14-07-2024

6001CJA10100124006 JA

PHYSICS

SECTION-I

1) A projectile is fired at an angle with the horizontal. Find the condition under which it
lands perpendicular on an inclined plane of inclination as shown in figure.

(A)
(B)
(C)
(D)

2) A ball is hit by a batsman at an angle of 30o as shown in figure. The man standing at P should run
at what minimum speed so that he catches the ball before it strikes the ground. Assume that height
of man is negligible in comparison to maximum height of projectile. [Take g = 10 m/s2]

(A) 3 ms–1
(B) 5 ms–1
(C) 6 ms–1
(D) 9 ms–1

3) A ball is thrown from the ground to clear a wall 3 m high at a distance of 6 m and falls 12 m away
from the wall, the angle of projection of ball is

(A)

(B)

(C)
(D)

4) A ball is projected from point A with a velocity 10 m/s perpendicular to the inclined plane as
shown in figure. Range of the ball on the inclined plane is : (Take g = 10m/s2)

(A)

(B) 40 m
(C)

(D)

5) A bird is flying towards south with a velocity 40 km/h and a train is moving with a velocity 40
km/h towards east. What is the velocity of train with respect to bird ?

(A) km/h. North - East

(B) km/h. South - East
(C) km/h. South - West
(D) km/h. North - West

6) Two ships A and B are 10 km apart on a line running south to north. Ship A (which is farther
north) is streaming west at 20 km/h and ship B is streaming north at 20 km/h. What is their distance
of closest approach?

(A) 5 km

(B)

(C)
(D) 8 km

7) A car A is going north east at 80 kmph and another car B is going south east with a velocity of 60
kmph. The velocity of A relative to B makes an angle with the east equal to

(A)

(B)

(C)

(D)
8) A man when standstill observes the rain falling vertically and when he walks at 4 km/h he has to
hold his umbrella at an angle of 53o from the horizontal. Find speed of the raindrops.

(A) 3 kmph
(B) 4 kmph
(C) 5 kmph
(D) 16/3 kmph

9) Three blocks A, B and C are vertically stacked at rest as shown in the figure. Magnitude of contact
force between blocks B and C will be equal to: [Take g = 10 m/s2]

(A) 70 N
(B) 50 N
(C) 30 N
(D) 20 N

10) A system of 2 blocks is shown. String AB is massless but CD has a mass of 20 kg. Find tension in
string AB. [Take g = 10 m/s2]

(A) 150 N
(B) 200 N
(C) 300 N
(D) 400 N

11) Two masses m and M are attached with strings as shown. For the system to be in equilibrium we
have
(A)

(B)

(C)

(D)

12) Rod B of mass m placed on smooth surface and connected with light string as shown in figure.
Find correct F.B.D. of rod

(A)

(B)
(C)

(D)

13) A gun is fitted on platform moving with velocity . A bullet is fired from the gun with

velocity with respect to the platform. Then the horizontal range of projectile,
seen from ground is

(A) 120 m
(B) 160 m
(C) 200 m
(D) 240 m

14) A box of mass m rests on a smooth slope with help of a thread as shown in the figure. The thread
is parallel to the incline plane.

Find normal force on the block.

(A)
(B)
(C)
(D)

15) Find magnitude of force exerted by string on pulley. [Take g = 10 m/s2]

(A) 40 N
(B) 400 N
(C)
(D) 800 N

16) A person standing at rest on the escalator takes time t1 to reach the top of a tower when the
escalator is moving. He takes time t2 to reach the top of the tower when the escalator is at rest .
How long will he take if he walks up a moving escalator?

(A) t2 – t1
(B) t1 + t2
(C) t1t2/(t1 - t2)
(D) t1t2/(t1 + t2)

17) Statement-I: A man can cross the river of width d in minimum time t. On increasing river
velocity, minimum time to cross the river by man will remain unchanged.
because
Statement-II : Velocity of river is perpendicular to width of river. So minimum time to cross the
river is independent of velocity of river.

(A) Statement-I is true, Statement-II is true ; Statement-II is correct explanation for Statement-I.
Statement-I is true, Statement-II is true ; Statement-II is NOT a correct explanation for
(B)
statement-I.
(C) Statement-I is true, Statement-II is false.
(D) Statement-I is false, Statement-II is true.

18) A boat which has a speed of 5 km/h in still water crosses a river of width 1 km along the shortest
possible path in 15 min. The speed of the water in km/h is

(A) 1 kmph
(B) 3 kmph
(C) 4 kmph
(D) kmph

19) A particle is projected at an angle to the horizontal, up and down a plane, inclined at an
angle to the horizontal.
If the ratio of time of flights be 1 : 2, then the ratio is.

(A) 2
(B) 3

(C)

(D)

20) Two stones A and B are projected simultaneously as shown in figure. It has been observed that
both the stones reach the ground at the same place after 7 seconds of their projection. Determine
difference in their vertical components of initial velocities in m/s. (g = 9.8 m/s²)

(A) 7 m/s
(B) 12 m/s
(C) 14 m/s
(D) 21 m/s

SECTION-II

1) A ball is thrown upwards at an angle of 60° to the horizontal. It falls on the ground at a distance
of 90 m. If the ball is thrown with the same initial speed at an angle 30o to horizontal, it will fall on
the ground at a distance of ______ m.

2) Three forces acting on a body is in equilibrium.

Find value of (a+b+c) in newton

3) A particle is moving along the x-axis with its coordinate with the time 't' given by x(t) = 10 + 8t -
3t2 meters. Another particle is moving along the y-axis with its coordinate as a function of time given
by y(t) 5–8t3m. At t = 1s, the speed of the second particle as measured in the frame of the first
particle is given as m/s. Find n.

4) A passenger train of length 60m travels at a speed of 80 km/hr. Another freight train of length
120 m travels at a speed of 30 km/hr. The ratio of times taken by the passenger train to completely
cross the freight train when : (i) they are moving in the same direction, and (ii) in the opposite
directions, is :

5) 'A' moves with constant velocity 5 m/s along the 'x' axis. B always has velocity towards A. After
how much time (in seconds) will B meet A if B moves with constant speed of 10 m/s. The initial
separation is 7.5 m.

6) Three particles A, B and C are situated at the vertices of an equilateral triangle ABC of side a at t
= 0. Each of the particles moves with constant speed v. A always has its velocity along AB, B along
BC and C along CA. At what time (in seconds) will the particles meet if v = 10 m/s and a = 15 m.

7) In the figure shown, the two projectiles are fired simultaneously. If the initial speed of the left side

projectile for the two projectiles to hit in the mid-air is , find a+b (a and b are co-prime).

8) An airplane moving horizontally with a speed of 180 kmph drops a food packet while flying at a
height of 490m. The horizontal range (in m) of the food packet is (g = 9.8 m/s2)

9) An object is projected in the air with initial velocity u at an angle . The projectile motion is such
that the horizontal range R, is maximum. Another object is projected in the air with a horizontal
range half of the range of first object. The initial speed remains same in both the case. The value of
such maximum angle of projection with horizontal, at which the second object is projected, will be
________ degree.
10) A person can throw a ball upto a maximum range of 100 m. How high above the ground he can
throw the same ball (in meters)?

CHEMISTRY

SECTION-I

1) The correct order of the ionic radii of and is :

(A)
(B)
(C)
(D)

2) The correct order of electron affinity is :

(A) O > F > Cl

(B) F > O > Cl
(C) F > Cl > O
(D) Cl > F > O

3) The electronic configuration with the highest ionization enthalpy is :

(A)
(B)
(C)
(D)

4) In general, the property (magnitudes only) that shows an opposite trend in comparison to other
properties across a period is :

(A) Ionization enthalpy

(B) Electronegativity
(C) Electron gain enthalpy
(D) Atomic radius

5) The hybridization of carbon atoms in C — C single bond of is:

(A) sp3 – sp3

(B) sp2 – sp3
(C) sp – sp2
(D) sp3 – sp
6) The electronegativities of the P, Q, R, S and T are given below
P Q R S T
0.7 1.1 1.6 2.5 1.7
Which of the following bonds has the most ionic character ?

(A) P-S
(B) P-Q
(C) R-S
(D) T-S

7) Lattice energy of an ionic compound depends upon

(A) Charge on the ion only

(B) Size of the ion only
(C) Packing of the ion only
(D) Charge and size of the ion

8) The IUPAC symbol for the element with atomic number 119 would be :

(A) uue
(B) une
(C) unh
(D) uun

9) The compound that has the largest bond angle is :

(A) H2O
(B) NH3
(C) H2S
(D) CH4

10) The second ionisation potentials in electron volts of oxygen and fluorine atoms are respectively
given by :

(A) 35.1, 38.3

(B) 38.3, 38.3
(C) 38.3, 35.1
(D) 35.1, 35.1

11) Which of the following order is correct for acidic property ?

(A)
(B)
(C)
(D)
12) The electronegativities of F and H are 4.0 and 2.1 respectively. The percent ionic character in H
and F bond is

(A) 43
(B) 34
(C) 94
(D) 39

13) Which will have the maximum value of electron affinity [x, y and z respectively are
0, and ]

(A) Ox
(B) Oy
(C) Oz
(D) All have equal

14) Following graph shows variation of ionization energies with atomic number in second period

. Value of ionization energies of Na(11) will be :

(A) Above Ne
(B) Below Ne but above O
(C) Below Li
(D) Between N and O

15) Set of elements having one electron in their valence shell are :

(A) Cl, Br, I

(B) Na, Mg, Al
(C) B, Al, Ga
(D) K, Rb, Cs

16) In the process is

(A) Positive
(B) Negative
(C) Zero
(D) None

17) Which of the following electronic configurations in the outermost shell is characteristic of alkali
metals ?

(A)
(B)
(C)
(D)

18) Electrovalent bond or ionic bond is formed by :

(A) Sharing of electrons

(B) Donation of electrons
(C) Transfer of electrons
(D) None of these

19) For a diatomic molecule, which of the following combination of orbitals does not form covalent
bond (x-axis is internuclear axis) ?

(A)
(B)
(C)
(D)

20) Descending order of electronegativity of sp3, sp2 & sp hybridised orbitals

(A) sp2, sp, sp3

(B) sp3, sp2, sp
(C) sp, sp2, sp3
(D) sp, sp3, sp2

SECTION-II

1) The atomic number of Unnilunium is ________.

2) Total number of lone pair of electrons in ion is :

3) Assuming Z-axis as molecular axis, lable the molecular orbitals formed by the following
combination of atomic orbitals :
(i) 1s + 1s (ii)
(iii) (iv) 2s + 2s
(v)
How many will form σ bond.
4) In a triple bond there is sharing of ________ electrons.

5) In cation of XeF6(s) total number of orbitals of Xe involved in hybridisation is :

6) The electronic configuration of an element is . The difference in atomic number

and the group number of the element 'X', which is just below the above element in the periodic table
is (Consider IUPAC group no)

7) If there were 10 periods in the periodic table then how many elements would this period can
maximum comprise of

8) In which of the given species central atom is sp3 hybridized ?

9) Among the given species, how many species have maximum '3' atoms lying in a plane ? BeCl2,
SO2, SF2, XeOF4, XeO3F2, IF7

10) Total number of covalent bonds in C3O2 is _____

MATHEMATICS

SECTION-I

1) Number of integral values of x satisfying

4cos2x – 8cosx + 3 > 0, 0 < x < 2π is:

(A) 2
(B) 3
(C) 4
(D) 5

2) The number of integral values of x satisfying

2sin2x – 3sinx + 1 ≥ 0, in the interval [0,2π] is :

(A) 0
(B) 1
(C) 5
(D) 3

3) If sinα and cosα are the roots of the equation

ax2 + bx + c = 0 then which of the following is true :
(A) a2 – b2 + 2ac = 0
(B) a2 + b2 + 2ac = 0
(C) a2 – b2 – 2ac = 0
(D) a2 + b2 –2ac = 0

4) The complete set of values of x lying in first quadrant and satisfying the

inequality is :

(A)

(B)

(C)

(D)

5) If , then
number of solutions belonging to (0, π) is:

(A) 2
(B) 3
(C) 4
(D) 5

6) The general solution of the equation

4cos2x + 6sin2x = 5 is

(A)
,n∈I

(B)
,n∈I

(C)
,n∈I
(D) nπ, n ∈ I

7) The number of solutions of the equation

in the interval is:

(A) 1
(B) 2
(C) 3
(D) 0

8) Total number of solutions of sinx.tan4x = cosx belonging to (0, π) are

(A) 4
(B) 7
(C) 8
(D) 5

9) If sum of solutions in [0, 3π] of the trigonometric equation cosecθ = 1 + cotθ is kπ, then the value
of k is

(A) 1
(B) 2
(C) 3
(D) 5

10) If are the roots of the equation , then the equation whose roots are is

(A)
(B)
(C)
(D)

11) The number of roots of the equation

in the interval [0, π] is equal to

(A) 8
(B) 2
(C) 4
(D) 0

12) Sachin and Rahul attempted to solve a quadratic equation. Sachin made a mistake in writing
down the constant term and ended up in roots(4, 3). Rahul made a mistake in writing down
coefficient of x to get roots (3, 2). The correct roots of equation are:

(A)
(B) 6, 1
(C) 4, 3
(D) –6, –1

13) The value of k for which the equation has both roots real, distinct and
negative is

(A) 4
(B) 3
(C) 6
(D) 1
14) Let Then number of equation of the form , having real roots,
is

(A) 15
(B) 9
(C) 7
(D) 8

15) A quadratic equation with rational coefficients one of whose roots is is

(A)
(B)
(C)
(D)

16) Let be the roots , with . If for , then the value of

is

(A) 1
(B) 2
(C) 6
(D) 4

17) The value of 'a' for which one root of the quadratic
equation is twice as large as the other is

(A)

(B)

(C)

(D)

18) If are the roots of the quadratic equation,

then is equal to:

(A)

(B)
(C)

(D)

19) If be two real roots of the equation ,

where and are real numbers. If then the value of is:

(A) 5
(B) 100
(C)
(D)

20) The principal solution set of the equation

is

(A)

(B)

(C)

(D)

SECTION-II

1) If α, β are the roots of x2 – 2kx + 6 = 0 such that α2 + β2 = 4, then the value of k2 is

2) If α & β are roots of the equation 2x2 + 6x – 5 = 0, then the value of is

3) If α and β are the roots of the equation x2 – x – 1 = 0 and the value of α4 + β4 is λ, then is equal
to

4)

The number of values of 'a' for which

is an identity in x is

5)
The number of solutions of the equation

cos2x + sin x = in the interval , is

6) Number of solutions of the equation

tan 2x = cot x , 0 ≤ x ≤ 2π, is

7) The sum of all real values of x satisfying the equation is:

8) Let be two real numbers such that .

Let and for some integer . Then, the value of is ______.

9) Let be in R. If are the roots of the equation , and are the

roots of equation , then is equal to _______.

10) If the quadratic equation x2 – (k + 4)x + = 0 has equal roots, then the value of

is
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D C D C A C B D A D A A C B C D A B C C

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 90.00 0.00 580.00 2.20 1.00 1.00 5.00 500.00 75.00 50.00

CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. C D C D C A D A D C D A A C D B C C A C

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 101.00 9.00 3.00 6.00 6.00 18.00 72.00 4.00 3.00 8.00

MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. C C A B B B D D C D C B B C C C D D B A

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 4.00 19.80 1.40 1.00 8.00 6.00 3.00 324.00 18.00 3.50
 SOLUTIONS

PHYSICS

1)

2)

3)

4)

5)

6)
 7)

8)

9)

10)

11)

12)

Normal force is perpendicular to the rod.

13)

The horizontal velocity of the particle in ground frame will be

ux=10+40=50m/s
Initial vertical velocity in ground frame will be uy=20+0=20m/s
so time of light will be
the horizontal distance covered in this interval or the range will be
R=ux × T = 50 × 4 = 200 m

14)

15)

16)

17)

18)
 19)

20)

21)

90.00 range is same when

22)

a=5
b=1
c = –6

23)

24) Let v1 and v2 be the velocity of passenger train and freight train respectively.
Let t1 and t2 be the time taken by the passenger train to completely cross the freight train
when they are moving in the same direction and when they are moving in the opposite
direction respectively.
When trains are moving in same direction releative speed = |v1−v2| and in opposite direction
relative speed = |v1+v2|
Hence, ratio of time when trains move in same direction with time and when trains move in
opposite direction is
25)

26)

27)

28)

29)

30)
CHEMISTRY

31)

All are isoelectronic species, so more is the Zeff less will be the ionic size
Correct order of ionic radii is

32)

On moving from left to right across a period, the electron affinity becomes more negative. On
moving from top to bottom in a group, the electron affinity becomes less negative.
Chlorine has exceptionally more negative electron affinity than fluorine, because adding an electron
to fluorine (2p orbital) causes greater repulsion than adding an electron to chlorine (3p orbital )
which is larger in size.

33)

The smaller the atomic size, larger is the value of IP.

Further the atoms having half filled or fully filled orbitals are comparatively more stable, hence more
energy is required to remove the electron from such atoms.

34)

On moving left to right along a period in the periodic table atomic radius decreases while
electronegativity, electron gain enthalpy and ionisation enthalpy increases, along a period.

35)

36)

Ionic character Difference in En.

37)

The value of lattice energy depends on the charges present on the two ions and the distance
between them.

Lattice energy where = Inter-ionic Distance.

Lattice energy
⇒ charge on cation in terms electronic charge.
⇒ charge on anion in terms electronic charge.

38) Symbol for 1 is u and for 9 is e.

 ∴ IUPAC symbol for 119 is uue.

39)

(sp3 with 2 lone pair at O)

(sp3 with 1 lone pair at N)

(sp3 with 2 lone pair at O)

Lone pair-bond pair repulsion in H2S will increase because 'S' has lower electronegativity than 'O'.
So there will be lesser electron density on 'S' and thus bond angle will be smaller than
H2O.

40)

41)

The acidic character of hydrides increase in a period from left to right and also increases when we
move down in a group from top to bottom.

42)

% ionic character

43)

Being neutral atom oxygen will have higher electron affinity as there is electrostatic repulsion
between additional electron and negative ion in case of and .
So option (A) is correct.

44)

Na is 3rd period element and is larger than Li .

Thus the outer most electron is loosely bounded with nucleus and removal of electron is easier.
So option (C) is correct.

45)

Conceptual

46)

Conceptual

47)

Conceptual

48)

Conceptual
 49)

50)

Electron negativity % s-character.

51)

IUPAC symbol = Unu

Atomic number (Z) = 101

52)

Total number of lone pair of electrons is 9.

53)
 54)

Conceptual

55)

sp3d2

56)

In p-block:
Group number
= Number of valence electrons + 10
= (2+4) + 10 = 6 + 10 = 16
Atomic number
= Number of electrons in electronic configuration
= 2 + 2 + 6 + 2+ 4 = 16 (i.e. sulphur)
But an element 'X' is first below the above element.
So, group number will be the same,
i.e., 16 and atomic number = 16 + 18 = 34
So, X is Selenium (Se) with atomic number
= 34 and group number = 16

57)

No. of elements in a period is calculated by the formula :

If the period no. is even, no. of elements

and if the period no. is odd, no of elements

Given, Number of period =10
n = 10 (even)
Number of element in 10th period

58)

59)

Max.
Number
of atoms

BeCl2 3
SO2 3

SF2 3

XeOF4 4

IF7 6

XeO3F2 4

60)

MATHEMATICS

61) (2cosx – 3)(2cosx –1) > 0

62) 2sin2x – 3sinx + 1 ≥ 0

(2sinx – 1)(sinx – 1) ≥ 0

63) sinα and cosα are the roots of ax2 + bx + c = 0

and

64)

(B)

65)
As
On solving
3tan3x = 3
or tan3x = 1

⇒ in (0, π)

66)

67)

68)

sinxtan4x = cosx
cos5x = 0

⇒
So 5 solutions

69)

∵ cosecθ = 1 +

⇒ sinθ + cosθ = 1 ; sinθ ≠ 0

or θ = 2nπ

θ = 0, 2π (reject)

70)

Required Q.E ⇒
 71)

Let

t2 – 30+ + 81 = 0
t = 27 t = 3

4sin2x = 3 4sin2x = 1

72)

If α and β are roots of a quadratic equation, the equation is (x−α)(x−β)=0

So according to Sachin, the equation is (x−4)(x−3)=0⇒x2−7x+12=0
And according to Rahul, the equation is (x−3)(x−2)=0⇒x2−5x+6=0
Since Sachin made a mistake in writing the constant term, so the correct constant term must be +6
And Rahul made a mistake in writing the coefficient of x so the correct coefficient of x must be -7
Therefore, the quadratic equation is x2−7x+6⇒(x−1)(x−6)=0
So its roots are 1 and 6 i.e. Option (B) is correct.

73) As we know that, for a quadratic equation ax2 + bx + c = 0 if the discriminant D > 0 then
roots are real and distinct.
Here, a = k – 2, b = 8 and c = k + 4
⇒ 64 – 4 (k – 2) (k + 4) > 0
⇒ 16 – k2 – 2k + 8 > 0
⇒ k2 + 2k – 24 < 0
⇒ (k + 6) (k – 4) < 0

For both the roots to be negative

Now from (1) and (2), we get

Hence, Option C is the correct answer.
74) Given equation is px2 + qx + 1 =0
For real roots, discriminant 0.
Thus
For p = 1,
For p = 2,
For p = 3,
For p = 4,
Thus, total seven solutions are possible.
Hence, 7 equations can be form px2 + qx + 1 = 0 has real roots.

75)

76)

77)

...(i)

....(ii)

From (i) and (ii)

78)
 79)

80)

---- (1)

or

81)

(α + β)2 – 2αβ = 4
4k2 – 12 = 4 ⇒ k2 = 4

82)

2x2 + 6x – 5 = 0
 83)

α + β = 1, αβ = –1
α2 + β2 = (α + β)2 – 2αβ = 1 + 2 = 3
λ = α4 + β4 = (α2 + β2)2 – 2(αβ)2 = 9 – 2 = 7

84)

only for a = 2 all the co-efficients become zero.

85) 1 – sin2x + sinx =

⇒ 9sin2x – 9sinx + 2 = 0

⇒
So, there are four principal solutions
in .

86)

tan2x = ⇒ tan x = or –

⇒
⇒ 6 solutions

87) If
If
Also

88)
Pn = 18

89)

90)

∴D=0

⇒ (k + 4)2 – 4.1. =0
⇒ –2k2 + 8k – 8 = 0
⇒ –2(k – 2)2 = 0
⇒k=2

So, = 3.5