Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

SECTION 1: Identification of the substance/mixture and of the company/ undertaking

1.1 Product identifier
Product name : DALTOFOAM® TS 22003
Registration number : Not available.
Product code : 00071610
Product description : Polyol blend

1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use : Component of a Polyurethane System

1.3 Details of the supplier of the safety data sheet

Supplier : Huntsman Holland BV

Merseyweg 10
3197 KG Botlek-Rotterdam
The Netherlands
Tel: +31 181 299111
Fax: +31 181 293900

e-mail address of person responsible for this SDS : Global_Product_EHS_HPU@huntsman.com

E-mail address to request full REACH registration number upon EU member State
Authority request : REACH_Registration_Nr_HPU@huntsman.com

1.4 Emergency telephone number

Supplier
Telephone number : EUROPE: +32 35 75 1234
USA: +1/800/424.9300
ASIA: +65 6542 9595
China: +86 20 39377888 / +86 532 83889090
India +91 22 42 87 5333
Australia: 1800 786 152
New Zealand: 0800 767 437
Saudi Arabia: +966 13 821 7255 / +966 13 821 7256

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Acute Tox. 4, H302
Skin Irrit. 2, H315
Eye Irrit. 2, H319

Ingredients of unknown toxicity:

Ingredients of unknown eco toxicity:

Classification according to Directive 1999/45/EC [DPD]

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

Classification : Xn; R22

Xi; R36/38
Human health hazards : Harmful if swallowed. Irritating to eyes and skin.
See Section 11 for more detailed information on health effects and symptoms.
See Section 16 for the full text of the R phrases or H statements declared above.

2.2 Label elements

!
Hazard pictograms :

Signal word : Warning

Hazard statements : Harmful if swallowed.
Causes serious eye irritation.
Causes skin irritation.

Precautionary statements
General : Not applicable.
Prevention : Wear protective gloves/protective clothing/eye protection/face protection. Do not eat,
drink or smoke when using this product.
Response : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON
SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/physician.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazardous ingredients : Glycerol, propoxylated
PPG 425
Benzyldimethylamine

Supplemental label : Not applicable.

elements

Special packaging requirements

Containers to be fitted : Not applicable.
with child-resistant
fastenings

Tactile warning of danger : Not applicable.

2.3 Other hazards

Other hazards which do : None known.
not result in classification

SECTION 3: Composition/information on ingredients

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

3.2 Mixtures : Mixture

Product/ingredient Identifiers % Classification Type

Name 67/548/EEC Regulation (EC)
No.
1272/2008 [CLP]
Polyether Polyol NA 10- 20 Xn; R22 Acute Tox. 4, H302 [1]

[1]
Xn; R22 Acute Tox. 4, H302

Xi; R36 Eye Irrit. 2, H319 [1]

[1]
Polyester Polyol NA 40-45 NA NA

[1]
8-10 NA NA

Bis CAS:103-83-3 1-5 R10

Xn; R20/21/22 Acute Tox. 4, H302 [1]
(2-dimethylaminoethyl) EC: 203 149-1
(methyl)amine C; R34 Acute Tox. 3, H311
R52/53 Acute Tox. 3, H331
Skin Corr. 1B, H314
Eye Dam. 1, H318
Aquatic Chronic 3,
H412
Flam. Liq. 3, H226

See Section 16
for the full text
of the R phrases See Section 16 for the
Declared above. full text of the H
statements declared
above.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not
breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband. In case of inhalation of decomposition products in a fire, symptoms may be
delayed. The exposed person may need to be kept under medical surveillance for 48
hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless
directed to do so by medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison
center or physician. Never give anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure.
Skin contact : Causes skin irritation
Ingestion : Harmful if swallowed. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

Skin contact : Adverse symptoms may include the following:

irritation
redness
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : Symptomatic treatment and supportive therapy as indicated. Following severe exposure
the patient should be kept under medical review for at least 48 hours.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media : None known

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or mixture : In a fire or if heated, a pressure increase will occur and the
container may burst.
Hazardous thermal decomposition products : Decomposition products may include the following materials:
carbon dioxide
Carbon monoxide
nitrogen oxides
halogenated compounds

5.3 Advice for firefighters

Special precautions for fire-fighters : Promptly isolate the scene by removing all persons from the
vicinity of the incident if there is a fire. No action shall be taken
involving any personal risk or without suitable training.
Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and
self-contained breathing apparatus (SCBA) with a full face-
piece operated in positive pressure mode. Clothing for fire
fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic
level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel : No action shall be taken involving any personal risk or without suitable
training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through spilt
material. Avoid breathing vapour or mist. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of
any information in Section 8 on suitable and unsuitable materials. See
also the information in "For non-emergency personnel".

6.2 Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or
air).
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

6.3 Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if
water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations.
Dispose of via a licensed waste disposal contractor.Contaminated absorbent material
may pose the same hazard as the spilt product.

6.4 Reference to other sections: See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).

7.1 Precautions for safe handling

Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not
ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or
mist. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Advice on general occupational hygiene
: Eating, drinking and smoking should be prohibited in areas where this material
is handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities:

Store in accordance with local regulations. Store in original container protected
from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Keep container
tightly closed and sealed until ready for use. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabelled containers. Use appropriate containment to avoid environmental
contamination.

7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific solution : Not available.

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).

8.1 Control parameters

Occupational exposure limits
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

No exposure limit value known.

Recommended monitoring procedures:

If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the
effectiveness of the ventilation or other control measures and/or the necessity to
use respiratory protective equipment. Reference should be made to European
Standard EN 689 for methods for the assessment of exposure by inhalation to
chemical agents and national guidance documents for methods for the
determination of hazardous substances.
Derived effect levels
No DELs available.

Predicted effect concentrations

No PECs available

8.2 Exposure controls

Appropriate engineering controls: No special ventilation requirements. Good general ventilation should be
sufficient to control worker exposure to airborne contaminants. If this
product contains ingredients with exposure limits, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker
exposure below any recommended or statutory limits.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
Before eating, smoking and using the lavatory and at the end of the working
period. Appropriate techniques should be used to remove potentially
contaminated clothing. Contaminated work clothing should not be allowed out of
the workplace. Wash contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a
risk assessment indicates this is necessary to avoid exposure to liquid
splashes, mists or dusts.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard
Should be worn at all times when handling chemical products if a risk
assessment indicates this is necessary.
Use gloves approved to relevant standards e.g. EN 374 (Europe), F739 (US).
Suitability and durability of a glove is dependent on usage, e.g. frequency and
duration of contact, chemical resistance of glove material and dexterity. Always
seek advice from glove suppliers. Additional information can be found for
instance at www.gisbau.de.
Body protection : Personal protective equipment for the body should be selected based on the
Task being performed and the risks involved and should be approved by a
specialist before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should
be approved by a specialist before handling this product
Respiratory protection : In case of inadequate ventilation wear respiratory protection. Respirator
Selection must be based on known or anticipated exposure levels, the hazards
of the product and the safe working limits of the selected respirator.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to
ensure they comply with the requirements of environmental protection
legislation. In some cases, fume scrubbers, filters or engineering modifications
to the process equipment will be necessary to reduce emissions to acceptable
levels.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid. [Oily liquid.]
Colour : Not available.
Odour : Not available.
Odour threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Initial boiling point and boiling range : Not available.
Flash point : Closed/Open cup: 100°C
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Burning time : Not available.
Burning rate : Not available.
Upper/lower flammability or explosive limits : Not available.
Vapour pressure : Not available.
Vapour density : Not available.
Relative density : Not available.
Water solubility : Not available.
Partition coefficient: noctanol/ water (LogKow): Not available.
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.
Explosive properties : Not available.
Oxidising properties : Not available.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its
ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will
not occur. None known
10.4 Conditions to avoid : No specific data.
10.5 Incompatible materials : No specific data.
10.6 Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition
Products should not be produced.

11. TOXICOLOGICAL INFORMATION

Potential acute health effects
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure
Ingestion : Irritating to mouth, throat and stomach.
Skin contact : Irritating to skin.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

Inhalation : No specific data.

Ingestion : No specific data.
Skin contact : Irritating & Redness.
Eye contact : Irritating, Watering & Redness.

Potential chronic health effects

Chronic effects : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Inhalation : No specific data.
Ingestion : No specific data.
Skin : No specific data.
Eyes : Irritating, Watering & Redness.
Target organs : Contains material which may cause damage to the following organs: the nervous
system, heart, central nervous system (CNS), testes

SECTION 12: Ecological information

12.1 Toxicity : Harmful to aquatic organisms if run directly to surface waters
12.2 Persistence and degradability : Not readily biodegradable
12.3 Bioaccumulative potential : low Potential
12.4 Mobility in soil
Soil/water partition coefficient (KOC) : Not available.
Mobility : Not available.
12.5 Results of PBT and vPvB assessment : Not applicable.
12.6 Other adverse effects : No known significant effects or critical hazards.
12.7 Other ecological information : Not available.

SECTION 13: Disposal considerations

Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Empty
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilt material and runoff and contact with soil, waterways, drains and
sewers.
European waste catalogue : The relevant EU Directives and local, regional and national regulations must be
complied with. It is among the tasks of the end user to assign the waste to waste codes
specific to industrial sectors and processes according to the European Waste catalogue.
It is recommended that the details be agreed with the waste disposer responsible.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste

SECTION 14: Transport information

International transport regulations
Regulatory UN number Classes Packing Label Additional
information group information
ADR/RID Class Not - - - -
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

Regulated
IMDG Class Not - - - -
Regulated
IATA Class Not - - - -
Regulated

15. REGULATORY INFORMATION

Chemical Weapons Convention List Schedule I Chemicals : Not listed
Chemical Weapons Convention List Schedule II Chemicals : Not listed
Chemical Weapons Convention List Schedule III Chemicals : Not listed

Chemical Safety Assessment : Chemical Safety Assessments are still required.

SECTION 16: Other information

Full text of abbreviated H statements H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H412 Harmful to aquatic life with long lasting effects.

Full text of abbreviated R Phrases R10- Flammable.

R24- Toxic in contact with skin.
R22- Harmful if swallowed.
R20/22- Harmful by inhalation and if swallowed.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R34- Causes burns.
R35- Causes severe burns.
R36- Irritating to eyes.
R36/38- Irritating to eyes and skin.
R52/53- Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Notice to reader
While the information and recommendations in this publication are to the best of our knowledge, information
and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY,
EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN
PARTICULAR PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

DALTOFOAM® TS 22003

HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY
HAZARDS THAT EXIST.
Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be
determined by the user and made known to handlers, processors and end users.
DALTOFOAM® is a registered trademark of Huntsman Corporation or an affiliate thereof in one or more
countries, but not all countries.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO
PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM
UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.
NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY
MEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO
REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER,
PRODUCT SAFETY AT THE ABOVE ADDRESS.
 Technical Data Sheet

Expected
Foam Properties Unit Test Standard
Values
Density Kg/m3 40-45 ISO 845
Thermal Conductivity
W/mk 0.019-0.021 ASTM C 518
@ 10 deg.C
Compression Strength Kpa > 190 ISO 844
Tensile Strength Kpa > 100 ASTM D 1623
Close Cell Content % > 90 ASTM D 2856
Water Absorption % Vol. < 10 ASTM D 2842
The word "Suprasec" is a trademark, the property of Huntsman
Corporation.

The manufacture of polyurethane materials and polymeric foams is the subject of granted patents and patent applications:
freedom to operate patented processes is not implied by this publication.
The information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the
date of publication. Nothing herein is to be construed as a warranty, express and otherwise. In all cases, it is the responsibility of
users to determine the applicability of such information or the suitability of any product for their own particular0purpose.
All sales of these products shall be subject to the general conditions of sale of Huntsman or its subsidiaries.