SDS-Nitobond-EP-India
SDS-Nitobond-EP-India
SDS-Nitobond-EP-India
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Adhesive
Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Repr. 1B - H360
Hazard pictograms
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Contains EPOXY RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP
3.2. Mixtures
Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411
Classification
Acute Tox. 3 - H331
Repr. 1B - H360
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410
Classification
Not Classified
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PROPAN-2-OL <1%
CAS number: 67-63-0 EC number: 200-661-7
Classification
Flam. Liq. 2 - H225
Eye Irrit. 2 - H319
STOT SE 3 - H336
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Inhalation Ensure supply of fresh air. Move affected person to fresh air and keep warm and at rest in a
position comfortable for breathing. Remove affected person from source of contamination.
Maintain an open airway. Get medical attention.
Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Remove affected person from
source of contamination. Never give anything by mouth to an unconscious person. Get
medical attention immediately.
Skin contact Remove affected person from source of contamination. Take off immediately all contaminated
clothing. Wash clothing and clean shoes thoroughly before reuse. Wash skin thoroughly with
soap and water. Get medical attention if symptoms are severe or persist after washing.
Eye contact Rinse with water. Remove any contact lenses and open eyelids wide apart. Continue to rinse
for at least 15 minutes and get medical attention. Get medical attention if symptoms are
severe or persist.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Skin contact May cause irritation. May cause sensitisation by skin contact. May cause an allergic skin
reaction.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
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Special protective equipment Self-contained breathing apparatus. Wear protective fire fighting clothing.
for firefighters
Advice on general When using do not eat, drink or smoke. Good personal hygiene procedures should be
occupational hygiene implemented. Wash contaminated skin thoroughly after handling. Take off immediately all
contaminated clothing and wash it before reuse. Wash at the end of each work shift and
before eating, smoking and using the toilet.
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TITANIUM DIOXIDE
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust
Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dust
PROPAN-2-OL
Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³
Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³
WEL = Workplace Exposure Limit
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)
Protective equipment
Appropriate engineering Provide adequate general and local exhaust ventilation. Avoid inhalation of vapours and
controls spray/mists. Observe any occupational exposure limits for the product or ingredients.
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Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection
Hygiene measures Good personal hygiene procedures should be implemented. Wash contaminated skin
thoroughly after handling. Do not eat, drink or smoke when using this product.
Colour White
Odour Mild
Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.
10.1. Reactivity
Reactivity The following materials may react with the product: Amines. Alcohols.
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reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
Species Rat
Species Rabbit
Skin corrosion/irritation
Skin sensitisation
DIBUTYL PHTHALATE
Species Rat
Species Rabbit
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Species Rat
Acute and chronic health INGESTION. May cause stomach pain or vomiting. Inhalation May cause
hazards respiratory system irritation. SKIN CONTACT. May cause skin irritation/eczema.
May cause sensitisation by skin contact. EYE CONTACT. Irritating to eyes.
PROPAN-2-OL
Species Rat
Species Rat
Species Rat
Carcinogenicity
Target organs Eyes Kidneys Liver Respiratory system, lungs Skin Central nervous system
Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
12.1. Toxicity
Ecological information on ingredients.
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
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Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)
Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants
DIBUTYL PHTHALATE
M factor (Acute) 10
Acute toxicity - fish LC₅₀, 96 hours: 0.85 mg/l, Pimephales promelas (Fat-head Minnow)
LC₅₀, 96 hours: 1.6 mg/l, Salmo gairdneri
M factor (Chronic) 10
PROPAN-2-OL
Acute toxicity - fish LC50, 96 hours: 1400 - 9640 mg/l, Pimephales promelas (Fat-head Minnow)
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
PROPAN-2-OL
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Mobility The product contains substances which are insoluble in water and which sediment in water
systems.
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
PROPAN-2-OL
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment
PROPAN-2-OL
Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.
14.1. UN number
UN No. (ADR/RID) 3082
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Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)
Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)
Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)
ADR/RID label 9
IMDG class 9
ICAO class/division 9
ADN class 9
Transport labels
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.
General information Only trained personnel should use this material. The data and advice given apply when the
product is used for the stated application or applications. The product is not sold as suitable
for any other application. Use of the product for applications other than as stated in this sheet
may give rise to risks not mentioned in this sheet. The product should not be used other than
for a stated application or applications without seeking advice from Fosroc Ltd. Further copies
of this Safety Data Sheet may be obtained from Fosroc Limited.
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision 4A
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The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.
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1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Adhesive
Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1
- H317 Muta. 2 - H341 Carc. 1B - H350 STOT SE 1 - H370 STOT RE 2 - H373
Classification (67/548/EEC or -
1999/45/EC)
Human health May cause serious eye damage. May cause skin sensitisation or allergic reactions in sensitive
individuals.
Environmental The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
Hazard pictograms
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Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P273 Avoid release to the environment.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.
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3.2. Mixtures
4,4'-METHYLENEDIANILINE 30-60%
CAS number: 101-77-9 EC number: 202-974-4
M factor (Acute) = 1 M factor (Chronic) = 10
Substance of very high concern (SVHC).
Classification
Acute Tox. 3 - H301
Acute Tox. 2 - H330
Skin Sens. 1 - H317
Muta. 2 - H341
Carc. 1B - H350
STOT SE 1 - H370
STOT RE 2 - H373
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410
Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411
Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Skin Sens. 1 - H317
Muta. 2 - H341
Carc. 1B - H350
STOT SE 3 - H335
Aquatic Chronic 3 - H412
Classification
Not Classified
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XYLENE <1%
CAS number: 1330-20-7 EC number: 215-535-7 REACH registration number: 01-
2119488216-32-0000
Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
ETHYLBENZENE <1%
CAS number: 100-41-4 EC number: 202-849-4
Classification
Flam. Liq. 2 - H225
Acute Tox. 4 - H332
STOT RE 2 - H373
Asp. Tox. 1 - H304
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Get medical attention.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Never give anything by mouth to
an unconscious person. Get medical attention immediately.
Skin contact Rinse immediately with plenty of water. Remove contaminated clothing. Wash contaminated
clothing before reuse. Get medical attention.
Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of
water. Continue to rinse for at least 15 minutes. Get medical attention immediately.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Skin contact Causes severe burns. May cause an allergic skin reaction.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
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Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Hazardous combustion Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of nitrogen.
products
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
Advice on general Do not eat, drink or smoke when using this product. Wash at the end of each work shift and
occupational hygiene before eating, smoking and using the toilet. Take off contaminated clothing and wash it before
reuse.
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4,4'-METHYLENEDIANILINE
Long-term exposure limit (8-hour TWA): WEL 0.01 ppm 0.08 mg/m³
Carc, Sk
PHENYL GLYCIDYL ETHER
Long-term exposure limit (8-hour TWA): WEL 1 ppm 6.2 mg/m³
Short-term exposure limit (15-minute): WEL
MICA POWDER
Long-term exposure limit (8-hour TWA): WEL 0,8 mg/m³
XYLENE
Long-term exposure limit (8-hour TWA): WEL 50 ppm 220 mg/m³
Short-term exposure limit (15-minute): WEL 100 ppm 441 mg/m³
Sk
ETHYLBENZENE
Long-term exposure limit (8-hour TWA): WEL 100 ppm 441 mg/m³
Short-term exposure limit (15-minute): WEL 125 ppm 552 mg/m³
Sk
WEL = Workplace Exposure Limit
Carc = Capable of causing cancer and/or heritable genetic damage.
Sk = Can be absorbed through the skin.
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)
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Protective equipment
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. Wear protective gloves made of the
following material: Butyl rubber. Nitrile rubber. Viton rubber (fluoro rubber).
Hygiene measures Provide eyewash station and safety shower. Discard contaminated shoes and clothing. Do not
smoke in work area. Do not eat, drink or smoke when using this product. Wash promptly with
soap and water if skin becomes contaminated. Wash at the end of each work shift and before
eating, smoking and using the toilet. Use appropriate skin cream to prevent drying of skin.
Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Gas filter, type K.
Colour White
Odour Amine.
Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.
10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Amines.
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Skin contact Causes severe burns. May be harmful in contact with skin. May cause an allergic
skin reaction.
Acute and chronic health Suspected of causing cancer. Suspected of causing genetic defects.
hazards
4,4'-METHYLENEDIANILINE
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Species Rat
Species Rat
Carcinogenicity
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
Species Rat
Species Rabbit
Skin corrosion/irritation
Skin sensitisation
Species Mouse
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Species Rabbit
Species Rat
SALICYLIC ACID
Species Rat
XYLENE
Carcinogenicity
ETHYLBENZENE
Carcinogenicity
Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
12.1. Toxicity
Ecological information on ingredients.
4,4'-METHYLENEDIANILINE
M factor (Acute) 1
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Acute toxicity - fish LC₅₀, 96 hours: 20.6 mg/l, Oryzias latipes (Red killifish)
M factor (Chronic) 10
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)
Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants
SALICYLIC ACID
XYLENE
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
XYLENE
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
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reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
XYLENE
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.
14.1. UN number
UN No. (ADR/RID) 3082
Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS 4,4'-
METHYLENEDIANILINE, EPOXY RESIN (Type A) (Number average MW <= 700 ))
Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS 4,4'-
METHYLENEDIANILINE, EPOXY RESIN (Type A) (Number average MW <= 700 ))
Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS 4,4'-
METHYLENEDIANILINE, EPOXY RESIN (Type A) (Number average MW <= 700 ))
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ADR/RID class 9
ADR/RID label 9
IMDG class 9
ICAO class/division 9
ADN class 9
Transport labels
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
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Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision 4A
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Revision date: 18/12/2018 Revision: 4A Supersedes date: 15/08/2015
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The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.
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