EXERCISE - I

Q.1 How many 1°carbon atom will be present in a simplest open chain hydrocarbon having two 3° and
one 2° carbon atom?
(A) 3 (B) 4 (C) 5 (D) 6

Q.2 Alicyclic compounds are

(A) Aromatic compounds (B) Aliphatic cyclic compounds
(C) Heterocyclic compounds (D) None of the above

*
Q.3 How many 1°, 2°, 3° C atoms does 1, 3, 5-Trimethyl cyclohexane have?
(A) 3, 6, 0 (B) 3, 4, 2 (C) 0, 3, 6 (D) 3, 3, 3

Q.4 The compound which has one isopropyl group is:

(A) 2,2,3,3-Tetramethyl pentane (B) 2,2-Dimethyl pentane
(C) 2,2,3-Trimethyl pentane (D) 2-Methyl pentane

Q.5 Which of the following is the first member of ester homologous series?
(A) Ethyl ethanoate (B) Methyl ethanoate
(C) Methyl methanoate (D) Ethyl methanoate

Q.6 A group closely related compounds which can be expressed by a general formula & in which two
conscutive members differ by 14 in their molecular masses is called
(A) a heterogeneous series (B) a homologous series
(C) a homogeneous series (D) a electrochemical series

Q.7 and

Number of secondary carbon atoms present in the above compounds are respectively:
(A) 6,4,5 (B) 4,5,6 (C) 5,4,6 (D) 6,2,1
Q.8 The molecular formula of the first member of the family of alkenynes and its name is given by the
set
(A) C3H6, Alkene (B) C5H6, Pent-1-en-3-yne
(C) C6H8, Hex-1-en-5-yne (D) C4H4, Butenyne
Q.9 Which of the following is a heterocyclic compound
HC = CH HC = COOH HC = CH HC = CH
(A) | S (B) | (C) | (D) |
HC = CH HC = COOH HC = CH HC = CH

CH 3 CH 3
| |
Q.10 The correct IUPAC name of the compound CH 3 - CH 2 - C = C - CH - C - CH 2 - CH 2 - CH 3 :
|
C2 H 5
(A) 5-Ethyl-3, 6-dimethyl non-3-ene (B) 5-Ethyl-4, 7-dimethyl non-3-ene
(C) 4-Methyl-5, 7-diethyl oct-2-ene (D) 2,4-Ethyl-5-methyl oct-2-ene

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Q.28 The IUPAC name of the given compound is:

(A) 1,1-Dimethyl-3-hydroxy cyclohexane (B) 3,3-Dimethyl-1-hydroxy cyclohexane

(C) 3,3-Dimethylcyclohexanol (D) 1,1-Dimethylcyclohexan-3-ol

Q.29 The IUPAC name of (C2H5)2 NCH 2CH.COOH is:

|
Cl
(A) 2-Chloro-4-N-ethylpentanoic acid (B) 2-Chloro-3-(N,N-diethyl amino)-propanoic acid
(C) 2-Chloro-2-oxo diethylamine (D) 2-Chloro-2-carboxy-N-ethyl ethane

Ph
|
Q.30 The IUPAC name of the compound is CH 3 - CH - CH - NH 2
|
CH 3
(A) 1-Amino-1-phenyl-2-methyl propane (B) 2-Methyl-1-phenyl propan-1-amine
(C) 2-Methyl-1-amino-1-phenyl propane (D) 1-Isopropyl-1-phenyl methyl amine

D
Q.31 Which of the following compound is wrongly named?
(A) CH 3CH 2CH 2CHCOOH ; 2-Chloro pentanoic acid
|
Cl

(B) CH 3C º CCHCOOH ; 2-Methyl hex-3-enoic acid

|
CH 3
(C) CH3CH2CH=CHCOCH3 ; Hex-3-en-2-one
(D) CH 3 - CHCH 2CH 2 CHO ; 4-Methyl pentanal
|
CH 3

Q.32 The correct IUPAC name of the following compound is:

O = C - CH 2 - CH - CHO
| |
OH H - C = O
(A) 3,3-Diformylpropanoic acid (B) 3-Formyl-4-oxo-butanoic acid
(C) 3,3-Dioxo propanoic acid (D) 3,3-Dicarbaldehyde propanoic acid
Q.33 The correct IUPAC name of compound:

CH 3 - CH 2 - C - CH - CHO
|| | is:
O CN
(A) 2-Cyano-3-oxopentanal (B) 2-Formyl-3-oxopentanenitrile
(C) 2-Cyanopentane-1,3-dione (D) 1,3-Dioxo-2-cyanopentane
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Q.34 IUPAC name of compound
CH2-CH3
CH3-CH-CH-CH3
CH2-CH3
(A) 2, 3-diethyl butane (B) 2-ethyl-3-methyl pentane
(C) 3-methyl-2-ethyl pentane (D) 3,4-dimethyl hexane

O CH 3
|| |

·
Q.35 The IUPAC name of compound CH 3 - C - CH - CH - CH - CH 3 is:
| |
CH 3 CHO

(A) 3,5-Dimethyl-4-Formyl pentanone (B) 1-Isopropyl-2-methyl-4-oxo butanal

(C) 2-Isopropyl-3-methyl-4-oxo pentanal (D) None of the above

HO - C = O CH 3
| |
Q.36 The IUPAC name of compound CH 3 - C = C — C - H is:
| |
NH 2 Cl

(A) 2-Amino-3-chloro-2-methylpent-2-enoic acid

(B) 3-Amino-4-chloro-2-methylpent-2-enoic acid
(C) 4-Amino-3-chloro-2-methylpent-2-enoic acid
(D) All of the above
Q.37 The IUPAC name of the structure is:
H 2 N - CH - CH - CHO
| |
HOOC COOH
(A) 3-Amino-2-formyl butane-1, 4-dioic acid
(B) 3-Amino-2, 3-dicarboxy propanal
(C) 2-Amino-3-formyl butane-1, 4-dioic acid
(D) 1-Amino-2-formyl succinic acid
Q.38 One among the following is the correct IUPAC name of the compound
H
|
CH 3CH 2 - N - CHO
(A) N-Formyl aminoethane (B) N-Ethyl formyl amine
(C) N-Ethyl methanamide (D) Ethylamino methanal

Q.39 The IUPAC name of the structure is:

(A) 1,2-Dimethyl-Cyclohexane (B) 1,6-Dimethyl-Cyclohexene

(C) 1,2-Dimethyl-Cyclohex-2-ene (D) 2,3-Dimethyl-Cyclohexane

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 EXERCISE - IV

Q.1 The IUPAC name of the compound having the formula is:
CH 3
|
H 3C - C - CH = CH 2
|
CH 3
(A) 3,3,3-trimethyl-1-propene (B) 1,1,1-trimethyl-2-propene
(C) 3,3-dimethyl-1-butene (D) 2,2-dimethyl-3-butene [JEE 1984]

Q.2 Write the IUPAC name of CH3CH2CH = CH · COOH [JEE 1986]

Q.3 The IUPAC name of the compound CH2=CH–CH(CH3)2 is:

(A) 1,1-dimethyl-2-propene (B) 3-methyl-1-butene
(C) 2-vinyl propane (D) None of the above [JEE 1987]

Q.4 The number of sigma and pi-bonds in 1-butene 3-yne are: [JEE 1989]
(A) 5 sigma and 5 pi (B) 7 sigma and 3 pi
(C) 8 sigma and 2 pi (D) 6 sigma and 4 pi

Q.5 Write I.U.P.A.C name of following:

(a) Me = methyl group [JEE 1990]

CH 3
|
(b) H 3C - N — CH - CH 2CH 3 [JEE 1991]
| |
CH 3 C 2 H 5

Q.6 Write IUPAC name of succinic acid. [JEE 1994]

Q.7 The IUPAC name of C6H5COCl is
(A) Benzoyl chloride (B) Benzene chloro ketone
(C) Benzene carbonyl chloride (D) Chloro phenyl ketone [JEE 2006]

·
Q.8 The IUPAC name of the following compound is
(A) 4-Bromo-3-cyanophenol
(B) 2-Bromo-5-hydroxybenzonitrile
Br
CN
[JEE 2009]

(C) 2-Cyano-4-hydroxybromobenzene
(D) 6-Bromo-3-hydroxybenzonitrile
OH
Q.9 The IUPAC name (s) of the following compound is (are) [JEE-2017]

(A) 4- methylchlorobenzene (B) 4-chlorotoluene

(C) 1-chloro-4-methylbenzene (D) 1-methyl-4-chlorobenzene
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10. What is the IUPA
AC name off the following compounnd? [JEE MAIN
N-2019]

(1) 3-Bromo-1, 2-dimethylbuut-1-ene

(2) 3-Bromo-3-m
methyl-1, 2-dimethylprop-1-ene
(3) 3-Bromo-3-m
methyl-1, 2-dimethylprop-1-ene
(4) 4-Bromo-3-m
methylpent-2-ene

·
11. me for the folllowing com
The IUPAC nam mpound is: [JEE MAIN
N-2019]

(1) 3,5-dimethyl-4-propylhept-6-en-1-yne (2) 3-m

methyl-4-(1- methylprop-2-ynyl)-1-heeptene
(3) 3,5-dimethyl-4-propylhept-1-en-6-yne (4) 3-m
methyl-4-(3- methylprop-1-enyl)-1-heeptyne

12. The IUPAC nam

me of the folll JEE MAIN
N-2019]
CH3 OH
H3C CH CH CH2 COOH

(1) 4-Methy 1-3-hydroxypenntanoic (2) 2-M

Methy 1-3-hydroxypentann-5-oic acid
(3) 4,4-Dimethyl 1-3-hydroxxybutanoic acid (4) 3-H
Hydroxy-4-methylpentannoic acid

13. The correct IUPA

AC name off the followinng compound is: [JEE MAIN
N-2019]
NO2

Cl
CH3
(1) 2-methy 1-5--nitrol-1-chlooro benzene (2) 3-chloro-4-methhyl-1-nitro benzene
(3) 5-chloro-4-m
methyl-1-nitrro benzene (4) 2-chhloro-1-methhyl-4-nitro benzene

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 EXERCISE-I
Q.1 The compounds C2H5OC2H5 and CH3OCH2CH2CH3 are
(A) Chain isomers (B) Geometrical isomers
(C) Metamers (D) Conformational isomers

Q.2 The number of primary, secondary and tertiary amines possible with the molecular formula C3H9N
respectively.
(A) 1, 2, 2 (B) 1, 2, 1 (C) 2, 1, 1 (D) 3, 0, 1

*
Q.3 How many benzenoid aromatic isomers shown by C7H7Cl ?
(A) 4 (B) 3 (C) 5 (D) 6

↓
Q.4 Molecular formula C3H6Br2 can have:
(A) Two gem dibromide (B) Three vic dibromide
(C) Two tert.- dibromo alkane (D) Two sec.-dibromo alkane

·
Q.5 Following compounds are :

Br COOH COOH Br

HOOC Br Br COOH

(A) Position isomer (B) Chain isomer (C) Geometrical isomer (D) Functional isomer

Q.6 Which of the following is incorrect relation :

Me
Pr Pr
(A) & identical
Me

Me Et
(B) & positional isomers
Pr Pr

Et Et
(C) & positional isomers
Pr
Pr

Me
Me
Et
(D) & homologues
Pr

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D
Q.7 Select whether given realationship is true or false?
COOH
OCOH
& functional isomer

OMe OEt
Et
& metamers
Me

CH2 – CH2 – OH CH2 – O – CH3

& metamers

Me – N – Me CH2 – NH – CH3

& functional isomers

(A) TFTF (B) FTTF (C) TTFT (D) TFFT

·Q.8 Following compounds are :

O O
Cl C—O C—O Cl
H CH3
C=C C=C
H CH3 H H
(A) Functional isomer (B) Geometrical isomer
(C) Metamer (D) Position isomer

Q.9 The type of isomerism observed in urea molecule is

(A) Chain (B) Position (C) Geometrical (D) Functional

Q.10 How many minimum no. of C-atoms are required for position & geometrical isomerism in alkene?
(A) 4, 3 (B) 4, 4 (C) 3, 4 (D) 3, 3

Q.11 Which of the following cannot be written in an isomeric form?

(A) CH3–CH(OH)–CH2–CH3 (B) CH3–CHO
(C) CH2=CH–Cl (D) Cl–CH2CH2–Cl
Q.12 Given compound shows which type of isomerism
O O
S—O and S—O
O O
(A) Chain isomerism (B) Positional isomerism
(C) Metamerism (D) Functional group isomerism
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Q.13 Which of the following involves Diad system for prototropy :
O

(A) CH3COCH3 (B) CH3CH2NO2 (C) (D) HCN

·
Q.14 Which of the following does not show geometrical isomerism?
(A) 1, 2-dichloro-1-pentene (B) 1, 3-dichloro-2-pentene
(C) 1, 1-dichloro-1-pentene (D) 1, 4-dichloro-2-pentene

Q.15 What characteristic is the best common to both cis-2-butene and trans-2-butene?
(A) Boiling point (B) Dipole moment
(C) Heat of hydrogenation (D) Product of hydrogenation

Q.16 The number of cis-trans isomer possible for the following compound

(A) 2 (B) 4 (C) 6 (D) 8

Q.17 Which of the following have zero dipole moment?

(A) benzene 1,4- diol (B) trans-1,2-dichloro ethene
(C) cis-1,2-dichloro ethene (D) 1,1-dichloro ethene

Q.18 Which of the following will not show geometrical isomerism.

Me Me
(A) (B) (C) Cl (D)
Me

Q.19 Geometrical isomerism is possible in:

(A) isobutene (B) acetone oxime
(C) acetophenone oxime (D) benzophenone oxime

Q.20 How many structural isomers of C5H10 are possible.

(A) 10 (B) 11 (C) 12 (D) 13
Q.21 The number of isomers of dibromoderivative of an alkene (molar mass 186 g mol–1) is
(A) 2 (B) 3 (C) 4 (D) 6
Q.22 How many structural isomeric primary amines are possible for the formula C4H11N?
(A) 2 (B) 3 (C) 4 (D) 5
Q.23 For the given compound, choose the incorrect option ?
O
CH3–CH=CH–C–CH3
(A) It can show both geometrical isomerism & tautomerism.
(B) It has all types of permanent electronic displacement effect present.
(C) It has IUPAC name "Pent-2-en-4-one."
(D) On treatment with NaOD/D2O for long time, it has 7 deuterium in its enol form

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 Q.30 Decreasing order of enol content of the following compound in liquid phase
O O O O
|| || || ||
(a) CH 3  C  CH 2  C  O  Et (b) CH 3  C  CH 2  C  CH 3

O
O O
|| ||
(c) Ph  C  CH 2  C  Ph (d)
(A) a > b > c > d (B) c > b > a > d (C) c > b > d > a (D) b > c > a > d

·
Q.31 What is the correct IUPAC name of the following compound

(A) 2E, 4E, 6Z 4-methyl octa-2, 4, 6 triene (B) 2E, 4Z, 6Z 5-methyl octa-2, 4, 6 triene
(C) 2Z, 4Z, 6Z 5-methyl octa-2, 4, 6 triene (D) 2E, 4Z, 6E 4-methyl octa-2, 4, 6 triene
Q.32 The IUPAC name of the given compound is
H CH3

H3C H
(A) 2, 4-di[(E)-ethylidene] cyclobutane (B) 1, 3-di-[(E)-ethylidene] cyclobutane
(C) 1, 4-di-E-ethyldenecyclobutane (D) (E)-1, 4-diethylidenecyclobutane
Q.33 Which of the following will show geometrical isomerism.
Me Br
Me
(A) (B) (C) (D)
Br
Br Me

Q.34 Total number of geometrical isomer of following compound is:

(A) 2 (B) 3 (C) 4 (D) 5

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Q.32 Column I Column II
Compound Number of geometrical isomers

(A) (P) 2

(B)
X (Q) 4

(C) (R) 6

(D) (S) 8

1 :
A- (P) ; B- (p) ; c
-
(S) ; D- (5)
.
2 A- (P) ; B- (s) ; c - (P) ; D- (S)
3 . A -
(p) ; B- (P) :
c- (S) : D- (P)

y .
A -
(S) ; B
-
(S) ; c- 15) ; D- (P)

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