NEET/JEE : 2020-21 Don’t Solve this DPP

.... If you don’t

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DPP - 10 want to be perfect

Structure of Atom
XIth Regular : Date :- 31/08/2020
Quantum Mechanical Model of 10. The number of radial nodes for 5p orbital.
Atom/Shape of orbitals 1) 2 2) 3 3) 4 4) 5

01. The number of nodal planes in px–orbital is : 11. An example for non directional orbital is

1) one 2) two 3) three 4) zero 1) 2s 2) 2p 3) 3d 4) 3f

02. The number of radial nodes in 3s and 2p orbitals 12. Which one of the following conditions is incorrect
are respectively : for a well behaved wave function ()

1) 2,0 2) 0, 2 3) 1, 2 4) 2, 1 1) must be finite

03. The number of nodal planes in a px orbital is : 2)  must be single valued

1) 1 2) 2 3) 3 4) 0 3)  must be infinite

04. The number of radial nodes, nodal planes for an 4)  must be continuous
orbital with n = 4 ; l = 1 is 13. (psi) the wave function represents the probability
1) 3, 1 2) 2, 1 of finding electron. Its value depends

3) 2, 0 4) 4, 0 1) Inside the nucleus

05. Consider the following statements : 2) Far from the nucleus

3) Near the nucleus
1) Electron density in XY plane in 3d 2 2
orbital
x y 4) Upon the type of orbital
is zero 14. In the Schrodinger wave equation  represents

2) Electron density in XY plane in 3d z2 orbital is 1) Orbitals 2) Wave function

zero 3) Amplitude function 4) Both 2 & 3

3) 2s orbital has only one spherical node 15. The electron density of 3dxy orbital in YZ plane is

4) For 2pz orbital YZ is the nodal plane 1) 50 % 2) 95 %

The correct statements are : 3) 33.33 % 4) Zero

1) 2 and 3 2) 1, 2, 3, 4 16. In an orbital, the signs of lobes indicate the

3) Only 2 4) 1 & 3 1) Sign of the wave function

06. The maximum probability of finding electron in the 2) Sign of the probability distribution
dxy orbital is 3) Presence or absence or electron
1) Along with x - axis 4) Sign of charge
2) Along the y - axis 17. The quantum no. not obtained from Schrodinger’s
3) At an angle of 450 from the X and Y axis wave equation is

4) At an angle of 900 from the x and y axis 1) n 2) l 3) m 4) s

07. Which one of the following orbitals has the shape 18. Which one of the following expressions
of a baby-boother ? represent the electron probability function (D)
1) 4r dr 2 2) 4r2 dr 
1) dxy 2) d x 2  y 2 3) d z 2 4) Py
3) 4r2 dr 2 4) 4r dr 
08. The number of nodes for 4f orbital is 19. The probability of finding an electron in an orbital
1) 0 2) 1 3) 2 4) 3 is approximately?
09. The number of nodal planes in each p–orbital 1) 95% 2) 50%
1) zero 2) one 3) two 4) three 3) 60% 4) 25%

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1

20. Which one of the following atomic orbitals is not 29. Which of the following statements is not correct?
directed along the axis?
1) The wave function depicting the dependence on

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1) Px 2) d x 2  y 2 3) dxy 4) d z 2 r involves two quantum numbers n and l.

21. The number of angular and radial nodes of 4d orbital 2) The wave function depicting the angular
respectively are (EAM-2014) dependence involves two quantum numbers l and
m.
1) 3, 1 2) 1, 2
3) The spin quantum number is not the outcome
3) 3, 0 4) 2, 1 of the Schrodinger equation.
22. The number of radial nodes of 3s and 2p orbitals 4) The lowest energy state of an atom corresponds
respectively are to n = 0
1) 0, 2 2) 2, 0 30. In a main energy level, the orbital with more number
3) 1, 2 4) 2, 1 of nodal planes will be ......
23. The basis of quantum mechanical model of an atom 1) Higher energy 2) Lower energy
is 3) Either 1 or 2 4) Neither 1 nor 2
1) Angular momentum of electron 31. Choose the correct statement among the following:
2) Qantum numbers 1) represents the atomic orbital
3) Dual nature of electron 2) The number of peaks in radial distribution is n-1
4) Black body radiation 3) A node is a point in space around nucleus where
24. In the plots of radial distribution function for the the wave function  has zero value
hydrogen 3s orbital versus ‘r’, the no. of peaks are 4) All of the these
1) 3 2) 2 3) 1 4) 0 32. Which of the following statements regarding an
25. Which of the following statements is correct? orbital are correct
1) An orbital describes the path of an electron in 1) An orbital is a definite trajectory around the
an atom nucleus in which electron can move
2) An orbital is a region where the electron is not 2) An orbital always has spherical trajectory
located 3) An orbital is the region around the nucleus
3) An orbital is a func tion whic h gives the where there is a 90 – 95% probability of finding
pr obab ilit ies of find ing the elec tron in a all the electrons of an atom
given region 4) An orbital is c harac terized by 3 quantum
4) All the above numbers n, l and m
26. For an electron in a hydrogen atom, the wave 33. Which of the following statements on the atomic
function  is proportional to exp, where a0 is the wave function  is not correct?
Bohr’s radius. What is the ratio of the probability 1) may be a real valued wave function
of finding the electron at the nucleus to the 2) may be in some cases be a complex function
probability of finding it at a0 ?
3) has a mathematical significance only
1) e 2) e 2
4)  is proportional to the probability of finding
3) 1/e2 4) zero an electron
27. The electron density between 1s and 2s is 34. The probability density plots of 1s and 2s orbitals
1) High 2) Low are given in figure
3) Zero 4) Abnormal
28. Wh ich of the followin g statement(s) is/are
correct about angular nodes
1) They are independent from the radial wave 1s 2s
function
2) They are directional in nature The density of dots in region represents the
probability density of finding electrons in the
3) The number of angular nodes of orbital is equal region.On the basis of above diagram which of the
to azimuthal quantum number. following statements is incorrect?
4) All are correct
Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2
 1) 1s and 2s orbitals are spherical in shape 42. Which of the following set (s) of orbitals has (have)
equal orbital angular momentum ?
2) The probability of finding the electron is
1) 1s and 2p 2) 2s and 2p

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maximum near the nucleus.
3) 3d and 4d 4) 1s and 2s
3) The probability of finding the electron at a given
43. What are the values of the orbital angular
distance is equal in all directions.
momentum of an electron in the orbitals 1s, 3s, 3d
4) The probability density of electrons for 2s and 2p ?
orbitals decreases uniformly as distance from
the nucleus increases. 1) 0, 0, 6 h, 2 h 2) 1, 1, 4 h, 2 h

Quantum Numbers 3) 0, 1, 6 h, 3 h 4) 0, 0, 20 h, 6 h
35. Which set of quantum numbers is possible for the 44. How many electrons can fit into the orbitals that
last electron of Mg+ ion. comprise the 3rd quantum shell
1 n = 3?
1) n = 3, l = 2, m = 0, s = +
2 1) 2 2) 8 3) 18 d) 32
1 45. The total number of electrons present in all the s
2) n = 2, l = 3, m = 0, s = +
2 orbitals, all the P orbitals and all the d orbitals of
cesium ion are respectively.
1
3) n = 1, l = 0, m = 0, s = + 1) 6, 26, 10 2) 10,24,20
2
3) 8, 22, 24 4) 12, 20, 23
1 46. The correct set of quantum numbers for the
4) n = 3, l = 0, m = 0, s = +
2 unpaired electron of Chlorine atom
36. The quantum number for the last electron in an atom 1) 2,0,0,+1/2 2) 2,1,-1,+1/2
are n = 3, 1 = 1 and m = – 1. The atom is
3) 3,0,0,+1/2 4) 3,1,-1,  1/2
1) Al 2) Si 3) Mg 4) C
37. Which set of quantum numbers represent the 47. Given K L M N
electron of the lowest energy 2 8 11 2
1) n = 2, l = 0, m = 0, s = – 1/2 The number of electrons present in l = 2 is
2) n = 2, l = 1, m = 0, s = + 1/2
1) 3 2) 6
3) n = 4, l = 0, m = 0, s = + 1/2
3) 5 4) 4
4) n = 4, l = 0, m = 0, s = – 1/2
48. During ionisation of copper atom, the quantum
38. Correct set of four quantum numbers for valency numbers of electron removed maybe
(outermost) electron of rubidium (Z=37) is
1) 5, 0, 0, + 1/2 2) 5, 1, 0, + 1/2 1
1) n  4 l  1 s
3) 5, 1, 1, + 1/2 4) 6, 0, 0, + 1/2 2
39. How many electrons can fit into the orbitals that
comprise the 3rd quantum shell ?
1
2) n  3 l  0 s
1) 2 2) 8 3) 18 4) 32 2
40. The quantum levels up to n = 3 has 1
1) s and p electrons 2) s, p, d, f electrons 3) n  4 l  0 s
2
3) s, p, d electrons 4) s – electrons
41. Which set of quantum number is not consistent
1
4) n  4 l  2 s
with the theory 2
1 49. Th e az imu th al q u an tu m n u m b e r a n d t h e
1) n = 2, l = 1, m = 0, s = – principal quantum number of the 17th electron
2
are
1 1) l = 1, n = 3 2) l = 3, n = 2
2) n = 4, l = 3, m = 2, s = –
2 3) l = 1, n = 17 4) l = 2, n = 1
1 50. The maximum number of sub levels,orbitals and
3) n = 3, l = 2, m = 3, s = + electrons in N shell of an atom are respectively
2
1) 4, 12, 32 2) 4, 16, 30
1
4) n = 4, l = 3, m = 3, s = + 3) 4, 16, 32 4) 4, 32, 64
2
Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 3