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Iupac (20M)

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\ r\/ U II 11\I VIJ'll;l l l.CI l'v \ U / , ,.... , v - u11111.1vt,.111c11v1 \V/ I.IIIIII.IVlVIU~IIC \ U / \111111,.

I VQIIIIIII~

17. CH 3-CH=CH-CeCH has IUPAC name :


(A) Pent-2-en-4-yne (B) Pent-4-yn-2-ene (C) Pent-1-yn-3-ene (0) Pent-3-en-1 -yne

CH~
18. The IUPAC name of the compound CH,-yH-CH2-?-CH3
OH OH
(A) 1, 1-0imethylbutane-1 ,3-diol (B) 1,3,3-Trimethylpropane-1.3-diol
(C) 2-Methylpentane-2,4-diol (0) 1,3,3-Trimethyl-1 ,3-propanediol

19. The IUPAC name of CH,-y=y - 9H-CH,-C: CH is


Cl CH3 C 2H,
(A) &-Chloro~ ethyl-6-methylhept-5 en -1-yne
(B) &-Chloro 4 ethyl-6-methylhept-1-yn-5-ene
(C) 2-Chloro-4 ethyl-3-methylhept-2~ne
(0) 2-Chloro4 ethyl-3-methylhep(-6--yn-2-ene

OH Br
I I
20. The correct name for the compound CH,-CH-CH,-CH,-CH-CHO
(A) 2-Bromo-5-hyaoxyhexanal (8) 1-Bromo-4-hydroxypentanal
(C) 2-Hyaoxy-5-bromohexanal (0) None of these

21. The IUPAC name of

Q c o N ~ is

(A) N-Cyclohexylbenzamide (B) N-Phenyl-N-cyclohexylmethanamide


(C) N-Phenylcyclohexanecarboxamide (0) N-Cyclohexenyt-N-phenylmethanamide
22. The correct structure for the compound Hept-3-en-5--yne -2-one is
0 0
II II
(A) HJC - CH = CH - C = C -C- CH, (B) HC .ce C - CH 2 - CH = CH - C - CH 3
0 0
II II
(C) H3C - HC = CH - CH = CH - C - CH 3 (D) H;C - C = C - CH = CH - C - CH3

23. IUPAC name oflho folio'Mng oompound C>-~ - N( CH, is :


CH3
(A) N, N-Dimethylcyclopropanecarboxamide (B) N-Methylcydopropanamide
(C) Cyclopropionamide (D) None of the above

24. The IUPAC name of the compound yH 2-yH""9H 2 is


CN CN CN
(A) 1,2,3-Tricyanopropane (B) 3-Cyanopentane-1,5-dinitrile
(C) Propane-1,2,3-tricarbonitrile (D) Propan-1 ,2,3-tricarbylamine.

25. The IUPAC name of OHC-CH=yH-CH-CH=CH2 is :


CH 2CH 2CH 2CH1
(A) ~Vinyloct-3-en-1-al (B) 3~utylhexa-2,5-dien-1-al
(C) ~Vinyloc~n-8-al (D) 3-Butyl-1,4-hexadien-6-al
2G. Indicate the wrongly named compound
(A) CH1-yH-CH2-CH2-CHO (4-Methyl-1;,entanal)
CH,
(B) CH)-yH-C::C-COOH (4-Methyl-2'1)8ntyn-1-oicacid)
CH 3
(C) CH 3CH2CH 2-CH-COOH (2-Methyl- 1;,entanoic acid)
I
CH3
0
(D) CH1CH 2-CH=CH.J!-eH 3 (3-Hexen~ne)

XI. Structural formula of 1,4-cyclohexanedione is


0

(A)o-0 (B) 0 - 0 - 0 0

28. The IUPAC name of CH3-Nt+-(CH2) 6 -NH-CH3 is


(A) N,N-dimethyl hexylamine (B) N-methyl, methyl hexylamine
(C) N,N'-dmethyl-1 ,6-hexanediamine (D) None of these
29. Structural formula of 2,5-<timethyl-2,3,4-hexatriene is
CHl yH3 fHl
I
(A) H,C = C - C = C = C = CH- CH3 (8) CH>- C C = = C = C - CH,

yH3
(C) CH 3-C=C=C=C=CH 2 (0) None of these
I
CH,

CH 3
I
30. IUPAC name of yH -yiH
2 2
is
HOOC CH 3COOH

(A) 3,3-dimethylpentanedioic acid (8) 1-carboxy-2,2-dlmethylbutanoic acid


(C) 1,3--dicarboxy-2,2-dimethylpropane (0) 4--carboxy-3,3-dimethylbutanoic acid

31. Structural formula of 3-vinyl-1 ,4--pentanediol is :

?H (8) yH 2- CH 2- yH-CH-CHa
(A) CH,-C~H2-yH-CH 20H
OH OH bH=CH2
CH=CH2

?H (0) None of these


(C) yH,-CH 2-yH-CH-CH3
OH CH=CH2

32. Which of the following compounds has wrong IUPAC name :


(A) CH3 - CH 2 -CH 2 - COO- CH 2CH3 ➔ Ethyl butanoate
(B) CH3- CH - CH2- CHO ➔ 3-Methylbutanal
I
CH 3

(C) CH3- CH - CH - CHl ➔ 2-Methyl-3-butanol


I I .
OH CH,

0
II
(0) CH, - CH - C - CH 2 - CH 3 ➔ 2-Methyl-3-pentanone
I
CH 3

33. The IUPAC name of the compound


HO
0 is

(A) 3, 3 - dimethyl - 1 - hydroxy cyclohexane (B) 1, 1 - dimethyl - 3 -hydroxy cyclohexane


(C) 3, 3 - dimethyl - 1 - cyclohexanol (0) 1, 1 - dimethyl - 3 - cyclohexanol

34. The IUPAC name of the compound shown below is .,,t..


UBr
(A) 2 - Brorno-6-chlorocyclohex-1-ene (B) 6-Bromo-2-chlorocyclohexene
(C) 3-Brorno-1 -chlorocyclohex -1-ene (0) 1-Bromo-3-chlorocyclohexene
35. The IUPAC n·ameof is :

(A) 5~5-Diethyl -4, 4-dimethylpentane (B) 3-Ethyl-4,4-dimethylheptane·


(C) 1, 1-0iethyl-2, 2-diinethylpentane .(0) 4, 4-Dimethyl-5, 5-diethylpentane
36. Name of some compounds are given . Which one is not in IUPAC system :
CH3
I
(A) CH3 - CH 2 - CH2 - 9H - CH - CH 2 - CH 3 3--Methyl 4 ethyl heptane
CH2CHa
(B) CH3- CH - CH - CH33--Methyl--2-butanol
I I
CH, OH
(C) CH3 - CH.2 -?i- rH - CH 9 2-Ethyl-~ethyl-but-1-ene
CH 2 CH3
(0) CH3 - C "' C - CH - CH34--Methyl-2-pentyne
l
CH 3

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