SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Trade name or designation Hylomar / Hylosil 302; Hylomar / Hylosil 303; Hylomar / Hylosil Instant Gasket
of the mixture
Registration number -
Synonyms None.
SDS number 20
Issue date 20-March-2017
Version number 01
Revision date -
Supersedes date -
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Silicone sealant.
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
Manufacturer: Hylomar Ltd.
Address: Hylo House, Cale Lane, New Springs,
Wigan, Greater Manchester,
UK, WN2 1JT
Telephone number: +44(0)1942 617000
E-mail address: info@hylomar.co.uk
Contact person: Technical Department
1.4. Emergency telephone +1-760-476-3961 (US)
number
Access code: 333544

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification
applies.
Classification according to Regulation (EC) No 1272/2008 as amended
Health hazards
Skin corrosion/irritation Category 2 H315 - Causes skin irritation.
Serious eye damage/eye irritation Category 1 H318 - Causes serious eye
damage.
Hazard summary Causes serious eye damage. Causes skin irritation. Occupational exposure to the substance or
mixture may cause adverse health effects.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Contains: Triacetoxyethylsilane
Hazard pictograms

Signal word Danger

Hazard statements
H315 Causes skin irritation.
H318 Causes serious eye damage.
Precautionary statements
Prevention
P264 Wash thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

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 Response
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTRE/doctor.
P302 + P352 IF ON SKIN: Wash with plenty of water.
Storage Store away from incompatible materials.
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Supplemental label information None.
2.3. Other hazards Not a PBT or vPvB substance or mixture.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
General information
Chemical name % CAS-No. / EC No. REACH Registration No. INDEX No. Notes
Polyalkyl siloxane 20 - 30 63148-62-9 - -
-
Classification: Eye Irrit. 2;H319
Triacetoxyethylsilane 3 -< 5 17689-77-9 - -
241-677-4
Classification: Met. Corr. 1;H290, Skin Corr. 1B;H314, Eye Dam. 1;H318

Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume. The full text for all H-statements is displayed in section 16.

SECTION 4: First aid measures

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
4.1. Description of first aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get
medical advice/attention. Wash contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
4.2. Most important symptoms Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
and effects, both acute and vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness
delayed and pain.
4.3. Indication of any Provide general supportive measures and treat symptomatically. Keep victim under observation.
immediate medical attention
and special treatment needed

SECTION 5: Firefighting measures

General fire hazards No unusual fire or explosion hazards noted.
5.1. Extinguishing media
Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.
media
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising During fire, gases hazardous to health may be formed.
from the substance or mixture
5.3. Advice for firefighters
Special protective Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
equipment for firefighters
Special fire fighting Move containers from fire area if you can do so without risk.
procedures
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Avoid contact with skin and eyes. Avoid inhalation of vapours. Do not touch damaged containers
personnel or spilled material unless wearing appropriate protective clothing.

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 For emergency responders Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
clean-up.
6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not discharge into drains, water courses or
onto the ground.
6.3. Methods and material for Ventilate the area.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb spill with vermiculite or other inert material, then place in a container for chemical
waste for proper disposal. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills in original containers for re-use.

6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe Do not breathe vapour. Do not get this material in contact with eyes. Avoid contact with skin and
handling clothing. Provide adequate ventilation. Wear appropriate personal protective equipment.
7.2. Conditions for safe Store in original tightly closed container. Store away from incompatible materials (see section 10 of
storage, including any the SDS).
incompatibilities
7.3. Specific end use(s) Silicone sealant.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits
UK. EH40 Workplace Exposure Limits (WELs)

Components Type Value Form

Carbon black (CAS STEL 7 mg/m3
1333-86-4)
TWA 3.5 mg/m3
Silicon dioxide, crystalline TWA 6 mg/m3 Inhalable dust.
silica-free (CAS 7631-86-9)
2.4 mg/m3 Respirable dust.
Titanium dioxide (CAS TWA 4 mg/m3 Respirable.
13463-67-7)
10 mg/m3 Inhalable
Decomposition Type Value
Methanol (CAS 67-56-1) STEL 333 mg/m3
250 ppm
TWA 266 mg/m3
200 ppm
EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU

Decomposition Type Value

Acetic acid (CAS 64-19-7) TWA 25 mg/m3
10 ppm
Methanol (CAS 67-56-1) TWA 260 mg/m3
200 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Follow standard monitoring procedures.
procedures
Derived no effect levels Not available.
(DNELs)
Predicted no effect Not available.
concentrations (PNECs)
Exposure guidelines
UK EH40 WEL: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
8.2. Exposure controls

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Appropriate engineering Provide adequate ventilation. Observe occupational exposure limits and minimise the risk of
controls exposure. Provide easy access to water supply and eye wash facilities.
Individual protection measures, such as personal protective equipment
General information Personal protective equipment should be chosen according to the CEN standards and in
discussion with the supplier of the personal protective equipment.
Eye/face protection Wear approved safety glasses or goggles.
Skin protection
- Hand protection Wear protective gloves. Nitrile or neoprene gloves are recommended. Suitable gloves can be
recommended by the glove supplier.
- Other Normal work clothing (long sleeved shirts and long pants) is recommended.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Use respiratory equipment with
combination filter, type A2/P2.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
Hygiene measures Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
Environmental exposure Environmental manager must be informed of all major releases.
controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Physical state Liquid.
Form Paste. Thixotropic gel.
Colour 302: Black.
303, Instant Gasket: Translucent.
Odour Vinegar-like.
Odour threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point > 100.0 °C (> 212.0 °F) Closed cup
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Vapour pressure Not available.
Vapour density Not available.
Relative density 1.02 (25 °C) ( Water = 1)
Solubility(ies) Insoluble in water.
Partition coefficient
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not relevant.
Explosive properties Not explosive.
Oxidising properties Not oxidising.
9.2. Other information No relevant additional information available.

SECTION 10: Stability and reactivity

10.1. Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability Material is stable under normal conditions.

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10.3. Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
10.4. Conditions to avoid Contact with incompatible materials.
10.5. Incompatible materials Strong oxidising agents. Fluorine. Chlorine. Fluorides.
10.6. Hazardous Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or
decomposition products vapours.

SECTION 11: Toxicological information

General information Occupational exposure to the substance or mixture may cause adverse effects.
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye damage.
Ingestion May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of
occupational exposure.
Symptoms Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision. Permanent eye damage including blindness could result. Skin irritation. May cause
redness and pain.
11.1. Information on toxicological effects

Acute toxicity Not expected to be acutely toxic.

Components Species Test results
Polyalkyl siloxane (CAS 63148-62-9)
Acute
Dermal
LD50 Rabbit > 5000 mg/kg
Oral
LD50 Rat > 17000 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory sensitisation Based on available data, the classification criteria are not met.
Skin sensitisation Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
Specific target organ toxicity - Based on available data, the classification criteria are not met.
single exposure
Specific target organ toxicity - Based on available data, the classification criteria are not met.
repeated exposure
Aspiration hazard Due to the physical form of the product it is not expected to be an aspiration hazard.
Mixture versus substance No information available.
information
Other information No other specific acute or chronic health impact noted.

SECTION 12: Ecological information

12.1. Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
12.2. Persistence and No data is available on the degradability of this product.
degradability
12.3. Bioaccumulative potential
Partition coefficient
n-octanol/water (log Kow)
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil The product is insoluble in water. Expected to have low mobility in soil.
12.5. Results of PBT Not a PBT or vPvB substance or mixture.
and vPvB
assessment

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12.6. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Residual waste Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
EU waste code 08 04 09*
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Disposal methods/information Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Special precautions Dispose in accordance with all applicable regulations.

SECTION 14: Transport information

ADR
14.1. - 14.6.: Not regulated as dangerous goods.
RID
14.1. - 14.6.: Not regulated as dangerous goods.
ADN
14.1. - 14.6.: Not regulated as dangerous goods.
IATA
14.1. - 14.6.: Not regulated as dangerous goods.
IMDG
14.1. - 14.6.: Not regulated as dangerous goods.
14.7. Transport in bulk Not applicable.
according to Annex II of Marpol
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed.
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at
work, as amended.
Not listed.

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Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Not listed.
Other regulations The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP
Regulation) as amended and respective national laws implementing EC directives.
National regulations Follow national regulation for work with chemical agents.
15.2. Chemical safety No Chemical Safety Assessment has been carried out.
assessment

SECTION 16: Other information

List of abbreviations
PBT: Persistent, bioaccumulative and toxic.
vPvB: Very Persistent and very Bioaccumulative.
TWA: Time weighted average.
References HSDB® - Hazardous Substances Data Bank
Registry of Toxic Effects of Chemical Substances (RTECS)
ESIS (European chemical Substances Information System)
Information on evaluation The mixture is classified based on test data for physical hazards. The classification for health and
method leading to the environmental hazards is derived by a combination of calculation methods and test data, if
classification of mixture available. For details, refer to Sections 9, 11 and 12.
Full text of any H-statements
not written out in full under
Sections 2 to 15 H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
Training information Follow training instructions when handling this material.
Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available.

Hylomar / Hylosil 302; Hylomar / Hylosil 303; Hylomar / Hylosil Instant Gasket SDS UK
908581 Version #: 01 Revision date: - Issue date: 20-March-2017 7/7