SAFETY DATA SHEET

According to OSHA Hazard Communication Standard, 29 CFR

1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

SECTION 1. IDENTIFICATION

Product name : BC Styrene Monomer

Product code : Q9275

CAS-No. : 100-42-5
Other means of identification : Phenyl ethene, Phenyl ethylene, Vinyl benzene

Manufacturer or supplier's details

Company : Shell Chemical LP
PO Box 576
HOUSTON TX 77001
USA
SDS Request : 1-800-240-6737

Customer Service : 1-855-697-4355

Emergency telephone number

Chemtrec Domestic (24 hr) : 1-800-424-9300

Chemtrec International (24 : 1-703-527-3887

hr)

Recommended use of the chemical and restrictions on use

Recommended use : Base chemical for the production of polystyrene, rubbers and
resins.

Restrictions on use : Restricted to professional users., This product must not be

used in applications other than the above without first seeking
the advice of the supplier.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Flammable liquids : Category 3

Aspiration hazard : Category 1

Skin irritation : Category 2

Eye irritation : Category 2A

Acute toxicity (Inhalation) : Category 4

1 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Specific target organ toxicity : Category 3 (Respiratory Tract)

- single exposure

Specific target organ toxicity : Category 1 (Auditory system)

- repeated exposure

Long-term (chronic) aquatic : Category 3

hazard

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : PHYSICAL HAZARDS:

H226 Flammable liquid and vapour.
HEALTH HAZARDS:
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H372 Causes damage to organs (Auditory system) through pro-
longed or repeated exposure if inhaled.
ENVIRONMENTAL HAZARDS:
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equip-
ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
P273 Avoid release to the environment.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P370 + P378 In case of fire: Use appropriate media to extin-
guish.
P301 + P310 IF SWALLOWED: Immediately call a POISON

2 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

CENTER/ doctor.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice/ atten-
tion.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P312 Call a POISON CENTER/ doctor if you feel unwell.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P235 Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards which do not result in classification

Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition
sources causing a flashback fire danger.
Highly reactive.
Maintain dissolved oxygen and inhibitor at proper levels to prevent runaway polymerisation.
May form flammable/explosive vapour-air mixture.
This material is a static accumulator.
Even with proper grounding and bonding, this material can still accumulate an electrostatic
charge.
If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air-
vapour mixtures can occur.
The classification of this material is based on OSHA HCS 2012 criteria.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Hazardous components
Chemical name Synonyms CAS-No. Concentration (% w/w)
styrene styrene 100-42-5 <= 100

SECTION 4. FIRST-AID MEASURES

General advice : Not expected to be a health hazard when used under normal
conditions.

If inhaled : Call emergency number for your location / facility.

Remove to fresh air. Do not attempt to rescue the victim un-
less proper respiratory protection is worn. If the victim has

3 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

difficulty breathing or tightness of the chest, is dizzy, vomiting,

or unresponsive, give 100% oxygen with rescue breathing or
Cardio-Pulmonary Resuscitation as required and transport to
the nearest medical facility.

In case of skin contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.

In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses, if present and easy to do. Continue
rinsing.
Transport to the nearest medical facility for additional treat-
ment.

If swallowed : Call emergency number for your location / facility.

If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical facili-
ty: fever greater than 101° F (38.3°C), shortness of breath,
chest congestion or continued coughing or wheezing.

Most important symptoms : Respiratory irritation signs and symptoms may include a tem-
and effects, both acute and porary burning sensation of the nose and throat, coughing,
delayed and/or difficulty breathing.
Skin irritation signs and symptoms may include a burning sen-
sation, redness, swelling, and/or blisters.
Eye irritation signs and symptoms may include a burning sen-
sation, redness, swelling, and/or blurred vision.
If material enters lungs, signs and symptoms may include
coughing, choking, wheezing, difficulty in breathing, chest
congestion, shortness of breath, and/or fever.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical facili-
ty: fever greater than 101° F (38.3°C), shortness of breath,
chest congestion or continued coughing or wheezing.
Defatting dermatitis signs and symptoms may include a burn-
ing sensation and/or a dried/cracked appearance.
Auditory system effects may include temporary hearing loss
and/or ringing in the ears.
Visual system disturbances may be evidenced by decreases
in the ability to discriminate between colours.

Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

Indication of any immediate : IMMEDIATE TREATMENT IS EXTREMELY IMPORTANT!

medical attention and special Call a doctor or poison control center for guidance.
treatment needed Potential for chemical pneumonitis.
Treat symptomatically.

4 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon diox-
ide, sand or earth may be used for small fires only.

Unsuitable extinguishing : Do not use water in a jet.

media

Specific hazards during fire- : Flammable vapours may be present even at temperatures
fighting below the flash point.
Sustained fire attack on vessels may result in a Boiling Liquid
Expanding Vapor Explosion (BLEVE).
The vapour is heavier than air, spreads along the ground and
distant ignition is possible.
Will float and can be reignited on surface water.
Hazardous combustion products may include:
Carbon monoxide.
Formaldehyde

Specific extinguishing meth- : Standard procedure for chemical fires.

ods

Further information : Clear fire area of all non-emergency personnel.

All storage areas should be provided with adequate fire
fighting facilities.
Keep adjacent containers cool by spraying with water.

Special protective equipment : Proper protective equipment including chemical resistant

for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Observe all relevant local and international regulations.
tive equipment and emer- Notify authorities if any exposure to the general public or the
gency procedures environment occurs or is likely to occur.
Local authorities should be advised if significant spillages
cannot be contained.
Isolate hazard area and deny entry to unnecessary or unpro-
tected personnel.
Avoid contact with skin, eyes and clothing.
Be ready for fire or possible exposure.
Do not operate electrical equipment.
Stay upwind and out of low areas.

Environmental precautions : Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area. Use ap-
propriate containment to avoid environmental contamination.
Prevent from spreading or entering drains, ditches or rivers by

5 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

using sand, earth, or other appropriate barriers. Attempt to

disperse the vapour or to direct its flow to a safe location for
example by using fog sprays. Take precautionary measures
against static discharge. Ensure electrical continuity by bond-
ing and grounding (earthing) all equipment.
Monitor area with combustible gas indicator.

Methods and materials for : For small liquid spills (< 1 drum), transfer by mechanical
containment and cleaning up means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain
as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely

Additional advice : For guidance on selection of personal protective equipment

see Section 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Section 13 of
this Safety Data Sheet.

U.S. regulations may require reporting releases of this materi-

al to the environment which exceed the reportable quantity
(refer to Section 15) to the National Response Center at (800)
424-8802.

SECTION 7. HANDLING AND STORAGE

Technical measures : Avoid breathing of or direct contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Section 8 of this Safety Data Sheet.
Use the information in this data sheet as input to a risk as-
sessment of local circumstances to help determine appropri-
ate controls for safe handling, storage and disposal of this
material.
Ensure that all local regulations regarding handling and stor-
age facilities are followed.

Advice on safe handling : Avoid inhaling vapour and/or mists.

Avoid contact with skin, eyes and clothing.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks.
The vapour is heavier than air. Beware of accumulation in pits
and confined spaces.
Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
Bulk storage tanks should be diked (bunded).
Properly dispose of any contaminated rags or cleaning mate-

6 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

rials in order to prevent fires.

Even with proper grounding and bonding, this material can still
accumulate an electrostatic charge.
If sufficient charge is allowed to accumulate, electrostatic dis-
charge and ignition of flammable air-vapour mixtures can oc-
cur.
Be aware of handling operations that may give rise to addi-
tional hazards that result from the accumulation of static
charges.
These include but are not limited to pumping (especially turbu-
lent flow), mixing, filtering, splash filling, cleaning and filling of
tanks and containers, sampling, switch loading, gauging, vac-
uum truck operations, and mechanical movements.
These activities may lead to static discharge e.g. spark for-
mation.
Restrict line velocity during pumping in order to avoid genera-
tion of electrostatic discharge (≤ 1 m/s until fill pipe submerged
to twice its diameter, then ≤ 7 m/s). Avoid splash filling.
Do NOT use compressed air for filling, discharging, or han-
dling operations.
Inhibitor levels should be maintained.
Protect against light.

Avoidance of contact : Strong oxidising agents.

Copper alloys.

Product Transfer : If positive displacement pumps are used, these must be fitted
with a non-integral pressure relief valve. Refer to guidance
under Handling section.

Conditions for safe storage : Refer to section 15 for any additional specific legislation cov-
ering the packaging and storage of this product.

Further information on stor- : Storage Temperature:

age stability 25 °C / 77 °F maximum.

Keep away from aerosols, flammables, oxidizing agents, cor-

rosives and from other flammable products which are not
harmful or toxic to man or to the environment.
Must be stored in a diked (bunded) well- ventilated area, away
from sunlight, ignition sources and other sources of heat.
Must be kept inhibited during storage and shipment as materi-
al can polymerise.
Vapours from tanks should not be released to atmosphere.
Breathing losses during storage should be controlled by a
suitable vapour treatment system.
Electrostatic charges will be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical con-
tinuity by bonding and grounding (earthing) all equipment to
reduce the risk.
The vapours in the head space of the storage vessel may lie
in the flammable/explosive range and hence may be flamma-
ble.

7 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Packaging material : Suitable material: For container paints, use epoxy paint, zinc
silicate paint., For containers, or container linings use mild
steel, stainless steel.
Unsuitable material: Copper., Copper alloys.

Container Advice : Containers, even those that have been emptied, can contain
explosive vapours. Do not cut, drill, grind, weld or perform
similar operations on or near containers.

Specific use(s) : Not applicable

Ensure that all local regulations regarding handling and stor-

age facilities are followed.
See additional references that provide safe handling practices
for liquids that are determined to be static accumulators:
American Petroleum Institute 2003 (Protection Against Igni-
tions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practices
on Static Electricity).
IEC/TS 60079-32-1: Electrostatic hazards, guidance

SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
styrene 100-42-5 TWA 20 ppm Shell Internal
85 mg/m3 Standard
(SIS) for 8-12
hour TWA.
Further information: The value is provided by the Industry Associ-
ation. This value is provided for information only.
styrene TWA 100 ppm OSHA Z-2
styrene CEIL 200 ppm OSHA Z-2
styrene Peak 600 ppm OSHA Z-2
(5 mins. in any 3
hrs.)
styrene TWA 10 ppm ACGIH
styrene STEL 20 ppm ACGIH
Biological occupational exposure limits
Components CAS-No. Control Biological Sam- Permissible Basis
parameters specimen pling concentra-
time tion
styrene 100-42-5 Mandelic Urine End of 400 mg/g ACGIH
acid plus shift (As creatinine BEI
phenylgly- soon as
oxylic acid possible
after

8 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

exposure
ceases)
Styrene Urine End of 40 µg/l ACGIH
shift (As BEI
soon as
possible
after
exposure
ceases)

Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure con-
trols. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and sam-
ples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or con-
tact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Meth-
ods http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substanc-
es http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil

Engineering measures : Use sealed systems as far as possible.

Adequate explosion-proof ventilation to control airborne con-
centrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended.
Firewater monitors and deluge systems are recommended.
Eye washes and showers for emergency use.
Where material is heated, sprayed or mist formed, there is
greater potential for airborne concentrations to be generated.
The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:

General Information:
Consider technical advances and process upgrades (includ-
ing automation) for the elimination of releases. Minimise ex-
posure using measures such as closed systems, dedicated
facilities and suitable general/local exhaust ventilation. Drain
down systems and clear transfer lines prior to breaking con-
tainment. Clean/flush equipment, where possible, prior to
maintenance. Where there is potential for exposure: restrict
access to authorised persons; provide specific activity train-
ing to operators to minimise exposures; wear suitable gloves
and coveralls to prevent skin contamination; wear respiratory
protection when there is potential for inhalation; clear up

9 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

spills immediately and dispose of wastes safely.Ensure safe

systems of work or equivalent arrangements are in place to
manage risks. Regularly inspect, test and maintain all control
measures. Consider the need for risk based health surveil-
lance.

Personal protective equipment

Respiratory protection : If engineering controls do not maintain airborne concentra-
tions to a level which is adequate to protect worker health,
select respiratory protection equipment suitable for the spe-
cific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are unsuitable (e.g. airborne
concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing appa-
ratus.
Where air-filtering respirators are suitable, select an appro-
priate combination of mask and filter.
If air-filtering respirators are suitable for conditions of use:
Select a filter suitable for organic gases and vapours [Type A
boiling point >65°C (149°F)].

Respirator selection, use and maintenance should be in ac-

cordance with the requirements of the OSHA Respiratory
Protection Standard, 29 CFR 1910.134.

Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. Longer term protection: Viton.
Incidental contact/Splash protection: Nitrile rubber.
For continuous contact we recommend gloves with break-
through time of more than 240 minutes with preference for >
480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model. Suitability and du-
rability of a glove is dependent on usage, e.g. frequency and
duration of contact, chemical resistance of glove material,
dexterity. Always seek advice from glove suppliers. Contami-
nated gloves should be replaced. Personal hygiene is a key
element of effective hand care. Gloves must only be worn on
clean hands. After using gloves, hands should be washed
and dried thoroughly. Application of a non-perfumed moistur-
izer is recommended.

10 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Eye protection : Wear goggles for use against liquids and gas.
Wear full face shield if splashes are likely to occur.

Skin and body protection : Wear chemical resistant gloves/gauntlets and boots. Where
risk of splashing, also wear an apron.
Wear antistatic and flame-retardant clothing, if a local risk
assessment deems it so.

Protective measures : Personal protective equipment (PPE) should meet recom-

mended national standards. Check with PPE suppliers.

Hygiene measures : Wash hands before eating, drinking, smoking and using the
toilet.
Launder contaminated clothing before re-use.

Environmental exposure controls

General advice : Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
Minimise release to the environment. An environmental as-
sessment must be made to ensure compliance with local envi-
ronmental legislation.
Information on accidental release measures are to be found in
section 6.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Oily liquid.

Colour : Colourless to yellowish

Odour : Aromatic hydrocarbon

Odour Threshold : 0.1 ppm

pH : Not applicable

Melting / freezing point : -31 °C / -24 °F

Boiling point : 145 °C / 293 °F

Flash point : 32 °C / 90 °F

Method: closed cup

Evaporation rate : 12.4

Method: ASTM D 3539, nBuAc=1

Flammability
Flammability (solid, gas) : Data not available

Lower explosion limit and upper explosion limit / flammability limit

Upper explosion limit / up- : 6.1 %(V)
per flammability limit

11 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Lower explosion limit / : 1.1 %(V)

Lower flammability limit

Vapour pressure : 670 Pa (20 °C / 68 °F)

Relative vapour density : 3.6

Relative density : Data not available

Density : 906 kg/m3 (20 °C / 68 °F)

Method: ASTM D4052

Solubility(ies)
Water solubility : 0.29 kg/m3 (20 °C / 68 °F
)

Solubility in other solvents : Data not available

Partition coefficient: n- : log Pow: 2.96

octanol/water Method: Literature data.

log Pow: 2.96

Method: Literature data.

Auto-ignition temperature : 490 °C / 914 °F

Decomposition temperature : Data not available

Viscosity
Viscosity, dynamic : 0.7 mPa.s (25 °C / 77 °F)

Method: ASTM D445

Viscosity, kinematic : Data not available

Explosive properties : Not applicable

Oxidizing properties : Not applicable

Surface tension : 34 mN/m

Conductivity : Low conductivity: < 100 pS/m, The conductivity of this material
makes it a static accumulator., A liquid is typically considered
nonconductive if its conductivity is below 100 pS/m and is
considered semi-conductive if its conductivity is below 10,000
pS/m., Whether a liquid is nonconductive or semiconductive,
the precautions are the same., A number of factors, for exam-
ple liquid temperature, presence of contaminants, and anti-
static additives can greatly influence the conductivity of a liq-
uid
Molecular weight : 104.15 g/mol

12 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Polymerises with risk of fire and explosion.

Reacts with strong oxidising agents.

Chemical stability : Material is stable when properly inhibited and an appropriate

dissolved oxygen level is maintained (see Storage in Chapter
7).
Polymerises with risk of fire and explosion.
Reacts with strong oxidising agents.

Possibility of hazardous reac- : Normally stable under ambient conditions and if properly in-
tions hibited.

Conditions to avoid : Heat, flames, and sparks.

Exposure to sunlight.
Exposure to air.
In certain circumstances product can ignite due to static elec-
tricity.

Incompatible materials : Strong oxidising agents.

Copper alloys.

Hazardous decomposition : Thermal decomposition is highly dependent on conditions. A

products complex mixture of airborne solids, liquids and gases, includ-
ing carbon monoxide, carbon dioxide and other organic com-
pounds will be evolved when this material undergoes combus-
tion or thermal or oxidative degradation.

SECTION 11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on data on the components and
the toxicology of similar products.
Unless indicated otherwise, the data presented is representa-
tive of the product as a whole, rather than for individual com-
ponent(s).

Information on likely routes of exposure

Inhalation is the primary route of exposure although absorption may occur through skin contact or
following accidental ingestion.
Acute toxicity

Components:
styrene:
Acute oral toxicity : LD 50 (Rat, male and female): > 5,000 mg/kg
Method: Based on weight of evidence.
Remarks: Low toxicity

13 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Acute inhalation toxicity : LC 50 (Rat, Unspecified): 11.8 mg/l, 2770 ppm

Exposure time: 4 h
Test atmosphere: vapour
Method: Based on weight of evidence.
Remarks: Harmful if inhaled.

Acute dermal toxicity : LD 50 (Rat, male and female): > 2,000 mg/kg
Method: OECD Test Guideline 402
Remarks: Based on available data, the classification criteria
are not met.

Skin corrosion/irritation

Components:
styrene:
Species: Rabbit
Method: Based on weight of evidence.
Remarks: Causes skin irritation.

Serious eye damage/eye irritation

Components:
styrene:
Species: Rabbit
Method: Based on weight of evidence.
Remarks: Causes serious eye irritation.

Respiratory or skin sensitisation

Components:
styrene:
Species: Humans
Method: Based on Human Evidence
Remarks: Based on available data, the classification criteria are not met.

Germ cell mutagenicity

Components:
styrene:
Genotoxicity in vitro : Method: Based on weight of evidence.
Remarks: Based on available data, the classification criteria
are not met.

Genotoxicity in vivo : Method: Based on weight of evidence.

Remarks: Based on available data, the classification criteria
are not met.

Germ cell mutagenicity- As- : This product does not meet the criteria for classification in
sessment categories 1A/1B.

Carcinogenicity

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SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Components:
styrene:
Species: Humans
Application Route: Occupational exposure
Method: Based on weight of evidence.
Remarks: Based on available data, the classification criteria are not met.

Species: Rat
Application Route: Inhalation
Method: Based on weight of evidence.
Remarks: Based on available data, the classification criteria are not met.

Species: Rat
Application Route: Oral
Method: Based on weight of evidence.
Remarks: Based on available data, the classification criteria are not met.

Carcinogenicity - Assess- : This product does not meet the criteria for classification in
ment categories 1A/1B.

IARC Group 2A: Probably carcinogenic to humans

styrene 100-42-5

OSHA No component of this product present at levels greater than or

equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP Reasonably anticipated to be a human carcinogen

styrene 100-42-5

Reproductive toxicity

Components:
styrene:
Effects on fertility :
Species: Rat
Application Route: Inhalation

Method: OECD Test Guideline 416

Remarks: Based on available data, the classification criteria
are not met.

Effects on foetal develop- : Species: Rat

ment Application Route: Inhalation
Method: OECD Test Guideline 416
Remarks: Causes foetotoxicity in animals at doses which are
maternally toxic.

15 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Reproductive toxicity - As- : This product does not meet the criteria for classification in
sessment categories 1A/1B.

STOT - single exposure

Components:
styrene:
Exposure routes: Inhalation
Target Organs: Respiratory system
Remarks: Inhalation of vapours or mists may cause irritation to the respiratory system.

STOT - repeated exposure

Components:
styrene:
Exposure routes: Inhalation
Target Organs: ear
Remarks: Harmful: danger of serious damage to health by prolonged exposure through inhala-
tion., Can cause liver damage., Respiratory system: repeated exposure affects the respiratory
system. Effects were seen at high doses only., Auditory system: prolonged and repeated expo-
sures to high concentrations have resulted in hearing loss in rats.

Repeated dose toxicity

Components:
styrene:
Species: Humans, Unspecified
Application Route: Inhalation
Method: Occupational exposure
Target Organs: ear
Remarks: Harmful: danger of serious damage to health by prolonged exposure through inhala-
tion.
Can cause liver damage.
Respiratory System: repeated exposure affects the respiratory system.
Auditory system: prolonged and repeated exposures to high concentrations have resulted in
hearing loss in rats. Solvent abuse and noise interaction in the work environment may cause
hearing loss.
Nervous system: repeated exposure affects the nervous system. Effects were seen at high dos-
es only.

Species: Rat, Unspecified

Application Route: Inhalation
Test atmosphere: vapour
Method: Acceptable non-standard method.
Target Organs: ear
Remarks: Harmful: danger of serious damage to health by prolonged exposure through inhala-
tion.
Can cause liver damage.
Respiratory System: repeated exposure affects the respiratory system.
Auditory system: prolonged and repeated exposures to high concentrations have resulted in
hearing loss in rats. Solvent abuse and noise interaction in the work environment may cause
hearing loss.
Nervous system: repeated exposure affects the nervous system. Effects were seen at high dos-

16 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

es only.

Aspiration toxicity

Components:
styrene:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Further information

Components:
styrene:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

SECTION 12. ECOLOGICAL INFORMATION

Basis for assessment : Information given is based on product data.

Unless indicated otherwise, the data presented is representa-
tive of the product as a whole, rather than for individual com-
ponent(s).

Ecotoxicity

Components:

styrene:
Toxicity to fish (Acute toxici- : LC50 (Pimephales promelas (fathead minnow)): 4.02 mg/l
ty) Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: Toxic
LC/EC/IC50 >1 - <=10 mg/l

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 4.7 mg/l
aquatic invertebrates (Acute Exposure time: 48 h
toxicity) Method: OECD Test Guideline 202
Remarks: Toxic
LC/EC/IC50 >1 - <=10 mg/l

Toxicity to algae (Acute tox- : ErC50 (Pseudokirchneriella subcapitata (algae)): 4.9 mg/l
icity) Exposure time: 96 h
Method: Test(s) equivalent or similar to OECD Guideline 202
Remarks: Toxic
NOEC/NOEL > 1.0 - <= 10 mg/l

Toxicity to fish (Chronic tox- : Remarks: Data not available

icity)

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 1.01 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Method: OECD Test Guideline 211

17 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Remarks: NOEC/NOEL > 1.0 - <=10 mg/l (based on test data)

Toxicity to microorganisms : LC50 (Activated sludge): 500 mg/l

(Acute toxicity) Exposure time: 3 h
Method: Test(s) equivalent or similar to OECD Guideline 209
Remarks: Practically non toxic:
LL/EL/IL50 > 100 mg/l

Persistence and degradability

Components:

styrene:
Biodegradability : Biodegradation: 70.9 %
Exposure time: 28 d
Method: Other guideline method.
Remarks: Readily biodegradable.

Bioaccumulative potential

Components:

styrene:
Bioaccumulation : Remarks: Does not bioaccumulate significantly.

Mobility in soil

Components:

styrene:
Mobility : Remarks: Floats on water.
If product enters soil, it will be highly mobile and may contam-
inate groundwater.

Other adverse effects

Components:

styrene:
Results of PBT and vPvB : The substance does not fulfill all screening criteria for persis-
assessment tence, bioaccumulation and toxicity and hence is not consid-
ered to be PBT or vPvB.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal meth-
ods in compliance with applicable regulations.
Waste product should not be allowed to contaminate soil or

18 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

ground water, or be disposed of into the environment.

Do not discharge extinguishing waters into the aquatic envi-
ronment.
Do not dispose of tank water bottoms by allowing them to
drain into the ground. This will result in soil and groundwater
contamination.
Waste arising from a spillage or tank cleaning should be dis-
posed of in accordance with prevailing regulations, preferably
to a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.

Disposal should be in accordance with applicable regional,

national, and local laws and regulations.
Local regulations may be more stringent than regional or na-
tional requirements and must be complied with.

MARPOL - see International Convention for the Prevention of

Pollution from Ships (MARPOL 73/78) which provides tech-
nical aspects at controlling pollutions from ships.

Contaminated packaging : Drain container thoroughly.

After draining, vent in a safe place away from sparks and fire.
Residues may cause an explosion hazard.
Do not puncture, cut, or weld uncleaned drums.
Send to drum recoverer or metal reclaimer.

SECTION 14. TRANSPORT INFORMATION

National Regulations
US Department of Transportation Classification (49 CFR Parts 171-180)
UN/ID/NA number : UN 2055
Proper shipping name : STYRENE MONOMER, STABILIZED
Class : 3
Packing group : III
Labels : 3
Reportable quantity Styrene
(1,000 lb)
ERG Code : 128P
Marine pollutant : no
International Regulations

IATA-DGR
UN/ID No. : UN 2055
Proper shipping name : STYRENE MONOMER, STABILIZED
Class : 3
Packing group : III
Labels : 3
IMDG-Code
UN number : UN 2055
Proper shipping name : STYRENE MONOMER, STABILIZED

19 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Class : 3
Packing group : III
Labels : 3
Marine pollutant : no
Maritime transport in bulk according to IMO instruments
Pollution category : Y
Ship type : 3; Must be Double Hulled
Product name : Styrene monomer

Special precautions for user

Remarks : Special Precautions: Refer to Section 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

Additional Information : This product may be transported under nitrogen blanketing.

Nitrogen is an odourless and invisible gas. Exposure to nitro-
gen enriched atmospheres displaces available oxygen which
may cause asphyxiation or death. Personnel must observe
strict safety precautions when involved with a confined space
entry. Transport in bulk according to Annex II of Marpol and
the IBC Code

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
styrene 100-42-5 1000 1000
*: SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Aspiration hazard
Specific target organ toxicity (single or repeated exposure)

SARA 313 : The following components are subject to reporting levels es-
tablished by SARA Title III, Section 313:

styrene 100-42-5 >= 90 - <= 100 %

20 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

Clean Water Act

The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table
117.3:
styrene 100-42-5 100 %
US State Regulations

Pennsylvania Right To Know

styrene 100-42-5
California Prop. 65
WARNING: This product can expose you to chemicals including styrene, which is/are known to
the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
California List of Hazardous Substances
styrene 100-42-5
Other regulations:
The regulatory information is not intended to be comprehensive. Other regulations may apply
to this material.

The components of this product are reported in the following inventories:

AIIC : Listed

DSL : Listed

IECSC : Listed

ENCS : Listed

KECI : Listed

NZIoC : Listed

PICCS : Listed

TSCA : Listed

TCSI : Listed

SECTION 16. OTHER INFORMATION

Further information

NFPA Rating (Health, Fire, Reac- 3, 3, 2

tivity)

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI : ACGIH - Biological Exposure Indices (BEI)
OSHA Z-2 : USA. Occupational Exposure Limits (OSHA) - Table Z-2

21 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

ACGIH / TWA : 8-hour, time-weighted average

ACGIH / STEL : Short-term exposure limit
OSHA Z-2 / TWA : 8-hour time weighted average
OSHA Z-2 / CEIL : Acceptable ceiling concentration
OSHA Z-2 / Peak : Acceptable maximum peak above the acceptable ceiling con-
centration for an 8-hr shift
Abbreviations and Acronyms : The standard abbreviations and acronyms used in this docu-
ment can be looked up in reference literature (e.g. scientific
dictionaries) and/or websites.

ACGIH = American Conference of Governmental Industrial

Hygienists
ADR = European Agreement concerning the International
Carriage of Dangerous Goods by Road
AICS = Australian Inventory of Chemical Substances
ASTM = American Society for Testing and Materials
BEL = Biological exposure limits
BTEX = Benzene, Toluene, Ethylbenzene, Xylenes
CAS = Chemical Abstracts Service
CEFIC = European Chemical Industry Council
CLP = Classification Packaging and Labelling
COC = Cleveland Open-Cup
DIN = Deutsches Institut fur Normung
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DSL = Canada Domestic Substance List
EC = European Commission
EC50 = Effective Concentration fifty
ECETOC = European Center on Ecotoxicology and Toxicolo-
gy Of Chemicals
ECHA = European Chemicals Agency
EINECS = The European Inventory of Existing Commercial
Chemical Substances
EL50 = Effective Loading fifty
ENCS = Japanese Existing and New Chemical Substances
Inventory
EWC = European Waste Code
GHS = Globally Harmonised System of Classification and
Labelling of Chemicals
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IC50 = Inhibitory Concentration fifty
IL50 = Inhibitory Level fifty
IMDG = International Maritime Dangerous Goods
INV = Chinese Chemicals Inventory
IP346 = Institute of Petroleum test method N° 346 for the
determination of polycyclic aromatics DMSO-extractables
KECI = Korea Existing Chemicals Inventory
LC50 = Lethal Concentration fifty
LD50 = Lethal Dose fifty per cent.
LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading
LL50 = Lethal Loading fifty
MARPOL = International Convention for the Prevention of
Pollution From Ships
NOEC/NOEL = No Observed Effect Concentration / No Ob-

22 / 23
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
BC Styrene Monomer
Version Revision Date: SDS Number: Print Date: 06/14/2023
1.0 06/12/2023 800010050232 Date of last issue: -

served Effect Level

OE_HPV = Occupational Exposure - High Production Volume
PBT = Persistent, Bioaccumulative and Toxic
PICCS = Philippine Inventory of Chemicals and Chemical
Substances
PNEC = Predicted No Effect Concentration
REACH = Registration Evaluation And Authorisation Of
Chemicals
RID = Regulations Relating to International Carriage of Dan-
gerous Goods by Rail
SKIN_DES = Skin Designation
STEL = Short term exposure limit
TRA = Targeted Risk Assessment
TSCA = US Toxic Substances Control Act
TWA = Time-Weighted Average
vPvB = very Persistent and very Bioaccumulative

A vertical bar (|) in the left margin indicates an amendment from the previous version.

Sources of key data used to : The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers’ data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).

Revision Date : 06/12/2023

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

US / EN

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