CHEMISTRY

CARBONYL
COMPOUND

www.etoosindia.com
 EXERCISE - I

01.

major product Structure of (P) is.

02.
03. (x) b - hydroxy ketone (x) can’t be

O
04.

Major product

(D) None
05.

major product structure of (x) is.

06. Aldol addition can be

(A) Acid catalysed

(B) Base catalysed

(C) Acid promoted

(D) A and B both

07.

Structure of (x) is.

08.

Total number of aldol condensation products are

(excluding stereoisomer)

(A) 2 (B) 3

(C) 4 (D) 5
09.

(x) and (y) are

(D) None
10.

product (P) is
11.

3
 AlH4
12.

Relationship between products is

(A) Meso (B) Racemic mixture

(C) Diastereomer (D) None

13.
Given reaction is an example of

(A) oxidation (B) Reduction

(C) Dispropornation (D) Fermentation

14. Compound which given cannizaro reaction ?

(A) CD3 CHO (B) C6 H5 CHO

(C) CH3 COCH3 (D)

15. Total number of intramolecular aldol condensation
products possible from givencompound is
(exclusding stereoisomer).

(A) 1 (B) 2

(C) 3 (D) 4
16.

Product Degree of unsaturation in product is ?

(A) 2 (B) 3

(C) 4 (D) 5
17. Which acid can be oxidised be Fehling solution ;

(A) Malonic acid (B) Acetic acid

(C) Oxalic acid (D) formic acid

18.

Positive Tollen’s Test compound (A) is :

19. Ease of reaction is maximum in which of the
following cases ?
(D) Rate is independent of halogens
20.

Product (C) is.

21.

Product (B) is
22.

; Product (B) is
23.

(A) Ph – CH = CH – Ph (B) Ph–CH = CH – CH = O

24.
25. Gem dihalide on hydrolysis gives :

(A) Vic diol (B) Gem diol

(C) Carbonyl compound (D) Carboxylic acid

26.

(A) Acetophenone (B) Benzophenone

(C) Acetone (D) Benzaldehyde

27. Arrange these compounds in decreasing order of
reactivity for the nucleophilic addition reaction :

(I) Acid chloride (II) Aldehyde

(III) Ketone (iv) Ester

Select the correct answer from the codes given

below :

(A) I > II > III > IV (B) IV > III > II > I

(C) III > II > I > IV (D) I > IV > II > III
`
28. Acetal or ketal is :

(A) Vic dialkoxy compound

(B) a, w – dialkoxy compound

(C) a – alkoxy alcohol

(D) Gem dialkoxy compound

29.

Product (A) is.

(A) Ph – N  C (B) Ph – C  N

(C) Ph – CH2 – NH2 (D) Ph – CH  NH

31. Schiff’s base is prepared from :

(A) Carbonyl compound and primary amine

(B) Carbonyl compound and secondary amine

(C) Carbonyl compound and tertiary amine

(D) All of these

32. Schiff’s reagent is used for the differentiation
between :

(A) HCHO and CH3 CHO

(B) CH3 COCH3 and CH3 CHO

(C)

(D) HCHO and C6 H5 CHO

33. In the reaction sequence, [X] is ketone :

[X] HOOC – (CH2)3 – CH2 – COOH

[X] will be :
34. Which of the following ketone / aldehyde can
undergoes haloform reaction ?

(A) (B) CH3 – CHO

(C) (D) All of these

35. Acetone can be converted into pinacold by :

(A) Mg / Hg / H2O (B) Zn / Hg / HCl

(C) Na / Hg / H2 SO4 (D) All of these

36. In the given reaction

[X] will be ;
37. Consider the given reaction :

The above reaction is known as :

(A) Baeyer - villiger oxidation

(B) Oppenaur oxidation

(C) Periodate oxidation

(D) Peroxide oxidation

38.
order of the reaction is :

(A) 2 (B) 3

(C) 4 (D) 1
39. In the given reaction

(X) and (Y) will respectively be :

(A) CH3 – CH2 – CHO and CH3 – CH2 – CHO

(B) CH3 – CHO and CH3 – CH2 –CHO

(C) CH3 – CHO and CH3 –CHO

(D)
40. Total number of products in the given reaction
(excluding stereoisomers)

C6 H5 CHO + CH3 – CHO

Product will be

(A) One (B) Three

(C) Two (D) Four

41.

Product (B) is
42. Product of Perkin reaction is :

(A) a, b – unsaturated aldehyde

(B) b - cyclohexyl a, b – unsaturated aldehyde

(C) b - Aryl - a, b – unsaturated acid

(D) All of these

43. The product of the reaction :

will be :
(A) C6 H5 – CH = CH – COOH

(B)
44. Cross cannizzaro reaction is example of :

(A) Redox reaction

(B) Disproportionation

(C) Both (A) and (B)

(D) Only oxidation

45. In the given reaction :

[X] will be :
(A) Methyl oxide

(B) Phorone

(C) 1, 3, 5- Trimethylbenzene

(D) 2 - Butyne
46. Which will give silver mirror test with tollens
rangent :

(A) C6 H5 CHO (B) CH3 – CHO

(C) HCOOH (D) All of these

47.

D
Z is.
48. Cyanohydrin of which compound on hydrolysis
will give lactic acid ?

(A) C6 H5 CHO (B) HCHO

(C) CH3 CHO (D) CH3 – CH2 – CHO

49. Acetaldehyde cannot give :

(A) lodoform test (B) Lucas test

(C) Benedict test (D) Tollens test

50. Compound formed by the

reaction of furfural

with ethanol is

(A) an aldol (B) an acetal

(C) a ketal (D) a hemiacetal

51.

Product (B) is :
H
52. Which of the following will reacts wil NaOI ?

(D) All
53.

Product (P) and(Q) respectively is :

54. Which of the following compound not reacts with
NaHSO3 ?
55.

Product (B) is.

56.

When A reacts with B in presence of KOH / D

Product C is formed. Product C is ?

(A) Ph – CH = CH – CHO

(B)
(C)

(D) None
57. Ph – CH = O + NH2 – NH2 (A). Product

(A) is known as :

(A) Aldo - Oxime (B) Hydrazone

(C) Hydrate (D) Phenyl hydrazone

58. HO – CH2 – CH2 – CH = O

(A), Product (A) is :

59.

Major product (B) is :

60.
major. product (A) is :
61.

How many hydrogen is replaced by Deuterium.

(A) 2 (B) 10

(C) 7 (D) 8
 Comprehansion : (Q. 62 to Q. 64) :

Aldehydes and ketones react with onemolecule of

an alcohol to form compound called hemiacetals,
in which there is one hydroxyl group and one ether
- like group. Reaction of a hemiacetal with a
second molecule of alcohol gives an acetal and a
molecule of water. We study this reaction.
Draw structural formulas for the hemiacetal and
acetal formed from these reagents. The
stoichiometry of each reaction is givenin the
problem.
O
62. Product P is.
63. Product Q is.
64. Product R is.
 EXERCISE - II

01. In a compound C, H and N atoms are present in

9 : 1 : 3.5 by weight. Molecular weight of
compound is 108. Molecular formula of compound
is. [AIEEE - 2002]

(A) C2H6N2 (B) C3 H4 N

(C) C6H8N2 (D) C9 H12 N3

02. Which one the following does not have sp2
hybridized carbon ? [AIEEE - 2004]

(A) Acetone (B) Acetamide

(C) Acetonitrile (D) Acetic acid

03. Which one of the following reduced with zinc and
hydrochloric acid to give the corresponding
hydrocarbon ? [AIEEE - 2004]

(A) Ethyl acetate (B) Butan - 2 - one

(C) Acetamide (D) Acetic acid

04. Which of the following undergoes reaction with
50% sodium hydroxide solution to give the
correspoding hydrocarbon ?
[AIEEE - 2004]

(A) Phenol (B) Benzoic acid

(C) Butanal (D) Benzaldehyde

05. lodoform can be prepared from all except :
[AIEEE - 20012]

(A) Ethyl methyl ketone

(B) isopropyl alcohol

(C) 3 - Methyl-2- butanone

(D) lsobutyl alcohol

06. Which of the following compounds can undergoes
haloform reaction ?
07. Among the following the one that gives positive
iodoform test upon reaction with l2 and NaOH is
[AIEEE - 2006]

(A) CH3 CH2 CH (OH) CH2 CH3

(B) C6 H5 CH2 CH2 OH

(C)

(D) PhCHOHCH3
08. In Cannizzaro reaction given below, 2 Ph CHO

Ph CH2 OH + Ph CO2 the slowest step is

[AIEEE - 2009]
(A) the abstraction of proton from the carboxylic
group

(B) the deprotonation of Ph CH2 OH

(C) the attack of : OH at the carboxyl group

(D) the transfer of hydride to the carbonyl group

09. Trichloroacetaldehyde was subjected to
Cannizzaro’s reaction by using NaOH. The
mixture of the products contains sodium
trichloroacetate ion and another compound. The
other compound is; [AIEEE - 2011]

(A) 2, 2, 2 - Trichloroethanol

(B) Trichloromethanol

(C) 2, 2, 2 - Trichloropropanol

(D) Chloroform
10. Sodium ethoxide has reacted with ethanoyl
chloride. The compound that is produced in the
above reaction is. [AIEEE - 2011]

(A) Diethyl ether (B) 2 - Butanone

(C) Ethyl chloride (D) Ethyl ethanoate

11. Silver Mirror test is given by which one of the
following compounds ? [AIEEE - 2011]

(A) Acetaldehyde (B) Acetone

(C) Formaldehyde (D) Benzophenone

12. lodoform can be prepared from all except :
[AIEEE - 2012]
(A) Ethyl methyl ketone

(B) lsopropyl alcohol

(C) 3 - Methyl - 2 - butanone

(D) lsobutyl alcohol

13. In the given transformation, which the following is
the most appropriate reagent ? [AIEEE - 2012]

(A) (B) Zn – Hg / HCl

(C) Na, Liq, NH3 (D) NaBH4

14. A gaseous hydrocarbon gives upon combustion
0.72 g of water and 3.08 g of CO2. The empirical
formula of the hydrocarbon is :
[IIT - JEE Main - 2013]

(A) C7H8 (B) C2H4

(C) C3H4 (D) C6H5

15. Compound (A), C8H9 Br, gives a white precipitate
when warmed with alcoholic AgNO3. Oxidation of
(A) gives an acid (B), C8,H6O4. (B) easily forms
anhydride on heating. ldentify the compound (A).
[IIT - JEE Main - 2013]
16. Which of the following compounds is not expected
to show lassaignes’ test for nitrogen ?
[IIT Mains Online - 2013]

(A) Hydroxylamine hydrochloride

(B) Ethanamine

(C) Propanenitrile

(D) Nitromethane
17. Formaldehyde can be distinguished from
acetaldehyde by the use of :
[IIT Mains Online - 2013]

(A) I2 / Alkali (B) Schiff’s reagent

(C) Fehling’s solution (D) Tollen’s reagent

18. For which of the following compounds kjeldehl
method can be used to determine the percentage of
* Nitrogen ? [IIT Mains Online - 2013]

(A) Nitrobenzene (B) Alanine

(C) Pyridine (D) Diazomethane

19. Which of the following is the product of aldol
condensation ? [IIT Mains Online - 2013]
20. 6 litres of an alkene require 27 litres of oxygen at
constant temperature and pressure for complete
combustion. The alkene is :
[IIT Mains Online - 2013]

(A) 2 - Butene (B) Propene

(C) 1 - Butene (D) Ethene

21. Cannizaro’s reaction is not given by :
[IIT Mains Online - 2013]

(A) (B)

(C) HCHO (D) CH3 CHO

22. Which one of the following reaction will not result
in the formation of carbon bond ?
[IIT Mains Online - 2014]

(A) Reimer - Tieman reaction

(B) Friedel Craft’s acylation

(C) Wurtz reaction

(D) Cannizzaro reaction

23. Which is the major product formed when acetone
is heated with iodine and potassium hydroxide ?
[IIT Mains Online - 2014]

(A) lodoacetone (B) Acetic acid

(C) Iodoform (D) Acetophenone

24. Chlorobenzne reacts with trichloro acetaldehyde in
the presence of H2SO4
[IIT Mains Online - 2014]

The major product formed is :

25. Tischenko reaction is a modification of :
[IIT Mains Online - 2014]

(A) Aldol condensation

(B) Claisen condensation

(C) Cannizzaro reaction

(D) Pinacol - pinacolon reaction

26. A compound A with molecular formula C10 H13 Cl
gives a white precipitate on adding silver nitrate
solution. A on reacting with alcoholic KOH gives
compound B as the main product. B on ozonolysis
gives C and D. C gives Cannizaro reaction but not
aldol and D gives aldol but not Cannizaro reaction.
A is. [IIT Mains Online - 2015]
27. is used as

[IIT Mains Online - 2015]

(A) Insecticide (B) Anthistamine

(C) Analgesic (D) Antacid

28. In the reaction sequence

[IIT Mains Online - 2015]

(A)

(B) CH3 – CH2 – CH2 – CH2 – OH

(C) CH3 – CH2 – CH2 –CH3

(D) CH3 – CH = CH – CHO

29. Which compound would give 5 - keto - 2 - methyl
hexanal upon ozonolysis ?
[JEE Mains - 2015]
30. A compound A with molecular formula C10 H13 Cl
gives a white precipitate on adding silver nitrate
solution A. on reaction with alcoholic KOH gives
compound B as the main product. B on ozonolysis
gives C and D. C gives Cannizaro reaction but not
aldol andD gives aldol but not Cannizaro reaction.
A is. [JEE Mains - 2015]

(A)

(B)
(C) C6 H5 – CH2 – CH2 – CH2 – CH2 – Cl

(D)
31. Which of the following pairs of compounds are
positional isomers ? [JEE Mains - 2015]
32. In the reaction sequence

[JEE Mains - 2015]

(A)

(B) CH3 – CH2 – CH2 – CH2 – OH

(C) CH3 – CH2 – CH2 – CH3

(D) CH3 – CH = CH – CHO

33. In the Hofmann bromamide degradation reaction,
the number of moles of NaOH and Br2 used per
mole of amine produced are :
[JEE Mains - 2016]

(A) One mole of NaOH and one mole of Br2.

(B) Four moles of NaOH and two moles of Br2.

(C) Two moles of NaOH and two moles of Br2.

(D) Four moles of NaOH and one mole of Br2.

 JEE ADVANCE
EXERCISE - I

01. Which one of the following is mixed ketone

(Aliphatic & aromatic)
02. Two isomeric ketones, 3 - pentanone and 2 -
pentanone can be distinguished by :

(A) l2/ NaOH (B) NaSO3H

(C) NaCN / HCl (D) 2, 4 - DNP

03. Which of following give positive test with 2, 4 -
DNP ?
04. Fehling solution gives red precipitate with :

(A) Aromatic aldehyde

(B) Aliphatic aldehyde

(C) Ketones

(D) a - hydroxy ketones

05. Silver mirror test with Tollens reagent is given by :

(A) C6 H5 CHO (B) Ph – CH2 – CHO

(C)

(D) CH3 CHO

06. Which one of the following compounds will not
give aldol :

(A) Acetaldehyde (B) Formaldehyde

(C) Pivaldehyde (D) Crotonaldehyde

07. Schiff’s reagent gives pink colour with :

(A) Acetaldehyde (B) Ph – CH3

(C) Acetic acid (D) Methyl acetate

08. Which of the following compound will give positive
Tollens test

(A) CH3 CHO (B)

(C) (D)
09. Mixture o f Ph – CHO & HCHO is treated with
NaOH then Cannizzaro reaction involves :

(A) Oxidation of HCHO

(B) Reduction of HCHO

(C) Oxidation of Ph – CHO

(D) Reduction of Ph – CHO

10. PhCHO + HCHO

Correct statement regarding reaction will be

(A) It is an example of redox reaction

(B) HCHO is oxidised

(C) It is cross cannizaro reaction

(D) Ph – CHO is reduced

 EXERCISE - II
01. The reagent with which both acetaldehyde and
acetone react easily is. [ IIT 1982 ]

(A) Tollen reagent (B) Schiff reagent

(C) Grignard reagent (D) Fehling reagent

02. The cannizzaro reaction is not given by

(A) trimethyl acetaldehyde

IIT 1983
(B) acetaldehyde

(C) benzaldehyde

(D) formaldehyde
03. When acetaldehyde is heated with Fehlling
solution, if gives a precipitate of

(A) Cu (B) CuO IIT 1983

(C) Cu2O (D) Cu + Cu2 O + CuO
04. m - chlorobenzaldehyde on reaction with conc.
KOH at room temperature gives :
IIT 1991
(A) Potassium m - chlorobenzoate and m - hydroxy
benzaldehyde

(B) m - hydroxybenzaldehyde and m –

chlorobenzyl alcohol

(C) m - chlorobenzyl and m - hydroxybenzyl

alcohol

(D) Potassium m - chlorobenzoate and m -

chlorobenzyl alcohol
05. Hydrogenation of benzoyl chloride in the presence
of Pd and BaSO4 gives :
IIT 1992
(A) Benzyl alcohol (B)Benzaldehyde

(C) Benzoic acid (D) Phenol

06. Under Wolff Kishner reduction conditions, the
conversions which may be brought about is ?
(A) Benzaldehyde into Benzyl alcohol
IIT 1995
(B) Cyclohexanol into Cyclohexane

(C) Cyclohexanone into Cyclohexanol

(D) Benzophenone into Diphenylmethane

07. In the reaction, P is
IIT 1995

(A) CH3COCHO (B) CH3 COOCH3

(C) CH3COCH2OH (D) None

08. In the Cannizzaro reaction given below,
IIT 1996
2Ph – CHO Ph – CH2 OH + PhCO2– the
slowest step is :

(A) The attack of OH- at the carbonyl group

(B) The transfer of hydride to the carbonyl group

(C) The abstraction of proton from the carboxylic

acid

(D) The deprotonation of Ph – CH2 OH

09. In a Cannizzaro reaction the intermediate which is
the best hydride donor is : IIT 1997

(A) (B)

(C) (D)
10. A mixture of benzaldehyde and formaldehyde on
heating with aqueous NaOH solution gives :
IIT 2001
(A) Benzyl alcohol and sodium formate

(B) Sodium benzoate and methyl alcohol

(C) Sodium benzoate and sodium formate

(D) Benzyl alcohol and methyl alcohol

11. 1 – propanol & 2 – propanol can be best
distinguished by : IIT 2001

(A) Oxidation with alkaline KMnO4 followed by

reaction with Fehling solution

(B) Oxidation with acedic dichromate followed by

reaction with Fehling solution

(C) Oxidation by heating with copper followed by

reaction with Fehling solution

(D) Oxidation with concentrated H2SO4 followed

by reaction with Fehling
 IIT 2003
12.

Any one of the products formed is :

(A) (B)

(C) (D)
13. Which of the following compounds will give a
yellow precipitate with iodine and alkali ?
IIT 1984
(A) 2 – hydroxy propane

(B) Acetophenone

(C) Methyl acetate

(D) Acetamide
14. IIT 2005

What is X ?

(A) CH3COOH (B) BrCH2, COOH

(C) (CH3 CO)2O (D) CHO - COOH

15. How will you convert butane – 2 – one to
propanoic acie ?
IIT 2005
(A) Tollen reagent (B) Fehling solution

(C) NaOH / I2 / H+ (D) NaOH / NaI/H+

16. Which of the following reactants on reaction with
conc. NaOH followed by acidification gives the
following lactone as the only product ? IIT 2006

(A) (B)

(C) (D)
17. Cyclohexene on ozonolysis followed by reaction
with zinc dust and water gives compound E.
Compound E on further treatment with aqueous
KOH yields compound F. Compound F is.
IIT 2007

(A) (B)

(C) (D)
18. Statement -1 : Glucose gives a reddish – brown
precipitate with Fehling’s solution. beacuse
Statement - 2 : Reaction of glucose with Fehling’s
solution gives CuO and gluconic acid.
IIT 2007
(A) Statement – 1 is True, Statement-2 is True;
Statement – 2 is a correct explanation for
Statement – 1
(B) Statement – 1 is True, Statement-2 is True;
Statement – 2 is Not a correct explanation for
Statement – 1
(C) Statement – 1 is True, Statement-2 is False.
(D) Statement – 1 is False, Statement-2 is True.
19. The number of aldol reaction (s) that occurs in the
given transformation is : IIT 2012

CH3 CHO + 4HCHO

(A) 1 (B) 2

(C) 3 (D) 4
20. The major product H in the given reaction
sequence is
IIT 2012
CH3 – CH2 – CO – CH3

(A) (B)

(C) (D)
21. The major product of the following reaction is

[JEE Advance 2015]

(A) (B)

(C) (D)
22. In the following reactions, the product S is
[JEE Advance 2015]

(A) (B)

(C) (D)
23. Match the compounds/ion in column I with their
properties/ reaction in Column II. Indicate your
anwer gby darkening the appropriate bubbes of
the 4 × 4 matrix given in the ORS.
IIT2017]
Column I Column II
(A) C6H5CHO (P) gives precipitate
with 2,
4 - dinitrophenylhydrazine
(B) CH3 C  CH (Q) gives precipitate with
AgNO3
(C) CN – (R) is a nucleophile

(D) l – (S) is involved in canohydrin

formation
24. Match the compounds in Column I with their
characteristic test (s)/ reaction (s) given in Column
II. Indicate your answer by darkening the
appropriate bubbles of the 4 × 4 matrix given in
the ORS.
[IIT2008]
Column I Column II

(A) H2N – NH3 Cl (P) sodium fusion extract of
the compound gives
Prussian blue colour with
FeSO4

(B) (Q) gives positive FeCl3

test
(C) (R) gives white

precipitate with
Ag NO3

(D) (S) reacts with

aldehydes to form
the corresponding
hydrazone
derivative
 Paragraph for Question No. 25 to 27
[IIT2008]
A tertiary alcohol H upon acid catalysed
dehydration gives a product I. Ozonolysis of I leads
to compounds J and K. Compound J upon reaction
with KOH gives benzyl alcohol and a compound L,
whereas K on reaction with KOH gives only M.
25. Compound H is formed by the reaction of

(A)

(B)

(C)

(D)
26. The structure of compound I is

(A) (B)

(C) (D)
27.The structures of compounds J, K and L,
respectively, are

(A) PhCOCH3, PhCH2 COCH3 and PhCH2COO– K +

(B) PhCHO, PhCH2 CHO and PhCOO – K +

(C) PhCOCH3, PhCH2 CHO and CH3 COO– K +

(D) PhCHO, PhCOCH3 and PhCOO– K +

 Paragraph for Question Nos. 28 to 30
[IIT2009]
A carbonyl compound P, which gives positive
iodoform test, undergoes reaction with MeMgBr
followed by dehydration to give an olefin Q.
Ozonolysis of Q leads to a dicarbonyl compound R,
which undergoes intramolecular aldol reaction to
give predominantly s.
28. The structure of the carbonyl compound P is

(A) (B)

(C) (D)
29. The structures of the products Q and R,
respectively, are

(A)

(B)
(C)

(D)
30. The structure of the product S is.

(A) (B)

(C) (D)
 Paragraph for Question Nos. 31 to 33
[IIT2010]
Two aliphatic aldehydes P and Q react in the
presence of aqueous K2CO3 to give compound R,
which upon treatment with HCN provides
compound S. On acidification and heating. S gives
the product shown below.
31. The compounds P and Q respectively are -

(A)

(B)
(C)

(D)
32. The compound R is

(A) (B)

(C) (D)
33. The compound S is

(A) (B)

(C) (D)
 Paragraph for Question Nos. 34 and 35
An acyclic hydrocarbon P, having molecular
formula C6 H10, gave acetone as the only organic
product through the following sequence of
reaction, in which Q is an intermediate organic
compound. [IIT 2011]
34. The structure of compound P is.

(A) CH3 CH2 CH2 CH2 – C  C – H

(B) H3 CCH2 – C  C – CH2 CH3

(C)

(D)
35. The structure of the compound Q is :

(A) (B)

(C) (D)
 Paragraph for Questions Nos. 36 to 37
In the following reactions sequence, the compound
J is anintermediate, [IIT 2012]

J (C9 H8 O2) gives effervescence on treatment with

NaHCO3 and positive Baeyer’s test
36. The compound K is

(A) (B)

(C) (D)
37. The compound I is

(A) (B)

(C) (D)
38. Different possible thermal decomposition pathways
for peroxyesters are shown below. Match each
pathway from List – I with an appropriate
structure from List – II and select the correct
answer using the code given below the lists.
[JEE Advance 2014]
List – I List – II

(P) Pathway P 1.

(Q) Pathway Q 2.

(R) Pathway R 3.

(S) Pathway S 4.
Codes :

P Q R S

(A) 1 3 4 2

(B) 2 4 3 1

(C) 4 1 2 3

(D) 3 2 1 4
39. The correct statement (s) about the following
reaction sequence is (are) [JEE Advance 2016]

(A) R is steam volatile

(B) Q given dark violet coloration with 1%
aqueous FeCl3 solution
(C) S gives yellow precipitate with 2, 4-
dintriophenylhdrazine.
(D) S gives dark violet coloration with 1%
aqueous FeCl3 Solution.
40. Positive Tollen’s test is observed for
[JEE Advance 2016]

(A) (B)

(C) (D)
41. The correct order of acidity for the following
compounds is : [JEE Advance 2016]

OH

(A) I > II > III > IV (B) III > I > II > IV

(C) III > IV > II > I (D) I > III > IV > II
42. The major product of the following reaction
sequence is : [JEE Advance 2016]

(A) (B)
(C)

(D)
 Paragraph (Q. 43 to Q. 44)
Treatment for compound O with KMnO4/H+ gave
P, which on heating with ammonia gave Q. The
compound Q on treatment with Br2/NaOH
produced R. On strong heating, Q gave S, which on
further treatment with ethyl 2–bromopropanoate
in the presence of KOH followed by acidification
gave a compound T.

[JEE Advance 2016]

43. The compound R is

(A) (B)

(C) (D)
44. The compound T is :

(A) Glycine (B) Alanine

(C) Valine (D) serine

 EXERCISE – III

Subjective : [IIT 2002]

01. Five isomeric para – disubstituted aromatic

compounds A to E with molecular formula C8H8O2
were given for identification. Based on the
following observations, give structure of the
compounds.
(i) Both A and B form a silver mirror with Tollen’s
reagent, also, B gives a positive test with FeCl3
solution
(ii) C gives positive iodoform test.
(iii) D is readily extracted in aqueous NaHCO3
solution.

(iv) E on acid hydrolysis gives 1,

4- dihydroxybenzeno.
02.
IIT 2003

(– HCl)

(D) Is isomer A. E gives negative test with Fehling

solution but gives iodoform test. F and G gives
Tollen’s test but do not give iodoform test Identify A
to G.
03. Give major products A,B,C and D in following
reaction sequence.
IIT 2004
04. Which of the following disaccharide will not
reduce Tollen’s reagent ?
IIT 2005

(a) (b)

(Q)
05.

Identify X, Y and Z
IIT 2005
06. In the scheme given below, the total number of
intramolecular aldol condensation products
formed from ‘Y’ is IIT 2010
07. The total number of carboxylic acid groups in the
product P is.
JEE Advance : 2013
00. Hy
(A)(B)(C)(D)