NEET/JEE : 2020-21 Don’t Solve this DPP

.... If you don’t

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DPP - 11 want to be perfect

Structure of Atom
XIth Regular : Date :- 02/09/2020
01. If n +1 value of an orbital is 5 it shape may be 11. The number of p–orbitals possible for L shell is
1) spherical 2) dumb-bell 1) 2 2) 1
3) double dumb-bell 4) any one of these 3) 4 4) 3
02. The electron density between 1s and 2s orbital is 12. All electrons in a 'd' sub shell should have the
1) High 2) Low quantum number
3) Zero 4) None of these 1) n = 3 2) I = 0
03. A filled or half filled set of p - or d - orbitals is 1
spherically symmetrical. Point out the species which 3) m = – 1 4) s = +
2
have spherical symmetry :
13. Quantum number accounts for the rotation of the
1) Na 2) C 3) Cl– 4) Fe
electron around its own axis
04. For the dumb-bell shaped orbital the value of l is
1) spin 2) magnetic
1) 3 2) 1 3) 0 4) 2
3) principal 4) azimuthal
05. The sum of the all four quantum number values of
14. In the 4th quantum level the number of electronic
the last electron in Boron is
subshells are
5 3 1) n 2) 2n 3) 2n 2 4) n + 1
1) 3 2) 3) 2 4)
2 2
15. If the quantum number n has the value 3 then
06. An orbital may never be occupied by
1) there are three possible values of m
1) 1 electron 2) 2 electron
2) the value of m must be zerob
3) 3 electron 4) 0 electron
3) l cannot be larger then +2
07. The quantum numbers of most energetic electron
4) m cannot be larger than –1
in Ne atom when it is in first excited state
16. The number of orbitals in the fourth main energy
1 1
1) 2, 1, 0, + 2) 3, 1, 1 + level of an atom is
2 2
1) 4 2) 32 3) 16 4) 8
1 1
3) 3, 0, 0, + 4) 3, 1, 0, + 17. The values of the second quantum number 1 for the
2 2
fourth main energy level of an atom are
08. The quantum number for the last electron of an atom
1) 4, 3, 2, 1 2) 4, 3, 2, 1, 0
1
are n = 2, l = 0, m = 0 and s = + The atom is 3) 0, 1, 2, 3 4) +3 to –3
2
1) Lithium 2) Boron 1
18. A 3d electron having s = + can have magnetic
3) Carbon 4) Hydrogen 2
09. Two electrons in the same orbital may be identified quantum nos
with 1) +2 2) +3 3) –3 4) +4
1) n 2) l 3) m 4) s 19. An electron has principal quantum number 3. The
number of its (i) subshells and (ii) orbitals would
10. Beryllium's fourth electron will have the four
be respectively
quantum numbers
1) 3 and 5 2) 3 and 7
n l m s
3) 3 and 9 4) 2 and 5
1) 1 0 0 + 1/2
20. Total number of orbitals in a shell with principal
2) 1 1 1 + 1/2
quantum number 'n' is
3) 2 0 0 + 1/2
1) 2n 2) 2n2 3) n 2 4) n + 1
4) 2 1 0 + 1/2
Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1
21. The quantum number sufficient to describe the 34. The maximum number of atomic orbitals associated
electron in hydrogen atom is with a principal quantum number 5 is
1) n 2) 1 3) m 4) s

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1) 9 2) 12 3) 16 4) 25
22. When the value of azimuthal quantum number is 3 35. The orbital with maximum number of possible
magnetic quantum number can have values orientations is
1) +1, –1 2) +3, +2, +1, 0, –1, –2, –3 1) s 2) p 3) d 4) f
3) +2, +1, 0, –1, –2 4) +1, 0, –1 36. The total values of magnetic quantum number of
23. Which set is not correct ? an electron when the value of
n = 2 is
1 1
1) 3, 1, 0, – 2) 3, 2, 1, + 1) 9 2) 6 3) 4 4) 2
2 2
37. In order to designate an orbital in an atom the number of
1 1 quantum numbers required are
3) 3, 1, 2 – 4) 3, 2, 0, +
2 2 1) 1 2) 2 3) 3 4) 4
24. Each p–orbital and d–orbital except one has lobes 38. Quantum number which specifies the size of the
respectively as atomic orbital and also the energy of the electron
1) 2, 4 2) 1, 4 3) 2, 3 4) 1, 1 1) Principal Quantum number
25. The quantum number that is no way related to other 2) Azimuthal Quantum number
quantum number is 3) Magnetic Quantum number
1) l 2) s 3) n 4) m 4) Spin Quantum number
26. The quantum number that does not describe the 39. Which set of quantum number represents
distance and the angular disposition of the electron permissible values
1) n 2) l 3) m 4) s
1
27. s orbital has ......... lobes 1) n = 3, l = 1, m = 1, s =
2
1) One 2) Two 3) Zero 4) Three 2) n = 3, l = 1, m = 4, s = + 1
28. The correct designation of an electron with 1
1 3) n = 3, l = 2, m = 4, s = +
n = 4, l = 3, m = 2 and s = is 2
2
1
1) 3d 2) 4f 3) 5p 4) 6s 4) n = 3, l = – 1, m = – 1, s = –
2
29. Which is correct in case of p–orbitals ?
40. Three electrons in p–sublevel must have the
1) They are spherical
quantum number
2) They have strong directional character
1) n = 2 2) m = 0
3) They are five fold degenerate
1 1
4) They have no directional character 3) l = 0 4) s = – or +
2 2
30. An electron in an atom can be identified by 41. In the absence of magnetic field p–orbitals are
1) its spin 2) charge known as ...... fold degenerate.
3) the path in which it is spinning 1) Three 2) Two 3) One 4) Four
4) four quantum numbers 42. Which of the subshell has doubled dumbell shape?
31. How many electrons can be accommodated in 1) s 2) p 3) d 4) f
subshell for which n = 3, l = 1 43. For a given value of azimuthal quantum number l,
1) 8 2) 6 3) 18 4) 32 the total number of values for the magnetic quantum
32. For d–electrons the value of azimuthal quantum number m are given by
number is 1) l + 1 2) 2l + 1 3) 2l – 1 4) l + 2
1) zero 2) 1 3) 2 d) 3 44. When the value of azimuthal quantum number is l,
33. The energy level quantum number n = 3, the number magnetic quantum number can have values
of possible orbitals are 1) – 1 only 2) +1 only
1) 1 2) 9 3) 3 4) 4 3) +1, 0, –1 4) +1, and –1

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2

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1
1) 4, 3, 2, + 2) 4, 2, 1, 0
2
1 1
3) 4, 3, –2, + 4) 4, 2, 1, +
2 2
46. The set of quantum numbers not applicable for an
electron in an atom is :
1
1) n = 1, l = 1, m1 = 1, m5 = +
2
1
2) n = 1, l = 0, m1 = 0, m5 = +
2
1
3) n = 1, l = 0, m1 = 0, m5 = –
2
1
4) n = 2, l = 0, m1 = 0, m5 = +
2
47. The orbital angular momentum of an electron in 2s
orbital is :
1 h
1) + . 2) Zero
2 2

h h
3) 4) 2 . 2
2
48. The electronic configuration of an element is 1s2 2s2
2p6 3s2 3p6 3d5 4s1. This represents its
1) excited state 2) ground state
3) cationic from 4) anionic form
49. A p-orbital can accommodate :
1) 4 electrons
2) 6 electrons
3) 2 electrons with parallel spins
4) 2 electrons with opposite spins

1 1
50. The quantum numbers + and – for the electron
2 2
spin represent :
1) Rotation of the electron in cloc kwise and
anticlockwise direction respectively
2) Rotation of the electron in anticlockwise and
clockwise direction respectively
3) Magnetic moment of the electron pointing up
and down respectively
4) Two quantum mechanical spin which have no
classical analogue.

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 3