cambridge Isotope Laboratories, Inc.
50 Frontage Road
Andover, MA 01810
USA
USA: 1-800-322-1174 Int: 1-978-749-8000
cilsales@isotope.com www.isotope.com
Emergency telephone number
Emergency numbers:
Chemtrec: 1-800-424-9300 (24 hours)
International: 1-703-741-5970 (24 hours)

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin Irrit. 2 H315
Eye Dam. 1 H318
Resp. Sens. 1 H334
Skin Sens. 1 H317
Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC or 1999/45/EC


F; R11
Xn; R21/22
R42
Xi; R41
R43
R52/53
Full text of R-phrases: see section 16

Classification (GHS-US)
Flam. Liq. Not classified
Acute Tox. Not classified (Oral)
Acute Tox. Not classified (Dermal)
Skin Irrit. 2 H315
Eye Dam. 1 H318
Resp. Sens. 1 H334
Skin Sens. 1 H317
Aquatic Acute 3 H402

Adverse physicochemical, human health and environmental effects


No additional information available

29/09/2015 EN (English US) 1/10


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

2.2. Label elements


Labeling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS08 GHS05
Signal word (CLP) : Danger
Hazardous ingredients : DIETHYLAMINE UNLABELED
Hazard statements (CLP) : H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
Precautionary statements (CLP) : P261 - Avoid breathing fume, mist, spray, vapors
P264 - Wash both hands thoroughly after handling
P272 - Contaminated work clothing should not be allowed out of the workplace
P280 - Wear eye protection, face protection, protective gloves, protective clothing
P284 - Wear respiratory protection
P302+P352 - IF ON SKIN: Wash with plenty of water/…
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing

GHS-US labeling

Hazard pictograms (GHS-US) :

GHS08 GHS05
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H402 - Harmful to aquatic life
Precautionary statements (GHS-US) : P261 - Avoid breathing fume, mist, spray, vapors
P264 - Wash Both hands thoroughly after handling
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P280 - Wear eye protection, face protection, protective clothing, protective gloves
P284 - Wear respiratory protection
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
P321 - Specific treatment (see Hazard pictograms (CLP) on this label)
P332+P313 - If skin irritation occurs: Get medical advice/attention
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention
P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
P362 - Take off contaminated clothing and wash before reuse
P362+P364 - Take off contaminated clothing and wash it before reuse
P501 - Dispose of contents/container to Comply with applicable regulations.

2.3. Other hazards


No additional information available

SECTION 3: Composition/information on ingredients


3.1. Substances
Not applicable

29/09/2015 EN (English US) 2/10


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

3.2. Mixtures
Name Product identifier % Classification according to
Directive 67/548/EEC
WATER UNLABELED (CAS No) 7732-18-5 (Unlabeled) 84.99297 Not classified
(EC no) 231-791-2
DIETHYLAMINE UNLABELED (CAS No) 109-89-7 15.00692 Xn; R20/21/22
(EC no) 203-716-3 T; R24
Xi; R38
Xi; R41
R42
R43
F; R11
R52

AMMELIDE (RING-13C3, 99%) (CAS No) 645-93-2 (Unlabeled) 0.00011 Xn; R22
Xi; R36

Name Product identifier % Classification according to


Regulation (EC) No.
1272/2008 [CLP]
WATER UNLABELED (CAS No) 7732-18-5 (Unlabeled) 84.99297 Not classified
(EC no) 231-791-2
DIETHYLAMINE UNLABELED (CAS No) 109-89-7 15.00692 Flam. Liq. 2, H225
(EC no) 203-716-3 Acute Tox. 4 (Oral), H302
Acute Tox. 3 (Dermal), H311
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:dust,mist),
H332
Skin Irrit. 2, H315
Eye Dam. 1, H318
Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
AMMELIDE (RING-13C3, 99%) (CAS No) 645-93-2 (Unlabeled) 0.00011 Acute Tox. 4 (Oral), H302
Eye Irrit. 2, H319

Name Product identifier % Classification (GHS-US)


DIETHYLAMINE UNLABELED (CAS No) 109-89-7 15.00692 Flam. Liq. 2, H225
Acute Tox. 4 (Oral), H302
Acute Tox. 4 (Dermal), H312
Acute Tox. 4 (Inhalation), H332
Skin Irrit. 2, H315
Eye Dam. 1, H318
Resp. Sens. 1, H334
Skin Sens. 1, H317
Aquatic Acute 3, H402

Full text of R-, H- and EUH-phrases: see section 16

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures general : Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of
dangerous area.
First-aid measures after inhalation : If breathed in, move person to fresh air. If not breathing, give artificial respiration. Consult a
physician.
First-aid measures after skin contact : Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
First-aid measures after eye contact : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue
rinsing eyes during transport to hospital.
First-aid measures after ingestion : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth
with water. Consult a physician.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous
membranes and upper respiratory tract.
Symptoms/injuries after skin contact : Toxic if absorbed through the skin. Causes skin burns.
Symptoms/injuries after eye contact : Causes eye burns. Causes severe eye burns.
Symptoms/injuries after ingestion : Harmful if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

29/09/2015 EN (English US) 3/10


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 5: Firefighting measures


5.1. Extinguishing media
suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No
smoking.

6.1.1. For non-emergency personnel


Emergency procedures : Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas.
Ensure adequate ventilation. Avoid breathing dust.

6.1.2. For emergency responders


No additional information available
6.2. Environmental precautions
Do not let product enter drains.
6.3. Methods and material for containment and cleaning up
For containment : Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable,
closed containers for disposal.
6.4. Reference to other sections
No additional information available

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : No naked lights. No smoking. Use only non-sparking tools.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash hands before
breaks and at the end of workday.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment.
Storage conditions : Store at room temperature away from light and moisture.
Incompatible materials : Heat sources.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)
Italy - Portugal - USA ACGIH ACGIH TWA (ppm) 5.0000000000 ppm Eye & Upper Respiratory Tract
irritation. Not classifiable as a human carcinogen
Italy - Portugal - USA ACGIH ACGIH STEL (ppm) 15.0000000000 ppm Eye & Upper Respiratory Tract
irritation. Not classifiable as a human carcinogen

DIETHYLAMINE UNLABELED (109-89-7)


Italy - Portugal - USA ACGIH ACGIH TWA (ppm) 5.0000000000 ppm Eye & Upper Respiratory Tract
irritation. Not classifiable as a human carcinogen
Italy - Portugal - USA ACGIH ACGIH STEL (ppm) 15.0000000000 ppm Eye & Upper Respiratory Tract
irritation. Not classifiable as a human carcinogen
USA OSHA OSHA PEL (TWA) (ppm) 10.0000000000 ppm USA. OSHA - Table Z-1 Limits
for Air Contaminants - 1910.1000
USA OSHA OSHA PEL (STEL) (ppm) 25.0000000000 ppm USA. OSHA - Table Z-1 Limits
for Air Contaminants - 1910.1000

29/09/2015 EN (English US) 4/10


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

8.2. Exposure controls


Personal protective equipment : Safety glasses. Gloves. Respiratory protection of the dependent type. Protective clothing.

Hand protection : protective gloves.


Eye protection : Wear safety glasses with side shields (or goggles) and a face shield.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of inadequate ventilation wear respiratory protection.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear, colorless liquid.
Color : No data available
Odor : No data available
Odor threshold : No data available
pH : 9 - 10
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Self ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Highly flammable liquid and vapor
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity


10.1. Reactivity
No additional information available
10.2. Chemical stability
See storage and expiration date on CoA.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Open flame. Direct sunlight.
10.5. Incompatible materials
Aldehydes, Alcohols, Dicyanofurazan, Ketones, Phenols, Acids, Halogenated.
10.6. Hazardous decomposition products
Formed under fire conditions: Carbon oxides, nitrogen oxides (NOx). hydrocarbon, Oxidizing agents, Epoxides.

29/09/2015 EN (English US) 5/10


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Acute toxicity : Not classified. Not classified.
AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)
LD50 oral rat 540 mg/kg
LD50 dermal rabbit 577 mg/kg
LC50 inhalation rat (ppm) 4000 ppm - 4h
ATE (oral) 540.000 mg/kg body weight
ATE (dermal) 577.000 mg/kg body weight

DIETHYLAMINE UNLABELED (109-89-7)


LD50 oral rat 540 mg/kg
LD50 dermal rabbit 577 mg/kg
LC50 inhalation rat (ppm) 4000 ppm - 4h
ATE (oral) 540.000 mg/kg body weight
ATE (dermal) 577.000 mg/kg body weight
ATE (dust, mist) 1.500 mg/l/4h

WATER UNLABELED (7732-18-5 (Unlabeled))


LD50 oral rat > 90000 mg/kg

AMMELIDE (RING-13C3, 99%) (645-93-2 (Unlabeled))


ATE (oral) 500.000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Not available
pH: 9 - 10
Serious eye damage/irritation : Causes serious eye damage.
Not available
pH: 9 - 10
Respiratory or skin sensitization : Not available
Not available
Germ cell mutagenicity : Not available
Carcinogenicity : This product is or contains a component that is not classifiable as to its carcinogenicity on its
IARC, ACGIH, NTP, or EPA classification.
Reproductive toxicity : Not available
Specific target organ toxicity (single exposure) : Not classified
Not available
Specific target organ toxicity (repeated : Not classified
exposure) Not available
Aspiration hazard : Not classified
Potential Adverse human health effects and : To the best of our knowledge, the chemical, physical, and toxicological properties have not been
symptoms thoroughly investigated.
Symptoms/injuries after inhalation : May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous
membranes and upper respiratory tract.
Symptoms/injuries after skin contact : Toxic if absorbed through the skin. Causes skin burns.
Symptoms/injuries after eye contact : Causes eye burns. Causes severe eye burns.
Symptoms/injuries after ingestion : Harmful if swallowed.

SECTION 12: Ecological information


12.1. Toxicity
AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)
LC50 fish 1 25 - 198 mg/l Orcorhynchus mykiss (Rainbow trout) - 96h
EC50 Daphnia 1 56 mg/l Daphnia manga (Water flea) - 48h
ErC50 (algae) 20 mg/l 96h

DIETHYLAMINE UNLABELED (109-89-7)


LC50 fish 1 25 - 198 mg/l Orcorhynchus mykiss (Rainbow trout) - 96h
EC50 Daphnia 1 56 mg/l Daphnia manga (Water flea) - 48h
29/09/2015 EN (English US) 6/10
AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

DIETHYLAMINE UNLABELED (109-89-7)


ErC50 (algae) 20 mg/l 96h

12.2. Persistence and degradability


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)
Persistence and degradability Not available.

WATER UNLABELED (7732-18-5 (Unlabeled))


Persistence and degradability Not available.

AMMELIDE (RING-13C3, 99%) (645-93-2 (Unlabeled))


Persistence and degradability Not available.

12.3. Bioaccumulative potential


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)
Bioaccumulative potential Not available.

DIETHYLAMINE UNLABELED (109-89-7)


Log Pow 0.58
Bioaccumulative potential Not available.

WATER UNLABELED (7732-18-5 (Unlabeled))


Log Pow No data available
Bioaccumulative potential Not available.

AMMELIDE (RING-13C3, 99%) (645-93-2 (Unlabeled))


Bioaccumulative potential Not available.

12.4. Mobility in soil


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)
Ecology - soil Not available.

DIETHYLAMINE UNLABELED (109-89-7)


Ecology - soil Not available.

WATER UNLABELED (7732-18-5 (Unlabeled))


Ecology - soil Not available.

AMMELIDE (RING-13C3, 99%) (645-93-2 (Unlabeled))


Ecology - soil Not available.

12.5. Results of PBT and vPvB assessment


No additional information available
12.6. Other adverse effects
Other adverse effects : Not available.

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Regional legislation (waste) : Waste materials should be disposed of under conditions which meet Federal, State, and Local
environmental control regulations.
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Additional information : Handle empty containers with care because residual vapors are flammable.

SECTION 14: Transport information


In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA
14.1. UN number
UN-No.(DOT) : 3266
DOT NA no. UN3266

14.2. UN proper shipping name


DOT Proper Shipping Name : Corrosive liquid, basic, inorganic, n.o.s.
Department of Transportation (DOT) Hazard : 8 - Class 8 - Corrosive material 49 CFR 173.136
Classes

29/09/2015 EN (English US) 7/10


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Hazard labels (DOT) : 8 - Corrosive

DOT Symbols : G - Identifies PSN requiring a technical name


Packing group (DOT) : II - Medium Danger
DOT Special Provisions (49 CFR 172.102) : B2 - MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are
not authorized.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T11 - 6 178.274(d)(2) Normal............. 178.275(d)(3)
TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the
following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the
temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of cubical
expansion of the liquid between the mean temperature of the liquid during filling (tf) and the
maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For
liquids transported under ambient conditions may be calculated using the formula: (image)
Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59
F) and 50 C (122 F), respectively.
TP27 - A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided
the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as
defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP.
DOT Packaging Exceptions (49 CFR 173.xxx) : 154
DOT Packaging Non Bulk (49 CFR 173.xxx) : 202
DOT Packaging Bulk (49 CFR 173.xxx) : 242

14.3. Additional information


Other information : No supplementary information available.

Overland transport
Packing group (ADR) : II
Class (ADR) : 8 - Corrosive substances
Hazard identification number (Kemler No.) : 80
Classification code (ADR) : C5
Danger labels (ADR) : 8 - Corrosive substances

Orange plates :

Tunnel restriction code : E


Limited quantities (ADR) 1L
EAC : 2X
APP : B
Excepted quantities (ADR) : E2

Transport by sea
DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
DOT Vessel Stowage Other : 40 - Stow ‘‘clear of living quarters’’,52 - Stow ‘‘separated from’’ acids
MFAG-No : 154

29/09/2015 EN (English US) 8/10


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Air transport
DOT Quantity Limitations Passenger aircraft/rail : 1L
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 30 L
CFR 175.75)
Civil Aeronautics Law : Corrosive substances

14.4. Environmental hazards


Other information : No supplementary information available.
14.5. Special precautions for user
14.6. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information


15.1. US Federal regulations
AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)
SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard
Immediate (acute) health hazard

DIETHYLAMINE UNLABELED (109-89-7)


SARA Section 311/312 Hazard Classes Fire hazard
Immediate (acute) health hazard

15.2. International regulations


CANADA
No additional information available

15.2.1. National regulations


No additional information available

15.3. US State regulations


AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE (80/20, V/V)()
State or local regulations U.S. - Massachusetts - Right To Know List
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - New Jersey - Right to Know Hazardous Substance List
This product does not contain any chemicals known to the State of California to cause
cancer, birth defects, or any other reproductive harm.

DIETHYLAMINE UNLABELED (109-89-7)

U.S. - Massachusetts - Right To Know List


U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - New Jersey - Right to Know Hazardous Substance List
This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm.

SECTION 16: Other information


Other information : This product is not radioactive. The data given for this product are those of the corresponding
unlabeled compound, unless specifically indicated otherwise. Health and safety data for labeled
compounds are generally not available, but are assumed to be similar or identical to the
corresponding unlabeled compound.
Full text of R-, H- and EUH-phrases::
Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3
Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
29/09/2015 EN (English US) 9/10
AMMELIDE (RING-13C3, 99%) 100 UG/ML IN WATER/DIETHYLAMINE
(80/20, V/V) CLM-8589-S
Safety Data Sheet
according to Regulation (EC) No. 453/2010 and according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Eye Dam. 1 Serious eye damage/eye irritation Category 1


Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Flam. Liq. 2 Flammable liquids Category 2
Resp. Sens. 1 Respiratory sensitisation Category 1
Skin Irrit. 2 skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization Category 1
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H225 Highly flammable liquid and vapor
H302 Harmful if swallowed
H311 Toxic in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H319 Causes serious eye irritation
H332 Harmful if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
R11 Highly flammable
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R21/22 Harmful in contact with skin and if swallowed
R22 Harmful if swallowed
R24 Toxic in contact with skin
R36 Irritating to eyes
R38 Irritating to skin
R41 Risk of serious damage to eyes
R42 May cause sensitization by inhalation
R43 May cause sensitization by skin contact
R52 Harmful to aquatic organisms
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
F Highly flammable
T Toxic
Xi Irritant
Xn Harmful

NFPA health hazard : 1 - Exposure could cause irritation but only minor residual
injury even if no treatment is given.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.

HMIS III Rating


Health : 1 Slight Hazard - Irritation or minor reversible injury possible
Flammability : 0 Minimal Hazard
Physical : 0 Minimal Hazard

CIL Multi-Solvent Mixture SDS

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

29/09/2015 EN (English US) 10/10

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