Solutions

Bright Tuition classes
Subject : Chemistry Paper Set : 1

Standard : 12 Solutions Date : 25-10-2024
Total Mark : 600 Time : 0H:0M
............................................. Chemistry - Section A (MCQ) .............................................
(1) How many grams of methyl alcohol should be added to 10 litre tank of water to prevent its freezing at 268 K ? ............. g (Kf for
water is 1.86 K kg mol−1 ) [JEE MAIN 2013]
(A) 880.07 (B) 899.04 (C) 886.02 (D) 868.06
(2) 1 molal aqueous solution of an electrolyte A2 B3 is 60% ionised. The boiling point of the solution at 1 atm is ......... K.
(Rounded-off to the nearest integer) ]
[Given Kb for (H2 O) = 0.52 K kg mol−1 [JEE MAIN 2021]
(A) 370 (B) 380 (C) 375 (D) 385
(3) 1 molal K4 F e(CN )6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of another solution which
contains 18.1 weight percent of] a non electrolytic solute A. The molar mass of A is ....... u. (Round off to the Nearest Integer).
[Density of water = 1.0 g cm−3 [JEE MAIN 2021]
ss
(A) 95 (B) 85 (C) 105 (D) 26
(4) Solute A associates in water. When 0.7 g of solute A is dissolved in 42.0 g of water, it depresses the freezing point by 0.2◦ C. The
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percentage association of solute A in water, is ..... %
[Given : Molar mass of A = 93 g mol−1 . Molal depression constant of water is 1.86 K kg mol−1 ] [JEE MAIN 2022]
(A) 50 (B) 60 (C) 70 (D) 80
on
(5) Two elements A and B which form 0.15 moles of A2 B and AB3 type compounds. If both A2 B and AB3 weigh equally, then the
atomic weight of A is .... times of atomic weight of B. [JEE MAIN 2022]
(A) 45 (B) 4 (C) 2 (D) 9
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(6) 2.7Kg of each of water and acetic acid are mixed, The freezing point of the solution will be −x C. Consider the acetic acid does
◦
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not dimerise in water, nor dissociates in water x = . . . . . . . (nearest integer)

[Given : Molar mass of water = 18 g mol−1 , acetic acid = 60 g mol−1 ]
T
Kf
H2 O : 1.86 K kg mol−1
ht
Kr acetic acid : 3.90 K kg mol−1

freezing point: H2 O = 273 K, acetic acid = 290 K ] [JEE MAIN 2024]
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(A) 31 (B) 35 (C) 37 (D) 40

(7) Of the following four aqueous solutions, total number of those solutions whose freezing point is lower than that of
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0.10 MC2 H5 OH is (Integer answer)

(i) 0.10 M Ba3 (PO4 )2 (ii) 0.10 M Na2 SO4 (iii) 0.10 M KCl (iv) 0.10 M Li3 PO4 [JEE MAIN 2021]
(A) 4 (B) 3 (C) 1 (D) 2
(8) Toluene in the vapour phase is in equilibrium with a solution of benzene and toluene having mole fraction of toulene 0.50 If
vapour pressure of pure benzene is 119 torr and that of toluene is 37.0 torr at the same temperature, mole fraction of toluene in
vapour phase will be: [NEET 2017]
(A) 0.462 (B) 0.237 (C) 0.506 (D) 0.325
(9) A solution containing 2 g of a non-volatile solute in 20 g of water boils at 373.52 K. The molecular mass of the solute is
.......g mol−1 . (Nearest integer) Given, water boils at 373 K, Kb for water = 0.52 K kg mol−1 [JEE MAIN 2023]
(A) 10 (B) 100 (C) 80 (D) 90
(10) 10.30 mg of O2 is dissolved into a liter of sea water of density 1.03 g/mL. The concentration of O2 in ppm is [JEE MAIN 2020]
(A) 13 (B) 10 (C) 8 (D) 6
(11) 20% of acetic acid is dissociated when its 5 g is added to 500 mL of water. The depression in freezing point of such water is
..... × 10−3 ◦ C. Atomic mass of C, H and O are 12, 1 and 16 a.m.u. respectively.
[Given : Molal depression constant and density of water are 1.86 K kg mol−1 and 1 g cm−3 respectively.] [JEE MAIN 2023]
(A) 371 (B) 372 (C) 373 (D) 375
(12) The vapour pressure of 30%(w/v) aqueous solution of glucose is ...... mm Hg at 25 C.[Given : The density of 30% (w/v),
◦
aqueous solution
) of glucose is 1.2 g cm−3 and vapour pressure of pure water is 24 mm Hg.](Molar mass of glucose is
−1
180 g mol . [JEE MAIN 2023]
(A) 23 (B) 22 (C) 21 (D) 24
1
(13) The van’t Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium hydroxide is [NEET 2016]
(A) 0 (B) 1 (C) 2 (D) 3
(14) Which of the following is dependent on temperature ? [NEET 2017]
(A) Molarity (B) Mole fraction (C) Weight percentage (D) Molality
(15) A soft drink was bottled with a partial pressure bf CO2 of 3 bar over the liquid at room temperature. The partial pressure of CO2
over the solution approaches a value of 30 bar when 44 g of CO2 is dissolved in 1 kg of water at room temperature. The
approximate pH of the soft drink is............... ×10−1 )
(First dissociation constant of H2 CO3 = 4.0 × 10−7 log 2 = 0.3; density of the soft drink = 1 g mL−1 [JEE MAIN 2020]
(A) 37 (B) 35 (C) 40 (D) 32
(16) AB2 is 10% dissociated in water to A and B . The boiling point of a 10.0 molal aqueous solution of AB2 is ............ ◦ C. (Round
2+ −
off to the Nearest Integer).

[Given : Molal elevation constant of water Kb = 0.5 K kg mol−1 boiling point of pure water = 100◦ C] [JEE MAIN 2021]
(A) 201 (B) 105 (C) 102 (D) 106
(17) How much amount of NaCl should be added to 600 g of water (ρ = 1.00 g/mL) to decrease the freezing point of water to
−0.2◦ C? ............. gm
(The freezing point depression constant for water = 2 K kg mol−1 ) [JEE MAIN 2020]
(A) 2.25 (B) 2 (C) 1.75 (D) 1.5
(18) An aqueous solution of a salt M X2 at certain temperature has a van’t Hoff factor of 2. The degree of dissociation for this solution
of the salt is [JEE MAIN 2016]
(A) 0.50 (B) 0.33 (C) 0.67 (D) 0.80
(19) The osmotic pressure of a solution of N aCl is 0.10 atm and that of a glucose solution is 0.20 atm. The osmotic pressure of a
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solution formed by mixing 1 L of the sodium chloride solution with 2 L of the glucose solution is x × 10−3 atm. x is.......... (nearest
integer) [JEE MAIN 2020]
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(A) 150 (B) 167 (C) 160 (D) 159
(20) 12 g of a nonvolatile solute dissolved in 108 g of water produces the relative lowering of vapour pressure of 0.1. The molecular
mass of the solute is [JEE MAIN 2013]
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(A) 80 (B) 60 (C) 20 (D) 40
(21) If a compound Ab dissociates to the extent of 75 % in an aqueous solution, the molality of the solution which shows a 2.5 K rise
in the boiling point of the solution is ......
[ molal.
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]
(Rounded-off to the nearest integer) Kb = 0.52 K kg mol−1 [JEE MAIN 2021]
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(A) 4 (B) 3 (C) 6 (D) 5

(22) Which one of the following is incorrect for ideal solution ? [NEET 2016]
T
(A) ∆Hmix = 0 (B) ∆Umix = 0

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(C) ∆P = Pobs − Pcalculated by Raoult′ s law = 0 (D) ∆Gmix = 0

(23) If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0.3, then the observed freezing
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point will be .....% higher than the expected/theoretical freezing point. (Nearest integer) [JEE MAIN 2023]
(A) 31 (B) 30 (C) 32 (D) 33
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(24) When 10 mL of an aqueous solution of KMnO4 was titrated in acidic medium, equal volume of 0.1 M of an aqueous solution of
ferrous sulphate was required for complete discharge of colour. The strength of KMnO4 in grams per litre is ...... × 10−2 . (Nearest
integer)
Atomic mass of K = 39, Mn = 55, O = 16] [JEE MAIN 2021]
(A) 94 (B) 152 (C) 316 (D) 656
(25) A set of solutions is prepared using 180 g of water as a solvent and 10 g of different non-volatile solutes A, B and C. The relative
lowering of vapour pressure in the presence of these solutes are in the order ]
[Given, molar mass of A = 100 g mol−1 ; B = 200 g mol−1 C = 10, 000 g mol−1 [JEE MAIN 2020]
(A) A > B > C (B) A > C > B (C) C > B > A (D) B > C > A
(26) Which of them is not equal to zero for an ideal solution ? [NEET 2015]
(A) ∆Vmix (B) ∆P = Pobserved − PRaoult (C) ∆Hmix (D) ∆Smix

(27) The solubility of N2 in water at 300 K and 500 torr partial pressure is 0.01 g L −1
.The solubility ( in g L−1 )at 750 torr partial
pressure is [JEE MAIN 2016]
(A) 0.0075 (B) 0.005 (C) 0.02 (D) 0.015
(28) What weight of glucose must be dissolved in 100g of water to lower the vapour pressure by 0.20 mm Hg ? (Assume dilute
solution is being formed) Given: Vapour pressure of pure water is 54.2 mm Hg at room temperature. Molar mass of glucose is
180 g mol−1 [JEE MAIN 2023]
(A) 4.69 g (B) 3.59 g (C) 2.59 g (D) 3.69 g
(29) Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing point depression ? [NEET 2014]
(A) KCl (B) C6 H12 O6 (C) Al2 (SO4 )3 (D) K2 SO4
2
(30) The following solutions were prepared by dissolving 10 g of glucose (C6 H12 O6 ) in 250 ml of water (P1 ), 10 g of urea (CH4 N2 O) in
250 ml of water (P2 ) and 10 g of sucrose (C12 H22 O11 ) in 250 ml of water (P3 ). The right option for the decreasing order of
osmotic pressure of these solutions is : [NEET 2021]
(A) P2 > P1 > P3 (B) P1 > P2 > P3 (C) P2 > P3 > P1 (D) P3 > P1 > P2
(31) The osmotic pressure exerted by a solution prepared by dissolving 2.0 g of protein of molar mass 60 kg mol−1 in 200 mL of water
at 27◦ C is .....P a. [integer value]
(use R = 0.083L bar mol−1 K −1 ) [JEE MAIN 2022]
(A) 236 (B) 654 (C) 313 (D) 415
(32) Which one of the following statements regarding Henry’s law is not correct? [JEE MAIN 2019]
(A) Higher the value of KH at a given pressure, higher is the solubility of the gas in the liquids
(B) Different gases have different KH (Henry’s law constant) values at the same temperature
(C) The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the solution
(D) The value of KH increases with increase of temperature and KH is function of the nature of the gas
(33) 0.05MCuSO4 when treated with 0.01MK2 Cr2 O7 gives green colour solution of Cu2 Cr2 O7 . The [SP M : Semi Permeable
Membrane]
K2 Cr2 O7 & CuSO 4
SideX SP M Side Y Due to osmosis : [JEE MAIN 2024]
(A) Green colour formation observed on side Y . (B) Green colour formation observed on side X.
(C) Molarity of K2 Cr2 O7 solution is lowered. (D) Molarity of CuSO4 solution is lowered.
(34) If 8 g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapour pressure to 80%, the molar mass (in
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gmol−1 ) of the solute is
Given that molar mass of n-octane is 114 g mol−1 [NEET 2020]
(A) 20 (B) 40
(35) Consider the dissociation of the weak acid HX as given below
HX(aq) ⇌ H+ (aq) + X(aq), Ka = 1.2 × 10−5
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(C) 60 (D) 80
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[Kn : dissociation constant]
The osmotic pressure of 0.03M aqueous solution of HX at 300 K is ............... ×10−2 bar (nearest integer).
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[ Given : R = 0.083 LbarMol−1 K−1 ] [JEE MAIN 2024]

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(A) 76 (B) 77 (C) 79 (D) 80

(36) The freezing point depression constant (Kf ) of benzene is 5.12 K kg mol . The freezing point depression for the solution of
−1
T
molality 0.078 m containing a non-electrolyte solute in benzene is.......... K (rounded off upto two decimal places) [NEET 2020]
ht
(A) 0.60 (B) 0.20 (C) 0.80 (D) 0.40

(37) The vapour pressure of pure benzene and methyl benzene at 27 C is given as 80Torr and 24Torr, respectively. The mole fraction
◦
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of methyl benzene in vapour phase, in equilibrium with an equimolar mixture of those two liquids (ideal solution) at the same
temperature is. . . . . . .×10−2 (nearest integer) [JEE MAIN 2024]
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(A) 20 (B) 25 (C) 23 (D) 30

(38) The molarity of a solution obtained by mixing 750 mL of 0.5(M ) HCl with 250 mL of 2(M ) HCl will be .........M [JEE MAIN 2013]
(A) 0.87 (B) 1.00 (C) 1.75 (D) 0.97

(39) Solution of 12 g of non - electrolyte (A) prepared by dissolving it in 1000 mL of water exerts the same osmotic pressure as that
of 0.05 M glucose solution at the same temperature. The empirical formula of A is CH2 O. The molecular mass of A is ..........g.
(Nearest integer) [JEE MAIN 2023]
(A) 241 (B) 242 (C) 240 (D) 243
(40) An aqueous solution of volume 300 cm contains 0.63 g of protein. The osmotic pressure of the solution at 300 K is 1.29 mbar.
3
The molar mass of the protein is ......... g mol−1 Given : R = 0.083 L bar K −1 mol−1 [JEE MAIN 2023]
(A) 40536 (B) 40537 (C) 40535 (D) 40538
(41) Elevation in boiling point for 1.5 molal solution of glucose in water is 4 K. The depression in freezing point for 4.5 molal solution
of glucose in water is 4 K The ratio of molal elevation constant to molal depression constant (Kb /Kf ) is .... [JEE MAIN 2022]
(A) 4 (B) 1 (C) 2 (D) 3
(42) Considering acetic acid dissociates in water, its dissociation constant is 6.25 × 10 . If 5 mL of acetic acid is dissolved in 1 litre
−5
water, the solution will freeze at −x × 10−2◦ C, provided pure water freezes at 0◦ C.
x = . . . . . . . . . (Nearest integer)
Given : (Kr )water = 1.86 K kg mol−1 .
density of acetic acid is 1.2 g mol−1
molar mass of water = 18 g mol−1 .
3
molar mass of acetic acid = 60 g mol−1 .
density of water = 1 g cm−3
Acetic acid dissociates as
CH3 COOH ⇌ CH3 COO⊕ + H⊕ [JEE MAIN 2024]
(A) 19 (B) 20 (C) 25 (D) 30
(43) The boiling point of 0.2 mol kg solution of X in water is greater than equimolal solution of Y in water. Which one of the
−1
following statements is true in this case ? [NEET 2015]

(A) Molecular mass of X is less than the molecular mass of Y.
(B) Y is undergoing dissociation in water while X undergoes no change.
(C) X is undergoing dissociation in water.
(D) Molecular mass of X is greater than the molecular mass of Y.
(44) Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : 3.1500 g of hydrated oxalic acid dissolved in water to make 250.0 mL solution will result in 0.1 M oxalic acid
solution.
Reason R : Molar mass of hydrated oxalic acid is 126 g mol−1 .
In the light of the above statements, chose the correct answer from the options given below: [JEE MAIN 2023]
(A) Both A and R are true but R is NOT the correct explanation of A.
(B) A is false but R is true.
(C) A is true but R is false.
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(D) Both A and R are true and R is the correct explanation of A.
(45) 2 molal solution of a weak acid HA has a freezing point of 3.885◦ C. The degree of dissociation of this acid is ........ ×10−3 . (Round
(A) 50 (B) 60
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[Given : Molal depression constant of water = 1.85 K kg mol−1 Freezing point of pure water = 0◦ C] [JEE MAIN 2021]
(C) 55 (D) 65
on
(46) 40 g of glucose (Molar mass = 180 ) is mixed with 200 mL of water. The freezing point of solution is ..... K. (Nearest integer)
[Given : Kf = 1.86 K kg mol−1 ; Density of water = 1.00 g cm−3 ; Freezing point of water = 273.15 K] [JEE MAIN 2021]
(A) 271 (B) 370 (C) 71 (D) 521
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(47) Isotonic solutions have same [NEET 2020]

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(A) Boiling temperature (B) Vapour pressure (C) Freezing temperature (D) Osmotic pressure
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(48) At 363 K, the vapour pressure of A is 21 kP a and that of B is 18 kP a. One mole of A and 2 moles of B are mixed. Assuming that
this solution is ideal, the vapour pressure of the mixture is ....... kP a. (Round of to the Nearest Integer). [JEE MAIN 2021]
ht
(A) 19 (B) 21 (C) 25 (D) 36

(49) A graph of vapour pressure and temperature for three different liquids X, Y and Z is shown below
ig
The following inferences are made

(A) X has higher intermolecular interactions compared to Y .
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(B) X has lower intermolecular interactions compared to Y .

(C) Z has lower intermolecular interactions compared to Y.
The correct inference(s) is/are [JEE MAIN 2020]
(A) (A) (B) (C) (C) (B) (D) (A) and (C)
( )
(50) The plot of osmotic pressure (�) vs concentration molL for a solution gives a straight line with slope 25.73 Lbarmol−1 . The
−1
temperature at which the osmotic pressure measurement is done is

(Use R = 0.083 L bar mol m−1 K−1 ) [NEET 2024]
(A) 310◦ C (B) 25.73◦ C (C) 12.05◦ C (D) 37◦ C
(51) 2.5 g of a non-volatile, non-electrolyte is dissolved in 100 g of water at 25◦ C. The solution showed a boiling point elevation by
2◦ C. Assuming the solute concentration in negligible with respect to the solvent concentration, the vapour pressure of the
resulting aqueous solution is . . . . . . mm of Hg (nearest integer)
[Given : Molal boiling point elevation constant of water (Kb ) = 0.52K.kgmol−1 ,
4
⌋
1 atm pressure = 760 mm of Hg, molar mass of water = 18 g mol−1 [JEE MAIN 2024]
(A) 702 (B) 704 (C) 705 (D) 707

(52) The elevation in boiling point for 1 molal solution of non-volatile solute A is 3 K. The depression in freezing point for 2 molal
solution of A in the same solvent is 6 K. The ratio of Kb and Kf i.e., Kb /Kf is 1 : X. The value of X is [nearest integer] [JEE MAIN 2022]
(A) 0 (B) 1 (C) 2 (D) 3
(53) A solution containing 10 g of an electrolyte AB2 in 100 g of water boils at 100.52 C. The degree of ionization of the electrolyte
◦
(α) is............ ×10−1 .

(nearest integer)
[Given : Molar mass of AB2 = 200 g mol−1 · Kb
(molal boiling point elevation const. of water)
= 0.52 K kg mol−1 , boiling point of water = 100◦ C;
]
AB2 ionises as AB2 → A2+ + 2 B− [JEE MAIN 2024]
(A) 3 (B) 5 (C) 6 (D) 8
(54) The mixture which shows positive deviation from Raoult’s law is [NEET 2020]
(A) Chloroethane + Bromoethane (B) Ethanol + Acetone
(C) Benzene + Toluene (D) Acetone + Chloroform
(55) The vapour pressures of two volatile liquids A and B at 25 C are 50 T orr and 100 T orr, respectively. If the liquid mixture
◦
contains 0.3 mole fraction of A, then the mole fraction of liquid B in the vapour phase is 17
x
. The value of x is ... [JEE MAIN 2022]
(A) 140 (B) 89 (C) 14 (D) 54
(56) A molecule M associates in a given solvent according to the equation M ⇌ (M )n For a certain concentration of M, the van’t
ss
Hoff factor was found to be 0.9 and the fraction of associated molecules was 0.2. The value of n is [JEE MAIN 2013]
(A) 3 (B) 5 (C) 2 (D) 4
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(57) ‘The vapour pressure vs. temperature curve for a solution solvent system is shown below.The boiling point of the solvent is
........ ◦ C [JEE MAIN 2023]
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T ui
ht
ig
(A) 81 (B) 82 (C) 83 (D) 84

(58) A gaseous mixture of two substances A and B, under a total pressure of 0.8 atm is in equilibrium with an ideal liquid solution.
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The mole fraction of substance A is 0.5 in the vapour phase and 0.2 in the liquid phase. The vapour pressure of pure liquid A ......
is atm. (Nearest integer) [JEE MAIN 2022]
(A) 1 (B) 0 (C) 2 (D) 3
(59) At 300 K, the vapour pressure of a solution containing 1 mole of n−hexane and 3 moles of n−heptane is 550 mm of Hg. At the
same temperature, if one more mole of n-heptane is added to this solution, the vapour pressure of the solution increases by
10 mm of Hg. What is the vapour pressure in mmHg of n−heptane in its pure state..........? [JEE MAIN 2020]
(A) 600 (B) 620 (C) 590 (D) 628
(60) Mass of Urea (N H2 CON H2 ) required to be dissolved in 1000g of water to reduce the vapour pressure of water by 25% is ......g.
(Nearest integer) Given: Molar mass of N, C, O and H are 14, 12, 16 and 12 mol−1 respectively. [JEE MAIN 2023]
(A) 1112 (B) 1113 (C) 1114 (D) 1111
(61) Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y . respectively in 1 kg of water. The ratio of
depression in freezing points for A and B is found to be 1 : 4. The ratio of molar masses of X and Y is. [JEE MAIN 2022]
(A) 1 : 4 (B) 1 : 0.25 (C) 1 : 0.20 (D) 1 : 5
(62) If molality of the dilute solution is doubled, the value of molal depression constant (Kf ) will be [NEET 2017]
(A) halved (B) tripled (C) unchanged (D) doubled.
(63) Which one of the following 0.10 M aqueous solutions will exhibit the largest freezing point depression? [JEE MAIN 2021]
(A) hydrazine (B) glucose (C) glycine (D) KHSO4

(64) The oxygen dissolved in water exerts a partial pressure of 20 kP a in the vapour above water. The molar solubility of oxygen in
water is ............ − × 10−5 mol dm−3
(Round off to the Nearest Integer).
5
[Given : Henry’s law constant = KH = 8.0 × 104 kP a for O2 Density of water with dissolved oxygen = 1.0 kg dm−3 ] [JEE MAIN 2021]
(A) 20 (B) 15 (C) 30 (D) 25
(65) A solution containing 2.5 × 10 kg of a solute dissolved in 75 × 10 kg of water boils at 373.535 K. The molar mass of the
−3 −3
solute is ..... g mol−1 . [nearest integer] (Given: Kb (H2 O) = 0.52 K Kg mol−1 , boiling point of water = 373.15 K ) [JEE MAIN 2022]
(A) 50 (B) 93 (C) 10 (D) 45
(66) If 80 g of copper sulphate CuSO4 · 5H2 O is dissolved in deionised water to make 5 L of solution. The concentration of the copper
sulphate solution is x × 10−3 mol L−1 . The value of x is .... .
[Atomic masses Cu : 63.54 u, S : 32 u, O : 16 u, H : 1 u] [JEE MAIN 2021]
(A) 49 (B) 80 (C) 64 (D) 17
(67) CO2 gas is bubbled through water during a soft drink manufacturing process at 298 K. If CO2 exerts a partial pressure of 0.835 bar
then x m mol of CO2 would dissolve in 0.9 L of water. The value of x is ..... (Nearest integer)
(Henry’s law constant for CO2 at 298 K is 1.67 × 103 bar) [JEE MAIN 2021]
(A) 50 (B) 25 (C) 55 (D) 35
(68) When a certain amount of solid A is dissolved in 100 g of water at 25 C to make a dilute solution, the vapour pressure of the
◦
solution is reduced to one-half of that of pure water. The vapour pressure of pure water is 23.76 mm Hg. The number of moles of
solute A added is ........... (Nearest Integer) [JEE MAIN 2022]
(A) 2 (B) 3 or 6 (C) 4 (D) 5
(69) Match List I with List II.
List I List II
A van’t Hoff factor, i I Cryoscopic constant
II Isotonic solutions
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B kf
C Solutions with same osmotic pressure III N ormal molar mass
Abnormal molar mass
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D Azeotropes IV Solutions with same composition of vapour
above it
Choose the correct answer from the options given below : [JEE MAIN 2023]
(A) A − III, B − I, C − II, D − IV (B) A − III, B − II, C − I, D − IV
on
(C) A − III, B − I, C − IV, D − II (D) A − I, B − III, C − II, D − IV
(70) The depression in freezing point observed for a formic acid solution of concentration 0.5 mL L−1 is 0.0405◦ C. Density of formic
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acid is 1.05 g mL−1 . The Van’t Hoff factor of the formic acid solution is nearly: (Given for water kf = 1.86 K kg mol−1 ) [JEE MAIN
ui
2022]
(A) 0.8 (B) 1.1 (C) 1.9 (D) 2.4

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(71) 80 mole percent of M gCl2 is dissociated in aqueous solution. The vapour pressure of 1.0 molal aqueous solution of M gCl2 at
38◦ C is ......... mm Hg. (Nearest integer)Given : Vapour pressure of water at 38◦ C is 50 mm Hg [JEE MAIN 2023]
ht
(A) 47 (B) 48 (C) 46 (D) 45

(72) The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient intravenously, it has to be isotonic with blood.
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The concentration of glucose solution in g L−1 is ...... (Molar mass of glucose = 180 g mol−1
R = 0.083 L bar K −1 mol−1 ) (Nearest integer) [JEE MAIN 2022]
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(A) 11 (B) 33 (C) 54 (D) 44

(73) Boiling point of a 2% aqueous solution of a nonvolatile solute A is equal to the boiling point of 8% aqueous solution of a
non-volatile solute B. The relation between molecular weights of A and B is. [JEE MAIN 2022]
(A) MA = 4MB (B) MB = 4MA (C) MA = 8MB (D) MB = 8MA
(74) A mixture of one mole each of H2 , He and O2 each are enclosed in a cylinder of volume V at temperature T. If the partial
pressure of H2 is 2 atm, the total pressure of the gases in the cylinder is.......atm [JEE MAIN 2020]
(A) 14 (B) 22 (C) 6 (D) 38
(75) At 27 C, a solution containing 2.5 g of solute in 250.0 mL of solution exerts an osmotic pressure of 400 P a. The molar mass of
◦
the solute is ..............g mol −1 (Nearest integer)(Given : R = 0.083 L bar K −1 mol−1 ) [JEE MAIN 2023]
(A) 62240 (B) 62258 (C) 62240 (D) 62250
(76) Which one of the following 0.06 M aqueous solutions has lowest freezing point? [JEE MAIN 2021]
(A) C6 H12 O6 . (B) K2 SO4 (C) KI (D) Al2 (SO4 )3

(77) C6 H6 freezes at 5.5 C. The temperature at which a solution 10 g of C4 H10 in 200 g of C6 H6 freeze is ...... ◦ C. (The molal freezing
◦
point depression constant of C6 H6 is 5.12 ◦ C/m. ) [JEE MAIN 2021]

(A) 3 (B) 1 (C) 5 (D) 9
(78) The Total pressure observed by mixing two liquid A and B is 350 mm Hg when their mole fractions are 0.7 and 0.3
respectively.The Total pressure becomes 410 mm Hg if the mole fractions are changed to 0.2 and 0.8 respectively for A and B.
The vapour pressure of pure A is ........... mm Hg. (Nearest integer)
Consider the liquids and solutions behave ideally. [JEE MAIN 2023]
(A) 314 (B) 312 (C) 311 (D) 310
6
(79) Which one of the following electrolytes has the same value of van’t Hoff factor (i) as that of Al2 (SO4 )3 (if all are 100% ionised)?
[NEET 2015]
(A) Al(N O3 )3 (B) K4 [F e(CN )6 ] (C) K2 SO4 (D) K3 [F e(CN )6 ]

(80) If O2 gas is bubbled through water at 303 K, the number of millimoles of O2 gas that dissolve in 1 litre of water is (Nearest
Integer) (Given : Henry’s Law constant for O2 at 303 K is 46.82 k bar and partial pressure of O2 = 0.920 bar ) (Assume solubility
of O2 in water is too small, nearly negligible) [JEE MAIN 2022]
(A) 0 (B) 1 (C) 2 (D) 3
(81) For an ideal solution, the correct option is [NEET 2019]
(A) ∆mix S = 0 at constant T and P (B) ∆mix V ̸= 0 at constant T and P
(C) ∆mix H = 0 at constant T and P (D) ∆mix G = 0 at constant T and P
(82) When ’ x ’ ×10 mL methanol (molar mass = 32 g; density = 0.792 g/cm3 ) is added to 100 mL water (density = 1 g/cm3 ), the
−2
following diagram is obtained.

(Image)
x =.. . . . . .(nearest integer)
[Given: Molal freezing point depression constant of water at 273.15 K2 is 1.86 K kg mol−1 ] [JEE MAIN 2024]
ss
(A) 540 (B) 542 cla
(C) 543 (D) 550
on
(83) 224 mL of SO2(g) at 298K and 1 atm is passed through 100 mL of 0.1 M N aOH solution. The non-volatile solute produced is
(dissolved in 36 g of water. The lowering of vapour pressure of solution (assuming the solution is dilute)
P(H2 O) = 24 mm of Hg) is x × 10−2 mm of Hg the value of x is ...... .(Integer answer) [JEE MAIN 2021]
ti
(A) 50 (B) 12 (C) 67 (D) 89

ui
(84) In water saturated air the mole fraction of water vapour is 0.02. If the total pressure of the saturated air is 1.2 atm, the partial
pressure of dry air is .....atm [NEET 2019]
T
(A) 1.21 (B) 1.76 (C) 1.17 (D) 0.98

ht
(85) How many grams of concentrated nitric acid solution should be used to prepare 250 mL of 2.0 M HN O3 ? The concentrated
acid is 70% HN O3 . [NEET 2013]
ig
(A) 70.0 g conc. HN O3 (B) 54.0 g conc. HN O3 (C) 45.0 g conc. HN O3 (D) 90.0 g conc. HN O3
(86) The mixture that forms maximum boiling azeotrope is [NEET 2019]
Br
(A) Water + Nitric acid (B) Ethanol + Water

(C) Acetone + Carbon disulphide (D) Heptane + Octane
(87) When 9.45 g of ClCH2 COOH is added to 500 mL of water, its freezing point drops by 0.5◦ C. The dissociation constant of
ClCH2 COOH is x × 10−3 . The value of x is ...............
(Rounded
[ off to the nearest integer)
]
Kf (H2 O) = 1.86 K kgmol−1 [JEE MAIN 2021]
(A) 38 (B) 42 (C) 36 (D) 44
(88) What is the mole fraction of the solute in a 1.00 m aqueous solution ? [AIPMT 2011 , NEET 2015]
(A) 1.770 (B) 0.0354 (C) 0.0177 (D) 0.177

(89) The elevation of boiling point of 0.10 m aqueous CrCl3 , xN H3 solution is two times that of 0.05 m aqueous CaCl2 solution. The
value of x is.........
[Assume 100% ionisation of the complex and CaCl2 , coordination number of Cr as 6, and that all N H3 molecules are present
inside the coordination sphere ] [JEE MAIN 2020]
(A) 10 (B) 5 (C) 12 (D) 15
(90) 0.004 M K2 SO4 solution is isotonic with 0.01 M glucose solution. Percentage dissociation of K2 SO4 is ........ (Nearest integer)
[JEE MAIN 2023]
(A) 71 (B) 73 (C) 74 (D) 75

(91) 83 g of ethylene glycol dissolved in 625 g of water.The freezing point of the solution is ......K.
(Nearest integer) ]
[Use : Molal Freezing point depression constant of water = 1.86 K kg mol−1
7
Freezing Point of water = 273 K
Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u] [JEE MAIN 2021]
(A) 369 (B) 269 (C) 209 (D) 296
(92) If 250 cm3 of an aqueous solution containing 0.73 g of a protein A is isotonic with one litre of another aqueous solution containing
1.65 g of a protein B, at 298 K, the ratio of the molecular mases of A and B is..........×10−2 (to the nearest integer). [JEE MAIN 2020]
(A) 172 (B) 175 (C) 180 (D) 177
(93) An artificial cell is made by encapsulating 0.2M glucose solution within a semipermeable membrane. The osmotic pressure
developed when the artificial cell is placed within a 0.05M solution of NaCl at 300 K is . . . . . . . . . .×10−1 bar. (Nearest Integer)
[Given : R = 0.083 Lbarmol−1 K−1 ]
Assume complete dissociation of NaCl [JEE MAIN 2024]
(A) 10 (B) 20 (C) 25 (D) 30
(94) The Henry’s law constant (KH ) values of three gases (A, B, C) in water are 145, 2 × 10 −5
and 35 kbar, respectively. The solubility
of these gases in water follow the order: [NEET 2024]
(A) B > C > A (B) A > C > B (C) A > B > C (D) B > A > C
(95) Which condition is not satisfied by an ideal solution? [NEET 2013]
(A) ∆mix V = 0 (B) ∆mix S = 0
(C) Obeyance to Raoult’s Law (D) ∆mix H = 0
(96) The correct option for the value of vapour pressure of a solution at 45◦ C with benzene to octane in molar ratio 3 : 2 is ...... mm of
Hg
[At 45◦ C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas] [NEET 2021]
ss
(A) 160 (B) 168 (C) 336 (D) 350
(97) 1 kg of 0.75 molal aqueous solution of sucrose can be cooled up to −4 C before freezing. The amount of ice (in g) that will be
◦
cla
separated out is .... . (Nearest integer) ]
[ Given : Kf (H2 O) = 1.86 K kg mol−1 [JEE MAIN 2021]
(A) 342 (B) 841 (C) 518 (D) 277
(98) A solution is prepared by adding 2 g of ’ X ’ of 1 mole of water. Mass percent of ’ X ’ in the solution is .............% [JEE MAIN 2023]
on
(A) 20 (B) 5 (C) 2 (D) 10
(99) 1.80 g of solute A was dissolved in 62.5 cm of ethanol and freezing point of the solution was found to be 155.1 K. The molar
3
ti
mass of solute A is ..........g mol−1 .

ui
[Given: Freezing point of ethanol is 156.0K Density of ethanol is 0.80] g cm−3 .

Freezing point depression constant of ethanol is 2.00 K kg mol m−1 [JEE MAIN 2022]
T
(A) 81 (B) 80 (C) 82 (D) 83

(100) If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio 2 : 1 and their enthalpy of
ht
vaporizations are in the ratio 1 : 2, then the boiling point elevation constant of X is m times the boiling point elevation constant
of Y . The value of m is ...... (Nearest integer) [JEE MAIN 2023]
ig
(A) 8 (B) 6 (C) 4 (D) 2

(101) The maximum prescribed concentration of copper in drinking water is ........ ppm [JEE MAIN 2019]
Br
(A) 0.5 (B) 3 (C) 5 (D) 0.05

(102) A solution containing 10 g per dm of urea (molecular mass = 60 g mol
3 −1
) is isotonic with a 5% solution of a non volatile solute.
The molecular mass of this non volatile solute is ........ g mol−1 [AIIMS 2014]
(A) 300 (B) 350 (C) 200 (D) 250
(103) Which of the following pairs of solutions are expected to be isotonic, temperature being the same? [AIIMS 2011]
(A) 0.1 M glucose and 0.1 M C6 H5 N + H3 Cl− (B) 0.1 M N aCl and 0.05 M BaCl2
(C) 0.1 M N a2 SO4 and 0.1 M KN O3 (D) 0.1 M BaCl2 and 0.075 M F eCl3
(104) The solubility product of sparingly soluble salt AX2 is 3.2 × 10 −11
. Its solubility (in mol/L) is [AIIMS 2018]
(A) 5.6 × 10 −6
(B) 3.1 × 10 −4
(C) 2 × 10−4 (D) 4 × 10−4
(105) Which of the following salt has the same value of Van’t Hoff factor i as that of K4 [F e(CN )6 ] [AIIMS 1998 , AIPMT 1994]
(A) Al2 (SO4 )3 (B) N aCl (C) N a2 SO4 (D) Al(N O3 )3
(106) Benzoic acid undergoes dimerisation in benzene solution. The van’t Hoff factor (i) is related to the degree of association ’ x′ of
the acid as [AIIMS 2018]
( ) ( )
(A) i = (1 − x) (B) i = (1 + x) (C) i = 1 − x2 (D) i = 1 + x2
(107) The vapour pressure of a solvent decreases by 10 mm of Hg when a non-volatile solute was added to the solvent. The mole
fraction of the solute in the solution is 0.2. What should be the mole fraction of the solvent if the decrease in the vapour pressure
is to be 20 mm of Hg ? [AIIMS 2015]
(A) 0.8 (B) 0.6 (C) 0.4 (D) 0.2
8
(108) The average osmotic pressure of human blood is 7.8 bar at 37 o C. What is the concentration of an aqueous N aCl solution that
could be used in the blood stream .........mol/L [AIIMS 2004]
(A) 0.16 (B) 0.32 (C) 0.60 (D) 0.45
(109) Which observation (s) reflect (s) colligative properties ?
(i) A 0.5 m N aBr solution has a higher vapour pressure than a 0.5 m BaCl2 solution at the same temperature
(ii) Pure water freezes at the higher temperature than pure methanol
(iii) a 0.1 m N aOH solution freezes at a lower temperature than pure water
Choose the correct answer from the codes given below [AIIMS 2017]
(A) (i), (ii) and (iii) (B) (i) and (ii) (C) (ii) and (iii) (D) (i) and (iii)
(110) An aqueous solution of N aCl shows the depression of freezing point of water equal to 0.372 K. The boiling point of BaCl2
solution of same molality will be .........o C .[Kf (H2 O) = 1.86 K kg mol−1 ; Kb (H2 O) = 0.52 K kg mol−1 ] [AIIMS 2011]
(A) 100.52 (B) 100.104 (C) 101.56 (D) 100.15
(111) At a particular temperature, the vapour pressures of two liquids A and B are respectively 120 and 180 mm of mercury. If 2 moles
of A and 3 moles of B are mixed to form an ideal solution, the vapour pressure of the solution at the same temperature will be
(in mm of mercury) [AIIMS 2013]
(A) 156 (B) 145 (C) 150 (D) 108
(112) Assertion : If one component of a solution obeys Raoult’s law over a certain range of composition, the other component will not
obey Henry’s law in that range.
Reason : Raoult’s law is a special case of Henry’s law. [AIIMS 2011 , AIIMS 2013 , AIIMS 2017]
(A) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(B) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
ss
(C) If the Assertion is correct but Reason is incorrect.
(D) If both the Assertion and Reason are incorrect.
(113) An aqueous solution of hydrochloric acid [AIIMS 2009]
(A) Obeys Raoult’s law cla
(B) Shows negative deviation from Raoult’s law
on
(C) Shows positive deviation from Raoult’s law (D) Obeys Henry’s law at all compositions
(114) The molal boiling point constant for water is 0.513 C kg mol . When 0.1 mole of sugar is dissolved in 200 ml of water, the
o −1
solution boils under a pressure of one atmosphere at ......... o C. [AIIMS 1991]

ti
(A) 100.51 (B) 100.05 (C) 100.25 (D) 101.02

ui
(115) A solution containing 1.8 g of a compound (empirical formula CH2 O ) in 40 g of water is observed to freeze at − 0.465 o C. The
molecular formula of the compound is ( Kf of water = 1.86 kg K mol−1 ) [AIIMS 2016]
T
(A) C2 H4 O2 (B) C3 H6 O3 (C) C4 H8 O4 (D) C6 H12 O6

ht
(116) The freezing point of equimolal aqueous solution will be highest for [AIIMS 2013]
(A) C6 H5 N H3+ Cl− (B) Ca(N O3 )2 (C) La(N O3 )2 (D) C6 H12 O6
ig
(117) The boiling point of water ( 100 C ) becomes 100.52 C, if 3 grams of a nonvolatile solute is dissolved in 200 ml of water. The
o o
molecular weight of solute is (Kb for water is ................. g mol−1 0.6 K − m) [AIIMS 1998]
Br
(A) 12.2 (B) 15.4 (C) 17.3 (D) 20.4

(118) Which one of the statements given below concerning properties of solutions, describes a colligative effect [AIIMS 2003]
(A) Boiling point of pure water decreases by the addition of ethanol
(B) Vapour pressure of pure water decreases by the addition of nitric acid
(C) Vapour pressure of pure benzene decreases by the addition of naphthaleneBoiling point of pure benzene increases by the
addition of toluene
(D) none
(119) Assertion : The water pouch of instant cold pack for treating athletic injuries breaks when squeezed and N H4 N O3 dissolves
lowering the temperature.
Reason : Addition of non-volatile solute into solvent results into depression of freezing point of the solvent. [AIIMS 2006]
(120) Which of the following modes of expressing concentration is independent of temperature [IIT 1988 , AIIMS 1997 , AIIMS 2001 , AIPMT 1992 , AIPMT
1995]
(A) Molarity (B) Molality (C) Formality (D) Normality
9
(121) Assertion : The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was
found to be different.
Reason : Water is polar and benzene is nonpolar. [AIIMS 2005]
(122) A 500 g tooth paste sample has 0.2 g fluoride concentration. What is the concentration of F in terms of ppm level [AIIMS 1992]
(A) 250 (B) 200 (C) 400 (D) 1000
(123) What will be the molarity of a solution containing 5 g of sodium hydroxide in 250 ml solution [AIIMS 2000]
(A) 0.5 (B) 1.0 (C) 2.0 (D) 0.1
(124) Assertion : Molecular mass of benzoic acid when determined by colligative properties is found high
Reason : Dimerisation of benzoic acid. [AIIMS 1998]
(125) What is the molarity of H2 SO4 solution, that has a density 1.84 gm/cc at 35 o C and contains solute 98% by weight ...... M [AIIMS 2001]
(A) 4.18 (B) 8.14 (C) 18.4 (D) 18
ss
(126) If Boiling point of water is 100 C. How much gram of N aCl is added in 500 g of water to increase the boiling point of water by
◦
approx.1 ◦ C. (Kb )H2 O = 0.52 K. kg/mole [AIIMS 2019]

(A) 2.182 g (B) 7.03 g
cla
(C) 14.06 g (D) 28.12 g
(127) How many grams of dibasic acid (mol. wt. 200) should be present in 100 ml of its aqueous solution to give decinormal strength
.......... gm. [AIIMS 1992 , AIPMT 1999]
on
(A) 1 (B) 2 (C) 10 (D) 20
(128) Normality of 2 M sulphuric acid is [AIIMS 1991 , AIIMS 1992]
ti
(A) 2 N (B) 4 N (C) N /2 (D) N /4

ui
(129) The normality of 0.3 M phosphorus acid (H3 P O3 ) is [IIT 1999 , AIIMS 2000]
(A) 0.1 (B) 0.9 (C) 0.3 (D) 0.6
T
(130) 12 g of urea is dissolved in 1 litre of water and 68.4 g of sucrose is dissolved in 1 litre of water. The lowering of vapour pressure
of first case is [AIIMS 2012]
ht
(A) equal to second (B) greater than second (C) less than second (D) double that of second
ig
(131) Which of the following is a colligative property [AIIMS 1999]

(A) Surface tension (B) Viscosity (C) Osmotic pressure (D) Optical rotation
Br
(132) Assertion : If red blood cells were removed from the body and placed in pure water, pressure inside the cells increases.
Reason : The concentration of salt content in the cells increases. [AIIMS 2006]
(133) At 25 o C, the highest osmotic pressure is exhibited by 0.1 M solution of [AIIMS 2000 , AIPMT 1994]
(A) CaCl2 (B) KCl (C) Glucose (D) Urea
(134) Vapour pressure of CCl4 , at 25 C is 143 mm Hg. 0.5 g of a non- volatile
◦
) solute (mol. wt. 65) is dissolved in 100 mL of CCl4 , Find
the vapour pressure of the solution. (Density of CCl4 , = 1.58 g/cm3 [AIIMS 2019]
(A) 141.93 mm Hg (B) 94.39 mm Hg (C) 199.34 mm Hg (D) 143.99 mm Hg
(135) When 0.05 M dimethyl amine is dissolve in 0.1 M N aOH solution then the percentage dissociation of dimethyl amine is :
(Kb )(CH3 ) N H = 5 × 10−4 [AIIMS 2019]
2
(A) 5 × 10−5 (B) 5 × 10−3 (C) 5 × 10−1 (D) 5 × 10−2

(136) Which of the following 0.10 m aqueous solutions will have the lowest freezing point ? [AIIMS 2014]
(A) Al2 (SO4 )3 (B) C6 H12 O6 (C) KCl (D) C12 H22 O11
(137) Which pair from the following will not form an ideal solution
(A) CCl4 + SiCl4 (B) H2 O + C4 H9 OH (C) C2 H5 Br + C2 H5 I (D) C6 H14 + C7 H16
10
(138) The relative lowering in vapour pressure of an aqueous solution of urea which is 6% by weight, is
(A) 0.2 (B) 0.8 (C) 0.01 (D) Can’t predict
(139) The osmotic pressure of a decinormal solution of BaCl2 in water is
(A) Inversely proportional to its celsius temperature (B) Inversely proportional to its absolute temperature
(C) Directly proportional to its celsius temperature (D) Directly proportional to its absolute temperature
(140) If 0.50 mol of CaCl2 is mixed with 0.20 mol of N a3 P O4 , the maximum number of moles of Ca3 (P O4 )2 which can be formed, is
(A) 0.7 (B) 0.5 (C) 0.2 (D) 0.1
(141) The molar solution of sulphuric acid is equal to
(A) N solution (B) 2 N solution (C) N /2 solution (D) 3 N solution
(142) At 80 C , the vapour pressure of pure liquid A is 520 mmHg and that of pure liquid B is 1000 mmHg . If a mixture of A and B
o
boils at 80 o C and 1 atm pressure, the amount of A in the mixture is ........ mol %.
(A) 25 (B) 50 (C) 34 (D) 48
(143) The freezing point of 1 percent solution of lead nitrate in water will be
(A) Below 0 o C (B) 0 o C (C) 1 o C (D) 2 o C
(144) 1 mole each of following solutes are taken in 5 moles water,
(i) N aCl (ii) K2 SO4 (iii) N a3 P O4 (iv) glucose
Assuming 100% ionisation of the electrolyte, relative decrease in V.P. will be in order
(A) i < ii < iii < iv (B) iv < iii < ii < i (C) iv < i < ii < iii (D) equal
(145) To 5.85 gm of N aCl one kg of water is added to prepare of solution. What is the strength of N aCl in this solution (mol. wt. of
N aCl = 58.5)
ss
(A) 0.1 Normal (B) 0.1 Molal (C) 0.1 Molar (D) 0.1 Formal
(146) When 10 g of a non-volatile solute is dissolved in 100 g of benzene, it raises boiling point by 1 C then molecular mass of the
o
solute is ....... g. (Kb for benzene = 2.53 k − m−1 )

(A) 223 (B) 233
cla
(C) 243 (D) 253
(147) At 25 C , the vapour pressure of pure liquid A (mol. wt. = 40) is 100 torr , while that of pure liquid B is 40 torr , (mol. wt. = 80 ).
o
on
The vapour pressure at 25 o C of a solution containing 20 g of each A and B is ........... torr.
(A) 80 (B) 59.8 (C) 68 (D) 48
ti
(148) Azeotropic mixture of HCl and water has .......... % HCl

(A) 84 (B) 22.2 (C) 63 (D) 20.2
ui
(149) Molarity is expressed as [AIPMT 1991]

T
(A) Gram/litre (B) M oles/litre (C) Litre/mole (D) M oles/ 1000 gms
(150) One mole of glucose is dissolved in 2 moles of water. The vapour pressure of solution relative to that of water is
ht
(A) 2
3 (B) 1
3 (C) 1
2 (D) 3
2
ig
Br
11

Solutions Date : 25-10-2024
Standard : 12
Total Mark : 600 (Answer Key) Time : 0H:0M
Chemistry - Section A (MCQ)
1-D 2-C 3-B 4-D 5-C 6-A 7-A 8-B 9-B 10 - B

11 - B 12 - A 13 - D 14 - A 15 - A 16 - D 17 - C 18 - A 19 - B 20 - C
21 - B 22 - D 23 - B 24 - C 25 - A 26 - D 27 - D 28 - D 29 - C 30 - A
31 - D 32 - A 33 - D 34 - B 35 - A 36 - D 37 - C 38 - A 39 - C 40 - C
41 - D 42 - A 43 - C 44 - D 45 - A 46 - A 47 - D 48 - A 49 - C 50 - D
51 - D 52 - B 53 - B 54 - B 55 - C 56 - C 57 - B 58 - C 59 - A 60 - D
61 - B 62 - C 63 - D 64 - D 65 - D 66 - C 67 - B 68 - B 69 - A 70 - C
ss
71 - B 72 - C 73 - B 74 - C 75 - D 76 - D 77 - B 78 - A 79 - B 80 - B
81 - C 82 - C 83 - B 84 - C 85 - C 86 - A 87 - C 88 - C 89 - B 90 - D
91 - B
111 - A
92 - D
112 - B
93 - C
113 - B
94 - A
114 - C
95 - B
101 - B 102 - A 103 - D 104 - C 105 - A 106 - C
115 - D 116 - D
cla
96 - C 97 - C
107 - B
117 - C
98 - D 99 - B
108 - B 109 - D
118 - B 119 - A
100 - A
110 - D
120 - B
on
121 - A 122 - C 123 - A 124 - A 125 - C 126 - D 127 - A 128 - B 129 - D 130 - A
131 - C 132 - C 133 - A 134 - A 135 - C 136 - A 137 - B 138 - C 139 - D 140 - D
ti
141 - B 142 - B 143 - A 144 - C 145 - B 146 - D 147 - A 148 - D 149 - B 150 - A
T ui
ht
ig
Br
12
Solutions Date : 25-10-2024
Standard : 12
Total Mark : 600 (Solutions) Time : 0H:0M
............................................. Chemistry - Section A (MCQ) .............................................
(1) How many grams of methyl alcohol should be added to 10 litre tank of water to prevent its freezing at 268 K ? ............. g (Kf for
water is 1.86 K kg mol−1 ) [JEE MAIN 2013]
(A) 880.07 (B) 899.04 (C) 886.02 (D) 868.06
Solution:(Correct Answer:D)
∆Tf = Kf m
where m = molality
273 − 268 = 1.86 × M w× V
5 = 1.86 × 32 w ×10
w = 5 ×32 × 10
1.86
= 860.2 ≈ 868.06 g
(2) 1 molal aqueous solution of an electrolyte A2 B3 is 60% ionised. The boiling point of the solution at 1 atm is ......... K.
(Rounded-off to the nearest integer) ]
[Given Kb for (H2 O) = 0.52 K kg mol−1 [JEE MAIN 2021]
(A) 370 (B) 380 (C) 375 (D) 385
ss
Solution:(Correct Answer:C)
∆Tb = iKb m
la
= (1 + 4α) × 0.52 × 1
= 3.4 × 0.52 × 1 = 1.768
dc
Tb = 1.768 + 313.15 = 374.918K

= 375K
Ve
(3) 1 molal K4 F e(CN )6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of another solution which
contains 18.1 weight percent of] a non electrolytic solute A. The molar mass of A is ....... u. (Round off to the Nearest Integer).
[Density of water = 1.0 g cm−3 [JEE MAIN 2021]
(A) 95 (B) 85 (C) 105 (D) 26
Solution:(Correct Answer:B)
K4 F e(CN )6 ⇌ 4K + + F e(CN )4−6
Initial conc. 1 m 0 0
Final conc. (1 − 0.4) m 4 × 0.4 0.4 m
= 0.6 m = 1.6 m
Effective molality = 0.6 + 1.6 + 0.4 = 2.6 m
For same boiling point, the molality of another solution should also be 2.6 m.
Now,18.1 weight percent solution means 18.1 gm solute is present in 100 gm solution and hence, (100 − 18.1 =)81.9 gm water.
Now, 2.6 = 81.9/1000
18.1/M
∴ Molar mass of solute, M = 85
(4) Solute A associates in water. When 0.7 g of solute A is dissolved in 42.0 g of water, it depresses the freezing point by 0.2◦ C. The
percentage association of solute A in water, is ..... %
[Given : Molar mass of A = 93 g mol−1 . Molal depression constant of water is 1.86 K kg mol−1 ] [JEE MAIN 2022]
(A) 50 (B) 60 (C) 70 (D) 80
∆T = i kf × m
93 × 42
0.2 = i × 1.86 × 0.7 1000
0.2×93×6
i = 1.86×100
i = 0.60
2A ⇌ A2
1−α
i = 1 − α + α2
13
i = 1 − α2
1 − α2 = 0.60
1 − 0.60 = α2
α = 0.80
(5) Two elements A and B which form 0.15 moles of A2 B and AB3 type compounds. If both A2 B and AB3 weigh equally, then the
atomic weight of A is .... times of atomic weight of B. [JEE MAIN 2022]
(A) 45 (B) 4 (C) 2 (D) 9
Given: Molar mass of A2 B = AB3
∴ (2A + B) = (A + 3B)[A → Atomic wt. of A, B → Atomic wt. of B]
⇒ A = 2B
∴ atomic wt. of A is 2 times of atomic wt. of B
Integer answer is 2
(6) 2.7Kg of each of water and acetic acid are mixed, The freezing point of the solution will be −x◦ C. Consider the acetic acid does
not dimerise in water, nor dissociates in water x = . . . . . . . (nearest integer)
[Given : Molar mass of water = 18 g mol−1 , acetic acid = 60 g mol−1 ]
Kf
H2 O : 1.86 K kg mol−1
Kr acetic acid : 3.90 K kg mol−1
freezing point: H2 O = 273 K, acetic acid = 290 K ] [JEE MAIN 2024]
(A) 31 (B) 35 (C) 37 (D) 40
Solution:(Correct Answer:A)
As moles of water > moles of CH3 COOH water is solvent.
T◦F − (TF )S = KF × M
2700/60
0 − (TF )S = 1.86 × 2700/1000
ss
( TF )S = −31◦ C.
la
(7) Of the following four aqueous solutions, total number of those solutions whose freezing point is lower than that of
0.10 MC2 H5 OH is (Integer answer)
dc
(i) 0.10 M Ba3 (PO4 )2 (ii) 0.10 M Na2 SO4 (iii) 0.10 M KCl (iv) 0.10 M Li3 PO4 [JEE MAIN 2021]
(A) 4 (B) 3 (C) 1 (D) 2
Ve
As 0.1 MC2 H5 OH is non-dissociative and rest all salt given are electrolyte so in each case effective molarity > 0.1 so each will
have lower freezing point.
(8) Toluene in the vapour phase is in equilibrium with a solution of benzene and toluene having mole fraction of toulene 0.50 If
vapour pressure of pure benzene is 119 torr and that of toluene is 37.0 torr at the same temperature, mole fraction of toluene in
vapour phase will be: [NEET 2017]
(A) 0.462 (B) 0.237 (C) 0.506 (D) 0.325
Ptotal = PA0 XA + PB0 XB
= 37 × 0.5 + 119 × 0.5
= 78
PA = YA Ptotal
P0X
∴ yA = PPtotal
A
= PAtotalA = 37×0.5
78 = 0.237
(9) A solution containing 2 g of a non-volatile solute in 20 g of water boils at 373.52 K. The molecular mass of the solute is
.......g mol−1 . (Nearest integer) Given, water boils at 373 K, Kb for water = 0.52 K kg mol−1 [JEE MAIN 2023]
(A) 10 (B) 100 (C) 80 (D) 90
∆Tb = 373.52 − 373
= 0.52
∆Tb = Kb · m
0.52 = 0.52 × Molar2Mass × 20×10
1
−3
Molar Mass = 100 g/mol
(10) 10.30 mg of O2 is dissolved into a liter of sea water of density 1.03 g/mL. The concentration of O2 in ppm is [JEE MAIN 2020]
(A) 13 (B) 10 (C) 8 (D) 6
14
10.3×10−3
ppm = 1030 × 106 = 10
(11) 20% of acetic acid is dissociated when its 5 g is added to 500 mL of water. The depression in freezing point of such water is
..... × 10−3 ◦ C. Atomic mass of C, H and O are 12, 1 and 16 a.m.u. respectively.
[Given : Molal depression constant and density of water are 1.86 K kg mol−1 and 1 g cm−3 respectively.] [JEE MAIN 2023]
(A) 371 (B) 372 (C) 373 (D) 375
i = 1 + (n − 1)α
i = 1 + 0.2(2 − 1) = 1.2
∆Tf = iKf m
∆Tf = 1.2 × 1.86 × 5×1000
60×500
∆tf = 3.72
∆Tf = 372 × 10−2
(12) The vapour pressure of 30%(w/v) aqueous solution of glucose is ...... mm Hg at 25◦ C.[Given : The density of 30% (w/v),
aqueous solution
) of glucose is 1.2 g cm−3 and vapour pressure of pure water is 24 mm Hg.](Molar mass of glucose is
−1
180 g mol . [JEE MAIN 2023]
(A) 23 (B) 22 (C) 21 (D) 24
24−Ps
Ps = m×18
1000
wt of solute = 30 gm
Volume of solution = 100 mL
wt. of solution = 1.2 × 100 = 120 gm
wt. of solvent = 120 − 30 = 90 gm
m = 30×1000
180×90 = 1.85
24−Ps
Ps = 1.85×18
1000
24 − Ps = 0.0333Ps
ss
Ps (1.033) = 24
Ps = 23.22
la
(13) The van’t Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium hydroxide is [NEET 2016]
dc
(A) 0 (B) 1 (C) 2 (D) 3
Ve
Ba(OH)2 −→ Ba+2 + 2OH−

i=3
(14) Which of the following is dependent on temperature ? [NEET 2017]
(A) Molarity (B) Mole fraction (C) Weight percentage (D) Molality
Molarity includes volume of solution which can change with change in temperature.
(15) A soft drink was bottled with a partial pressure bf CO2 of 3 bar over the liquid at room temperature. The partial pressure of CO2
over the solution approaches a value of 30 bar when 44 g of CO2 is dissolved in 1 kg of water at room temperature. The
approximate pH of the soft drink is............... ×10−1 )
(First dissociation constant of H2 CO3 = 4.0 × 10−7 log 2 = 0.3; density of the soft drink = 1 g mL−1 [JEE MAIN 2020]
(A) 37 (B) 35 (C) 40 (D) 32
PCO2 = KH × CO2
KH ·nCO2
3
30 = KH 1 ⇒ nCO2 −0.1 mol
pH = 2 (pka1 − log c) = 21 (6.4 × 1) = 3.7
1
pH = 37 × 10−1
(16) AB2 is 10% dissociated in water to A2+ and B − . The boiling point of a 10.0 molal aqueous solution of AB2 is ............ ◦ C. (Round
[Given : Molal elevation constant of water Kb = 0.5 K kg mol−1 boiling point of pure water = 100◦ C] [JEE MAIN 2021]
(A) 201 (B) 105 (C) 102 (D) 106
AB2 → A2+ + 2B −
t = 0a00
15
t = ta − aαaα2aα
nT = a − aα + aα + 2aα
= a(1 + 2α)
so i = 1 + 2α
Now ∆Tb = i × m × Kb
∆Tb = (1 + 2α) × m × Kb
α = 0.1 m = 10 Kb = 0.5
∆Tb = 1.2 × 10 × 0.5
=6
So boiling point = 106
(17) How much amount of NaCl should be added to 600 g of water (ρ = 1.00 g/mL) to decrease the freezing point of water to
−0.2◦ C? ............. gm
(The freezing point depression constant for water = 2 K kg mol−1 ) [JEE MAIN 2020]
(A) 2.25 (B) 2 (C) 1.75 (D) 1.5
∆Tf = i × m × Kf
w/58.5
0.2 = 2 × 2 × 600/1000
w = 1.755gm
(18) An aqueous solution of a salt M X2 at certain temperature has a van’t Hoff factor of 2. The degree of dissociation for this solution
of the salt is [JEE MAIN 2016]
(A) 0.50 (B) 0.33 (C) 0.67 (D) 0.80
(a) Van’t Hoff factore (i)
= NNo.o.of
of particles af ter association or dissociation
particles bef ore association or dissociation
For M X2 ⇌ M 2+ + 2X −
t = 0100
ss
at.eq. 1 − α α 2α
Total no. of particles
la
= 1 − α + α + 2α = 1 + 2α
∴ i = 1+2α = 2
dc
1
∴ α = 0.50 or 50%
(19) The osmotic pressure of a solution of N aCl is 0.10 atm and that of a glucose solution is 0.20 atm. The osmotic pressure of a
Ve
solution formed by mixing 1 L of the sodium chloride solution with 2 L of the glucose solution is x × 10−3 atm. x is.......... (nearest
integer) [JEE MAIN 2020]
(A) 150 (B) 167 (C) 160 (D) 159
Osmotic pressure = π = i × C × RT
For N aCli = 2 so
πN aCl = i × CN aCl × RT CN aCl = conc. of N aCl
0.1 = 2 × CN aCl × RT
CN aCl = 0.05
RT Cglucose = conc. of glucose
For glucose i = 1 so
πGlucose = i × Cglucose × RT
0.2 = 1 × Cglucose × RT
CGlucose = RT 0.2
ηN aCl = No. of moles N aCl
ηN aCl in 1L = CN aCl × VLitre
= 0.05
RT ηglucose = No. of moles glucose
ηglucose in 2L = Cglucose × VLitre
0.4
= RT
VTotal = 1 + 2 = 3L
so Final conc. N aCl = 3RT 0.05
Final conc. glucose = 3RT 0.4
πTotal = πN aCl + πglucose

( × CN aCl 0.4
= [i + C)glucose ] × RT
= 2×0.05
3RT + 3RT × RT
= 0.53 atm
= 0.1666atm
= 166.6 × 10−3 atm
⇒ 167.00 × 10−3 atm
so x = 167.00
16
(20) 12 g of a nonvolatile solute dissolved in 108 g of water produces the relative lowering of vapour pressure of 0.1. The molecular
mass of the solute is [JEE MAIN 2013]
(A) 80 (B) 60 (C) 20 (D) 40
P o − Ps
Po = N n w
= m × W
M
0.1 = m × 108
12 18
12 × 18
m = 0.1 × 108 = 20
(21) If a compound Ab dissociates to the extent of 75 % in an aqueous solution, the molality of the solution which shows a 2.5 K rise
in the boiling point of the solution is ......
[ molal. ]
(Rounded-off to the nearest integer) Kb = 0.52 K kg mol−1 [JEE MAIN 2021]
(A) 4 (B) 3 (C) 6 (D) 5
α = 0.75, n = 2
i = 1 − α + nα = 1 − 0.75 + 2 × 0.75 = 1.75
∆Tb = ikb m
or, 2.5 = 1.75 × 0.52 × m
or, m = 1.75×0.52
2.5
= 2.74
∴ nearest integer answer will be 3
(22) Which one of the following is incorrect for ideal solution ? [NEET 2016]
(A) ∆Hmix = 0 (B) ∆Umix = 0
ss
(C) ∆P = Pobs − Pcalculated by Raoult′ s law = 0 (D) ∆Gmix = 0
la
The concept of an ideal solution is fundamental to chemical thermodynamics and its applications, such as the use of colligative
dc
properties. An ideal solution or ideal mixture is a solution in which the enthalpy of solution (∆Hsolution = O) is zero. As the
enthalpy of the solution nears zero, the solution becomes more ideal.
Ve
Since the enthalpy of mixing (solution) is zero, the change in Gibbs energy on mixing is determined solely by the entropy of
mixing ( ∆Ssolution ).
So the ∆G is not zero.
(23) If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0.3, then the observed freezing
point will be .....% higher than the expected/theoretical freezing point. (Nearest integer) [JEE MAIN 2023]
(A) 31 (B) 30 (C) 32 (D) 33
i = 1 + α( for HA)
= 1.3
(∆Tf )obs −(∆Tf )cal
% increase = (∆Tf ) × 100
cal
Kf ×i×m−Kf ×m
= Kf ×m × 100
1 × 100 = 30%
i−1
=
(24) When 10 mL of an aqueous solution of KMnO4 was titrated in acidic medium, equal volume of 0.1 M of an aqueous solution of
ferrous sulphate was required for complete discharge of colour. The strength of KMnO4 in grams per litre is ...... × 10−2 . (Nearest
integer)
Atomic mass of K = 39, Mn = 55, O = 16] [JEE MAIN 2021]
(A) 94 (B) 152 (C) 316 (D) 656
Let molarity of KMnO4 = x
KMnO4 + FeSO4 → Fe2 (SO4 )3 + Mn2+
n=5 n=1
(Equivalents of KMnO4 reacted ) = (Equivalents of FeSO4 reacted )
⇒ (5 × x × 10 ml) = 1 × 0.1 × 10 ml
⇒ x = 0.02 M
Molar mass of KMnO4 = 158 gm/mol
⇒ Strength = (x × 158) = 3.16 g/ℓ
17
(25) A set of solutions is prepared using 180 g of water as a solvent and 10 g of different non-volatile solutes A, B and C. The relative
lowering of vapour pressure in the presence of these solutes are in the order ]
[Given, molar mass of A = 100 g mol−1 ; B = 200 g mol−1 C = 10, 000 g mol−1 [JEE MAIN 2020]
(A) A > B > C (B) A > C > B (C) C > B > A (D) B > C > A
Relative lowering of V.P. = ∆P P 0 = xsolute
( ∆P ) 10 ( ∆P
) 10
P 0 A = 100 : P 0 B = 10 200
100
10
+ 180 180
200 + 18
( ∆P ) ( ∆P ) ( ∆P ) ( )
18
10
P0 C = 10
10,000
+ 180
: P 0 A > P 0 B > ∆P P0 C
10,000 18
(26) Which of them is not equal to zero for an ideal solution ? [NEET 2015]
(A) ∆Vmix (B) ∆P = Pobserved − PRaoult (C) ∆Hmix (D) ∆Smix

For an ideal solution ∆Smix > 0
(27) The solubility of N2 in water at 300 K and 500 torr partial pressure is 0.01 g L−1 .The solubility ( in g L−1 )at 750 torr partial
pressure is [JEE MAIN 2016]
(A) 0.0075 (B) 0.005 (C) 0.02 (D) 0.015
According to Henry law
P1 S1
P2 = S 2
500 0.01
750 = S2
∴ = 750×0.01
500 = 0.015 g/L
(28) What weight of glucose must be dissolved in 100g of water to lower the vapour pressure by 0.20 mm Hg ? (Assume dilute
solution is being formed) Given: Vapour pressure of pure water is 54.2 mm Hg at room temperature. Molar mass of glucose is
180 g mol−1 [JEE MAIN 2023]
(A) 4.69 g (B) 3.59 g (C) 2.59 g (D) 3.69 g
ss
la
P 0 −P5
P0 =N n
(for dilute solution)
0.2 n×18
=
dc
54.2 100
100
n = 271×18
w = 100×180
271×18 ; w = 3.69 g
Ve
(29) Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing point depression ? [NEET 2014]
(A) KCl (B) C6 H12 O6 (C) Al2 (SO4 )3 (D) K2 SO4

Depression in freezing point ∝ vant Hoff’s factor
(i) for Al2 (SO4 )3 −→ i = 5
(30) The following solutions were prepared by dissolving 10 g of glucose (C6 H12 O6 ) in 250 ml of water (P1 ), 10 g of urea (CH4 N2 O) in
250 ml of water (P2 ) and 10 g of sucrose (C12 H22 O11 ) in 250 ml of water (P3 ). The right option for the decreasing order of
osmotic pressure of these solutions is : [NEET 2021]
(A) P2 > P1 > P3 (B) P1 > P2 > P3 (C) P2 > P3 > P1 (D) P3 > P1 > P2
Π = CRT
Π ∝ C ⇒ Π ∝ M1w
Glucose ⇒ Mw1 = 180
Urea ⇒ Mw2 = 60
Sucrose ⇒ Mw3 = 342
P2 > P1 > P3
(31) The osmotic pressure exerted by a solution prepared by dissolving 2.0 g of protein of molar mass 60 kg mol−1 in 200 mL of water
at 27◦ C is .....P a. [integer value]
(use R = 0.083L bar mol−1 K −1 ) [JEE MAIN 2022]
(A) 236 (B) 654 (C) 313 (D) 415
π = iCRT
1×2
= 60000×0.2 × 0.083 × 300
)
= 0.00415 bar (∵ 1 bar = 105 P a
So, 0.00415 × 105 P a = 415 P a
18
(32) Which one of the following statements regarding Henry’s law is not correct? [JEE MAIN 2019]
(A) Higher the value of KH at a given pressure, higher is the solubility of the gas in the liquids
(B) Different gases have different KH (Henry’s law constant) values at the same temperature
(C) The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the solution
(D) The value of KH increases with increase of temperature and KH is function of the nature of the gas
Gases having higher KH value are less soluble
(33) 0.05MCuSO4 when treated with 0.01MK2 Cr2 O7 gives green colour solution of Cu2 Cr2 O7 . The [SP M : Semi Permeable
Membrane]
K2 Cr2 O7 & CuSO 4
SideX SP M Side Y Due to osmosis : [JEE MAIN 2024]
(A) Green colour formation observed on side Y . (B) Green colour formation observed on side X.
(C) Molarity of K2 Cr2 O7 solution is lowered. (D) Molarity of CuSO4 solution is lowered.
Only solvent Molecules are allowed to pass through the SP M .
(34) If 8 g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapour pressure to 80%, the molar mass (in
ss
gmol−1 ) of the solute is
Given that molar mass of n-octane is 114 g mol−1 [NEET 2020]
la
(A) 20 (B) 40 (C) 60 (D) 80

dc
Assuming dilute solution
∆P
= nnB =m wB
·WmA
Ve
P0
A A B A
20
100= m8B · 114
114
mB = 8×100
20 = 40gmol−1
(35) Consider the dissociation of the weak acid HX as given below

HX(aq) ⇌ H+ (aq) + X(aq), Ka = 1.2 × 10−5
[Kn : dissociation constant]
The osmotic pressure of 0.03M aqueous solution of HX at 300 K is ............... ×10−2 bar (nearest integer).
[ Given : R = 0.083 LbarMol−1 K−1 ] [JEE MAIN 2024]
(A) 76 (B) 77 (C) 79 (D) 80
HX ⇌ H+ + X− Ka = 1.2 × 10−5
0.03M
0.03 − x x x
x2
Ka = 1.2 × 10−5 = 0.03−x
0.03 − x ≈ 0.03 ( Ka is very small)
x2
0.03 = 1.2 × 10−5
x = 6 × 10−4
Final solution : 0.03 − x + x + x
= 0.03 + x = 0.03 + 6 × 10−4
( ( ))
Π = 0.03 + 6 × 10−4 × 0.083 × 300
= 76.19 × 10−2 ≈ 76 × 10−2
(36) The freezing point depression constant (Kf ) of benzene is 5.12 K kg mol−1 . The freezing point depression for the solution of
molality 0.078 m containing a non-electrolyte solute in benzene is.......... K (rounded off upto two decimal places) [NEET 2020]
(A) 0.60 (B) 0.20 (C) 0.80 (D) 0.40
19
∆Tf = Kf × m
= 5.12 × 0.078
∆Tf = 0.40K
(37) The vapour pressure of pure benzene and methyl benzene at 27◦ C is given as 80Torr and 24Torr, respectively. The mole fraction
of methyl benzene in vapour phase, in equilibrium with an equimolar mixture of those two liquids (ideal solution) at the same
temperature is. . . . . . .×10−2 (nearest integer) [JEE MAIN 2024]
(A) 20 (B) 25 (C) 23 (D) 30
Xmethylbezzene = 0.5
Pmethylbenzene
Ymehylibenzene = Ptotal
Ymehhylibenzene = 0.5×80+0.5×24
0.5×24
12
= 40+12 = 0.23 = 23 × 10−2
(38) The molarity of a solution obtained by mixing 750 mL of 0.5(M ) HCl with 250 mL of 2(M ) HCl will be .........M [JEE MAIN 2013]
(A) 0.87 (B) 1.00 (C) 1.75 (D) 0.97
From Molarity equation:
M1 V 1 + M2 V 2 = M × V
M = M1 V1 V+M2 V2
where V = total volume
= 750×0.5+250×2
1000 = 0.875 M
(39) Solution of 12 g of non - electrolyte (A) prepared by dissolving it in 1000 mL of water exerts the same osmotic pressure as that
of 0.05 M glucose solution at the same temperature. The empirical formula of A is CH2 O. The molecular mass of A is ..........g.
(Nearest integer) [JEE MAIN 2023]
ss
(A) 241 (B) 242 (C) 240 (D) 243
la
π1 = π2
dc
⇒ C1 = C2
x = 0.05[x → Molar Mass of A]
12
Ve
X = 240
(40) An aqueous solution of volume 300 cm3 contains 0.63 g of protein. The osmotic pressure of the solution at 300 K is 1.29 mbar.
The molar mass of the protein is ......... g mol−1 Given : R = 0.083 L bar K −1 mol−1 [JEE MAIN 2023]
(A) 40536 (B) 40537 (C) 40535 (D) 40538
∵ π = CRT
π = Vn RT
π = Vω RT
M
ωRT
M = π×V
0.63×0.083×300
M = 1.29×10 −3 ×300×10−3
M = 40535 gm/moL
(41) Elevation in boiling point for 1.5 molal solution of glucose in water is 4 K. The depression in freezing point for 4.5 molal solution
of glucose in water is 4 K The ratio of molal elevation constant to molal depression constant (Kb /Kf ) is .... [JEE MAIN 2022]
(A) 4 (B) 1 (C) 2 (D) 3
∆Tb = i Kb m
∆Tf = i Ki m
4 Kb 1.5
4 = Kf 4.5
Kb
Kf =3
(42) Considering acetic acid dissociates in water, its dissociation constant is 6.25 × 10−5 . If 5 mL of acetic acid is dissolved in 1 litre
water, the solution will freeze at −x × 10−2◦ C, provided pure water freezes at 0◦ C.
x = . . . . . . . . . (Nearest integer)
Given : (Kr )water = 1.86 K kg mol−1 .
20
density of acetic acid is 1.2 g mol−1
molar mass of water = 18 g mol−1 .
molar mass of acetic acid = 60 g mol−1 .
density of water = 1 g cm−3
Acetic acid dissociates as
CH3 COOH ⇌ CH3 COO⊕ + H⊕ [JEE MAIN 2024]
(A) 19 (B) 20 (C) 25 (D) 30
Mass of CH3 COOH = V × d
= 5ml × 1.2 g/ml
= 6gm
nCH3 COOH = 60
6
= 0.1 mol
mCH3 COOH ≈ MCH3 COOH = 0.1
1 = 0.1M
CH3 COOH ⇌ CH3 COO + H+
−
C
C − Cα
Cα2
Ka = 1−α
1 − α ≈ 1 ⇒ Ka = C2
√ √
α = KaC = 6.25×10
−5
= 25 × 10−3
2
0.1
V.f.(i) = 1 + α(n − 1) = 1 + α(2 − 1) = 1 + α
= 1 + 25 × 10−3 = 1.025
∆Tr = i K m
= (1.025)(1.86)(0.1)
= 0.19
= 19 × 10−2
ss
(43) The boiling point of 0.2 mol kg −1 solution of X in water is greater than equimolal solution of Y in water. Which one of the
la
following statements is true in this case ? [NEET 2015]

(A) Molecular mass of X is less than the molecular mass of Y.
dc
(B) Y is undergoing dissociation in water while X undergoes no change.

(C) X is undergoing dissociation in water.
Ve
(D) Molecular mass of X is greater than the molecular mass of Y.
∆Tb = iKb m
For equimolal solutions, elevation in boiling point will be higher if solution undergoes dissociation i.e., i > 1
(44) Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : 3.1500 g of hydrated oxalic acid dissolved in water to make 250.0 mL solution will result in 0.1 M oxalic acid
solution.
Reason R : Molar mass of hydrated oxalic acid is 126 g mol−1 .
In the light of the above statements, chose the correct answer from the options given below: [JEE MAIN 2023]
(A) Both A and R are true but R is NOT the correct explanation of A.
(B) A is false but R is true.
(C) A is true but R is false.
(D) Both A and R are true and R is the correct explanation of A.
Assertion is correct.
H2 C2 O4 · 2H2 O
M = 3.15×1000
126×250
12.6
126 = 0.1
Reason is correct. It is used as a fact in explanation of assertion.
(45) 2 molal solution of a weak acid HA has a freezing point of 3.885◦ C. The degree of dissociation of this acid is ........ ×10−3 . (Round
[Given : Molal depression constant of water = 1.85 K kg mol−1 Freezing point of pure water = 0◦ C] [JEE MAIN 2021]
(A) 50 (B) 60 (C) 55 (D) 65
21
∆Tf = (1 + α)Kf m
α = 0.05 = 50 × 10−3
(46) 40 g of glucose (Molar mass = 180 ) is mixed with 200 mL of water. The freezing point of solution is ..... K. (Nearest integer)
[Given : Kf = 1.86 K kg mol−1 ; Density of water = 1.00 g cm−3 ; Freezing point of water = 273.15 K] [JEE MAIN 2021]
(A) 271 (B) 370 (C) 71 (D) 521
( 40 ) mol ( )
molality = 180
0.2 Kg = 10
9 molal
⇒ ∆Tf = Tf − T′f = 1.86 × 109
⇒ T′f = 273.15 − 1.86 × 10
9
= 271.08 K
≃ 271 K (nearest-integer)
(47) Isotonic solutions have same [NEET 2020]

(A) Boiling temperature (B) Vapour pressure (C) Freezing temperature (D) Osmotic pressure
Solutions having same osmotic pressure at a given temperature are called isotonic solutions.
(48) At 363 K, the vapour pressure of A is 21 kP a and that of B is 18 kP a. One mole of A and 2 moles of B are mixed. Assuming that
this solution is ideal, the vapour pressure of the mixture is ....... kP a. (Round of to the Nearest Integer). [JEE MAIN 2021]
(A) 19 (B) 21 (C) 25 (D) 36
Given PA0 = 21 kP a ⇒ PB0 = 18 kP a
→ An Ideal solution is prepared by mixing 1 mol A and 2 mol B.
→ XA = 13 and XB = 23
ss
→ Acc to Raoult’s low
PT = (XA PA0 +) XB( PB0 )
la
PT = 13 × 21 + 23 × 18
PT = 7 + 12 = 19 KP a
dc
(49) A graph of vapour pressure and temperature for three different liquids X, Y and Z is shown below
The following inferences are made
Ve
(A) X has higher intermolecular interactions compared to Y .

(B) X has lower intermolecular interactions compared to Y .
(C) Z has lower intermolecular interactions compared to Y.
The correct inference(s) is/are [JEE MAIN 2020]
(A) (A) (B) (C) (C) (B) (D) (A) and (C)
Order of B.P. is : Z > Y > X
Order of vapour pressure : Z < Y < X
order of intermolecular interaction : Z > Y > X
( )
(50) The plot of osmotic pressure (�) vs concentration molL−1 for a solution gives a straight line with slope 25.73 Lbarmol−1 . The
temperature at which the osmotic pressure measurement is done is
(Use R = 0.083 L bar mol m−1 K−1 ) [NEET 2024]
(A) 310◦ C (B) 25.73◦ C (C) 12.05◦ C (D) 37◦ C
Π = CRT
Slope = RT
22
25.73 = 0.083 × T
0.083 = 309.47 ≈ 310 K
T = 25.73
∴ Temperature in ◦ C= 310 − 273
= 37 C
◦
(51) 2.5 g of a non-volatile, non-electrolyte is dissolved in 100 g of water at 25◦ C. The solution showed a boiling point elevation by
2◦ C. Assuming the solute concentration in negligible with respect to the solvent concentration, the vapour pressure of the
resulting aqueous solution is . . . . . . mm of Hg (nearest integer)
[Given : Molal boiling point elevation constant of water (Kb ) = 0.52K.kgmol−1 ,
⌋
1 atm pressure = 760 mm of Hg, molar mass of water = 18 g mol−1 [JEE MAIN 2024]
(A) 702 (B) 704 (C) 705 (D) 707
2 = 0.52 × m
m = 0.52
2
According to question, solution is much diluted

nsolate
so ∆P
P◦ = nsoltron:
m
∆P
P◦ = 1000 × Msolvent
m
∆P = P◦ × 1000 × Msohtwat
2
= 760 × 1000
0.52
× 18 = 52.615
P5 = 760 − 52.615 = 707.385 mm of Hg
(52) The elevation in boiling point for 1 molal solution of non-volatile solute A is 3 K. The depression in freezing point for 2 molal
solution of A in the same solvent is 6 K. The ratio of Kb and Kf i.e., Kb /Kf is 1 : X. The value of X is [nearest integer] [JEE MAIN 2022]
(A) 0 (B) 1 (C) 2 (D) 3
∆Tb = iKb m1 ∆Tf = iKf m2
ss
Kb ×1
∆Tf = Kf ×2 ⇒ 6 = 2 = Kf ×
∆Tb 3 1 Kb 1
2
Kb
= 1
⇒x=1
la
Kf 1
(53) A solution containing 10 g of an electrolyte AB2 in 100 g of water boils at 100.52◦ C. The degree of ionization of the electrolyte
dc
(α) is............ ×10−1 .

(nearest integer)
Ve
[Given : Molar mass of AB2 = 200 g mol−1 · Kb

(molal boiling point elevation const. of water)
= 0.52 K kg mol−1 , boiling point of water = 100◦ C;
]
AB2 ionises as AB2 → A2+ + 2 B− [JEE MAIN 2024]
(A) 3 (B) 5 (C) 6 (D) 8
AB2 → A+2 + 2 B⊖
i = 1 + (3 − 1)α
i = 1 + 2α
∆Tb = kb im
10
0.52 = 0.52(1 + 2α) 200
100
1000
10
1 = (1 + 2α) 20
2 = 1 + 2α
α = 0.5
Ans. α = 5 × 10−1
(54) The mixture which shows positive deviation from Raoult’s law is [NEET 2020]
(A) Chloroethane + Bromoethane (B) Ethanol + Acetone
(C) Benzene + Toluene (D) Acetone + Chloroform
Hydrogen bond of ethanol gets weakened by addition of acetone.
(55) The vapour pressures of two volatile liquids A and B at 25◦ C are 50 T orr and 100 T orr, respectively. If the liquid mixture
contains 0.3 mole fraction of A, then the mole fraction of liquid B in the vapour phase is 17
x
. The value of x is ... [JEE MAIN 2022]
(A) 140 (B) 89 (C) 14 (D) 54
23
◦
yB PB XB
1−yB = PA
◦ 1−X
B
⇒ 1−yB = 50 [ 0.3 ]
yB 100 0.7
= 14
3
⇒ yB = 14
17
Ans. 14
(56) A molecule M associates in a given solvent according to the equation M ⇌ (M )n For a certain concentration of M, the van’t
Hoff factor was found to be 0.9 and the fraction of associated molecules was 0.2. The value of n is [JEE MAIN 2013]
(A) 3 (B) 5 (C) 2 (D) 4
van’t Hoff factor
( (i))and the degree of association are related as below :
i = 1 − α 1− 1
( n 1)
0.9 = 1 − 0.2 1 − n
On
( solving,
)
1 − n1 = 21
n = 1 − 2 = 2
1 1 1
∴ n=2
(57) ‘The vapour pressure vs. temperature curve for a solution solvent system is shown below.The boiling point of the solvent is
........ ◦ C [JEE MAIN 2023]
ss
la
(A) 81 (B) 82 (C) 83 (D) 84

dc
Boiling point of solvent is 82◦ C
Ve
Boiling point of solution is 83◦ C
(58) A gaseous mixture of two substances A and B, under a total pressure of 0.8 atm is in equilibrium with an ideal liquid solution.
The mole fraction of substance A is 0.5 in the vapour phase and 0.2 in the liquid phase. The vapour pressure of pure liquid A ......
is atm. (Nearest integer) [JEE MAIN 2022]
(A) 1 (B) 0 (C) 2 (D) 3
YA = 0.5 ⇒ YB = 0.5
PA = PB = 0.4atm
PA = PA0 XA
PA0 = 2
(59) At 300 K, the vapour pressure of a solution containing 1 mole of n−hexane and 3 moles of n−heptane is 550 mm of Hg. At the
same temperature, if one more mole of n-heptane is added to this solution, the vapour pressure of the solution increases by
10 mm of Hg. What is the vapour pressure in mmHg of n−heptane in its pure state..........? [JEE MAIN 2020]
(A) 600 (B) 620 (C) 590 (D) 628
550 = PA◦ × 14 + PB◦ × 34
2200 = PA◦ + 3PB◦ ....(i)
2800 = PA◦ + 4PB◦ ....(ii)
560 = PA◦ × 15 + PB◦ × 45
PB◦ = 600, PA◦ = 400
(60) Mass of Urea (N H2 CON H2 ) required to be dissolved in 1000g of water to reduce the vapour pressure of water by 25% is ......g.
(Nearest integer) Given: Molar mass of N, C, O and H are 14, 12, 16 and 12 mol−1 respectively. [JEE MAIN 2023]
(A) 1112 (B) 1113 (C) 1114 (D) 1111
24
x
P 0 −Ps nsolute P 0 −0.75P 0
Ps = nsolvent = 60
1000 = 0.75P 0
18
⇒x= 10000
9 = 1111 gm
(61) Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y . respectively in 1 kg of water. The ratio of
depression in freezing points for A and B is found to be 1 : 4. The ratio of molar masses of X and Y is. [JEE MAIN 2022]
(A) 1 : 4 (B) 1 : 0.25 (C) 1 : 0.20 (D) 1 : 5
1/Mx
∆Tex kf ·mx 1/My
∆Tf y = kf ·my = 1
1
1 My
4 = Mx
Mx : My = 1 : 0.25
(62) If molality of the dilute solution is doubled, the value of molal depression constant (Kf ) will be [NEET 2017]
(A) halved (B) tripled (C) unchanged (D) doubled.
Kf does not depend on concentration of solution. It only depends on nature of solvent so it will be unchanged.
(63) Which one of the following 0.10 M aqueous solutions will exhibit the largest freezing point depression? [JEE MAIN 2021]
(A) hydrazine (B) glucose (C) glycine (D) KHSO4
∵ Van’t Hoff factor is highest for KHSO4
∴ colligative property (∆Tf ) will be highest for KHSO4
(64) The oxygen dissolved in water exerts a partial pressure of 20 kP a in the vapour above water. The molar solubility of oxygen in
water is ............ − × 10−5 mol dm−3
(Round off to the Nearest Integer).
ss
[Given : Henry’s law constant = KH = 8.0 × 104 kP a for O2 Density of water with dissolved oxygen = 1.0 kg dm−3 ] [JEE MAIN 2021]
la
(A) 20 (B) 15 (C) 30 (D) 25
dc
P = KH · x ( )
or, 20 × 103 = 8 × 104 × 103 ×
nO 2
Ve
nO2 +nwater
or , 4000
1 O2n O2 n
= nO +n water
= nwater
2
Means 1 mole water (= 18gm = 18ml) dissolves
4000 moles O2 . Hence, molar solubility
1
( 1 )
= 400018 × 1000 = 72 1
moldm−3
= 1388.89 × 10 mol dm−3 ≈ 1389mol dm−3
−5
(65) A solution containing 2.5 × 10−3 kg of a solute dissolved in 75 × 10−3 kg of water boils at 373.535 K. The molar mass of the
solute is ..... g mol−1 . [nearest integer] (Given: Kb (H2 O) = 0.52 K Kg mol−1 , boiling point of water = 373.15 K ) [JEE MAIN 2022]
(A) 50 (B) 93 (C) 10 (D) 45
w = 2.5 g Kb = 0.52
wsolvent = 75g M = Mol . Wt .of solute
TB′ = 373.535 K
TBo = 373.15 K
∆TB = 0.385 =(Kb molality )
M × 75
0.385 = 0.52 × 2.5 1000
M = 45 g mol−1
(66) If 80 g of copper sulphate CuSO4 · 5H2 O is dissolved in deionised water to make 5 L of solution. The concentration of the copper
sulphate solution is x × 10−3 mol L−1 . The value of x is .... .
[Atomic masses Cu : 63.54 u, S : 32 u, O : 16 u, H : 1 u] [JEE MAIN 2021]
(A) 49 (B) 80 (C) 64 (D) 17
Moles of CuSO4 · 5H2 O = 249.54
80
Molarity = 249.54 = 64.117 × 10−3

80
5
Nearest integer, x = 64
25
(67) CO2 gas is bubbled through water during a soft drink manufacturing process at 298 K. If CO2 exerts a partial pressure of 0.835 bar
then x m mol of CO2 would dissolve in 0.9 L of water. The value of x is ..... (Nearest integer)
(Henry’s law constant for CO2 at 298 K is 1.67 × 103 bar) [JEE MAIN 2021]
(A) 50 (B) 25 (C) 55 (D) 35
From Henry’s Law
n(CO2 )
0.835 = 1.67 × 103 × 0.9×1000
18
n (CO2 ) = 0.025
Millimoles of CO2 = 0.025 × 1000 = 25
(68) When a certain amount of solid A is dissolved in 100 g of water at 25◦ C to make a dilute solution, the vapour pressure of the
solution is reduced to one-half of that of pure water. The vapour pressure of pure water is 23.76 mm Hg. The number of moles of
solute A added is ........... (Nearest Integer) [JEE MAIN 2022]
(A) 2 (B) 3 or 6 (C) 4 (D) 5
∵ Diliute solution given:
P 0 −Ps n
solute
P0 ∼ n solvent
= nsolute
P 0 −P 0 /2 n
P0 solvent
’ solute ∼ solvent
n
100
2 = 18×2 = 2.78 mol
More accurate approach:
P 0 −PS n
solute
PS = n solvent
P 0 −P 0 /2 n
solute
P 0 /2 = n solvent
’ solute = solvent =
n 100
18 = 5.55 mol
(69) Match List I with List II.

List I List II
ss
A van’t Hoff factor, i I Cryoscopic constant
II Isotonic solutions
la
B kf
C Solutions with same osmotic pressure III N ormal molar mass
dc
Abnormal molar mass
D Azeotropes IV Solutions with same composition of vapour

above it
Ve
Choose the correct answer from the options given below : [JEE MAIN 2023]
(A) A − III, B − I, C − II, D − IV (B) A − III, B − II, C − I, D − IV
(C) A − III, B − I, C − IV, D − II (D) A − I, B − III, C − II, D − IV
(A) van’t Hoff factor, i
Normal molar mass
i = Abnormal molar mass
(B) kf = Cryoscopic constant
(C) Solutions with same osmotic pressure are known as isotonic solutions.
(D) Solutions with same composition of vapour over them are called Azeotrope.
(70) The depression in freezing point observed for a formic acid solution of concentration 0.5 mL L−1 is 0.0405◦ C. Density of formic
acid is 1.05 g mL−1 . The Van’t Hoff factor of the formic acid solution is nearly: (Given for water kf = 1.86 K kg mol−1 ) [JEE MAIN
2022]
(A) 0.8 (B) 1.1 (C) 1.9 (D) 2.4
[HCOOH]
( = 0.5 ml 1−1)
⇒ 0.5ml × 1.05 g ml−1 HCOOH in 1L
⇒ 0.525 g HCOOH in 1 L
m = (0.525/46)
1 kg mol [Assuming dilute solution]
∆Tf
∴ ∆Tf = iKf m ⇒ i = kf m = 0.0405×46
1.86×0.525 = 1.9
(71) 80 mole percent of M gCl2 is dissociated in aqueous solution. The vapour pressure of 1.0 molal aqueous solution of M gCl2 at
38◦ C is ......... mm Hg. (Nearest integer)Given : Vapour pressure of water at 38◦ C is 50 mm Hg [JEE MAIN 2023]
(A) 47 (B) 48 (C) 46 (D) 45
26
M gCl2 → M g +2 + 2Cl−
1 − α α 2α
i = 1 + 2α(α = 0.8)
i = 2.6
∆p i×n2
p ◦ = n1
∆p = 2.34
ps = 47.66
ps ∼= 48
(72) The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient intravenously, it has to be isotonic with blood.
The concentration of glucose solution in g L−1 is ...... (Molar mass of glucose = 180 g mol−1
R = 0.083 L bar K −1 mol−1 ) (Nearest integer) [JEE MAIN 2022]
(A) 11 (B) 33 (C) 54 (D) 44
π = C.R.T
7.47 = C × 0.083 × 300
C = 0.3M
= 0.3 × 180gL−1
= 54gL−1
(73) Boiling point of a 2% aqueous solution of a nonvolatile solute A is equal to the boiling point of 8% aqueous solution of a
non-volatile solute B. The relation between molecular weights of A and B is. [JEE MAIN 2022]
(A) MA = 4MB (B) MB = 4MA (C) MA = 8MB (D) MB = 8MA
For A: 100gm solution → 2 gm solute A
∴ Molality = 2/M A
0.098
For B : 100 gm solution → 8 gm solute B
∴ Molality = 8/M B
ss
0.092
∵ (∆TB )A = (∆TB )B
∴ Molality of A = Molality of B
la
∴ 0.098M
2
A
8
= 0.092M B
98 × 8 = MB
2 92 MA
dc
1 MA
4.261 = MB
∴ MB = 4.261 × MA
Ve
(74) A mixture of one mole each of H2 , He and O2 each are enclosed in a cylinder of volume V at temperature T. If the partial
pressure of H2 is 2 atm, the total pressure of the gases in the cylinder is.......atm [JEE MAIN 2020]
(A) 14 (B) 22 (C) 6 (D) 38
According to Dalton’s law of partial pressure
p i = x i × PT
Pi = partial pressure of the ith component
xi = mole fraction of the ith component
pT = total pressure
( of mixture
)
n 2
⇒ 2atm = nH +nH H +nO
× pT
2 e 2
⇒ pT = 2atm × 3
1 = 6atm
(75) At 27◦ C, a solution containing 2.5 g of solute in 250.0 mL of solution exerts an osmotic pressure of 400 P a. The molar mass of
the solute is ..............g mol −1 (Nearest integer)(Given : R = 0.083 L bar K −1 mol−1 ) [JEE MAIN 2023]
(A) 62240 (B) 62258 (C) 62240 (D) 62250
π = CRT 2.5 g
105 = 250/1000 L × 0.83 K·mol × 300 K
400 P a Mo L−bar
M0 = 62250
(76) Which one of the following 0.06 M aqueous solutions has lowest freezing point? [JEE MAIN 2021]
(A) C6 H12 O6 . (B) K2 SO4 (C) KI (D) Al2 (SO4 )3
∆Tf = ikf × m
∆Tf α i but F.P α1/i
27
(77) C6 H6 freezes at 5.5◦ C. The temperature at which a solution 10 g of C4 H10 in 200 g of C6 H6 freeze is ...... ◦ C. (The molal freezing
point depression constant of C6 H6 is 5.12 ◦ C/m. ) [JEE MAIN 2021]
(A) 3 (B) 1 (C) 5 (D) 9
Pure Solvent : C6 H6 (ℓ)
Given : Tf◦ = 5.5◦ C
Kf = 5.12◦ C/m
∵ ∆Tf = kf × m
( )
( 10 )
⇒ Tf0 − Tf′ = 5.12 × 20058 kg mol
( 1000 )
⇒ 5.5 − Tf′ = 5.12×5×10
58
⇒ Tf′ = 1.086◦ C ≃ 1◦ C
(78) The Total pressure observed by mixing two liquid A and B is 350 mm Hg when their mole fractions are 0.7 and 0.3
respectively.The Total pressure becomes 410 mm Hg if the mole fractions are changed to 0.2 and 0.8 respectively for A and B.
The vapour pressure of pure A is ........... mm Hg. (Nearest integer)
Consider the liquids and solutions behave ideally. [JEE MAIN 2023]
(A) 314 (B) 312 (C) 311 (D) 310
Let V.P. of pure A be PA0
Let V.P of pure B be PB0
When XA = 0.7&XB = 0.3 Ps = 350
ss
⇒ PA0 × 0.7 + PB0 × 0.3 = 350
When XA = 0.2&XB = 0.8
la
Ps = 410
⇒ PA0 × 0.2 + PB0 × 0.8 = 410
Solving (i) and (ii) PA0 = 314 mm Hg
dc
PB0 = 434 mm Hg
= (314)
Ve
(79) Which one of the following electrolytes has the same value of van’t Hoff factor (i) as that of Al2 (SO4 )3 (if all are 100% ionised)?
[NEET 2015]
(A) Al(N O3 )3 (B) K4 [F e(CN )6 ] (C) K2 SO4 (D) K3 [F e(CN )6 ]
Al2 (SO4 )3 → 2Al3+ + 3SO2−
4 ,i = 5
Al (NO3 )3 → Al3+ + 3NO−3 ,i = 4
−4
K4 [Fe(CN)6 ] → 4K + [Fe(CN)6 ] , i = 5
+
K2 SO4 −→ 2K+ + SO2− 4 ,i = 3

K3 [Fe(CN)6 ] → 3K+ + [Fe(CN)6 ] , i = 4
3−
(80) If O2 gas is bubbled through water at 303 K, the number of millimoles of O2 gas that dissolve in 1 litre of water is (Nearest
Integer) (Given : Henry’s Law constant for O2 at 303 K is 46.82 k bar and partial pressure of O2 = 0.920 bar ) (Assume solubility
of O2 in water is too small, nearly negligible) [JEE MAIN 2022]
(A) 0 (B) 1 (C) 2 (D) 3
p = KH × x
0.920 = 46.82 × 103 bar × molof
molof O2
H2 O
of O2
0.920 = 46.82 × 103 × mol
1000/18
0.920 = 46.82 × nO2
0.920
p = 46.82×18 = n02
⇒ 1.09 × 10−3 = n02
⇒ m mol of O2 = 1
(81) For an ideal solution, the correct option is [NEET 2019]

(A) ∆mix S = 0 at constant T and P (B) ∆mix V ̸= 0 at constant T and P
(C) ∆mix H = 0 at constant T and P (D) ∆mix G = 0 at constant T and P
28
For ideal solution ∆Hmax − 0
(82) When ’ x ’ ×10−2 mL methanol (molar mass = 32 g; density = 0.792 g/cm3 ) is added to 100 mL water (density = 1 g/cm3 ), the
following diagram is obtained.
(Image)
x =.. . . . . .(nearest integer)
[Given: Molal freezing point depression constant of water at 273.15 K2 is 1.86 K kg mol−1 ] [JEE MAIN 2024]
(A) 540 (B) 542 (C) 543 (D) 550
∆Tf = 273.15 − 270.65 = 2.5 K
n
∆Tf = Kf m ⇒ 2.5 = 1.86 × 0.1
⇒ n = 0.1344 moles
⇒ w = 0.1344 × 32 = 4.3 g
Volume = 0.792
4.3
= 5.43ml = 543 × 10−2 ml
(83) 224 mL of SO2(g) at 298K and 1 atm is passed through 100 mL of 0.1 M N aOH solution. The non-volatile solute produced is
ss
(dissolved in 36 g of water. The lowering of vapour pressure of solution (assuming the solution is dilute)
P(H2 O) = 24 mm of Hg) is x × 10−2 mm of Hg the value of x is ...... .(Integer answer) [JEE MAIN 2021]
la
(A) 50 (B) 12 (C) 67 (D) 89

dc
SO2 + N aOH → N aHSO3
−
Ve
9.2 10
− 0.8 9.2
∆P = P 0 · Xsolute
= 24 × (1.6+18.4)
2020
= 0.2376 = 23.76 × 10−2
(84) In water saturated air the mole fraction of water vapour is 0.02. If the total pressure of the saturated air is 1.2 atm, the partial
pressure of dry air is .....atm [NEET 2019]
(A) 1.21 (B) 1.76 (C) 1.17 (D) 0.98
XH2 O = 0.02
∴ Xgas = 0.98
Ptotal = 1.2atm
partial pressure of dry-air = PT × mole fraction of dry-air
Partial pressure of dry-air = 1.2 atm × 0.98 = 1.176 atm
(85) How many grams of concentrated nitric acid solution should be used to prepare 250 mL of 2.0 M HN O3 ? The concentrated
acid is 70% HN O3 . [NEET 2013]
(A) 70.0 g conc. HN O3 (B) 54.0 g conc. HN O3 (C) 45.0 g conc. HN O3 (D) 90.0 g conc. HN O3
No. of moles = (250 × 1000)/2
= 0.5 moles No. of moles = molarity × volume
Requird mass of HNO3 = 0.5 × 63
= 31.5gm
70gm of HNO3 are present in 100gm of solution,
So 1 gm will be present in 100/70gm of solution.
31.5gm be present in (100/70) × 31.5gm of solution
= 45 gm
29
(86) The mixture that forms maximum boiling azeotrope is [NEET 2019]
(A) Water + Nitric acid (B) Ethanol + Water
(C) Acetone + Carbon disulphide (D) Heptane + Octane
Maximum boiling azeotrope are formed by solutions which show negative deviation from ideal behaviour.
Water + Nitric acid shows negative deviation.
(87) When 9.45 g of ClCH2 COOH is added to 500 mL of water, its freezing point drops by 0.5◦ C. The dissociation constant of
ClCH2 COOH is x × 10−3 . The value of x is ...............
(Rounded
[ off to the nearest integer)
]
Kf (H2 O) = 1.86 K kgmol−1 [JEE MAIN 2021]
(A) 38 (B) 42 (C) 36 (D) 44
ClCH2 COOH ⇌ ClCH2 COO ⊖ + H +
i = 1 + (2 − 1)α
i=1+α
∆Tf = ikf m ( )
94.5 )
( 9.45
0.5 = (1 + α)(1.86)
( 1000
500
)
5
3.72 = 1 + α ⇒ α = 3.72
1.28
α = 32
93
ClCH2 COOH ⇌ ClCH2 COO ⊖ + H +
C − CαCα Cα
= 0.036
Ka = 36 × 10−3
(88) What is the mole fraction of the solute in a 1.00 m aqueous solution ? [AIPMT 2011 , NEET 2015]
(A) 1.770 (B) 0.0354 (C) 0.0177 (D) 0.177

ss
1.00 m solution means 1 mole solute is present in 1000 g water.
la
18 = 55.5 mol H2 O
nH2 = 1000
Xsolute = nsolutencalle 1
+nH O = 1+55·5 = 0.0177
dc
(89) The elevation of boiling point of 0.10 m aqueous CrCl3 , xN H3 solution is two times that of 0.05 m aqueous CaCl2 solution. The
value of x is.........
Ve
[Assume 100% ionisation of the complex and CaCl2 , coordination number of Cr as 6, and that all N H3 molecules are present
inside the coordination sphere ] [JEE MAIN 2020]
(A) 10 (B) 5 (C) 12 (D) 15
∆Tb = i × Kb × m
i × 0.1 × Kb = 3 × 0.05 × Kb × 2
i=3
[Cr (N H3 )5 · Cl] Cl2 → [Cr (N H3 )5 Cl] + 2Cl−
+2
x=5
(90) 0.004 M K2 SO4 solution is isotonic with 0.01 M glucose solution. Percentage dissociation of K2 SO4 is ........ (Nearest integer)
[JEE MAIN 2023]
(A) 71 (B) 73 (C) 74 (D) 75

Isotonic solutions,
πK2 SO4 = πGlucose
i × 0.004 × RT = 0.01 × RT
i = 2.5
For K2 SO4 { for dissociation i = 1 + (n − 1)α}
DOD(α) = n−1i−1
= 2.5−1
3−1 = 0.75
% dissociation = 75
(91) 83 g of ethylene glycol dissolved in 625 g of water.The freezing point of the solution is ......K.
(Nearest integer) ]
[Use : Molal Freezing point depression constant of water = 1.86 K kg mol−1
Freezing Point of water = 273 K
Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u] [JEE MAIN 2021]
(A) 369 (B) 269 (C) 209 (D) 296
30
kf = 1.86 k · kg/mol
T◦f = 273 k
solvent : H2 O(625 g)
Solute : 83 g CH2 OH − CH2 OH ⇒ Non dissociative
solute
⇒ (∆Tf = kf)× m
⇒ T◦f − T1f = 1.86 × 624/1000
83/62
⇒ 273 − T1f = 1.86×83×1000

62×625 = 154380
38750
⇒ 273 − Tf = 4
1
⇒ T1f = 259 K
(92) If 250 cm3 of an aqueous solution containing 0.73 g of a protein A is isotonic with one litre of another aqueous solution containing
1.65 g of a protein B, at 298 K, the ratio of the molecular mases of A and B is..........×10−2 (to the nearest integer). [JEE MAIN 2020]
(A) 172 (B) 175 (C) 180 (D) 177
Let molar mass of protein A = x g/mol
Let molar mass of protein B = yg/mol
( 0.73
x )
πA = osmotic pressure of protein A = 0.25 RT
( 1.65
y )
πB = osmotic pressure of protein B = 1 RT
πA (= πB ) ( )
⇒ x×0.25
0.73
RT = 1.65 RT
( ) y
⇒ xy = 0.25×1.65
0.73
= 1.769 ∼= 1.77
(93) An artificial cell is made by encapsulating 0.2M glucose solution within a semipermeable membrane. The osmotic pressure
developed when the artificial cell is placed within a 0.05M solution of NaCl at 300 K is . . . . . . . . . .×10−1 bar. (Nearest Integer)
ss
[Given : R = 0.083 Lbarmol−1 K−1 ]
Assume complete dissociation of NaCl [JEE MAIN 2024]
la
(A) 10 (B) 20 (C) 25 (D) 30

dc
NaCl −→ Na+ + Cl−
Ve
0.05M 0.05M 0.05M

Total C1 = 0.05 + 0.05 = 0.1M(NaCl)
C2 = 0.2M( glucose )
π = (C2 − C1 ) RT
= (0.2 − 0.1) × 0.083 × 300
= 2.49 bar
= 24.9 × 10−1 bar
(94) The Henry’s law constant (KH ) values of three gases (A, B, C) in water are 145, 2 × 10−5 and 35 kbar, respectively. The solubility
of these gases in water follow the order: [NEET 2024]
(A) B > C > A (B) A > C > B (C) A > B > C (D) B > A > C
Sol. Value of Henry’s law constant ∝ Solubility
1
of gas
Higher the value of KH at a given pressure, lower is the solubility of the gas in the liquid.
KH value of gases (given) : A > C > B
∴ Order of solubility of gases in water : B > C > A
(95) Which condition is not satisfied by an ideal solution? [NEET 2013]

(A) ∆mix V = 0 (B) ∆mix S = 0
(C) Obeyance to Raoult’s Law (D) ∆mix H = 0
31
For an ideal solution
∆mixing H = 0; ∆mixing V = 0
and it should obey Raoult’s law.
(96) The correct option for the value of vapour pressure of a solution at 45◦ C with benzene to octane in molar ratio 3 : 2 is ...... mm of
Hg
[At 45◦ C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas] [NEET 2021]
(A) 160 (B) 168 (C) 336 (D) 350
Ps = POA xA + POB xB
= 280 × 35 + 420 × 25
= 56 × 3 + 84 × 2
= 168 + 168
= 336
(97) 1 kg of 0.75 molal aqueous solution of sucrose can be cooled up to −4◦ C before freezing. The amount of ice (in g) that will be
separated out is .... . (Nearest integer) ]
[ Given : Kf (H2 O) = 1.86 K kg mol−1 [JEE MAIN 2021]
(A) 342 (B) 841 (C) 518 (D) 277
Let mass of water initially present = x gm
⇒ Mass of sucrose = (1000 ( − x)
) gm
⇒ moles of sucrose = 1000−x 342
( 1000−x
342 ) x
⇒ 0.75 = x ⇒ 1000 = 342×0.75
1000−x
( 1000 )
⇒ 256.5x = 106 − 1000x
⇒ x = 795.86 gm
ss
⇒ moles of sucrose = 0.5969
New mass of H2 O = a kg
× 1.86 ⇒ a = 0.2775 kg
la
⇒ 4 = 0.5969
a
⇒ ice separated = (795.86 − 277.5) = 518.3 gm
dc
(98) A solution is prepared by adding 2 g of ’ X ’ of 1 mole of water. Mass percent of ’ X ’ in the solution is .............% [JEE MAIN 2023]
(A) 20 (B) 5 (C) 2 (D) 10
Ve
Solute (X) = 2 g
Solvent (H2 O) = 1 mole = 18 g
Total mass = 2 + 18 = 20 g
% mass of X = 20 2
× 100 = 10%
(99) 1.80 g of solute A was dissolved in 62.5 cm3 of ethanol and freezing point of the solution was found to be 155.1 K. The molar
mass of solute A is ..........g mol−1 .
[Given: Freezing point of ethanol is 156.0K Density of ethanol is 0.80] g cm−3 .
Freezing point depression constant of ethanol is 2.00 K kg mol m−1 [JEE MAIN 2022]
(A) 81 (B) 80 (C) 82 (D) 83
Mass of C2 H5 OH = 62.5 × 0.8 = 50 g
∆Tf = Kf × m
0.9 = 2 × 1.8×1000
Mπ ×50
Mw = 2×1.8×1000
0.9×50 = 80
(100) If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio 2 : 1 and their enthalpy of
vaporizations are in the ratio 1 : 2, then the boiling point elevation constant of X is m times the boiling point elevation constant
of Y . The value of m is ...... (Nearest integer) [JEE MAIN 2023]
(A) 8 (B) 6 (C) 4 (D) 2
(TB )x 2 (∆H)x 1
(TB )y = 1 (∆H)y = 2
(∆TB )x (KB )x × molality
(∆TB )y = m = (KB )y × molality
(T ·B)2 ∆H
= (T ·B)x2 × (∆Hyx = (2)2 × 2 =8
y
32
(101) The maximum prescribed concentration of copper in drinking water is ........ ppm [JEE MAIN 2019]
(A) 0.5 (B) 3 (C) 5 (D) 0.05
Maximum prescribed concentration of copper in drinking water is 3 ppm. Above this concentration water becomes toxic
(102) A solution containing 10 g per dm3 of urea (molecular mass = 60 g mol−1 ) is isotonic with a 5% solution of a non volatile solute.
The molecular mass of this non volatile solute is ........ g mol−1 [AIIMS 2014]
(A) 300 (B) 350 (C) 200 (D) 250
Molar concentration of urea = 1060 per dm
3
Molar concentration of volatile solute solution = M5

per 100 ml or , M
50
per dm3
For solution of same concentration or, isotonic solution at same temperature
60 = M or, M = 300 g mol
10 50 −1
(103) Which of the following pairs of solutions are expected to be isotonic, temperature being the same? [AIIMS 2011]
(A) 0.1 M glucose and 0.1 M C6 H5 N + H3 Cl− (B) 0.1 M N aCl and 0.05 M BaCl2
(C) 0.1 M N a2 SO4 and 0.1 M KN O3 (D) 0.1 M BaCl2 and 0.075 M F eCl3
Effective molarity of BaCl2 = 3 × 0.1 = 0.3 ;
effective molarity of F eCl3 = 4 × 0.075 = 0.3
(104) The solubility product of sparingly soluble salt AX2 is 3.2 × 10−11 . Its solubility (in mol/L) is [AIIMS 2018]
(A) 5.6 × 10−6 (B) 3.1 × 10−4 (C) 2 × 10−4 (D) 4 × 10−4
AX2 is ionized as follows:
ss
−
AX2 ⇌ A2+ s + 2X
mol L−1 2S
Solubility
[ product
] of AX2
la
2
Ksp = A2+ [X − ] = [S] × [2S]2 = 4S 3
∵ Ksp of AX2 = 3.2 × 10−11
dc
∴ 3.2 × 10−11 = 4s3

or, S 3 =√0.8 × 10−11 = 8 × 10−12
or, S = 3 8 × 10−12
Ve
= 2 × 10−4 mol/L
Solubility = 2 × 10−4 mol/L
(105) Which of the following salt has the same value of Van’t Hoff factor i as that of K4 [F e(CN )6 ] [AIIMS 1998 , AIPMT 1994]
(A) Al2 (SO4 )3 (B) N aCl (C) N a2 SO4 (D) Al(N O3 )3
(a) K4 [F e(CN )6 ]dissociates as 4K + + [F e(CN )6 ]4− , thus 1 molecule dissociates into five particles in the similar way Al2 (SO4 )3
also gives five particles per molecule.
(106) Benzoic acid undergoes dimerisation in benzene solution. The van’t Hoff factor (i) is related to the degree of association ’ x′ of
the acid as [AIIMS 2018]
( ) ( )
(A) i = (1 − x) (B) i = (1 + x) (C) i = 1 − x2 (D) i = 1 + x2
2C6 H5 COOH → (C6 H5 COOH)2
Before association 1 mole
After association 1 − x x/2
Total = 1 − x + x2 = 1 − x2
∴ i = 1−x/2
1
or, i = 1 − x2
(107) The vapour pressure of a solvent decreases by 10 mm of Hg when a non-volatile solute was added to the solvent. The mole
fraction of the solute in the solution is 0.2. What should be the mole fraction of the solvent if the decrease in the vapour pressure
is to be 20 mm of Hg ? [AIIMS 2015]
(A) 0.8 (B) 0.6 (C) 0.4 (D) 0.2
33
According to Raoult’s law
po = n+N (Mole fraction of solute)
∆p n
po = 0.2 ∴ p = 50 mm Hg
10 o
For other solution of same solvent

po = n+N (Mole fraction of solute)
20 n
⇒ 50 = Mole fraction of solute

20
⇒ Mole fraction of solute = 0.4

As Mole fractionof solute + Mole fraction of solvent = 1
Hence, Mole fraction of solvent = 1 − 0.4 = 0.6
(108) The average osmotic pressure of human blood is 7.8 bar at 37 o C. What is the concentration of an aqueous N aCl solution that
could be used in the blood stream .........mol/L [AIIMS 2004]
(A) 0.16 (B) 0.32 (C) 0.60 (D) 0.45
(b) π = C R T ; C = RπT = ·082×310
7.8
= 0 · 31 mol/litre
(109) Which observation (s) reflect (s) colligative properties ?

(i) A 0.5 m N aBr solution has a higher vapour pressure than a 0.5 m BaCl2 solution at the same temperature
(ii) Pure water freezes at the higher temperature than pure methanol
(iii) a 0.1 m N aOH solution freezes at a lower temperature than pure water
Choose the correct answer from the codes given below [AIIMS 2017]
(A) (i), (ii) and (iii) (B) (i) and (ii) (C) (ii) and (iii) (D) (i) and (iii)
Colligative properties depends upon the no. of particles. Since methanol is non electrolyte hence cannot be considered.
(110) An aqueous solution of N aCl shows the depression of freezing point of water equal to 0.372 K. The boiling point of BaCl2
solution of same molality will be .........o C .[Kf (H2 O) = 1.86 K kg mol−1 ; Kb (H2 O) = 0.52 K kg mol−1 ] [AIIMS 2011]
ss
(A) 100.52 (B) 100.104 (C) 101.56 (D) 100.15
la
∆Tf i1 K f m 2×1.86
dc
∆Tb = i2 Kb m = 3× 0.52
∆Tf = 0.372 Hence ,∆Tb = 0.156 o C
i.e., Tb = 100.156 o C
Ve
(111) At a particular temperature, the vapour pressures of two liquids A and B are respectively 120 and 180 mm of mercury. If 2 moles
of A and 3 moles of B are mixed to form an ideal solution, the vapour pressure of the solution at the same temperature will be
(in mm of mercury) [AIIMS 2013]
(A) 156 (B) 145 (C) 150 (D) 108
Vapour pressure of solution = PA + PB
= poA xA + poB xB = 120×2
5 + 180×3
5 = 156 mm Hg
(112) Assertion : If one component of a solution obeys Raoult’s law over a certain range of composition, the other component will not
obey Henry’s law in that range.
Reason : Raoult’s law is a special case of Henry’s law. [AIIMS 2011 , AIIMS 2013 , AIIMS 2017]
Raoult’s law holds over the entire concentration range x = 0 to 1 in a binary solution then, for the second component, the same
must also hold.
If deviations from the ideal are not too large, Raoult’s law is still valid in a narrow concentration range when approaching x = 1.
for the majority phase (the solvent) The solute also shows a linear limiting law, but with a different coefficient. This law is known
as Henry’s Law.
(113) An aqueous solution of hydrochloric acid [AIIMS 2009]

(A) Obeys Raoult’s law (B) Shows negative deviation from Raoult’s law
(C) Shows positive deviation from Raoult’s law (D) Obeys Henry’s law at all compositions
34
Shows negative deviation from Raoult’s law. If the attraction between different molecules, for example between HCl and H2 O
molecules, is stronger, the escaping tendency from the solution to the vapour phase will be smaller, then the partial vapour
pressure will be smaller than predicted by Raoult’s law and the system exhibits a negative deviation.
(114) The molal boiling point constant for water is 0.513 o C kg mol−1 . When 0.1 mole of sugar is dissolved in 200 ml of water, the
solution boils under a pressure of one atmosphere at ......... o C. [AIIMS 1991]
(A) 100.51 (B) 100.05 (C) 100.25 (D) 101.02
( 0.1 )
(c)∆Tb = Kb × m = 0.513 × 200 × 1000 = 0.2565 o C, Tb = 100 . 256 o C
(115) A solution containing 1.8 g of a compound (empirical formula CH2 O ) in 40 g of water is observed to freeze at − 0.465 o C. The
molecular formula of the compound is ( Kf of water = 1.86 kg K mol−1 ) [AIIMS 2016]
(A) C2 H4 O2 (B) C3 H6 O3 (C) C4 H8 O4 (D) C6 H12 O6
∆Tf = Kf × m
1000 ×K × W2 (solute)
M = ∆Tf ×fW1 (solvent)
1.86 × 1.8
= 1000×
0.465 × 40 ⇒ M = 180
Molecular formula = (empirical formula) n
M olecular mass 180
n = Empirical f ormula mass = 30 = 6
Molecular formula = (CH2 O)6 = C6 H12 O6
(116) The freezing point of equimolal aqueous solution will be highest for [AIIMS 2013]
(A) C6 H5 N H3+ Cl− (B) Ca(N O3 )2 (C) La(N O3 )2 (D) C6 H12 O6
Glucose is non electrolyte hence depression in freezing point will be minimum, hence freezing point will be highest.
ss
(117) The boiling point of water ( 100 o C ) becomes 100.52 o C, if 3 grams of a nonvolatile solute is dissolved in 200 ml of water. The
molecular weight of solute is (Kb for water is ................. g mol−1 0.6 K − m) [AIIMS 1998]
la
(A) 12.2 (B) 15.4 (C) 17.3 (D) 20.4

dc
(c) First boiling point of water = 100 o C
Ve
Final boiling point of water = 100.52 o C

w = 3 g, W = 200 g, Kb = 0.6 kg −1
∆Tb = 100.52 − 100 = 0.52 o C
m = Kb∆T ×w×1000
b ×W
= 0.6×3×1000 1800
0.52×200 = 104 = 17.3 gmol
−1
.
(118) Which one of the statements given below concerning properties of solutions, describes a colligative effect [AIIMS 2003]
(A) Boiling point of pure water decreases by the addition of ethanol
(B) Vapour pressure of pure water decreases by the addition of nitric acid
(C) Vapour pressure of pure benzene decreases by the addition of naphthaleneBoiling point of pure benzene increases by the
addition of toluene
(D) none
It’s Obvious.
(119) Assertion : The water pouch of instant cold pack for treating athletic injuries breaks when squeezed and N H4 N O3 dissolves
lowering the temperature.
Reason : Addition of non-volatile solute into solvent results into depression of freezing point of the solvent. [AIIMS 2006]
A is true and B is also true and B is correct explanation of A.
35
(120) Which of the following modes of expressing concentration is independent of temperature [IIT 1988 , AIIMS 1997 , AIIMS 2001 , AIPMT 1992 , AIPMT
1995]
(A) Molarity (B) Molality (C) Formality (D) Normality
No. of moles of solute per kg of solvent, molality is independent of temperature
(121) Assertion : The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was
found to be different.
Reason : Water is polar and benzene is nonpolar. [AIIMS 2005]
In polar solvent, acetic acid will dissociate leading to greater depression in freezing point.
(122) A 500 g tooth paste sample has 0.2 g fluoride concentration. What is the concentration of F in terms of ppm level [AIIMS 1992]
(A) 250 (B) 200 (C) 400 (D) 1000
(c) F − ions in P P m = 500
0.2
× 106 = 400
(123) What will be the molarity of a solution containing 5 g of sodium hydroxide in 250 ml solution [AIIMS 2000]
(A) 0.5 (B) 1.0 (C) 2.0 (D) 0.1
ss
(a) M = m.wt.
W
× Volume
1000
in ml. =
5×1000
40×250 = 0.5 M
la
(124) Assertion : Molecular mass of benzoic acid when determined by colligative properties is found high
Reason : Dimerisation of benzoic acid. [AIIMS 1998]
dc
Ve

A molecular mass of benzoic acid is found high because of dimerisation of benzoic acid.
(125) What is the molarity of H2 SO4 solution, that has a density 1.84 gm/cc at 35 o C and contains solute 98% by weight ...... M [AIIMS 2001]
(A) 4.18 (B) 8.14 (C) 18.4 (D) 18
(c) 98% H2 SO4 means 98 g H2 SO4 in 100 g solution.
100
1.84 cc = 54.3 cc; 98 g H2 SO4 = 1 mol
Hence molarity = 54.3 1
× 1000 = 18.4 M
(126) If Boiling point of water is 100 ◦ C. How much gram of N aCl is added in 500 g of water to increase the boiling point of water by
approx.1 ◦ C. (Kb )H2 O = 0.52 K. kg/mole [AIIMS 2019]
(A) 2.182 g (B) 7.03 g (C) 14.06 g (D) 28.12 g
The change in boiling point is calculated as :
∆Tb = i × Kb × m
The molality is equal to :
WN aCl ×1000
m = MN aCl ×WH2 0 (g)
Therefore, the mass of N aCl can be calculated as :
aCl ×1000
1 = 2 × 0.52 × WN 58.5×500
58.5×500
WN aCl = 2×0.52×1000
= 28.125 g
36
(127) How many grams of dibasic acid (mol. wt. 200) should be present in 100 ml of its aqueous solution to give decinormal strength
.......... gm. [AIIMS 1992 , AIPMT 1999]
(A) 1 (B) 2 (C) 10 (D) 20
(a)N = E×Vw
(l) ⇒ 0.1 = 100×0.1 ⇒ w = 1 gm
w
(128) Normality of 2 M sulphuric acid is [AIIMS 1991 , AIIMS 1992]

(A) 2 N (B) 4 N (C) N /2 (D) N /4
(b) N = M ×bosicity ; N = 2 × 2 = 4.
(129) The normality of 0.3 M phosphorus acid (H3 P O3 ) is [IIT 1999 , AIIMS 2000]
(A) 0.1 (B) 0.9 (C) 0.3 (D) 0.6
(d)Basicity of H3 P O3 is 2.
Hence 0.3 M H3 P O3 = 0.6 N .
(130) 12 g of urea is dissolved in 1 litre of water and 68.4 g of sucrose is dissolved in 1 litre of water. The lowering of vapour pressure
of first case is [AIIMS 2012]
(A) equal to second (B) greater than second (C) less than second (D) double that of second
Moles of urea = 60
12
= 0.2
Moles of sucrose = 68.4
342 = 0.2
Both are non electrolyte hence lowering of V.P. will be same.
(131) Which of the following is a colligative property [AIIMS 1999]

(A) Surface tension (B) Viscosity (C) Osmotic pressure (D) Optical rotation
ss
la
Colligative properties- The properties that depend upon the ratio of the number of solute molecules and total molecules not
upon the nature of solute molecules named as colligative properties.
dc
Example- Osmotic pressure, elevation of boiling point, depression in freezing point and relative lowering of vapour pressure.
(132) Assertion : If red blood cells were removed from the body and placed in pure water, pressure inside the cells increases.
Ve
Reason : The concentration of salt content in the cells increases. [AIIMS 2006]
A is true. Pressure inside the cell increases due to osmosis. Water enters the cell because concentration is higher inside the cell.
This results in lowering of concentration of medium inside the cell. So, A is true but R is false.
(133) At 25 o C, the highest osmotic pressure is exhibited by 0.1 M solution of [AIIMS 2000 , AIPMT 1994]
(A) CaCl2 (B) KCl (C) Glucose (D) Urea
(a)Highest osmotic pressure is given by solution which produce maximum number of ions i.e. CaCl2 .
(134) Vapour pressure of CCl4 , at 25 ◦ C is 143 mm Hg. 0.5 g of a non- volatile

) solute (mol. wt. 65) is dissolved in 100 mL of CCl4 , Find
the vapour pressure of the solution. (Density of CCl4 , = 1.58 g/cm3 [AIIMS 2019]
(A) 141.93 mm Hg (B) 94.39 mm Hg (C) 199.34 mm Hg (D) 143.99 mm Hg
The mole fraction of solute is equal to the relative lowering of vapour pressure,
x2 = pop−p s
Substitute the given values in the above equation.

o
65 )
( 0.5
= 143−p
143
s
( 158
154 )
After solving,
ps = 141.93 mm Hg
37
(135) When 0.05 M dimethyl amine is dissolve in 0.1 M N aOH solution then the percentage dissociation of dimethyl amine is :
(Kb )(CH3 ) N H = 5 × 10−4 [AIIMS 2019]
2
(A) 5 × 10−5 (B) 5 × 10−3 (C) 5 × 10−1 (D) 5 × 10−2

0.05 M dimethyl amine (weak base), Kb = 5 × 10−4
0.1 M N aOH
(OH − ) = 0.1 + 0.05 α ≈ 0.1
[Cα][OH − ]
Kb = [C−Cα]
5 × 10−4 = α×0.1
1−α
α = 5 × 10−1 %
(136) Which of the following 0.10 m aqueous solutions will have the lowest freezing point ? [AIIMS 2014]
(A) Al2 (SO4 )3 (B) C6 H12 O6 (C) KCl (D) C12 H22 O11
Depression in freezing point ∝ No. of particles.
(when concentration of different solution is equal)
Al2 (SO4 )3 provides five ions on ionisation
Al2 (SO4 )3 → 2Al3+ + 3SO42−
while KCl provides two ions
KCl → K + + Cl−
C6 H12 O6 and C12 H22 O11 are not ionised so they have single particle in solution.
Hence, Al2 (SO4 )3 have maximum value of depression in freezing point or lowest freezing point.
(137) Which pair from the following will not form an ideal solution
(A) CCl4 + SiCl4 (B) H2 O + C4 H9 OH (C) C2 H5 Br + C2 H5 I (D) C6 H14 + C7 H16
(b)H2 O and C4 H9 OH do not form ideal solution because there is hydrogen bonding between H2 O and C4 H9 OH.
ss
(138) The relative lowering in vapour pressure of an aqueous solution of urea which is 6% by weight, is
(A) 0.2 (B) 0.8 (C) 0.01 (D) Can’t predict
la
dc
(139) The osmotic pressure of a decinormal solution of BaCl2 in water is

(A) Inversely proportional to its celsius temperature (B) Inversely proportional to its absolute temperature
Ve
(C) Directly proportional to its celsius temperature (D) Directly proportional to its absolute temperature
It’s Obvious.
(140) If 0.50 mol of CaCl2 is mixed with 0.20 mol of N a3 P O4 , the maximum number of moles of Ca3 (P O4 )2 which can be formed, is
(A) 0.7 (B) 0.5 (C) 0.2 (D) 0.1
(d) 3 CaCl2 + 2 N a3 P O4 → Ca3 (P O4 )2 + 6N aCl
∴ M ole of N a3 P O4 = 3 mole of CaCl2 = 1 mole Ca3 (P O4 )2
∴ 0.2 mole of N a3 P O4 = 0.3 mole of CaCl2 = 0.1 mole of Ca3 (P O4 )2 .
(141) The molar solution of sulphuric acid is equal to

(A) N solution (B) 2 N solution (C) N /2 solution (D) 3 N solution
(b)Molar solution of sulphuric acid is equal to 2 N because it is show dibasic nature.
(142) At 80 o C , the vapour pressure of pure liquid A is 520 mmHg and that of pure liquid B is 1000 mmHg . If a mixture of A and B
boils at 80 o C and 1 atm pressure, the amount of A in the mixture is ........ mol %.
(A) 25 (B) 50 (C) 34 (D) 48
Let the amount of A in the mixture be χA and B be the χB
PT = 760 = PAo χA + PBo χB
760 = 520χA + 1000 (1 − χA )
480χA = 240
χA = 12 or 50 %
38
(143) The freezing point of 1 percent solution of lead nitrate in water will be
(A) Below 0 o C (B) 0 o C (C) 1 o C (D) 2 o C
(a) Dissolution of a non-volatile solute lowers the freezing pt. of the solution H2 O.
(144) 1 mole each of following solutes are taken in 5 moles water,

(i) N aCl (ii) K2 SO4 (iii) N a3 P O4 (iv) glucose
Assuming 100% ionisation of the electrolyte, relative decrease in V.P. will be in order
(A) i < ii < iii < iv (B) iv < iii < ii < i (C) iv < i < ii < iii (D) equal
Po ∝ i
∆P
(145) To 5.85 gm of N aCl one kg of water is added to prepare of solution. What is the strength of N aCl in this solution (mol. wt. of
N aCl = 58.5)
(A) 0.1 Normal (B) 0.1 Molal (C) 0.1 Molar (D) 0.1 Formal
(b) 5.85 g N aCl = 0.1 mol as it present in 1 kg of
water ; molality = m wt.×l
wt. 5.85
= 58.5×1 = 0.1
(146) When 10 g of a non-volatile solute is dissolved in 100 g of benzene, it raises boiling point by 1 o C then molecular mass of the
solute is ....... g. (Kb for benzene = 2.53 k − m−1 )
(A) 223 (B) 233 (C) 243 (D) 253
∆Tb = Kb ×w×1000
m×W
×w×1000
m = Kb∆T b ×W
ss
= 2.53×10×1000
1×100 = 253 g
(147) At 25 o C , the vapour pressure of pure liquid A (mol. wt. = 40) is 100 torr , while that of pure liquid B is 40 torr , (mol. wt. = 80 ).
la
The vapour pressure at 25 o C of a solution containing 20 g of each A and B is ........... torr.

dc
(A) 80 (B) 59.8 (C) 68 (D) 48
Ve
Moles of A = 2040 ⇒ 0.5

Moles of B = 2080 ⇒ 0.25
0.5
XA = 0.5+0.25 = 0.67, XB = 0.33
Ptotal = PA◦ XA + PB◦ XB
⇒ 100 × 0.67 + 40 × 0.33 ⇒ 80 torr
(148) Azeotropic mixture of HCl and water has .......... % HCl

(A) 84 (B) 22.2 (C) 63 (D) 20.2
(d)It is known that azeotropic mixture of HCl and water 20.2% HCl.
(149) Molarity is expressed as [AIPMT 1991]

(A) Gram/litre (B) M oles/litre (C) Litre/mole (D) M oles/ 1000 gms
Molarity = Number of moles of solute
Volume of solution(litre)
So, Molarity is expressed in moles/litre.
Molarity is dependent upon temperature. But Molality does not depend upon temperature.
(150) One mole of glucose is dissolved in 2 moles of water. The vapour pressure of solution relative to that of water is
(A) 2
3 (B) 1
3 (C) 1
2 (D) 3
2
◦
Relative lowering in vapor pressure = P P−P ◦
S
= xA
Where◦
x A = mole fraction of non-volatile solute.
∴ P P−P◦
s
= 13
∴ PPs◦ = 1 − 13 = 23
39

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Bright Tuition classes

Subject : Chemistry Paper Set : 1

............................................. Chemistry - Section A (MCQ) .............................................

not dimerise in water, nor dissociates in water x = . . . . . . . (nearest integer)

Kr acetic acid : 3.90 K kg mol−1

(A) 31 (B) 35 (C) 37 (D) 40

0.10 MC2 H5 OH is (Integer answer)

off to the Nearest Integer).

(A) 4 (B) 3 (C) 6 (D) 5

(A) ∆Hmix = 0 (B) ∆Umix = 0

(C) ∆P = Pobs − Pcalculated by Raoult′ s law = 0 (D) ∆Gmix = 0

(A) ∆Vmix (B) ∆P = Pobserved − PRaoult (C) ∆Hmix (D) ∆Smix

(A) KCl (B) C6 H12 O6 (C) Al2 (SO4 )3 (D) K2 SO4

[ Given : R = 0.083 LbarMol−1 K−1 ] [JEE MAIN 2024]

(A) 76 (B) 77 (C) 79 (D) 80

(A) 0.60 (B) 0.20 (C) 0.80 (D) 0.40

(A) 20 (B) 25 (C) 23 (D) 30

(A) 0.87 (B) 1.00 (C) 1.75 (D) 0.97

following statements is true in this case ? [NEET 2015]

(47) Isotonic solutions have same [NEET 2020]

(A) 19 (B) 21 (C) 25 (D) 36

The following inferences are made

(B) X has lower intermolecular interactions compared to Y .

temperature at which the osmotic pressure measurement is done is

(A) 702 (B) 704 (C) 705 (D) 707

(α) is............ ×10−1 .

(A) 81 (B) 82 (C) 83 (D) 84

(A) hydrazine (B) glucose (C) glycine (D) KHSO4

(A) 0.8 (B) 1.1 (C) 1.9 (D) 2.4

(A) 47 (B) 48 (C) 46 (D) 45

(A) 11 (B) 33 (C) 54 (D) 44

(A) C6 H12 O6 . (B) K2 SO4 (C) KI (D) Al2 (SO4 )3

point depression constant of C6 H6 is 5.12 ◦ C/m. ) [JEE MAIN 2021]

(A) Al(N O3 )3 (B) K4 [F e(CN )6 ] (C) K2 SO4 (D) K3 [F e(CN )6 ]

following diagram is obtained.

(A) 50 (B) 12 (C) 67 (D) 89

(A) 1.21 (B) 1.76 (C) 1.17 (D) 0.98

(A) Water + Nitric acid (B) Ethanol + Water

(A) 1.770 (B) 0.0354 (C) 0.0177 (D) 0.177

(A) 71 (B) 73 (C) 74 (D) 75

mass of solute A is ..........g mol−1 .

[Given: Freezing point of ethanol is 156.0K Density of ethanol is 0.80] g cm−3 .

(A) 81 (B) 80 (C) 82 (D) 83

(A) 8 (B) 6 (C) 4 (D) 2

(A) 0.5 (B) 3 (C) 5 (D) 0.05

solution boils under a pressure of one atmosphere at ......... o C. [AIIMS 1991]

(A) 100.51 (B) 100.05 (C) 100.25 (D) 101.02

(A) C2 H4 O2 (B) C3 H6 O3 (C) C4 H8 O4 (D) C6 H12 O6

(A) 12.2 (B) 15.4 (C) 17.3 (D) 20.4

(A) Molarity (B) Molality (C) Formality (D) Normality

(A) 4.18 (B) 8.14 (C) 18.4 (D) 18

approx.1 ◦ C. (Kb )H2 O = 0.52 K. kg/mole [AIIMS 2019]

(A) 2 N (B) 4 N (C) N /2 (D) N /4

(131) Which of the following is a colligative property [AIIMS 1999]

(A) 5 × 10−5 (B) 5 × 10−3 (C) 5 × 10−1 (D) 5 × 10−2

solute is ....... g. (Kb for benzene = 2.53 k − m−1 )

(148) Azeotropic mixture of HCl and water has .......... % HCl

(149) Molarity is expressed as [AIPMT 1991]

Subject : Chemistry Paper Set : 1

Chemistry - Section A (MCQ)