selfstudys_com_file (1866)
selfstudys_com_file (1866)
Chemistry
Time Allowed: 2 hours Maximum Marks: 80
General Instructions:
The time given at the head of this Paper is the time allowed for writing the answers.
The intended marks for questions or parts of questions are given in brackets [ ].
Section A
1. Question 1 Choose one correct answer to the questions from the given options: [15]
(a) Ionisation potential increases over a period from left to right because the ________. [1]
a) Atomic radius increases and nuclear b) Atomic radius decreases and nuclear
charge increases charge decreases
c) Atomic radius increases and nuclear d) Atomic radius decreases and nuclear
charge decreases charge increases
(b) An element with the atomic number 19 will most likely combine chemically with the element whose [1]
atomic number is
a) 17 b) 11
c) 18 d) 20
(c) The property which is characteristic of an electrovalent compound is that [1]
c) CO(OH)2 d) Cu(OH)2
a) C2H15 b) C4H12
c) C2H5 d) C3H8
(h) The vapour density of a gas A is four times that of B. If molecular mass of B is M, then molecular [1]
mass of A is
a) 4M b) 2M
c) M d) M
(i) A simple cell is set up with magnesium and copper as the electrodes and dilute sulphuric acid as the [1]
electrolyte. Which of the following will not occur?
a) The electrons will flow from the b) A gas will be given off at the
magnesium electrode to the copper magnesium electrode
electrode
c) The bulb will light up d) A gas will be given off at the copper
electrode
(j) An ore after levigation is found to have basic impurities. Which of the following can be used as flux [1]
during smelting?
a) H2SO4 b) CaCO3
(k) When dilute sulphuric acid reacts with iron, sulphide, the gas evolved is: [1]
a) AgNO3 b) NH3
c) H2SO4 d) MnO2
a) Wohler b) Haber
c) Berzelius d) Lavoisier
(o) The property of carbon to form chains and rings is called: [1]
a) Cracking b) Catenation
c) Hydrogenation d) Polymerization
2. Question 2 [25]
(a) Reaction: [5]
a. Name the catalyst which helps in the conversion of sulphur dioxide to sulphur trioxide in step C.
b. In the contact process for manufacture of the sulphuric acid, sulphur trioxide is not converted to
sulphuric by reacting it with water, instead two steps procedure is used. Write equation for the two
steps involved.
c. What type of substance will liberate dioxide from sodium sulphite?
d. Write the equation for the reaction, where sulphur dioxide is converted sodium sulphite in step F.
e. Name the process used in A.
f. What is the reaction involved in B?
(b) Match the salts given in Column I with their method of preparation given in Column II: [5]
Column I Column II
(c) Complete the following by choosing the correct answers from the bracket:
i. Metals are good ________ (oxidizing agents/reducing agents) because they are electron [1]
________ (acceptors/donors).
ii. The basicity of acetic acid is ________. (3, 1, 4) [1]
iii. A formula which shows the simplest whole number ratio is ________. [1]
iv. ________ the concentration of an ion in a solution, the greater is the probability of its being [1]
discharged at its appropriate electrode.
v. Nitric acid is a strong ________ agent therefore it does not liberate hydrogen on reaction with [1]
metals.
(d) Identify the following:
O [1]
||
weight of X is 10 and that of Y is 5 and the compound has a vapour density 25, find the
molecular formula.
ii. Draw the electron dot diagram for the compounds given below. Represent the electron by (⋅ ) [3]
and (× ) in the diagram. [Atomic No.: Ca = 20, O = 8, Cl = 17, H = 1]
i. Calcium oxide
ii. Chlorine molecule
iii. Water molecule
Section B
Attempt any 4 questions
3. Question 3 [10]
(a) Why phosphorous pentaoxide and quick lime cannot be used for drying hydrochloric acid gas? [2]
(b) Write the products and balance the equation.
i. Magnesium metal is treated with dilute hydrochloric acid [1]
ii. Action of dilute sulphuric acid on sodium sulphite [1]
(c) Arrange the following as per the instruction given in the brackets:
i. Mg2+, Cu2+, Na+, H+ (In the order of preferential discharge at the cathode) [1]
compound and water. The chemical reaction which takes place is called ________
(dehydration/esterification/hydrogenation).
ii. ________ is a cyclic hydrocarbon. [1]
iii. Calculate the ________ of the compound from its empirical formula. [1]
4. Question 4 [10]
(a) What is the difference between the fluoride ion and neon atom even when the electronic configuration [2]
of both are same?
(b) Calculate the mass of lime stone required to produce 112 kg of quicklime by burning it. [2]
(c) Give the chemical formula of: [3]
i. Bauxite
ii. Cryolite
iii. Sodium aluminate
(d) Explain the following:
i. Copper is used to make hot water tanks and not steel. [1]
ii. People suffering from acidity are advised to drink cold milk. [1]
iii. Sea water is a strong electrolyte. [1]
5. Question 5 [10]
(a) i. Solid which can be used instead of conc. sulphuric acid to prepare ethylene by the dehydration [1]
of ethanol. Identify the substance.
ii. Gas used for ripening of fruits. Identify the gas. [1]
(b) Compare the properties of covalent and electrovalent compounds on the following points: [2]
i. Solubility
ii. Structure
(c) Give balanced chemical equation for the following:
i. Reaction of Ammonia with heated copper oxide [1]
ii. Concentrated hydrochloric acid and potassium permanganate solution [1]
iii. Action of dilute sulphuric acid on zinc sulphide [1]
(d) State one relevant observation for each of the following reactions:
i. Barium chloride solution is slowly added to sodium sulphate solution. [1]
ii. Ammonium hydroxide solution is added in excess to copper sulphate solution. [1]
iii. At the anode when aqueous copper sulphate solution is electrolysed using copper electrodes. [1]
6. Question 6 [10]
(a) Observe the table and fill the blanks. [2]
Li(7) Cl Ca(40)
- Br -
K(39) I Ba(137)
(b) Calculate the volume of oxygen required for the complete combustion of 8.8 g of propane (C3H8). [2]
What volume of ethyne gas at STP is required to produce 8.4 dm3 of carbon dioxide at STP? (H = 1,
C = 12, O = 16)
(c) Name the particles present in: [3]
i. Strong electrolyte
ii. Non-electrolyte
iii. Weak electrolyte.
(d) Give the molecular formula of one homologous of each of the following: [3]
i. C6H14
ii. C3H6
iii. C4H8
8. Question 8 [10]
(a) Two non-metals combine with each other by the sharing of electrons to form a compound X. [2]
i. What type of chemical bond is present in X?
ii. State whether X will have a high melting point or low melting point.
iii. Will it be a good conductor of electricity or not?
iv. Will it dissolve in organic solvents or not?
(b) 560 ml of carbon monoxide is mixed with 500 ml of oxygen and ignited. The chemical equation for [2]
the reaction is as follows:
2CO + O2 → 2CO2
Calculate the volume of oxygen used and carbon dioxide formed in the above reaction.
(c) Solution A is a sodium hydroxide solution. Solution B is a weak acid. Solution C is dilute sulphuric [3]
acid. Which solution will:
i. liberate sulphur dioxide from sodium sulphite?
ii. give a white precipitate with zinc sulphate solution?
iii. contain solute molecules and ions?
(d) Why SO3 is not directly dissolved in water to form sulphuric acid? [3]