XII-NEET : 2023-24 Don’t Solve this DPP

.... If you don’t

want to be perfect

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DPP- 04 : Solution
XIIth Batch Date : 09-03-2023
Solubility 07. Henry law constant for the solubility of methane
in benzene at 298K is 4.27 × 105 mm Hg then the
01. Set - I Set - II solubility of methane in benzene at 298K under
760mm Hg is
1) bends A) bubblesofN 2 in blood
blocks capillaries 1) 7.8  10–2 mole/kg

2) anoxia B) Low blood oxygen in 2) 7.8  10–3 mole/kg

climbers at higher altitudes 3) 7.8  10–4mole/kg
3) 11.7% He + 56.2% C) Scuba divers 4) 1.78  10–3 mole/kg
Incorrect match is 08. Which of the following graph is a correct
representation of Henry’s law?
1) (1)-(A) 2) (2)-(B)
1) 2)
3) (3)-(C) 4) (2)-(C)
02. If 0.05 mole of gas are dissolved in 500 grams of
water under 1 atm. pressure , 0.1 moles will be
dissolved if the pressure is 2atm. It illustrates
1) Graham’s Law 2) Dalton’s Law
3) 4)
3) Henry’s Law 4) Boyle’s Law
03. O2 is bubbled through water at 293K, assuming
that O2 exerts a partial pressure of 0.98 bar, the
solubility of O2 in gm.L–1 is
(Henry's law constant = 34 k bar)
1) 0.025 2) 0.5 09. Variation of K H (Henry’s law constant) with
temperature T is shown by following graphs
3) 0.1 4) 0.2
I–IV
04. H2S a toxic gas with rottenegg like smell is used
for the qualetative analysis, if the solubility of H2S I
in water, at STP is 0.195 mole. kg–1, the Henry's
law constant is
1) 285.6 bar 2) 324.8 bar
3) 462.9 bar 4) 534.8 bar
05. Air contains O2 and N2 in the ratio 0.2 : 0.8. If Henry
law constant for O2 and N2 are 3.3 × 107 torr and
6.6 × 107 torr respectively, then the ratio of mole
fractions of O2 to N2 dissolved in water at 1 bar Correct represetnation is
pressure is
1) IV 2) III
1) 1 : 1 2) 2 :1
3) I 4) II
3) 1 : 2 4) 1 : 3
06. The quantity of CO2 in 500ml of soda water when
packed under 2.5 atm CO 2 pressure at 298 k is
(Henry's law constant 1.67 x 108 pa at 298 k)
1) 0.64 gm 2) 1.86 gm
3) 6.4 gm 4) 18.6gm
1
10. Consider the two figure given below 14. Select the incorrect statement
1) Dissolution and crystallisation are opposite
processes

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2) When dissolution and crystallisation occur with
same rate, a saturated solution is obtained
3) When rate of dissolution is equal to rate of
Which of the following statement regarding the crystallisation, no more solute can be added to
experiment is true? it

1) The solublity of a gas in liquid in beaker (i) is 4) In satturated solution, the solution is in dyanmic
greater than that in beaker (ii) equilibrium with dissolved solute
15. Which of the following statements is not true ?
2) The solublity of a gas in beaker (i) is less than
that in beaker (ii) 1) Pressure is higher under water than at the surface
of a sea
3) The solublity of a gas is equal in both beakers
2) Low surface pressure is responsible for the
4) The solublity of a gas remains unaffected by formation of bends in the body of scuba divers
change in weights
3) Bends are actually the bubbles of nitroge in the
11. Arrange the following in order to decrease blood
solubility in H 2O. Phenol (i), toluene (ii),
4) Due to high pressure, solubility of atmospheric
chloroform (iii).
gases in the blood decreases
1) (i) > (ii) > (iii) 2) (iii) > (ii) > (i)
16. Select the incorrect statement out of the following:
3) (i) > (iii) > (ii) 4) (iii) > (i) > (ii) 1) Henry’s law is, p = KH
12. When a binary solution of two volatile liquiuds is 2) Different gases have different KH values at the
taken in a closed vessel, then same temperature
1) Both the components would evaporate and an 3) Higher the value of KH, lower is the solubility of
equilibrium would be established between the gas in a liquid at a given pressure
vapour phase and liquid phase 4) Increase in temperature increases the solubility
2) Both the ocmponents would evaporate but of gas
equilibrium would not be established between 17. Select the correct response for the following
vapour phase and liquid phase statements about a liquid solution.
3) None of components would evaporate and no I. A liquid solution may contain one or more
equilibrium would be established between volatile component.
vapour phase anad liquid phase II. In a liquid solution, the solvent is always
4) none of the above volatile
III. In a liquid solution, the solute may or may not
13. Which one of the following statements regarding
be volatile
Henry’s law is not correct ?
1) Only I is correct
1) Different gases have different KH(Henry’s law
constant) values at the same temperature 2) II and III both are correct
3) Only III is correct
2) Higher the value of KH at a given pressure, higher
is the solubility of the gas in the liquids 4) All of I, II and III are correct

3) The value of K H increases with increase of 18. Solubility of a substance is its maximum amount
temperature and KH is function of the nature of that can be dissolved in a specified amount of
the gas solvent. It depends upon
(i) nature of solute
4) The partial pressure of the gas in vapour phase
is proportional to the mole fraction of the gas in (ii) nature of solvent
the solution (iii) temperature
(iv) pressure
1) (i), (ii) and (iii) 2) (i), (iii) and (iv)
3) (i) and (iv) 4) (i), (ii), (iii) and (iv)
2
19. At equilibrium the rate of dissolution of a solid 24. In the graph given below, what does the slope of
solute in a volatile liquid solvent is _ the line represent?
1) less than the rate of crystallisation

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2) greater than the rate of crystallisation
3) equal to the rate of crystallisation
4) zero
20. In a nearly saturated solution, the solubility
1) Partial pressure of the gas in vapour phase (p)
increases with increase in temperature, then
H sol. is 2) Mole fraction of gas in the solution ()

1) +Ve 2) -Ve 3) Henry’s law constant (KH)

4) All of the above
3) +Ve (or) - Ve 4) 0
25. Which of the following statements is true about
21. Incorrect statement is ( KH = Henry’s constant) henry’s law?
1) K H is c haracteristic c onstant for a given 1) The solubility of solid in a liquid is directly
gas - solvent system proportional to the partial pressure of the solid
present above the surface of liquid or solution
2) Higher is the value of KH , Lower is solubility of
gas for a given partial pressure of gas 2) The solubility of a gas in liquid is directly
proportional to the partial pressure of the gas
3) KH has temperature dependence present above the surface of liquid or solution
4) KH decreases with temperature 3) The solubility of a liquid in gas is directly
proportional to the partial pressure of liquid
22. Which of the following statement is correct about
present above the surface of gas
Henry’s law
4) The solubility of a gas in solid is directly
1) It is applicable only when pressure is high proportional to the pressure of gas present above
the surface of solid
2) It is applicable only when temperature is very
high 26. The solubility of gas in liquid depends upon:

3) It is applicable only when gas reacts with the 1) nature of gas

solvent 2) nature of solvent
4) KH (Henry’s constant) is a function of the nature 3) temperature & pressure
of the gas 4) all of the above
23. KH value for Ar(g), CO2(g), HCHO (g) and CH4 (g)
are 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively.
Arrange these gases in the order of their increasing
solubility.
1) HCHO < CH4 < CO2 < Ar
2) HCHO < CO2 < CH4 < Ar
3) Ar < CO2 < CH4 < HCHO
4) Ar < CH4 < CO2 < HCHO
Answer Key
1. 4 7. 4 13. 2 19. 3 25. 2
2. 3 8. 3 14. 4 20. 1 26. 4
3. 2 9. 3 15. 2 21. 4
4. 1 10. 2 16. 4 22. 4
5. 3 11. 3 17. 4 23. 3
6. 2 12. 1 18. 4 24. 3