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 Read the passage quvenbelow answer the that follow
0) Is Silverplate the anode ot cathode:
(Il)What Will happen If the salt IS "
(Ill)When does electro chenucal ( ell behaves like elec t' olytlUcell
Ov)WhatWillhappen to the ( one entratton of and Aq when Ecell 0
(v) Why does conductivity ot a solution With dilution
(VI) The molar conductivity of a M solution of an electrolyte IS found to be 38 9 S cm• mol-I Calculate the
conductivity of this solution
YEAR 2020
1 Kohlrausch given the followtnq relation for strong electiolytes

Which of the followtnq equality holds?

(b) A - m as C
(C)A = as C (d) A = as C
2 In an electrochemical process, a salt bridge ts used
as a reductng agent
as an oxidizing agent
to complete the ctrcutt so that current can flow
None of these
3. Assertion (A): Conductivity of an electrolyte Increases Withdecrease cnconcentration
Reason (R) : Number of tons per unit volume decreases on dilution.
4 When a steady current of 2A was passed through two electrolytic cells A and B contacntng electrolytes ZnSOaand CuS04
connected cn series, 2g of Cu were deposited at the cathode of cell B,
(a)How long did the current flow?
(b) What mass of Zn was deposited at cathode of cell A? [Atomtcmass:Cu = 63.5 g mol¯l Zn = 65 g mol¯l• IF = 96500
C mol¯ll
5. Name the cell used In heartng aids and watches.
6. How much charge tn terms of Faraday ts required to reduce one mol of MnO to Mn2 +?
YEAR 2019
+
l. EOcell for the given redox reaction IS 271 V Mg(s) + Cu 2 (001 M) Mg2 +(0 001 M) + CUI(s)
Calculate Ecell for the reaction. Write the direction of flow of current when an external opposite potential applied IS
less than 2.71 V and
(11) greater than 2 71 V
2. (a) A steady current of 2 amperes was passed through two electrolytic cells X and Y connected tn senes containcng
electrolytes FeS04 and ZnS04 until 2.8 g of Fe deposited at the cathode of cell X. How long did thecurrent flow? Calculate
the mass of Zn deposited at the cathode of cell Y. (Molar mass : Fe = 56 g mol¯l Zn = 65.3 g mol¯l , IF = 96500 C mol¯l )
2
(b) In the plot of molar conductivity (Am) vs square root of concentration (c I / ), following curves are obtained for two
electrolytes A and B

Answer the following•

Predict the nature of electrolytes A and b.
What happens on extrapolation of Am to concentration approaching zero for electrolytes A and B?
YEAR 2018
1 . (a) Write the cell reaction and calculate the e.m.f of the following cell at 298 K: Sn2+(0 004 M)IIH+ (0.020
bar) Pt (s)
(Given EOSn2+/Sn= —0.14 V)
(b)Gtve reasons:
0) On the basis of EOvalues, 02 gas should be liberated at anode but it is C12gas which IS liberated in theelectrolysis of
aqueous NaCl.
(u) Conductivity of CH3COOH decreases on dilution.
2. (a) For the reaction. 2AgCl (s)+H2(9)(latm)—• 2 Ag (s)+2H+ (0. 1 M) +2 Cl- (0. 1 M), AG O = -43600 J at 25 0C
Calculate the e.mf of the cell. [log 10¯n _=
(b) Define fuel cell and write its two advantages.
YEAR 2017
1.Calculate the degree of dissociation (a) of acetic acid If it's molar conductivity (Am) IS 39 05 S cm2 mol -l Gwen, XO(H +) =
349.8 S cm2 mol¯l and = 40.9 S cm mol¯l
2. Calculate the mass of Ag deposited at cathode when a current of 2 amperes was passed through a soluttonof AgNOi
for 15 minutes.
(Given : Molar mass of Ag = 108 g mol ¯l IF 96500 C mol -I )
 .(a) Define fuel cell
(b) Write the name of the cell which ts generally used in transistors. Wnte the reactions
cathode of this cell,
4. The cell in which the followtng reaction occurs 2 + 21
has EOcell 0236 V at 298 K. Calculate the standard Gibbs energy of the cell reactton,(Gtven : 1 F C
5.How many electrons flow through a metllic wire if a current of A is passed for 2 hours> (Guen 1 C •ci.¯
YEAR 2016
1. From the given cells: Lead storagece/l Mercury cell, Fuel cellpod Dry cell Answer the folLc;mng'
(i) Which cell (s used in hearing aids?
(ii) Which cell was used in Apollo Space Programme?
(iii) Which cell (s used in automobiles and inverters?
(w) Which cell does not have long life?
2. Calculate e.m.fof the following cell at 298 K: 2Cr(s) + 3Fe2 + (0.1M)-Y 2Cr3 + (OOIM) + 3 Fe's)
Given: EO(Cr 3 +/Cr) = -- 0.74 V (Fe2+/Fe) = 0.44 V
3. (a) Calculate EOcellfor the following reaction at 298 K: 2Al(s) + 3Cu2+ (0.01 M) 2A13+ (0.01M) + 3Cufs;
Given: Ecell = 1.98V
(b) Using the EOvalues of A and B, predict which is better for coating the surface of iron [EO(FeZ+/Fe) =
corrosion and why?
Given: EO(A 2 +/A) = -2.37V : (B2 +/B) = -0.14V
4. The conductivity of 0.001 mol solution of CH3COOH is 3.905 x 10¯5 S cm¯l . Calculate its mol-arconducüi•y rd
degree of dissociation (a). [Given (H+) = 349.6S cm mol¯l and (CH3COO¯) = 40.9 S crn2 moc¯ll
5. Define electrochemical cell. What happens if external potential applied becomes greater than E'ceU
cell?
YEAR 2015
1. How much charge is required for the reduction of 1 mol of Zn 2+ to Zn?
Calculate e.m.f. and AG for the following cell: Mg (s) mg 2+(O.001 M) // Cu2+(O.0001 M)/Cu(s)
Given Mg2+/Mg= -2.37v. EOCu2+/Cu = +0.34 v)
2. The conductivity of 0.20 mol solution of KCI is 2.48 x 10¯2 S cm ¯l . Calculate its molar conductivity and degree
dissociation (a). [Given (K+ ) = 73.5 S cm mol¯l and XO (Cl = 76.5 S crn2 mol¯l J
3. What type of battery is mercury cell? Why is it more advantageous than dry cell?
4. Following reactions occur at cathode during the electrolysis of aqueous copper(ll) chloride solution :
Cu 2+ (aq) + 2e — Cu (s) o. 34 v

5. On the basis of their standard reduction electrode potential (EO)values, which reaction is feasible at thecathcde and
? State Kohlrausch law of independent migration of [ons. Write its one application.
6. Calculate the emf of the following cell at 250C: zn I zn2+ (0.001 M) Il H+ (0.01 M) I H2(g) (1 bar) 1Pt(s)
[ EOZn 2+/Zn = -O. 76 V, EO(H+/H2) = O.00 V]
7. Define limiting molar conductivity. Why conductivity of an electrolyte solution decreases with the decrease
concentration ?
Calculate emf of the following cell at 25 oc :Fe /Fe 2+ (O. 001 M) // H + (O. 01 M)/H2 (g) /(1 bar)Pt(s)
EO(Fe2+/Fe) = —0.44 v EO(H + H2 ) = 0.00 v]
YEAR 2014
1. Define the following terms:
(a)Molar conductivity (Am)
(b)Secondary batteries
2. CalculateArG0 for the given reaction: Mg (s) + Cu 2 + (aq.) Mg2 + (aq.) + Cu (s)
[Given : EOcetl = +271 V, 1 F = 96500 cmol -l l
3. Name the type of cell which was used in Apollo space program for providing electrical power
4. Resistance of a conductivity cell filled with 0.1 mol L -l KCI solution is 100 Q. If the resistance of the samecell •hen
with 0.02 M KCI solution is 520 Q, calculate the conductivity and molar conductivity of 0.02 M KCI solution The conductmt••,
1
of 0.1 M KCI solution is 1.29 x 10¯2 Scm¯
5. State Faraday's first law of electrolysis, How much charge in terms of Faraday is required for the reduct•nof rnoQof
cu 2+ to cu.
Calculateemf of the following cell at 298 K:Mg(s) I Mg2+(O.1 M) Il Cu2+ (0.01) | Cu(s) (Gven EOce11 = .27' Vt F
96500 C mol-I )
6. Define the following terms .
(a) Limiting molar conductivity (b) Fuel cell
7. State Faraday's first law of electrolysis. How much charge in terms of Faraday is required for the reductionof mol of
Cu 2+ to Cu.
8. Why does the conductivity of a solution decrease withdilution?