Assignment – Mole concept

Atoms Molecules
1. Which of the following contains atoms equal to those in 8. The number of molecules in 4.25 g of ammonia is about
12 g Mg ? (At. wt. Mg = 24)
(a) 1.0 × 1023 (b) 1.5 × 1023
(a) 12 gm C (b) 7 gm N2
(c) 2.0 × 1023 (d) 2.5 × 1023
(c) 32 gm O2 (d) None of These
9. If 20% nitrogen is present in a compound, its minimum
1 molecular weight can be
2. If 1 moles of oxygen combine with Al to form Al2 O3, the
2
(a) 144 (b) 28
weight of Al used in the reaction is (Al = 27)
(c) 100 (d) 70
(a) 27 g (b) 54 g
10. The weight of molecule of the compound C60H122 is
(c) 40.5 g (d) 81 g
3. Which has the highest mass? (a) 1.4 × 10–21 g (b) 1.09 × 10–21 g

(a) 50 g of iron (b) 5 moles of N2 (c) 5.025 × 1023 g (d) 16.023 × 1023 g

(c) 0.1 mol atom of Ag (d) 1023 atoms of carbon 11. Choose the wrong statement :

4. The number of atoms present in 0.5 mole of nitrogen is (a) 1 mole means 6.02 × 1023 particles
same as the atoms in
(b) Molar mass is mass of one molecule
(a) 12 g of C (b) 64 g of S
(c) Molar mass is mass of one mole of a substance
(c) 8 g of O (d) 48 g of Mg
(d) Molar mass is molecular mass expressed in grams
5. Which of the following weighs the least?
12. Which among the following is the heaviest ?
(a) 2 g atom of N (at. wt. of N = 14)

(b) 3 × 1023 atoms of C (at. wt. of C = 12) (a) One mole of oxygen

(c) 1 mole of S (at. wt. of S = 32) (b) One molecule of sulphur trioxide

(d) 7 g silver (at. wt. of Ag = 108) (c) 100 amu of uranium

6. If NA is Avogadro’s number then number of valence (d) 44g of carbon dioxide

electrons in 4.2 g of nitride ions (N3–) is
13. Rearrange the following I to IV in order of increasing
(a) 2.4 NA (b) 4.2 NA masses and choose the correct answer [At. wt. of N = 14 u,
(c) 1.6 NA (d) 3.2 NA O = 16 u, Cu = 63 u]

7. Haemoglobin contains 0.33% of iron by weight. The I 1 molecule of oxygen

molecular weight of haemoglobin is approximately 67200. II 1 atom of nitrogen
The number of iron atoms (at. wt. of Fe = 56) present in
one molecule of haemoglobin is III 1 × 10–10 mol molecule of oxygen

(a) 6 (b) 1 IV 1 × 10–10 mol atom of copper

(c) 4 (d) 2 (a) II < I < III < IV (b) IV < III < II < I
(c) II > I > III > IV (d) I < II < IV < III
14. The number of moles of SO2Cl2 in 13.5 g is : 21. A sample of pure calcium weighing 1.35 g was
(a) 0.1 (b) 0.2 quantitatively converted to 1.88 g of pure calcium oxide.
Atomic mass of calcium would be :
(c) 0.3 (d) 0.4
15. The largest number of molecules is in (a) 20 (b) 40

(a) 36 g of water (c) 16 (d) 35.5

(b) 28 g of carbon monoxide 22. 30g of magnesium and 30g of oxygen are reacted, then the
(c) 46 g of ethyl alcohol residual mixture contains
(d) 54 g of nitrogen pentoxide. (a) 60g of Magnesium oxide only
16. Which of the following contains maximum number of
(b) 40g of Magnesium oxide and 20 g of oxygen
atoms ?
(a) 6.023 × 1021 molecules of CO 2 (c) 45 g of Magnesium oxide and 15g of oxygen

(b) 22.4 L of CO2 at STP (d) 50 g of Magnesium oxide and 10g of oxygen

(c) 0.44 g of CO2 23. Silicon carbide, is produced by heating SiO2 and C to high
(d) None of these temperatures according to the equation :

Stoichiometric Calculations SiO2 (s) + 3C (s) 🠊 SiC (s) + 2CO (g)

17. If 0.5 mol of BaCl2 is mixed with 0.2 mol of Na3 PO4 ,
the How many grams of SiC could be formed by reacting 2.00

maximum number of mole of Ba3(PO4)2 that can be formed g of SiO2 and 2.0 g of C ?
is
(a) 1.33 (b) 2.56
(a) 0.7 (b) 0.5
(c) 3.59 (d) 4.0
(c) 0.30 (d) 0.10
24. Given the reaction
18. One mole of a mixture of CO and CO2 requires exactly 20 gram
of NaOH in solution for complete conversion of all the CO2

into Na2 CO3. How many moles more of NaOH would it require What is the mass of PbI2 that will precipitate if 10.2 g of
for conversion into Na2CO3 if the mixture (one mole) is Pb(NO3)2 is mixed with 5.73 g of KI in a sufficient quantity
completely oxidised to CO2. of H2O ?
(a) 0.2 (b) 0.5
(a) 2.06 g (b) 4.13 g
(c) 0.4 (d) 1.5
(c) 7.96 g (d) 15.9 g
19. The number of water molecules present in a drop of water
(volume = 0.0018 ml) at room temperature is (density of 25. If 9 moles of O2 and 14 moles of N2 are placed in a container
H2O = 1 g/mL) and allowed to react according to the equation :

(a) 6.023 × 1019 (b) 1.084 × 1018 3O2 + 2N2 → 2N2O3

(c) 4.84 × 1017 (d) 6.023 × 1023 The reaction proceeds until 3 moles of O2 remain, how
20. What is the weight of oxygen required for the complete many moles of N2O3 are present at that instant ?
combustion of 2.8 kg of ethylene ? (a) 6 (b) 3
(a) 2.8 kg (b) 6.4 kg (c) 4 (d) 12

(c) 9.6 kg (d) 96 kg

26. Iron (III) oxide can be reduced with CO to form metalic 32. Mole fraction of ethanol in ethanol ­ water mixture is 0.25.
iron as described by unbalanced chemical reaction Hence, percentage concentration of ethanol (C2H6O) by
Fe2 O3 + CO → Fe + CO2 weight of mixture is

The number of moles of CO required to form one mole of (a) 25 (b) 75

Fe from its oxide is
(c) 46 (d) 54
(a) 1 (b) 1.5
Strength : Molality
(c) 2 (d) 3
33. A molal solution is one that contains one mole of a
Percentage Purity solute in

27. The mass of CaO that shall be obtained by heating 20 kg (a) 1000 g of the solvent
of 90% pure lime­stone (CaCO3) is (b) one litre of the solvent
(a) 11.2 kg (b) 8.4 kg (c) one litre of the solution
(c) 10.08 kg (d) 16.8 kg (d) 22.4 litres of the solution
28. If potassium chlorate is 80% pure, then 48 g of oxygen 34. An aqueous solution of ethanol has density 1.025 g/mL
would be produced from (atomic mass of K = 39)
and it is 2 M. What is the molality of this solution ?
(a) 153.12g of KClO3 (b) 122.5 g of KClO3
(a) 1.79 (b) 2.143
(c) 245 g of KClO3 (d) 98.0 g of KClO3
(c) 1.951 (d) None of these
Percentage Yield
29. Antimony reacts with sulphur according to the equation 35. What volume of 0.4 M FeCl3 . 6H2O will contain 600 mg of
Fe3+ ?
2Sb(s) + 3S(s) Sb2S3(s)
The molar mass of Sb S is 340 g mol–1. (a) 49.85 mL (b) 26.78 mL
2 3
(c) 147.55 mL (d) 87.65 mL
What is the percentrage yield for a reaction in which 1.40
g of Sb2S3 is obtained from 1.73 g of antimony and a slight 36. A sample of H2SO4 (density 1.8 g/ml) is 90% by weight.
excess of sulphur ? What is the volume of the acid that has to be used to make
(a) 80.9 % (b) 58.0 % 1 litre of 0.2 MH2SO4?
(c) 40.5 % (d) 29.0 % (a) 16 mL (b) 10 mL
30. NH3 is produced according to the following reaction : (c) 12 mL (d) 18 mL
N2(g) + 3H2(g) 2NH3(g)
37. The density (in g mL–1) of a 3.60 M sulphuric acid
In an experiment 0.25 mol of NH3 is formed when 0.5 mol of
solution that is 29% H2 SO4 (molar mass = 98 g mol–1) by
N2 is reacted with 0.5 mol of H2. What is % yield ?
mass will be
(a) 75% (b) 50%
(c) 33% (d) 25% (a) 1.45 (b) 1.64

Strength : Mass Percent (c) 1.88 (d) 1.22

31. What is the weight % sulhuric acid in an aqueous solution 38. An antifreeze mixture contains 40% ethylene glycol
which is 0.502 M in sulphuric acid ? The specify gravity of
(C2H6O2) by weight in the aqueous solution. If the density
the solution is 1.07
of this solution is 1.05 g mL, what is the molar
(a) 4.77 % (b) 5.67 % concentration?
(c) 9.53 % (d) 22.0 %
(a) 6.77 M (b) 6.45 M

(c) 0.0017 M (d) 16.9 M

39. What is the molarity of SO2 ion in aqueous solution that 46. A sample of H2 SO4 (density 1.8 g mL–1) is 90% by weight.
4 What is the volume of the acid that has to be used to make
contain 34.2 ppm of Al2(SO4)3 ? (Assume complete
1 L of 0.2 M H2SO4 ?
dissociation and density of solution 1 g/mL)
(a) 16 mL (b) 18 mL
(a) 3 × 10–4 M (b) 2 × 10–4 M
(c) 12 mL (d) 10 mL
(c) 10–4 M (d) None of these
Strength : Stoichiometric Calculations
Strength : Mole Fraction
47. What is the concentration of nitrate ions if equal volumes
40. The mole fraction of a given sample of I2 in C6 H 6 is 0.2. of 0.1 M AgNO3 and 0.1 M NaCl are mixed together ?
The molality of I2 in C6H6 is (a) 0.1 M (b) 0.2 M
(a) 0.32 (b) 3.2
(c) 0.05 M (d) 0.25 M
(c) 0.032 (d) 0.48
48. How many grams of NaBr could be formed if 14.2 g of NaI
Strength : Variation are reacted with 40.0 mL of a 0.800 M Br2 ?

2NaI + Br2 → 2NaBr + I2

41. In which mode of expression, the concentration of a
solution remains independent of temperature ? (a) 3.30 (b) 4.80

(a) Molarity (b) Normality (c) 6.59 (d) 9.75

(c) Formality (d) Molality 49. If AgBr is assumed to be completely insoluble, What mass
of AgBr precipitates when 30.0 mL of a 0.500 mol/L solution
42. With increase of temperature, which of these changes ? of AgNO3 is added to 50.0 mL of an 0.400 mol/L solution of
NaBr ?
(a) molality
(a) 3.76 g (b) 1.28 g
(b) weight fraction of solute
(c) 2.82 g (d) 3.76 kg
(c) fraction of solute present in unit volume of water
50. In a titration, 15.0 cm3 of 0.100 M HCl neutralizes 30.0 cm3
(d) mole fraction. of Ca(OH)2. What is the molarity of Ca(OH)2 solution ?

43. Molarity and Normality changes with temperature (a) 0.0125 (b) 0.0250
because they involve :
(c) 0.0500 (d) 0.200
(a) Moles (b) equivalents
51. 10 mL of 1 M BaCl2 solution and 5 mL 0.5 M K2SO4 are
(c) weights (d) volumes mixed together to precipitate out BaSO4. The amount of

44. When 500.0 mL of 1.0 M LaCl3 BaSO4 precipated will be

–
and 3.0 M NaCl are mixed.
What is molarity of Cl ion ? (a) 0.005 mol (b) 0.00025 mol

(a) 4.0 M (b) 3.0 M (c) 0.025 mol (d) 0.0025 mol

(c) 2.0 M (d) 1.5 M Molar Volume of Gas based Calculations

45. When 50 mL of 2.00 M HCl, 100 mL of 1.00 M HCl and 100 52. M g of a substance when vaporised occupy a volume of
5.6 litre at NTP. The molecular mass of the substance will
mL of 0.500 M HCl are mixed together, the resulting HCl
be :
concentration of the solution is
(a) M (b) 2M
(a) 0.25 M (b) 1.00 M
(c) 3M (d) 4M
(c) 3.50 M (d) 6.25 M
53. Number of molecules in 1 litre of oxygen at NTP is : 61. The Ew of an element is 13. It forms an acidic oxide which
with KOH forms a salt isomorphous with K2SO4. The atomic
6.02 x1023 6.02 x1023 weight of element is
(a) (b)
32 22.4
(a) 13 (b) 26

(c) 32 × 22.4 (d) 32 (c) 52 (d) 78

22.4 62. A hydrate of Na2SO3 losses 22.2% of H2O by mass on

54. The number of molecules in 89.6 litre of a gas at NTP are : strong heating. The hydrate is
(a) 6.02×1023 (b) 2×6.02×1023 (a) Na2SO3 . 4H2O (b) Na2SO3 . 6H2O

(c) Na2SO3 .H2O (d) Na2SO3 .2H2O

23 23
(c) 3×6.02×10 (d) 4×6.02×10

55. The mass of 112 cm3 of CH 4gas at STP is

Laws of Chemical Combination
(a) 0.16 g (b) 0.8 g
63. One of the following combinations illustrate law of
(c) 0.08 g (d) 1.6 g reciprocal proportions

Empirical Formula (a) N2 O3 , N2 O4 , N2 O5

(b) NaCl, NaBr, Nal

56. An oxide of metal (M) has 40% by mass of oxygen. Metal M (d) PH3 , P2O3 , P2O5
(c) CS2 , CO2 ,SO2

has atomic mass of 24. The empirical formula of the oxide is

64. If water samples are taken from sea, river, clouds, lake or
(a) M2O (b) M2O3
snow, they will be found to contain H2 and O2 in the
(c) MO (d) M3O4 approximate ratio of 1 : 8. This indicates the law of
57. What is the empirical formula of a compound composed (a) Multiple proportion (b) Definite proportion
of O and Mn in equal weight ratio ?
(c) Reciprocal proportions (d) none of these
(a) MnO (b) MnO2
65. The law of multiple proportion is illustrated by
(c) Mn2O3 (d) Mn2O7 (a) Carbon monoxide and carbon dioxide

58. Determine the empirical formula of Kelvar, used in making (b) Potassium bromide and potassium chloride
bullet proof vests, is 70.6% C, 4.2% H, 11.8% N and 13.4% (c) Water and heavy water
O:
(d) Calcium hydroxide and barium hydroxide
(a) C7H5NO2 (b) C7H5N2O
66. The percentage of copper and oxygen in samples of CuO
(c) C7H9NO (d) C7H5NO obtained by different methods were found to be the same.
This illustrates the law of
59. A compound contains atoms of three elements A, B and C.
If the oxidation number of A is +2, B is +5 and C is –2, the (a) constant proportions (b) conservation of mass
possible formula of the compound is : (c) multiple proportions (d) reciprocal proportions
(a) A(BC3)2 (b) A3(BC4)2 67. Two samples of lead oxide were separately reduced to
metallic lead by heating in a current of hydrogen. The
(c) A3(B4C)2 (d) ABC2 weight of lead from one oxide was half the weight of lead
60. The carbonate of a metal is isomorphous (similar formula) obtained from the other oxide. The data illustrates.
with magnesium carbonate and contains 6.091 percent of (a) law of reciprocal proportions
carbon. The atomic weight of metal is (b) law of constant proportions
(a) 24 (b) 56 (c) law of multiple proportions
(c) 137 (d) 260 (d) law of equivalent proportions
68. One part of an element A combines with two parts of 73. H2 S contains 5.88% hydrogen, H2 O contains 11.11%

another element B. Six parts of the element C combine

with four parts of the element B. If A and C combine hydrogen while SO2 contains 50% sulphur. These figures
together the ratio of their weights will be governed by illustrate the law of :
(a) law of definite proportions (a) conservation of mass (b) constant proportions
(b) law of multiple proportions (c) multiple proportions (d) reciprocal proportions
(c) law of reciprocal proportions
74. Hydrogen combines with chlorine to form HCl. It also
(d) law of conservation of mass. combines with sodium to form NaH. If sodium and chlorine
69. n g of substance X reacts with m g of substance Y to form also combine with each other, they will do so in the ratio of
p g of substance R and q g of substance S. This reaction their masses as :
can be represented as follows :
(a) 23 : 35.5 (b) 35.5 : 23
X+ Y=R+S
(c) 1 : 1 (d) 23 : 1
The relation which can be established in the amounts of
the reactants and the products will be Principle of Atom Conservation
(a) n – m = p – q (b) n + m = p + q 75. x g of Ag was dissolved in HNO3 and the solution was
(c) n = m (d) p = q treated with excess of NaCl when 2.87 g of AgCl was
precipitated. The value of x is
70. Which one is the best example of law of conservation of
mass ? (a) 1.08 g (b) 2.16 g

(a) 6 g of carbon is heated in vacuum, there is no change (c) 2.70 g (d) 1.62 g
in mass
76. A 1.50 g sample of an ore containing silver was dossolved,
(b) 6 g of carbon combines with 16 g of oxygen to form 22 g and all the Ag+ was converted to 0.125 g Ag 2S. What was

of CO2 the percentage of silver in the ore ?

(c) 6 g water is completely converted into steam (a) 14.23% (b) 10.8%

(d) A sample of air is heated at constant pressure when its (c) 8.27% (d) 7.2%
volume increases but there in no change in mass. 77. NaOH is formed according to the reaction
71. SO2 gas was prepared by (i) burning sulphur in oxygen,
1
(ii) reacting sodium sulphite with dilute H2SO4 and 2Na + O2 → Na2 O
2

(iii) heating copper with conc. H2SO4. It was found that in

each case sulphur and oxygen combined in the ratio of Na2O + H2O → 2NaOH
1 : 1. The data illustrates the law of :
To make 4g of NaOH, Na required is
(a) conservation of mass (b) multiple proportions
(a) 4.6g (b) 4.0g
(c) constant proportions (d) reciprocal proportions
(c) 2.3g (d) 0.23g
72. A sample of CaCO3 has Ca = 40%, C = 12% and O = 48%. If
the law of constant proportions is true, then the mass of Equivalent Concept
Ca in 5 g of CaCO3 from another source will be : 78. 2H3PO4 + 3 Ca(OH)2 → Ca3(PO4)2 + 6 H2O
(a) 2.0g (b) 0.2g
Equivalent weight of H3PO4 in this reaction is
(c) 0.02g (d) 20.0g
(a) 98 (b) 49

(c) 32.66 (d) 24.5

79. The Ew of H3PO4 in the reaction is 87. Normality of 0.74 g Ca(OH)2 in 5 mL solution is

Ca(OH)2 + H3 PO4 → CaH2PO4 + 2H2 (a) 8 N (b) 4 N

O(Ca = 40, P = 31, O = 16) (c) 0.4 N (d) 2 N
(a) 49 (b) 98 88. Normality of a 2 M sulphuric acid is
(c) 32.66 (d) 147 (a) 2 N (b) 4 N
80. What weight of a metal of equivalent weight 12 will give (c) N / 2 (d) N / 4
0.475 g of its chloride ?
89. 1 L of a normal solution is diluted to 2000 ml. The
(a) 0.12 g (b) 0.24 g resulting normality is :
(c) 0.36 g (d) 0.48 g (a) N / 2 (b) N/ 4
81. How many grams of phosphoric acid would be needed to (c) N (d) 2 N
neutralise 100 g of magnesium hydroxide ? (The molecular
90. What volume of 0.232 N solution contains 3.17
weights are : H3PO4 = 98 and Mg (OH)2 = 58.3)
milliequivalent of solute ?
(a) 66.7 g (b) 252 g
(a) 137 mL (b) 13.7 mL
(c) 112 g (d) 168 g
(c) 27.3 mL (d) 12.7 mL
82. 0.116 g of C4H4O4 (A) is neutralised by 0.074 g of Ca(OH)2.
Hence, protonic hydrogen (H+ ) in (A) will be 91. 1L solution of NaOH contains 4.0 g of it. What shall be
the difference between molarity and the normality ?
(a) 1 (b) 2
(c) 3 (d) 4 (a) 0.10 (b) zero

83. 4.2 g of metallic carbonate MCO3 was heated in a hard (c) 0.05 (d) 0.20
glass tube and CO2 evolved was found to have 1120 mL of
92. 100 ml of 0.3 N HCl is mixed with 200 ml of 0.6 N H2SO4. The
volume at STP. The EW of the metal is
final normality of the resulting solution will be
(a) 12 (b) 24
(a) 0.1 N (b) 0.2 N
(c) 18 (d) 15
84. 1.0 g of a monobasic acid when completely aceted upon (c) 0.3 N (d) 0.5 N
Mg gave 1.301 g of anhydrous Mg salt. Equivalent weight
of acid is 93. Normality of a mixture of 30 mL of 1N H2SO4 and 20 mL
of 4N H2SO4 is
(a) 35.54 (b) 36.54
(a) 1.0 N (b) 1.1 N
(c) 17.77 (d) 18.27
85. 0.1 g of metal combines with 46.6 mL of oxygen at STP. The (c) 2.0 N (d) 2.2 N
equivalent weight of metal is
94. Normality of solution obtained by mixing 10 mL of
(a) 12 (b) 24
1N HCl, 20 mL of 2N H2SO4 and 30 mL of 3N HNO3 is
(c) 6 (d) 36
(a) 1.11 N (b) 2.22 N
Normality
(c) 2.33 N (d) 3.33 N
86. When 100 ml of 1 M NaOH solution and 10 ml of 10 N
H2 SO4 solution are mixed together, the resulting solution (Use the Final volume as sum of all volumes).
will be

(a) alkaline (b) acidic

(c) strongly acidic (d) neutral