NEET/JEE : 2020-21

Don’t Solve this DPP

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DPP - 9 .... If you don’t

want to be perfect
Structure of Atoms
XI Regular : Date :- 28-08-2020
01. The orbital angular momentum of a p-electron 09. If n = 6, the correct sequence for filling of
is given as electrons will be
1) ns  (n – 2) f  (n – 1) d  np
h h 3h h
1) 2) 3 3) 4) 6 2) ns  (n – 1) d  (n – 2) f  np
2 2 2 2
3) ns  (n – 2) f  np  (n – 1)d
02. Out of the following electronic arrangements for
4) ns  np (n – 1) d  (n – 2)f
outer electronic configurations
10. Which of the following set of quantum numbers
represents the 19th electron in chromium ? (Z =
24 for Cr)
1 1
1) 4, 0, 0, 2) 4, 1, –1,
2 2
1 1
the most stable arrangement is 3) 3, 2, 2, 4) 3, 2, –2,
2 2
1) (i) 2) (ii) 3) (iii) 4) (iv)
11. The electrons identified by quantum numbers
03. Maximum number of electrons in a shell with
n and l :
principle quantum number n is given by
(1) n = 4, l = 1 (2) n = 4, l = 0
1) n 2) 2n 3) n2 4) 2n2
(3) n = 3, l = 2 (4) n = 3, l = 1
04. Which set of quantum numbers are not
can be placed in order of increasing energy as
possible?
1) (4) < (2) < (3) < (1) (2) (2) < (4) < (1) < (3)
n l m s
3) (1) < (3) < (2) < (4) (4) (3) < (4) < (2) < (1)
1) 3 2 0 +1/2
12. Which one of the following sets of quantum
2) 2 2 1 +1/2
numbers represents the highest energy level in
3) 1 0 0 –1/2
4) 3 2 –2 +1/2 an atom ?
05. The correct set of four quantum numbers for 1
1) n = 4, l = 0, m = 0, s = 
the outermost electron of sodium (Z = 11) is 2
1 1
1) 3, 1, 0, 2) 3, 1, 1, 1
2 2 2) n = 3, l = 1, m = 1, s = 
2
1 1
3) 3, 2, 1, 4) 3, 0, 0,
2 2 1
3) n = 3, l = 2, m = –2, s = 
06. Impossible orbital among the following is 2
1) 2s 2) 3f 3) 2p 4) 4d
1
07. Which law represents the pairing of electron in 4) n = 3, l = 0, m = 0, s = 
2
a sub-shell after each orbital is filled with one
13. In a given atom no two electrons can have the
electron ?
same values for all the four quantum numbers.
1) Pauli’s exclusion principle
2) Hund’s rule This is called
3) Heisenberg’s principle 1) Hund’s rule
4) Hess’s law 2) Aufbau principle
08. The total number of atomic orbitals in fourth 3) Uncertainty principle
4) Pauli’s exclusion principle
energy level of an atom is
1) 8 2) 16 3) 32 4) 4
Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1
14. Which one of the following decides the shapes 23. Which of the following orbitals will have zero
of orbitals in an energy shell ? probability of finding the electron in the yz plane?

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1) Magnetic quantum number 1) px 2) py 3) pz 4) dyz
2) Principal quantum number 24. Maximum number of electrons in a subshell of
3) Azimuthal quantum number an atom is determined by the following
4) Spin quantum number 1) 2l + 1 2) 4l – 2 3) 2n2 4) 4l + 2
15. The representation of the ground state electronic 25. Which of the following is not permissible
configuration of He by box-diagram as is arrangement of electrons in an atom ?
wrong because it violates 1) n = 5, l = 3, m = 0, s = +1/2
2) n = 3, l = 2, m = –3, s = –1/2
1) Heisenberg’s uncertainty principle
3) n = 3, l = 2, m = –2, s = –1/2
2) Bohr’s quantization theory of angular momenta
4) n = 4, l = 0, m = 0, s = –1/2
3) Pauli’s exclusion principle
4) Hund’s rule 26. For principal quantum number n = 4, the total
16. In the ground state of Cu+, the number of shells number of orbital having l = 3 is
occupied, subshells occupied, filled orbitals and 1) 3 2) 7 3) 5 4) 9

unpaired electrons respectively are 27. The five d-orbitals are designated as dxy, dyz ,
1) 4, 8, 15, 0 2) 3, 6, 15, 1 dxz, dx2–y2 and dz2. Choose the correct statement.
3) 3, 6, 14, 0 4) 4, 7, 14, 2 1) The shapes of the first three orbitals are similar
17. For 2s orbital, the nodal surfaces exists at a but that of the fourth and fifth orbitals are different
2) The shapes of all five d-orbitals are similar
distance of
3) The shapes of the first four orbitals are similar but
1) a0 from the nucleus 2) 1.5 a0 from the nucleus
that of the fifth orbital is different
3) 2a0 from the nucleus 4) None of these is correct
4) The shapes of all five d-orbitals are different
18. Out of the following which is the correct set of
28. Probability of finding an electron at the nodal
quantum numbers for outermost electron of
surface is
potassium (Z = 19) ?
1) Unity 2) Low 3) High 4) Zero
n l m s
29. How many orbitals are associated with principal
1) 4 3 2 –1/2
quantum number n = 4 ?
2) 4 2 0 –1/2
1) 4 2) 16 3) 32 4) None of these
3) 4 1 0 +1/2
4) 4 0 0 –1/2 30. The set of quantum numbers n = 4, l = 0, m = 0
1
19. The set of quantum numbers for the outermost and s = + correspond to the most loosely
2
electron for copper in its ground state is
bound, ground state electron of which one of
1) 4, 1, 1, +1/2 2) 3, 2, 2, +1/2
the following atoms ?
3) 4, 0, 0, +1/2 4) 4, 2, 2, +1/2
1) Na 2) Cl 3) Cr 4) Rb
20. For n = 2 the correct set of azimuthal and
31. Orientation of orbital is shown by which
magnetic quantum numbers are
quantum number ?
1) l = 2; m = –2, –1, 0, +1, +2
1) n 2) l 3) m 4) s
2) l = 1; m = –2, –1, 0, +1, +2
32. The probability of finding an electron residing
3) l = 0; m = –1, 0, +1
in a px orbital is zero
4) l = 1; m = –1, 0, +1
1) in the yz plane 2) in the xy plane
21. Ground state configuration of Cr atom is
3) in the y-direction 4) in the z-direction
1) [Ar]3d44s2 2) [Ar]3d54s1
3) [Ar]3d64s0 4) [Ar]3d54s2
33. Electron density in the yz plane of 3dx2–y2 orbital
22. An electron will have the highest energy in the is
1) Zero 2) 0.50 3) 0.75 4) 0.90
set
1) 3, 2, 1, 1/2 2) 4, 2, –1, 1/2
34. When the azimuthal quantum number has the
3) 4, 1, 0, –1/2 4) 5, 0, 0, 1/2 value of 2, the number of orbitals possible are
1) 3 2) 0 3) 7 4) 5
Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2