REF: 17649

Name: CK-MB Liquid 112 mL (2x44+2x12)

SAFETY DATA SHEET

Release Date: 14-04-2015

REF Number Name

17649 CK-MB Liquid 112 mL (2x44+2x12)

COMPOSITION:

1) CK-MB Liquid REAGENT 1 44 mL (pag. 2)

2) CK-MB Liquid REAGENT 2 12 mL (pag. 8)

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

Safety Data Sheet dated 14/4/2015, version 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING
1.1. Product identifier
Mixture identification:
Trade name: CK-MB Liquid REAGENT 1 44 mL
Trade code: 27649A
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use:
For In Vitro Diagnostic use only.
For professional users only.
1.3. Details of the supplier of the safety data sheet
Company:
SENTINEL CH. SpA - Via Robert Koch 2 - 20152 Milan - Italy
SENTINEL CH. SpA - Phone n. [(+)39] 02 3455 141 working time.
Competent person responsible for the safety data sheet:
customerservice@sentinel.it
1.4. Emergency telephone number
SENTINEL CH. SpA - Phone n. [(+)39] 02 3455 1495 working time: Mon-Fri 9.00 am - 1.00 pm, 2.00
pm - 6.00 pm

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
None.

EC regulation criteria 1272/2008 (CLP)

Danger, Repr. 1A, May damage fertility or the unborn child.

Adverse physicochemical, human health and environmental effects:

No other hazards
2.2. Label elements
Symbols:

Danger
Hazard statements:
H360 May damage fertility or the unborn child.
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P281 Use personal protective equipment as required.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container in accordance with applicable regulations.
Special Provisions:
None
Contents
Imidazolo
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
N.A.

vPvB Substances: None - PBT Substances: None

Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related
classification:
>= 0.1% - < 0.5% Imidazolo
CAS: 288-32-4
Xn,C; R22-34-61
3.1/4/Oral Acute Tox. 4 H302

3.2/1A Skin Corr. 1A H314

3.7/1A Repr. 1A H360

>= 0.01% - < 0.1% Sodio Azide

Index number: 011-004-00-7, CAS: 26628-22-8, EC: 247-852-1
T+,N; R32-28-50/53
3.1/2/Oral Acute Tox. 2 H300

4.1/A1 Aquatic Acute 1 H400

4.1/C1 Aquatic Chronic 1 H410

4. FIRST AID MEASURES

4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention.
In case of Ingestion:
Get Medical advice/attention if you feel unwell.
In case of Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
Treatment:
None

5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13

7. HANDLING AND STORAGE

7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
2 - 8°C
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters
Sodio Azide - CAS: 26628-22-8
ACGIH - LTE(8h): 0.1 mg/m3 - STE: 0.3 mg/m3 - Behaviour: Indicative
EU - LTE: 0.1 mg/m3 - STE: 0.3 mg/m3 - Notes: Assorbimento attraverso la pelle
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.
8.2. Exposure controls
Eye protection:
Eye glasses.
Protection for skin:
Lab coat.
Protection for hands:
One-time gloves.
Respiratory protection:
Not needed for normal use.
Thermal Hazards:
None
Environmental exposure controls:
None

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
Appearance and colour: Liquido incolore
Odour: Debole odore di tiolo
Odour threshold: N.A.
pH: 6.0
Melting point / freezing point: N.A.
Initial boiling point and boiling range: N.A.

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

Solid/gas flammability: N.A.

Upper/lower flammability or explosive limits: N.A.
Vapour density: N.A.
Flash point: N.A.
Evaporation rate: N.A.
Vapour pressure: N.A.
Relative density: 1.009
Solubility in water: Completamente miscibile
Solubility in oil: N.A.
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A.
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: N.A.
Oxidizing properties: N.A.
9.2. Other information
Miscibility: N.A.
Fat Solubility: N.A.
Conductivity: N.A.
Substance Groups relevant properties N.A.

10. STABILITY AND REACTIVITY

10.1. Reactivity
No hazardous reactions known.
10.2. Chemical stability
Stable when properly stored.
10.3. Possibility of hazardous reactions
None
10.4. Conditions to avoid
Exposure to direct light.
10.5. Incompatible materials
Acids, Alkalis
10.6. Hazardous decomposition products
None.

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
Sodio Azide - CAS: 26628-22-8
a) acute toxicity:
Test: LD50 - Route: Oral - Species: Rat 27 mg/kg - Source: RTECS
Test: LD50 - Route: Skin - Species: Rabbit 20 mg/kg - Source: RTECS

If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered as
N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.

12. ECOLOGICAL INFORMATION

12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

Do not use when plants are in flower: the product is toxic for bees.
Sodio Azide - CAS: 26628-22-8
Endpoint: LC50 - Species: Fish - Duration h: 96 - mg/l: N.A.
Endpoint: EC50 - Species: Daphnia - Duration h: 48 - mg/l: N.A.
12.2. Persistence and degradability
None
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Recover if possible. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION

14.1. UN number
Not classified as dangerous in the meaning of transport regulations.
14.2. UN proper shipping name
N.A.
14.3. Transport hazard class(es)
N.A.
14.4. Packing group
N.A.
14.5. Environmental hazards
N.A.
14.6. Special precautions for user
N.A.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC
(Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to chemical
agents at work). Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE. Regulation (CE) n.
1907/2006 (REACH), Regulation (CE) n.1272/2008 (CLP), Regulation (CE) n.790/2009.
Where applicable, refer to the following regulatory provisions :
Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)

15.2. Chemical safety assessment

No

16. OTHER INFORMATION

Full text of phrases referred to in Section 3:
R22 Harmful if swallowed.
R28 Very toxic if swallowed.
R32 Contact with acids liberates very toxic gas.
R34 Causes burns.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R61 May cause harm to the unborn child.

H302 Harmful if swallowed.

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

H314 Causes severe skin burns and eye damage.

H360 May damage fertility or the unborn child.
H300 Fatal if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand
Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It refers
solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the
specific use intended.
This MSDS cancels and replaces any preceding release.

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

Safety Data Sheet dated 14/4/2015, version 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING
1.1. Product identifier
Mixture identification:
Trade name: CK-MB Liquid REAGENT 2 12 mL
Trade code: 27649B
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use:
For In Vitro Diagnostic use only.
For professional users only.
1.3. Details of the supplier of the safety data sheet
Company:
SENTINEL CH. SpA - Via Robert Koch 2 - 20152 Milan - Italy
SENTINEL CH. SpA - Phone n. [(+)39] 02 3455 141 working time.
Competent person responsible for the safety data sheet:
customerservice@sentinel.it
1.4. Emergency telephone number
SENTINEL CH. SpA - Phone n. [(+)39] 02 3455 1495 working time: Mon-Fri 9.00 am - 1.00 pm, 2.00
pm - 6.00 pm

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
None.

EC regulation criteria 1272/2008 (CLP)

Warning, Skin Irrit. 2, Causes skin irritation.

Warning, Eye Irrit. 2, Causes serious eye irritation.

Danger, Repr. 1A, May damage fertility or the unborn child.

Adverse physicochemical, human health and environmental effects:

No other hazards
2.2. Label elements
Symbols:

Danger
Hazard statements:
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H360 May damage fertility or the unborn child.
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with applicable regulations.
Special Provisions:
None
Contents
Imidazolo
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

vPvB Substances: None - PBT Substances: None

Other Hazards:
No other hazards
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
N.A.

vPvB Substances: None - PBT Substances: None

Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related
classification:
>= 1% - < 3% Imidazolo
CAS: 288-32-4
Xn,C; R22-34-61
3.1/4/Oral Acute Tox. 4 H302

3.2/1A Skin Corr. 1A H314

3.7/1A Repr. 1A H360

>= 0.01% - < 0.1% Sodio Azide

Index number: 011-004-00-7, CAS: 26628-22-8, EC: 247-852-1
T+,N; R32-28-50/53
3.1/2/Oral Acute Tox. 2 H300

4.1/A1 Aquatic Acute 1 H400

4.1/C1 Aquatic Chronic 1 H410

4. FIRST AID MEASURES

4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention.
In case of Ingestion:
Get Medical advice/attention if you feel unwell.
In case of Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
Treatment:
None

5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13

7. HANDLING AND STORAGE

7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
2 - 8°C
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters
Sodio Azide - CAS: 26628-22-8
ACGIH - LTE(8h): 0.1 mg/m3 - STE: 0.3 mg/m3 - Behaviour: Indicative
EU - LTE: 0.1 mg/m3 - STE: 0.3 mg/m3 - Notes: Absorption through the skin.
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.
8.2. Exposure controls
Eye protection:
Eye glasses.
Protection for skin:
Lab coat.
Protection for hands:
One-time gloves.
Respiratory protection:
Not needed for normal use.
Thermal Hazards:
None
Environmental exposure controls:
None

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
Appearance and colour: Colourless liquid.
Odour: Odorless
Odour threshold: N.A.

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

pH: 9.0
Melting point / freezing point: N.A.
Initial boiling point and boiling range: N.A.
Solid/gas flammability: N.A.
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.A.
Flash point: N.A.
Evaporation rate: N.A.
Vapour pressure: N.A.
Relative density: 1.039
Solubility in water: Completely miscible
Solubility in oil: N.A.
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A.
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: N.A.
Oxidizing properties: N.A.
9.2. Other information
Miscibility: N.A.
Fat Solubility: N.A.
Conductivity: N.A.
Substance Groups relevant properties N.A.

10. STABILITY AND REACTIVITY

10.1. Reactivity
No hazardous reactions known.
10.2. Chemical stability
Stable when properly stored.
10.3. Possibility of hazardous reactions
None
10.4. Conditions to avoid
Exposure to direct light.
10.5. Incompatible materials
Acids, Alkalis
10.6. Hazardous decomposition products
None.

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
Sodio Azide - CAS: 26628-22-8
a) acute toxicity:
Test: LD50 - Route: Oral - Species: Rat 27 mg/kg - Source: RTECS
Test: LD50 - Route: Skin - Species: Rabbit 20 mg/kg - Source: RTECS

If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered as
N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.

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 REF: 17649
Name: CK-MB Liquid 112 mL (2x44+2x12)

12. ECOLOGICAL INFORMATION

12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
Do not use when plants are in flower: the product is toxic for bees.
Sodio Azide - CAS: 26628-22-8
Endpoint: LC50 - Species: Fish - Duration h: 96 - mg/l: N.A.
Endpoint: EC50 - Species: Daphnia - Duration h: 48 - mg/l: N.A.
12.2. Persistence and degradability
None
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Recover if possible. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION

14.1. UN number
Not classified as dangerous in the meaning of transport regulations.
14.2. UN proper shipping name
N.A.
14.3. Transport hazard class(es)
N.A.
14.4. Packing group
N.A.
14.5. Environmental hazards
N.A.
14.6. Special precautions for user
N.A.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC
(Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to chemical
agents at work). Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE. Regulation (CE) n.
1907/2006 (REACH), Regulation (CE) n.1272/2008 (CLP), Regulation (CE) n.790/2009.
Where applicable, refer to the following regulatory provisions :
Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)

15.2. Chemical safety assessment

No

16. OTHER INFORMATION

Full text of phrases referred to in Section 3:
R22 Harmful if swallowed.
R28 Very toxic if swallowed.
R32 Contact with acids liberates very toxic gas.
R34 Causes burns.

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Name: CK-MB Liquid 112 mL (2x44+2x12)

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R61 May cause harm to the unborn child.

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.
H360 May damage fertility or the unborn child.
H300 Fatal if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand
Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It refers
solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the
specific use intended.
This MSDS cancels and replaces any preceding release.
SDS cancels and replaces any preceding release.

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