MCQ - D04 Oct 2024
MCQ - D04 Oct 2024
MCQ - D04 Oct 2024
9. ) Which will be the final product by reaction of formaldehyde with ethyl magnesium bromide ?
(A) propane-l-ol (B) propane-2-o
(C) butane-2-ol (D) 2-methyl propane-2-ol
10. ) Under identical condition, which of the following has highest boiling point ?
(A) Propan-1-ol (B) Butan-1-ol (C) 2-Methylpropan-2-ol (D) Butan-2-ol
11. ) Which product is obtained by oxidation of phenol with chromic acid ?
(A) Benzene (B) Benzoic acid (C) Benzoquinone (D) Acetophenone
12. ) Reduction of which compound gives 2° alcohol ?
(A) Acetaldehyde (B) Acetic acid (C) Acetone (D) Ethyl acetate
13. ) How many chiral carbons are in pentan-2, 3, 4-triol ?
(A) 3 (B) 4 (C) 1 (D) 2
14. ) What is the product of Riemer-Temann reaction ?
(A) Salicylic acid (B) Benzoquinone (C) Salicylaldehyde (D) Picric acid
15. ) Which of the following has highest value of pKa ?
(A) m-nitro phenol (B) p-nitrophenol (C) phenol (D) p-cresol
16. ) From which of the following organic compounds phenol can not be prepared ?
(A) Isopropyl benzene (B) Benzene sulphonic acid
(C) Chloro benzene (D) Toluene
) From which of the following organic compounds phenol can not be prepared ?
(A) Isopropyl benzene (B) Benzene sulphonic acid
(C) Chloro benzene (D) Toluene
17. ) Which one would be useful to distinguish between phenol and ethanol ?
(A) Sodium metal (B) Anhydrous ZnCl2 + Conc. HCl
(C) Neutral FeCl3 (D) All of them
18. ) Which of the following compound does not contain phenolic “–OH” group in it ?
OH OH CH2OH CH3
OH
(A) (B) (C) (D)
OH
19. ) Which product is obtained when one mole of ether (R–O–R) is reacted with one mole of HX ?
(A) Only R – X (B) Only R – OH (C) R – X + R – OH (D) 2R – X + H2O
23. ) By which of the following reactions, ether compound will be obtained easily ?
(A) (CH 3)3CONa + CH3Cl ® (B) (CH3)3CONa + (CH3)3C – Cl ®
(C) (CH3)3CONa + (CH3)2CHCl ® (D) (CH3)2CHONa + (CH3)2CHCl ®
24. ) How much litres of dihydrogen gas will be produced at STP in the reaction of ethanol with 12 gram
of Mg ? (Mg = 24 gram/mol)
(A) 11.2 litre (B) 2.24 litre (C) 22.4 litre (D) 5.6 litre
Cu / 573 K
197) Substance A ¾¾¾¾¾¾
25. ® isobutlyene, which is the structural formula of the substance A in
thisreaction?
(A) CH3CH2CH2CH2 – OH (B) CH3CH(CH3)CH2OH
(C) CH3CH(OH)CH2CH3 (D) (CH3)3C – OH
26. ) Which of the following substance does not produce tri-iodomethane with the mixture of alkali and
I2 ?
(A) Propan-1-ol (B) Ethanol (C) Dimethyl ketone (D) Ethanal
27. ) Give the IUPAC name of the product obtained when phenol is oxidized by chromic acid (Na2Cr2O7
+ Conc. H2SO4)
(A) Cyclohexa-2,5-diene-1,4-dione (B) Cyclohexa-1,4-dione
(C) Cyclohexanone (D) Cyclohexa-1,4-diene-2,5-dione
28. ) Name the product obtained by the following reaction ?
(BH3 )2
CH3 – CH2 – CH2 – CH = CH2 ¾¾¾¾¾¾ +
®?
H2 O2/OH
(A) Pentan-3-ol (B) Pentan-2-ol
(C) Pentan-1-ol (D) 2-methyl butan-2-ol
29. ) Identify Pyridinium chlorochromate from the following :
+ – + – + – + –
(A) NHCrO3Cl (B) NHCrO2Cl (C) NCrO3Cl (D) NH 2CrO3Cl
(i) CH 3 Mg1
(II) CH3CHO ¾¾¾¾¾¾(ii) H2O
®
(i) CH 3MgI
(III) HCHO ¾¾¾¾¾¾ ®
(ii) H2O
Hydrolysis
(IV) 2 - Chloropropane ¾¾¾¾¾¾
Aq. NaOH
®
(A) (I) & (II) (B) (II) & (IV) (C) (II) & (III) (D) (I), (II) & (IV)
Hydro-
Reduction Dehydration
191) ¾¾¾¾¾
31. P ® Q¾¾¾¾¾¾¾
¾ ® R¾¾¾¾¾¾® S What is P, Q, R, S ?
chlorination
33. ) Which of the following pair gets converted into alcohol by reduction ?
(A) Acetic acid and acetaldehyde (B) Ethyl benzoate and benzoic acid
(C) Chloro ethane (D) (A) and (B) both
34. ) Which of the following alcohol is most reactive with HCl in presence of anhydrous Zinc chloride
at room temperature ?
(A) CH 3 – CH2 – CH2 – OH (B) (CH3)3 – C – OH
(C) (CH3)3 – C – CH2OH (D) (CH3)2 CH – OH
(A) (1) ® (e), (2) ® (b), (3) ® (a), (4) ® (d) (B) (1) ® (b), (2) ® (d), (3) ® (c), (4) ® (a)
(C) (1) ® (c), (2) ® (e), (3) ® (d), (4) ® (b) (D) (1) ® (d), (2) ® (a), (3) ® (e), (4) ® (c)
37. ) Which is the correct priority order for absolute configuration ?
(A) –COOH, –CONH2, –CHO, –COCH3 (B) –COCH3, –CONH2, –COOH, –CHO
(C) –COOH, –COCH3, –CONH2, –CHO (D) –COOH, –CONH2, –COCH3, –CHO
45. ) In “lucas test” which of the following alcohol cannot give any change ?
(A) Butylalcohol (B) 2-butanol (C) 2-methyl propan-2-ol (D) 2-propanol
46. ) Match Column-I with Column-II :
Column-I Column-II
(P) CH3CHO + CH3CH2MgBr ® Intermediate Product ® (i) 2-methyl
hexan-2-ol
NaOH
(Q) C6H5OH + CH3 COCl ¾¾¾¾ ® (ii) Ethyl Bromide
D
(R) CH3CH2 – O – CH2CH3 + 2HBr ¾¾® (iii) Phenyl
acetate
(S) CH3CH2CH2CH2MgBr + CH3COCH3 ® Intermediate Product ® (iv) Butan-2-ol
(A) P ® (iv), Q ® (iii), R ® (ii), S ® (i) (B) P ® (i), Q ® (iii), R ® (iv), S ® (ii)
(C) P ® (ii), Q ® (iv), R ® (i), S ® (iii) (D) P ® (iv), Q ® (iii), R ® (i), S ® (ii)
47. ) Sodium phenoxide on reaction with methyl iodide produces compound X, which on Friedel-Craft’s
acylation produces compounds Y and Z. Mention compounds X, Y and Z.
(A) X = Methoxy Benzene,Y = o-methoxy toluene,Z = p-methoxy toluene
(B) X = Methoxy Benzene,Y = o-chloro anisole,Z = p-chloro anisole
(C) X = Anisole, Y = 1(2-methoxy phenyl) ethan - 1 - one,Z = 1(4-methoxy phenyl) ethan - 1 - one
(D) X = Anisole, Y = o - nitro Anisole,Z = p-nitro anisole
48. ) Which of the following compound cannot be oxidized by chromic acid and when Lucas test is
performed on it, oily drops appear in on the upper layer of mixture ?
(A) Butane-1-o1 (B)Best
Wish You - All The Propane-2-o1
(C) Propane-1-o1 (D) 2-methyl propane-2-o1
) Which of the following compound cannot be oxidized by chromic acid and when Lucas test is
performed on it, oily drops appear in on the upper layer of mixture ?
(A) Butane-1-o1 (B) Propane-2-o1
(C) Propane-1-o1 (D) 2-methyl propane-2-o1
49. ) Give the correct order of acidic strength of the following alcohols.
(A) 2-methyl propan-2-o1 > propan-1-o1> propan-2-o1
(B) Propan-1-o1 > propan-2-o1 > 2-methyl propan-2-o1
(C) 2-methyl propan-2-o1 > propan-2-o1> propan-1-o1
(D) Propan-1-o1 > 2-methyl propan-2-o1 > propan-2-o1 >
50. ) Which of the following product is obtained on performing Riemer Tiemann reaction on phenol ?
(A) Salicylic acid (B) Phenyl acetate
(C) Salicylaldehyde (D) 1, 4 Benzoquinone
51. ) Which of the following is a product of hydrolysis of diethyl ether ?
(A) Ethene (B) Ethane (C) Ethanol (D) Ethyne
170) Which of the following is used as a solvent in oxidation of Alcohol by Pyridinium chloro chromate ?
52.
(A) Chloro methane (B) Trichloro ethane (C) Trichloro methane (D) Dichloro methane
53. ) What is obtained as end product when phenol dissolved in aqueous solution of sodium hydroxide
is heated with carbon dioxide gas at 398K temperature and 4-7 bar pressure ?
(A) Cumene hydro peroxide (B) Sodium phenoxide
(C) Salicylaldehyde (D) Sodium salicylate
54. ) Which of the following alcohol will respond to Lucas test slowest ?
(A) Secondary butyl alcohol (B) 3° - butanol
(C) Neo pentyl alcohol (D) None of the above
55. ) How many alcohols and ethers are possible with general formula C4H10O ?
(A) 7 (B) 4 (C) 5 (D) 8
56. ) What is the IUPAC name of the product obtained from oxidation of phenol ?
(A) 1, 4 - Benzoquinone (B) 1, 2 - Benzo Catechol
(C) Cyclohexa - 2, 5 - diene - 1, 4 - dione (D) None of these
CH2 – CH3
57.
165) IUPAC name of the is ...........
H 3C OH
(A) 2-Ethyl-5-methyl cyclohexanol (B) 5-Methyl-2-ethyl cyclohexanol
(C) 2-Methyl-5-ethyl cyclohexanol (D) 5-Ethyl-2-methyl cyclohexanol
58. ) Choose the correct order of boiling point for ethanol, ethylene glycol and glycerol.
(A) Ethanol > ethylene glycol > glycerol (B) Ethanol > glycerol > ethylene glycol
(C) Glycerol > ethylene glycol > ethanol (D) Glycerol > ethanol > ethylene glycol
59. ) Minimum carbon containing 2° alcohol undergoes dehydration and gives A. Benzene diazonium
chloride when heated with water gives B which on reduction by zinc metal gives A and C also react
with other. Name the process between A and C.
(A) Reimer – Tiemann Reaction (B) Kolbe–Schmitt Reaction
(C) Cumene Process (D) Fries Rearrangement
60. ) Which of the following alcohol undergo dehydration reaction with Cu (Copper) metal at 573 K
temperature ?
(A) Primary and Tertiary (B) Secondary and Tertiary
(C) Primary and Secondary (D) Only Tertiary
Wish You - All The Best
temperature ?
(A) Primary and Tertiary (B) Secondary and Tertiary
(C) Primary and Secondary (D) Only Tertiary
61. ) Which product is obtained between reaction of CH3ONa and (CH3)3 CBr ?
(A) Both alkene and ether(B) Only Ether (C) Only Alkene (D) Alcohol
62. ) Which reaction is used to prepare salicylic acid from phenol ?
(A) Etard’s reaction (B) Kolbe’s reaction
(C) Stephen reaction (D) Reimer-Tiemann reaction
63. ) Which of the following reactions will not give Benzene ?
D
(A) C 6 H5OH + Zn ¾¾
® (B) C6 H5N +2 Cl - + H3PO2 + H2O ®
D
(C) C6 H5COONa + Sodalime ¾¾
® [O]
(D) C 6 H5OH + H 2 CrO 4 ¾¾®
64. ) Which compound having maximum value of pKa from following ?
(A) o – O2N – C6H4 – OH (B) m – O2N – C6H4 – OH
(C) p – O2N – C6H4 – OH (D) C6H5OH
65. ) Which Grignard reagent gives 2-methyl propane-1-ol with reaction with methanal ?
(A) CH3 – CH2 – CH2 – Mg – X
(B) CH3 – CH = CH – Mg – X
(C) CH3 – CH – Mg – X
|
CH3
CH3
66. ) From following IUPAC name of compound is ?
CH3
OC2H5
(A) 2-ethoxy-1, 1-dimethyl cyclohexane (B) 1-ethoxy-2, 2-dimethyl cyclohexane
(C) 5-ethoxy-6, 6-dimethyl cyclohexane (D) 1-ethoxy-6, 6-dimethyl cyclohexane
O
CH2 – C – OCH3 NaBH4
155)
67. ¾¾¾¾® “X”.. What is “X” in reaction ?
O
OH O
CH2 – CH2 – CH2 – OH CH2 – CH – CH3
(A) (B)
OH
OH OH
CH2 – C – OCH3 CH2 – CH2 – CH3
(C) (D)
O
75.7) Which is the final product obtained by the reaction of a Grignard reagent ethyl Magnesium bromide
with propanone ?
(A) Pentane-1-ol (B) 2-Methylbutane-2-ol
(C) Pentane-2-ol (D) 3-Methylbutane-2-ol
76. ) The IUPAC name of the product obtained by the oxidation of phenol with the help of chromic acid
is ........... .
(A) Cyclo hexa – 2,4 – diene – 1,4 – dione (B) Cyclo hexa – 2,5 – diene – 1,4 – dione
(C) Cyclo hexa – 2,5 – diene – 1,4 – diol (D) Cyclo hexa – 2,4 – diene – 1,4 – diol
77. ) How many gm. of ethanol is required in the reaction with Na metal in order to give 560 ml.
dihydrogen gas at STP ? [mole. mass of ethanol = 46 gm mol–1]
(A) 1.15 (B) 2.3 (C) 4.6 (D) 11.5
78. ) Which products are otained when phenyl ethanoate reacts in presence of Anh. AICl3 ?
(A) o – Hydroxy acetophenone andp – Hydroxy acetophenone
(B) o – Methoxy acetophenone andp – Methoxy acetophenone
(C) o – Methyl acetophenone andp – Methyl acetophenone
(D) o – Ethoxy acetophenone andp – Ethoxy acetophenone
143) How many s and p bonds are present respectively in the final product obtained by the Reimer-
79.
Tiemann reaction of phenol ?
(A) 15 and 3 (B) 14 and 4 (C) 15 and 4 (D) 14 and 3
80. ) Which of the following reagent reacts with but-1-ene to give optically inactive product ?
(A) Br2/CCl4 (B) HBr
(C) H2 O/H+ (D) (BH3)2/H2O2(OH–)
81. ) Which reagents from the following give aldehyde by reacting with primary alcohol ?
(A) PCC + CH2Cl2 (B) KMnO4 + H2SO4
(C) KMnO4 + KOH (D) Na2Cr2O7 + H2SO4
OH COOH OH OH
NO2 NO2
NO2
(I) (II) (III) (IV)
(A) IV > III > II > I (B) I > III > IV > II (C) IV > III > I > II (D) IV > II > III > I
98. ) The products (A) and (B) are respectively.
Choose the correct reaction for the following process
OH OH
HBr HBr
A B
D D
CH2OH OCH3
OH OH OH Br
(A) A = B= (B) A = ,
B=
,
CH2Br OH CH2Br OCH3
Br Br OH OH
(C) A = B= (D) A = B=
, ,
CH2OH Br CH2Br Br
99. ) Following compounds are given
OH OH
O2N NO2 Wish You - All The Best
(I) (II)
Cl
) Following compounds are given
OH OH
O2N NO2
(I) (II)
Cl
NO2
OH OH
CH3 CH3 NO2
(III) (IV)
CH3
(A) I > IV > II > III (B) I > IV > III > II (C) III > II > IV > I (D) IV > I > II > III
100. ) Given below are two statements :
Statement-I : In Lucas test, primary, secondary and tertiary alcohols are distinguished on the basis
of their reactivity with conc. HCl + ZnCl2, known as Lucas Reagent.
Statement-II : Primary alcohols are most reactive and immediately produce turbidity at room
temperature on reaction with Lucas Reagent.
In the light of the above statements, choose the most appropriate answer from the options given
below :
(A) Statement-I is correct but Statement-II is incorrect.
(B) Statement-I is incorrect but Statement-II is correct.
(C) Both Statement-I and Statement-II are correct.
(D) Both Statement-I and Statement-II are incorrect.