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Process GCs/Process Analyzers (Total VOCs)

The document discusses gas chromatography (GC) and continuous analyzer systems from PID Analyzers for process and environmental monitoring. It describes the Model 301C GC and Model 200-B continuous analyzer series, which can monitor a wide range of compounds. These systems feature flexible detector options, easy-to-use software, remote operation capabilities, and multipoint sampling options. The document also provides details on common detector types including photoionization detectors (PID), flame ionization detectors (FID), and thermal conductivity detectors (TCD).

Uploaded by

Jennifer Maclachlan
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© Attribution Non-Commercial (BY-NC)
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Download as PDF, TXT or read online on Scribd
143 views

Process GCs/Process Analyzers (Total VOCs)

The document discusses gas chromatography (GC) and continuous analyzer systems from PID Analyzers for process and environmental monitoring. It describes the Model 301C GC and Model 200-B continuous analyzer series, which can monitor a wide range of compounds. These systems feature flexible detector options, easy-to-use software, remote operation capabilities, and multipoint sampling options. The document also provides details on common detector types including photoionization detectors (PID), flame ionization detectors (FID), and thermal conductivity detectors (TCD).

Uploaded by

Jennifer Maclachlan
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as PDF, TXT or read online on Scribd
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Process GCs/Process Analyzers (total)

For Process and Environmental Monitoring in Chemical, Petrochemical & Manufacturing Plants
FENCELINE, PROCESS, STACKS, AREA MONITORING, CARBON BEDS

Model 301C GC Series

Model 200-B Series

19 Rack Mount

19 Rack Mount

Wall Mount

Wall Mount

301C- GC - BTX, ETO, non-methane HC, H2S, Total S compounds, Natural Gas, Odorants,.. 200 - Continuous Analyzers for total VOCs, Total HCs, Total S compounds, H2, (ppm to %)

MODEL 200/301C PRODUCT LINE

Hydroarbons, VOCs, benzene, 1,3 BD, VC, ETO, H2, CO, CO2, fixed gases, methane, ethylene, natural gas, O2, H2S, Dimethyl sulfate, DMS, SO2, PH3, ASH3, amines, NH3, Methylene chloride, nerve gases, WMDs, transformer gases, ...

Detectors & Applications


Introduction
The Model 301-C PID is a flexible and

GC Applications: PID, FID, FUV, TCD, FPD

versatile Analyzer that is in its fourth generation. This Model is, by far, the most powerful and versatile (with its embedded Pentium PC) 300 series GC developed by us since 1985. The addition of these new Analyzers greatly improves the capability and range of Process Analyzers from PID.

Monitoring effluents from chemical pharmaceutical manufacturing, carbon beds ( Gasoline, Cl HC) Leak detection- from process equipment Stack & Vent monitoring Drying ovens for removing solvents ncineration BTX, VC, ETO, freons, solvents in
ambient, waste sitec or plant atmospheres

GC 301-C Features-

Embedded Pentium Computer with touch screen color VGA display, Microsoft Windows XP ( embedded) & 32 bit PeakWorks Chromatography Software Wide Range of Universal to Specific Detectors Universal: TCD, FUV; Selective: PID, FID, Specific: FPD (S or P)
Easy to use PeakWorks software

Remediation site monitoring Oil and gas exploration Sulfur cpds in air or stacks Odorants in natural gas Natural gas composition VOCs in water with optional
Sparging system (Model 650) Detector Range/Species PID range - ppb-ppm; ppm- %; sub ppb with optional concentrator hyrdocarbons > C4 plus, VOCs, inorganic species such as H2S, NH3, I2, PH3, AsH3, etc. FID Range- 50 ppb- 200,000 ppm measures hydrocarbons only TCD Range- ppm to 100%-Fixed gases, H2, inorganic gases & hydrocarbons FPD Range- ppb-ppm- S cpds; P cpds ppbppm FUV Range- ppb to %- Organic & inorganic cpds, Fixed gases

Easy to modify method software


Compact 19 Rack- NEMA 2 enclosure; or NEMA 4 wall mount

Automatic Restart- In the event of a power outage Automatic calibration; automatically adjusts response on timed frequency; Autozero each run-no zero drift Wide operating range- 16 Bit ADC with 4 decades of autoranging- uses USB 2.0 PID- lamp out alarm; FID/FPD-flame out- shuts off hydrogen and provides alarm, TCD carrier out RS232 digital output; 0-1 VDC analog output Connect directly to Network via T10/ 100 Remote PC operation Diagnostics- lamp/flame out Remote servicing capability via the internet Optional MODBUS or 4-20 mA output

Total Hydroarbons, total VOCs, non methane hydrocarbons, total S, H2S, H2, He, CO2, binary mixtures...

201-B Total VOC Analyzers


Introduction
The Model 201-B PID is a flexible and versatile Analyzer for . More than three thousand of these photoionization detector (PID) based Analyzers have been sold worldwide for applications ranging from carbon bed breakthrough, leak detection to stack and ambient air monitoring. This is attributed to the rugged and durable design that is characteristic of all PID Analyzers products. Several years ago, we added the flame ionization detector (FID) to the 200 series product line. Other Continuous Analyzers in the 200 series include the Model 204 TCD and a Model 205 Total Sulfur Analyzer. The addition of these new Analyzers greatly improves the capability and range of process analyzers from PID.

Applications- total VOCs; total HC, total S, H2,

Leak detection- from process equipment EPA Method 25 Non methane hydrocarbons ina m b i e n t Drying ovens for removing solvents ncineration Inlet & outlet of scrubbers,control devices Total S in stacks, ambient, process
H2, He, snigle component in a binary mixture-TCD air or stacks- FID/Catalyst/dual streams Stack & Vent monitoring

Monitoring effluents from chemical, refining, or manufacturing Carbon bed breakthrough

Features
Bright red LED displays Reliability- This rugged instrument has been improved and upgraded from a very durable line Easy to operate- In the event of a power outage, the instrument will automatically restart Low cost of ownership- The long lifetime of the analyzer coupled with the low level of maintenance results in a low cost of ownership Wide operating range with no range changing necessary- 16 Bit ADC Push button Automatic calibration; automatically adjusts response No span or zero pots; all data stored in uProcessor memory Autozero for PID; Auto zero gas for FID, FPD, TCD PID- lamp out alarm FID/FPD-flame out- shuts off hydrogen and provides alarm RS232 digital output 0-1 VDC analog output Up to 6 dual setpoints that are pregrammablecan be used to shut down a process, remotely dial a number... Two line or multiple sensor displays

Detector Range/Species
PID range - sub-ppm- %; sub ppb with optional concentrator Hyrdocarbons > C4 plus, VOCs, inorganic species such as H2S, NH3, I2, PH3, AsH3, etc. FID Range- 1- 200,000 ppm measures hydrocarbons only TCD Range- ppm to 100%-Fixed gases, H2, inorganic gases & hydrocarbons FPD Range- ppb-ppm- S cpds; P cpds ppbppm

Options
4-20 mA output; RS485 output, MODBUS Dual setpoints- Customer Programmable Data acquisition and storage using DataWorks software- runs under Windows or Windows NT on a Pentium PC 2 point, Separate Display of Each Sample Poin Multipoint sequencer- see back page of brochure

Detectors for Process GC or Continuous Analyzers

Detector Description for 301-C/200-B


PID has been building detectors for more than thirty years and has sold more than 20,000 detectors of all types.. Ours are the best on the maerket in terms of sensitivity, durability and technology. A descripition of the three most common type of detectors for our analyzers are given below:

Multipoint Sequencers for 301-C/ 200-B


The 301-C/ 200-B have several multipoint options The first is a simple 2 point system that can be used to monitor the inlet and output of a scrubber, catalytic oxidizer, carbon bed etc. to determine the efficiency of the system. The second option can be a 4, 8, or 12 (up to 32) point system. This system employs a manifold with needle valves and a 2 way valve for each channel. The flow for each channel is measured with a flowmeter indicator to determine whether points have inadequate flows. The channel sequence in the 301-C can be programmed (optional). The channels can be turned on/ off in the 301-C by clicking on a box in the method; the flows in the 200-B by turning on/off a switch. Two levels of alarm can be programmed for each channel in the system on the 301C. The alarm levels in the 200-C are the same for all channels. These Multipoint systems provides an inexpensive alternative to a sensor for each point. The cost of maintaining and/or calibrating this single system is considerably less expensive than maintaining a 8 or 12 individual sensor system. The 301-C/201-C multipoint system can be easily interfaced with a PLC or DCS system that is already at the Plant. The 301C can also be hooked into an intranet in the plant. Contact PID for additional information on in this area.

PID-Description
The process of photoionization is initiated by the absorp-tion of a photon of ultraviolet radiation energetic enough to ionize a molecule (RH) by the process shown below: RH + h RH+ + ewhere h represents a photon with an energy the ionization potential of species RH. The ions are collected in an ionization chamber which is adjacent to the lamp and contains an accelerat-ing electrode (biased positively) and a collection electrode where the current is measured. After amplification, the current measured is proportional to concentration. The response measured will be a summation (total) of the hydrocarbons ionized.

FID Description
In the FID, the sample is burned in a hydrogen-air flame and the ions formed from carbon containing compounds are collected by applying a positive potential to the jet and measuring the current at collection electrode just above the flame. After amplification, the current measured is proportional to concentration. The response measured will be a summation (total) of the hydrocarbons ionized.

TCD Description
Measures difference between the thermal transfer characteristics of the sample gas and a reference gas, generally helium. The sample and reference filaments are two legs of a Wheatstone Bridge. A constant current is applied with a resultant in a rise

in filament temperature. As the sample passes through the detector, the resistance changes as the carrier/reference gas is replaced by the sample with a different thermal conductivity. The change in
resistance is proportional to the concentration.

PID ANALYZERS, LLC


780 Corporate Park Dr., Pembroke, MA 02359 Tel. 1-781-709-2131 USA or Canada 1-800-PID-6826 Fax. 1-781-709-2050 Web: http://www.hnu.com E-mail: sales@hnu.com PID Analyzers, UK, 9 Pennington Close, Frodsham Cheshire WA6 7NL Tel/Fax 01928-732-395 Web: http://www.pidanalyzers.co.uk E-mail: sales@pidanalyzers.co.uk HNU Nordion, Ltd, OY, Atomitie 5 A 3, PL 1, Helsinki, Finland Tel. +358-9-565 7240 Fax +350-9-562 6801 Web: http://www.hnunordion.fi E-mail: Info@hnunordion.fi

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