6564ccece216ac00181ec079 - ## - Kinetic Theory of Gases and Gas Law - DPP 01 (Lec 03)

1
Arjuna JEE AIR (2024)

KTG & Thermodynamics DPP-01
SINGLE CORRECT QUESTIONS 7. Figure shows graphs of pressure vs density for an
1. When an ideal gas is compressed isothermally then ideal gas at two temperatures T1 and T2.
its pressure increases because :
(A) its potential energy decreases
(B) its kinetic energy increases and molecules
move apart
(C) its number of collisions per unit area with
(A) T1 > T2
walls of container increases
(D) molecular energy increases (B) T1 = T2
(C) T1 < T2
2. Which of the following is correct for the molecules (D) any of the three is possible
of a gas in thermal equilibrium ?
(A) All have the same speed 8. Suppose a container is evacuated to leave just one
(B) All have different speeds which remain molecule of a gas in it. Let nmp and nav represent the
constant most probable speed and the average speed of the
(C) They have a certain constant average speed gas, then
(D) They do not collide with one another. (A) nmp > nav (B) nmp < nav
3. Keeping the number of moles, volume and pressure (C) nmp = nav (D) none of these
the same, which of the following are the same for
all ideal gas? 9. The average speed of nitrogen molecules in a gas is
(A) rms speed of a molecule v. If the temperature is doubled and the N2 molecule
(B) density dissociate into nitrogen atoms, then the average
(C) temperature speed will be
(D) average of magnitude of momentum. (A) v (B) v 2
4. In a sample of an ideal gas the average momentum (C) 2 v (D) 4v
of a molecule depends on
(A) pressure 10. Four containers are filled with monoatomic ideal
(B) mass of gas gases. For each container, the number of moles, the
(C) number of moles mass of an individual atom and the rms speed of the
(D) none of these atoms are expressed in terms of n, m and vrms
5. The temperature at which the r.m.s velocity of respectively. If TA, TB, TC and TD are their
oxygen molecules equal that of nitrogen molecules temperatures respectively then which one of the
at 100ºC is nearly: options correctly represents the order?
(A) 426.3 K (B) 456.3 K A B C D
(C) 436.3 K (D) 446.3 K Number of n 3n 2n n
moles
6. A gas behaves more closely like an ideal gas at Mass 4m m 3m 2m
(A) low pressure and low temperature Rms speed Vrms 2 Vrms Vrms 2 Vrms
(B) low pressure and high temperature Temperature TA TB TC TD
(C) at all pressure and temperature (A) TB = TC > TA > TD (B) TD > TA > TC > TB
(D) none of these (C) TD > TA = TB > TC (D) TB > TC > TA > TD
2
11. For a gas sample with N0 number of molecules, 16. The speeds of three molecules are 3V, 4V and 5V
function N(V) is given by: N(V) = respectively. Find their rms speed.
dN  3N0  2
=  V for 0 < V < V0 and N(V) = 0 for 17. At room temperature (300 K) , the rms speed of the
dV  V03 
molecules of a certain diatomic gas is found to be
V > V0. Where dN is number of molecules in speed
1930 m/s. Can you guess name of the gas ? Find the
range V to V+ dV. The rms speed of the molecules
temperature at which the rms speed is double of the
is:
speed in part one (R = 25/3 J/mol – k)
2 3
(A) V0 (B) V0
5 5 18. The average translational kinetic energy of nitrogen
(C) 2 V0 (D) 3 V0 gas molecules is 0.02 eV (1eV = 1.6 × 10–19 J).
Calculate the temperature of the of gas. Boltzmann
MULTIPLE CORRECT QUESTION constant k = 1.38 × 10–23 J/K.
12. For an ideal gas molecules the following quantities
having zero average values are. 19. A gas is filled in a rigid container at pressure P0. If
(A) velocity (B) momentum the mass of each molecule is halved keeping the
(C) kinetic energy (D) density total number of molecules same and their r.m.s.
speed is doubled then find the new pressure.
13. Consider a collision between an argon molecule
and a nitrogen molecule in a mixture of argon and 20. The molecules of a given mass of gas have r.m.s.
nitrogen kept at room temperature. Which of the speed 200 ms–1 at 27ºC and 105 Nm–2 pressure.
following are possible? When the absolute temperature is doubled and the
(A) The kinetic energies of both the molecules pressure is halved, then find rms speed of the
decrease. molecules of the same gas.
(B) The kinetic energies of both the molecules
increase 21. Find the number of molecules in 10 cm3 of an ideal
(C) The kinetic energy of the argon molecule gas at 0ºC and at a pressure of 2 × 10–5 mm of
increases and that of the nitrogen molecules mercury.
decrease. Take density of Hg = 13.6 g/cc and g = 10 m/s2, R
(D) The kinetic energy of the nitrogen molecules = 25/3 J/mol–K
increases and that of the argon molecule
decrease. 22. Butane gas burns in air according to the following
SUBJEVTIVE TYPE QUESTIONS reaction,
14. Find the average momentum of molecules of 2 C4H10 + 13 O2 ⎯⎯ → 10 H2O + 8 CO2.
hydrogen gas in a container at temperature 300 K.
Suppose the initial and final temperatures are equal
and high enough so that all reactants and products
15. A cubical container having each side as  is filled act as perfect gases. Two moles of butane are mixed
with a gas having N molecules in the container. with 13 moles of oxygen and then completely
Mass of each molecule is m. If we assume that at reacted. Find the final pressure (if the volume
every instant half of the molecules are moving remains unchanged and the pressure before reaction
towards the positive x-axis and half of the is P0)?
molecules are moving towards the negative x-axis.
Two walls of the container are perpendicular to the 23. Equal masses of air are sealed in two vessels, one
x-axis. Find the force acting on the two walls of volume V0 and the other of volume 2V0. If the
given? Assume that all the molecules are moving first vessel is maintained at a temperature 300 K
with speed v0 . and the other at 600 K, find the ratio of the pressures
in the two vessels.
3
24. A cylinder contains gas at 2 × 105 Pa and 47ºC. The

cylinder is steadily heated. Neglecting any change
in its volume, find the temperature at which the
cylinder will break if the walls of cylinder can bear
a maximum pressure of 8 × 105 Pa.
25. At a pressure of 3 atm air (treated as an ideal gas)

is pumped into the tubes of a cycle rickshaw. The 28. A conducting cylinder whose inside diameter is
volume of each tube at given pressure is 0.004 m3. 4.00 cm contains air compressed by a piston of
One of the tubes gets punctured and the volume of mass m = 13.0 kg, which can slide freely in the
the tube reduces to 0.0008 m3. Find the number of cylinder shown in the figure. The entire
moles of air that have leaked out? Assume that the
arrangement is immersed in a water bath whose
temperature remains constant at 300 K .
temperature can be controlled. The system is
(R = 25/3 J mol–1 K–1)
initially in equilibrium at temperature ti = 20°C.
The initial height of the piston above the bottom of
26. A vessel contains 0.5 g of hydrogen and 0.8 g of
the cylinder is hi = 4.00 cm. Patm = 1 × 105 N/m2 and
5 3
oxygen. The volume of vessel is m while its g = 10 m/s2.
28
If the temperature of the water both is gradually
temperature is maintained at 300 K. Find the
pressure of the mixture. (Assuming no reaction increased to a final temperature tg = 100°C Find the
takes place between hydrogen and oxygen) hight hg of the piston (in cm) at that insane?
25
( MH2 = 2, MO2 = 32 & R = J/mol–K)
3
27. In given figure, A uniform cylindrical tube closed

at one end, contains a pallet of mercury 5 cm long. 29. In the above question, if we again start from the
When the tube is kept vertically with the closed end initial conditions and the temperature is again
downward, the length of the air column trapped is gradually raised, and weights are added to the
30 cm. Now the tube is inverted so that the closed piston to keep its height fixed at hi. Find the value
end goes up find the new length of the air column of the added mass when the final temperature
trapped. Atmospheric pressure = 75 cm of mercury. becomes tf = 100°C?
(Assume temperature remains constant in this
process)
4
Answer Key
1. (C) 32000
18. ( K)
2. (C) 207
3. (C) 19. (2P0)
4. (D) 20. (200 2 ms–1)
5. (A) 21. (7.2 × 1012)
6. (B) 6P0
7. (A) 22. ( )
5
8. (C) 23. (1 : 1)
9. (C) 24. (1280K)
10. (C) 112
11. (B) 25. ( mole)
250
12. (AB) 26. (3850 N/m2)
13. (CD) 240
14. (zero) 27. ( cm)
7
 mv02  1492
15. ( N) 28. ( cm)
  293
320  13 
50 1+
293  4 
16. ( V) 29. ( kg)
3
17. (H2, 1200 K)
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1

Arjuna JEE AIR (2024)

24. A cylinder contains gas at 2 × 105 Pa and 47ºC. The

25. At a pressure of 3 atm air (treated as an ideal gas)

27. In given figure, A uniform cylindrical tube closed

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