Selfstudys Com File (2)
Selfstudys Com File (2)
Chemistry
Time Allowed: 2 hours Maximum Marks: 80
General Instructions:
The time given at the head of this Paper is the time allowed for writing the answers.
The intended marks for questions or parts of questions are given in brackets [ ].
Section A
1. Question 1 Choose one correct answer to the questions from the given options: [15]
(a) The set representing the correct order of first ionisation energy is [1]
a) 1 b) 7
c) 5 d) 3
(c) Which of the following does not conduct electricity? [1]
a) CaO b) Al2O3
(e) An aqueous solution turns red litmus solution blue. Excess addition of which of the following solution [1]
would reverse the change?
a) Sodium b) Copper
c) Zinc d) Manganese
(g) If NA is Avogadro’s number, then the number of oxygen atom in one g-equivalent of oxygen is [1]
NA
a) NA b) 4
NA
c) 2NA d)
2
a) Hydrogen b) Sodium
c) Oxygen d) Chlorine
(j) The neutral oxide: [1]
a) NO2 b) N2O
c) P2O5 d) Fe2O3
(k) A solid which bursts into flames on addition of concentrated nitric acid is ________. [1]
a) Methanol b) Ethane
a) saponification b) distillation
c) esterification d) condensation
2. Question 2 [25]
(a) i. Why silver nitrate is dissolved in tap water? [5]
ii. A compound A when warmed with dilute sulphuric acid, gives a gas. Name that gas.
iii. Complete and balance the following reaction.
NH3 + O2 ⟶ N2 + H2O
N2 + H2 ⇌ NH3
Mg + N2 ⟶ Mg3N2 → Ma(OH)2
(b) Match the salts given in Column I with their method of preparation given in Column II: [5]
Column I Column II
(c) Complete the following by choosing the correct answers from the bracket:
i. As we move across the period metallic characters ________. (decreases/increases) [1]
ii. ________ indicators can differentiate between the acidic or basic solutions of different pH [1]
values.
iii. The number of molecules present in 35.5 g of chlorine is ________ × 1023. (3.01/6.02) [1]
iv. Electrolysis of aqueous sodium chloride solution will form ________ at the cathode, [1]
(hydrogen gas/sodium metal)
v. Ammonia gas is collected by ________ (an upward displacement of air/a downward [1]
displacement of water/a downward displacement of air)
(d) Identify the following:
i. Series of compounds having similar structural formulae, same functional group and similar [1]
chemical properties.
ii. The gas evolved in warming ammonium sulphate with sodium hydroxide solution. [1]
iii. The particle that move when electric current is passed through metal wire. [1]
iv. The process by which soluble salt like sodium sulphate can be prepared. [1]
v. The most metallic element in its respective group is placed at the ________. (top/bottom) [1]
(e) i. A gaseous compound of nitrogen and hydrogen contains 12.5% hydrogen by mass. Find the [2]
molecular formula of the compound if its relative molecular mass is 37.
(N = 14, H = 1)
ii. The following table shows the electronic configuration of the elements W, X, Y, Z: [3]
Element W X Y Z
Electronic Configuration 2, 8, 1 2, 8, 7 2, 5 1
Section B
Attempt any 4 questions
3. Question 3 [10]
(a) i. Of the two gases, ammonia and hydrogen chloride, which is more dense? Name the method of [2]
collection of this gas.
ii. Give one example of a reaction between the above two gases which produces a solid compound.
(b) Write the products and balance the equation.
i. Sodium thiosulphate is reacted with dilute hydrochloric acid [1]
ii. Lead sulphate from lead carbonate. [1]
(c) Arrange the following as per the instruction given in the brackets:
i. He, Ar, Ne (Increasing order of the number of shells) [1]
ii. F, B, N, O (In the increasing order of electron affinity) [1]
iii. Cs, Na, Li, K, Rb (increasing order of metallic character) [1]
(d) Fill in the blanks by selecting the appropriate word from the given choice:
i. Two adjacent members of homologous series differ by CH2 units and ________ amu. [1]
ii. A carbon atom linked with two carbon atoms is known as ________ carbon. [1]
iii. CH2O is an ________ for the molecular formula, C6H12O6. [1]
4. Question 4 [10]
(a) What is lone pair effect? In what kind of compound does this effect occur? [2]
(b) Given: 2C2H6 + 7O2 → 4CO2 + 6H2O [2]
| | |
i. H − C = C − C − H
| |
H H
H H
| |
ii. H − C − C ≡ C − C − H
| |
H H
H H
| |
iii. H − C − C = O
|
8. Question 8 [10]
(a) An element L consists of molecules: [2]
i. What type of bonding is present in the particle that make up L?
ii. When L is heated with iron metal, it forms a compound FeL. What chemical term would you use
to describe the charge undergone by L?
(b) What are the applications of Avogadro’s law? [2]
(c) The pH values of three solutions A, B and C are given in the table. [3]
Answer the following questions:
Solution pH value
A 12
B 2
C 7
Section A
1. Question 1 Choose one correct answer to the questions from the given options:
(i) (d) Be > Mg > Ca
Explanation: {
Be > Mg > Ca
(ii) (b) 7
Explanation: {
7
(iii) (b) Solid NaCl
Explanation: {
As, attractive force between ions in solid state are very strong and ions are not free to move, therefore they do not
conduct electricity in solid state.
NaCl (solid) is an ionic solid hence, do not conduct electricity.
(iv) (d) conc. H2SO4
Explanation: {
conc. H2SO4
Explanation: {
Each oxygen atom in O2(g) bear two electrons.
N
Thus, 1 g equivalent of O2 = 2
A
NA
Hence, 1 g equivalent of oxygen atom = 4
14
= 6.25 6.25
6.25
=1
H 12.5 1
12.5
1
= 12.5 12.5
6.25
=2
Empirical formula of compound = NH2
Empirical formula weight = 14 + 2 = 16
Molecular weight
Molecular weight = 37 n = =
37
= 2.3 = 2
Empirical formula weight 16
2
× 400 cc of CO2
400 cc of C2H6 gives 800 cc of CO2
So, CO2 produced = 800 cc
2 Volume of C2H6 uses 7 volumes of O2
400 cc of C2H6 uses 7
2
× 400 volumes of O2
400 cc of C2H6 uses 1400 volumes of O2
Unused O2 = 2000 - 1400 = 600 cc
(iii) i. Al3+ + 3e- ⟶ Al
ii. Anode is renewed from time to time because they get oxidized.
iii. Graphite acts as anode.
(iv)Explain the following:
i. This is due to fact that cast iron expands on solidification. It takes the shape of the mould and is used to make
castings.
ii. Ammonium chloride is a salt of weak base and strong acid. It undergoes salt hydrolysis to produce an acidic solution
whereas sodium chloride is a salt of strong acid and strong bases, it does not undergo salt hydrolysis. Hence, its
solution remains neutral.
iii. An electrolyte must have free ions which act as charge carriers whereas in copper the free electrons act as charge
carriers.
5. Question 5
(i) i. Ethyne
ii. Methanal is prepared by the controlled oxidation of methanol (CH3OH) at 873-923 K and using silver or iron oxide
as catalyst.
873−923K
ii. 2Pb(NO3)2 −
→ 2PbO + 4NO2 ↑ + O2 ↑
150
75 cc of gas B = X
150
× 75
= 75×X
150
=
X
2
molecules
ii. Avogadro's law
(iii) i. They have same molecular formula.
ii. They have different physical and chemical properties.
iii. They have same molecular mass.
(iv) i. On adding concentrated hydrochloric acid if a greenish yellow gas is evolved it is Manganese dioxide. If no gas is
evolved it is CuO.
ii. On adding sodium hydroxide solution if a dirty green precipitate is formed it is ferrous sulphate solution. If a
reddish-brown precipitate is formed, it is Ferric sulphate solution.
iii. On adding lead nitrate solution, if white precipitate is formed which dissolves on heating, then it is dilute HCl.
If white precipitate formed does not dissolve on heating, it is dilute H2SO4.
7. Question 7
(i) Sodium chloride has high melting point and boiling point because it has strong electrostatic force of attraction between
its ions hence, more energy is required whereas carbon tetrachloride has weak van der Waals forces of attraction and
hence, energy required is less.
(ii) Molar mass of H2O = 2 × atomic mass of H + 1 × atomic mass of O
= 2 × 1.01 + 1 × 16.00 = 18.02 g
2×1.008
Mass % of hydrogen = × 100 = 11.18%
18.02
16.00
Mass % of oxygen = 18.02
× 100 = 88.79%
(iii) Electrolyte- CuSO4 Solution
Copper metal
The flow of electricity takes place by flow of electrons which The flow of electricity takes place by flow of ions
have negligible mass. which are dense particles as compared to electrons.
During metallic conduction, there is no transfer of matter. The Electrolytic conduction involves transfer of ions. The
flow of electricity only produces heat energy and no new electrolyte is decomposed and new products are
products are formed. formed.
(iv) H H H
| | |
i. H − C = C − C − H
| |
H H
| |
ii. H − C − C ≡ C − C − H
| |
H H
| |
iii. H − C − C = O
|
ii. Concentrated sulphuric acid reacts with ammonia/form ammonium sulphate or NH3 being basic combines with
concentrated H2SO4/as follow in chemical equation.
2NH 3 + H2 SO4 → (NH 4 )2 SO4
salt