MEMORY TIPS

c
1. Frequency, =

hc
2. Energy/photon, E = h =

12375
Also, E = eV, if is in Å

3. Electronic energy change during transition, E = En2  En1
n2 > n1, emission spectra if electron jumps from n2 to n1 shell and absorption spectra if electron
excites from n1 to n2 shell.
n 2h 2
4. Radius of nth Bohr orbit of H atom, rn = (where K = 9 × 109)
4 me K
2 2

n2
r1 for H = 0.529 Å ; rn for H like atom rn = 0.529 × Å
Z
2KZe2
5. Velocity of electron in nth Bohr orbit of H atom, v =
nh
Z
v = 2.18 × 108 cm / sec.
n
22 mZ2e4 K 2
6. Energy of electron in nth Bohr orbit of H atom, E =
n 2h 2
where n = 1, 2, 3..........
Z2
[E = –13.6 × 2 kcal/mole (1 cal = 4.18 J)]
n
E1 for H = – 21.72 × 10–12 erg = – 13.6 eV, E1 for H like atom = E1 for H × Z2

7. Wavelength emitted during transition in H atom,

1  1 1  22me4  1 1 
 RH  2  2    2  2  (in C.G.S.)
  1
n n 2 ch 3
 n1 n 2 

1 2
8. Photoelectric effect hv = w + mu or hv = I.E. + K.E.
2

9. Possible transitions for a jump from n2 to n1 = (n  n )

2 1

10. Angular momentum of electron in an orbit = n. (h/2)

BY SHIVAM SIR (C16)

11. Angular momentum of electron in an orbital = (nh/2) ( 1)

1 
12. Total spin =    n  ; where n is number of unpaired electrons.
2 

13. Magnetic moment of an atom n(n  2) B.M.; where n is number of unpaired electrons.

14. Nodal planes : Radial nodes = n – l – 1, Angular nodes = 1, Total nodes = (n – l)

h h2
15. de Broglie equation : l = =
mu 2  K.E.  m
where is wavelength, m is mass and u is velocity of particle.

16. Heisenberg uncer tainty principle :

h
p.x 
4
h
u.x 
4m
where p, u and x are uncertainties in momentum, velocity and position respectively.
Planck's constant is h and m is mass of subatomic particle.

BY SHIVAM SIR (C16)

 (JEE-MAINS QUESTIONS)
1. An atom has a mass of 0.02 kg and uncertainty in its velocity is 9.218 × 10–6 m/s then
uncertainty in position is (h = 6.626 × 10–34 Js) [AIEEE 2002]
–28 –32 –27 –10
(1) 2.86× 10 m (2) 2.86 × 10 cm (3) 1.5 × 10 m (4) 3.9 × 10 m
2. Energy of H- atom in the ground state is –13.6 eV, Hence energy in the second excited state is-
[AIEEE 2002]
(1) –6.8 eV (2) –3.4 eV (3) –1.51 eV (4) –4.3 eV
3. Uncertainty in position of a particle of 25 g in space is 10–5 m. Hence uncertainty in velocity
(ms–1) is (Planck's constant h = 6.6 × 10–34 Js) [AIEEE-2002]
–28 –34 –34 –24
(1) 2.1 × 10 (2) 2.1 × 10 (3) 0.5 × 10 (4) 5.0 × 20

    1 .
h
4. The orbital angular momentum for an electron revolving in an orbit is given by .
2
This momentum for an s-electron will be given by [AIEEE-2003]
h 1 2 h
(1) 2. (2) + . (3) zero (4)
2 2 2 2
2+
5. The number of d-electrons retained in Fe (At. number of Fe = 26) ion is : [AIEEE-2003]
(1) 6 (2) 3 (3) 4 (4) 5

6. The de Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 meters
per second is approximately : [AIEEE 2003]
–25 –33 –31 –16
(1) 10 meters (2) 10 meters (3) 10 meters (4) 10 meters

7. In Balmer series of lines of hydrogen spectrum, the third line from the red end corresponds to
which one of the following inter-orbit jumps of the electron for Bohr orbits in an atom of
hydrogen ? [AIEEE-2003]
(1) 2  5 (2) 3  2 (3) 5  2 (4) 4  1
8. Which of the following sets of quantum number is correct for an electron in 4f orbital ?
[AIEEE-2004]
1 1
(1) n = 3, l = 2, m = – 2, s = + (2) n = 4, l = 4, m = – 4, s = –
2 2
1 1
(3) n = 4, l = 3, m = + 1, s = + (4) n = 4, l = 3, m = + 4, s = +
2 2
9. The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity
to stationary state 1, would be (Rydberg constant = 1.097× 107 m–1) : [AIEEE-2004]
(1) 9.1 × 10–8 nm (2) 192 nm (3) 406 nm (4) 91 nm

BY SHIVAM SIR (C16)

10. Which of the following statements in relation to the hydrogen atom is correct ?
(1) 3s, 3p and 3d orbitals all have the same energy [AIEEE-2005]
(2) 3s and 3p orbitals are of lower energy than 3d orbitals
(3) 3p orbital is lower in energy than 3d orbital
(4) 3s orbitals is lower in energy than 3p orbital
11. According to Bohr's theory angular momentum of electron in 5th shell is : [AIEEE-2006]
(1) 1.0 h/ (2) 10 h/ (3) 2.5 h/  (4) 25 h/
–31
12. Uncertainty in the position of an electron (mass = 9.1 × 10 Kg) moving with a velocity 300
–1 –34
ms , accurate upto 0.001%, will be :- (h = 6.63 × 10 Js) [AIEEE-2006]
–2 –2 –2
(1) 5.76 × 10 m (2) 1.92 × 10 m (3) 3.84 × 10 m (4) 19.2 × 10–2 m
13. The ionziation enthalpy of hydrogen atom is 1.312 x 106 J mol–1. The energy required to excite
the electron in the atom from n =1 to n =2 is [AIEEE-2008]
–1 –1 –1
5
(1) 8.51 x 10 J mol 5
(2) 6.56 x 10 J mol 5
(3) 7.56 x 10 J mol (4) 9.84 x 105 J mol–1
14. In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%.
Certainty with which the position of the electron can be located is (h = 6.6 × 10–34 kg m2 s–1,
mass of electron, em = 9.1 × 10–31 kg): [AIEEE-2009]
–3 –3 –4
(1) 1.92 × 10 m (2) 3.84 × 10 m (3) 1.52 × 10 m (4) 5.10 × 10–3 m
15. Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 × 103 ms–1
(Mass of proton = 1.67 × 10–27 kg and h = 6.63 × 10–34 Js) : [AIEEE-2009]
(1) 2.5 nm (2) 14.0 nm (3) 0.032 nm (4) 0.40 nm
16. The energy required to break one mole of Cl–Cl bonds in Cl2 is 242 kJ mol–1. The longest
wavelength of light capable of breaking a single Cl–Cl bond is
(C = 3 × 108 ms–1 and NA = 6.02 × 1023 mol–1 ) [AIEEE-2010]
(1) 494 nm (2) 594 nm (3) 640 nm (4) 700 nm
+ –18 –1
17. Ionisation energy of He is 19.6 × 10 J atom . The energy of the first stationary state (n = 1)
2+
of Li is: [AIEEE-2010]
(1) 8.82 × 10–17 J atom–1 (2) 4.41 × 10–16 J atom–1
(3) –4.41 × 10–17 J atom–1 (4) –2.2 × 10–15 J atom–1
18. A gas absorbs a photon of 355 nm and emits at two wavelengths. If one of the emissions is at
680 nm, the other is at : [AIEEE-2011]
(1) 743 nm (2) 518 nm (3) 1035 nm (4) 325 nm
19. The frequency of light emitted for the transition n = 4 to n = 2 of He+ is equal to the transition
in H atom corresponding to which of the following [AIEEE-2011]
(1) n = 3 to n = 1 (2) n = 2 to n = 1 (3) n = 3 to n = 2 (4) n = 4 to n = 3

BY SHIVAM SIR (C16)

20. The electrons identified by quantum numbers n and l : [AIEEE-2012]
(a) n = 4 ,  = 1 (b) n = 4,  = 0 (c) n = 3,  = 2 (d) n = 3,  = 1
Can be placed in order of increasing energy as
(1) (a) < (c) < (b) < (d) (2) (c) < (d) < (b) < (a)
(3) (d) < (b) < (c) < (a) (4) (b) < (d) < (a) < (c)
21. If the kinetic energy of an electron is increased four times, the wavelength of the de-Broglie
wave associated with it would become : [JEE-Main(online) 2012]
(1) Two times (2) Half (3) One fourth (4) Four times
22. If the radius of first orbit of H atom is a0, the de-Broglie wavelength of an electron in the third
orbit is : [JEE-Main(online) 2012]
(1) 6  a0 (2) 8  a0 (3) 2  a0 (4) 4  a0
23. The wave number of the first emission line in the Balmer series of H-Spectrum is :
(R = Rydberg constant) :
3 9 5 R 7
(1) R (2) R (3) (4) R
4 400 36 6
24. The de Broglie wavelength of a car of mass 1000 kg and velocity 36 km/hr is :
(h = 6.63 × l0–34 Js) [JEE-Main(online) 2013]
(1) 6.626 × l0 m (2) 6.626 × 10 m (3) 6.626 × 10 m (4) 6.626 × 10–30 m
–31 –34 –38

25. For which of the following particles will it be most difficult to experimentally verify the de-
Broglie relationship? [JEE-Main(online) 2014]
(1) a dust particle (2) an electron (3) a proton (4) an a-particle
26. If the binding energy of the electron in a hydrogen atom is 13.6 eV, the energy required to
remove the electron from the first excited state of Li++ is : [JEE-Main(online) 2014]
(1) 13.6 eV (2) 30.6 eV (3) 122.4 eV (4) 3.4 eV
27. Based on the equation [JEE-Main(online) 2014]
1 1
E = –2.0 × 10–18 J  2
 2
 2 n1 
n
the wavelength of the light that must be absorbed to excite hydrogen electron from level n = 1
to level n = 2 will be (h = 6.625 × 10–34 Js, C = 3 × 108 ms–1)
(1) 2.650 × 10–7 m (2) 1.325 × 10–7 m (3) 1.325 × 10–10 m (4) 5.300 × 10–10 m
28. If 0 and  be the threshold wavelength and wavelength of incident light, the velocity of
photoelectron ejected from the metal surface is [JEE-Main(online) 2014]

2hc  0    2h  1 1  2h 2hc
(1)   (2)    (3)  0    (4)  0   
m  0  m  0   m m

BY SHIVAM SIR (C16)

29. Ionization energy of gaseous Na atoms is 495.5 kjmol–1. The lowest possible frequency of light
that ionizes a sodium atom is
(h = 6.626 × 10–34 Js, NA = 6.022 × 1023 mol–1) [JEE-Main(online) 2014]
15 –1 14 –1 15 –1
(1) 3.15 × 10 s (2) 4.76 × 10 s (3) 1.24 × 10 s (4) 7.50 × 104 s–1
30. Which of the following is the energy of a possible excited state of hydrogen?
[JEE-Main(offline) 2015]
(1) –3.4 eV (2) +6.8 eV (3) +13.6 eV (4) –6.8 eV
31. At temperature T, the average kinetic energy of any particle is kT- The de Broglie wavelength
follows the order : [JEE-Main(online) 2015]
(1) Visible photon > Thermal electron > Thermal neutron
(2)Thermal proton > Thermal electron > Visible photon
(3)Visible photon > Thermal neutron > Thermal electron
(4) Thermal proton > Visible photon > Thermal electron
32. The radius of the second Bohr orbit for hydrogen atom is : [JEE Main 2017]
–34
(Plank's const. h = 6.6262 × 10 Js
–31
mass of electron = 9.1091 × 10 kg
charge of electron e = 1.60210 × 10–19 C
permittivity of vacuum 0 = 8.854185 ×10–12 kg–1 m–3 A2)
(1) 1.65A (2) 4.76A (3) 0.529A (4) 2.12A
33. For emission line of atomic hydrogen from ni = 8 to nf = the plot of wave number
   against  1  will be (The Rydberg constant, R is in wave number unit).
   n2  H
   
[JEE Main (Jan.) 2019]
(1) Linear- with slope - RH (2) Linear with intercept - RH
(3) Non linear (4) Linear with slope RH
34. Which of the following combination of statements is true regarding the interpretation of the
atomic orbitals ? [JEE Main (Jan.) 2019]
(a) An electron in an orbital of high angular momentum stays away from the nucleus than an
electron in the orbital of lower angular momentum.
(b) For a given value of the principal quantum number, the size of the orbit is inversely
proportional to the azimuthal quantum number.
h
(c) According to wave mechanics, the ground state angular momentum is equal to .
2
(d) The plot of  Vs r for various azimuthal quantum numbers, shows peak shifting towards
higher r value.
(1) (a), (c) (2) (a), (d) (3) (b), (c) (4) (a), (b)

BY SHIVAM SIR (C16)

35. Which of the graphs shown below does not represent the relationship between incident light
and the electron ejected from metal surface? [JEE Main (Jan.) 2019]

(1) (2)

(3) (4)

36. The ground state energy of hydrogen atom is –13.6 eV. The energy of second excited state He+
ion in eV is : [JEE Main (Jan.) 2019]
(1) –54.4 (2) –6.04 (3) –3.4 (4) –27. 2
37. Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which
spectral line of H-atom is suitable for this purpose ? [JEE Main (Jan.) 2019]
5 –1 –34 8 –1
[RH = 1 × 10 cm , h = 6.6 × 10 Js, c = 3 × 10 ms ]
(1) Paschen, 5  3 (2) Balmer,  2 (3) Lyman,  1 (4) Paschen,  3
38. The de Broglie wavelength () associated with a photoelectron varies with the frequency (v) of
the incident radiation as, [v0 is threshold frequency] : [JEE Main (Jan.) 2019]
1 1 1 1
(1)   (2)   (3)   (4)  
1 1
(v – v0 ) 3
(v – v0 ) 2
(v – v0 ) 4
(v – v0 ) 2
39. What is the work function of the metal if the light of wavelength 4000 Å generates
photoelectrons of velocity 6 × 105 ms–1 form it ?
(Mass of electron = 9 × 10–31 kg
Velocity of light = 3 × 108 ms–1
Planck's constant = 6.626 × 10–34 Js
Charge of electron = 1.6 × 10–19 JeV–1) [JEE Main (Jan.) 2019]
(1) 2.1 eV (2) 3.1 eV (3) 0.9 eV (4) 4.0 eV
40. If the de Broglie wavelength of the electron in nth Bohr orbit in a hydrogenic atom is equal to
1.5 a0(a0 is Bohr radius), then the value of n/z is : [JEE Main (Jan.) 2019]
(1) 0.40 (2) 0.75 (3) 1.0 (4) 1.50

BY SHIVAM SIR (C16)

41. The quantum number of four electrons are given below : [JEE Main (April) 2019]
1 1
I. n = 4, l = 2, ml = – 2, ms = – II. n = 3, l = 2, ml = 1, ms = +
2 2
1 1
III. n = 4, l = 1, ml = 0, ms = + IV. n = 3, l = 1, ml = 1, ms = –
2 2
(1) I < III < II < IV (2) IV < III < II < I (3) I < II < III < I (4) IV < II < III < I
42. If p is the momentum of the fastest electron ejected from a metal surface after the irradiation of
light having wavelength , then for 1.5 p momentum of the photoelectron, the wavelength of
the light should be : (Assume kinetic energy of ejected photoelectron to be very high in
comparison to work function) : [JEE Main (April) 2019]
3 4 1 2
(1)  (2)  (3)  (4) 
4 9 2 3
43. For any given series of spectral lines of atomic hydrogen, let   max – min be the difference

in maximum and minimum frequencies in cm–1. The ratio Lyman / Balmer is:

[JEE Main (April) 2019]

(1) 4 : 1 (2) 5 : 4 (3) 9 : 4 (4) 27 : 4
44. Which one of the following about an electron occupying the 1s orbital in a hydrogen atom is
incorrect ? (The Bohr radius is represented by a0) [JEE Main (April) 2019]
(1) The electron can be found at a distance 2a0 from the nucleus
(2) The total energy of the electron is maximum when it is at a distance a0 from the nucleus.
(3) The magnitude of potential energy is double that of its kinetic energy on an average.
(4) The probability density of finding the electron is maximum at the nucleus.
45. The graph between ||2 and r(radial distance) is shown below. This represents:
[JEE Main (April) 2019]

(1) 1s orbital (2) 3s orbital (3) 2s orbital (4) 2p orbital

BY SHIVAM SIR (C16)

46. The ratio of the shortest wavelength of two special series of hydrogen spectrum is found to be
about 9. The spectral series are : [JEE Main (April) 2019]
(1) Paschen and Pfund (2) Balmer and Brackett
(3) Lyman and Paschen (4) Brackett and Pfund
47. The electrons are more likely to be found:
[JEE Main (April) 2019]

(1) only in the region c (2) in the region a and c

(3) only in the region a (4) in the region a and b

BY SHIVAM SIR (C16)

 (JEE-ADVANCE QUESTIONS)
1. The quantum numbers +1/2 and –1/2 for the electron spin represent: [JEE 2001]

(A) rotation of the electron in clockwise and anticlockwise direction respectively.

(B) rotation of the electron in anticlockwise and clockwise direction respectively.

(C) magnetic moment of the electron pointing up and down respectively.

(D) two quantum mechanical spin states which have no classical analogue

2. Rutherford‟s experiment , which established the nuclear model of atom, used a beam of :–

(A)  - particles, which impinged on a metal foil and get absorbed. [JEE 2002]

(B)  - rays, which impinged on a metal foil and ejected electron.

(C) Helium atoms, which impinged on a metal foil and got scattered.

(D) Helium nuclei, which impinged on a metal foil and got scattered.

3. The magnetic moment of cobalt of the compound Hg[Co(SCN)4] is [Given : Co+2] [JEE 2004]

(A) 3 (B) 8 (C) 15 (D) 24

4. The radius of which of the following orbit is same as that of the first Bohr‟s orbit of hydrogen
atom? [JEE 2004]
+ 2+ 2+ 3+
(A) He (n = 2) (B) Li (n = 2) (C) Li (n = 3) (D) Be (n = 2)

5. (a) The Schrodinger wave equation for hydrogen atom is [IIT-2004]

 r0  –r/a
3/2
1 1
2s = 1/2   2  e
4  2  a 0   a0 

Where a0 is Bohr's radius. Let the radial node in 2s be at r0. Then find r0 in terms of a0.
(b) A base ball having mass 100 g moves with velocity 100 m/s. find out the value of
wavelength of base ball.
6. (a) Calculate velocity of electron in first Bohr orbit of hydrogen atom (Given r = a0)
(b) Find de-Broglie wavelength of the electron in first Bohr orbit. [IIT-2005]

(c) Find the orbital angular momentum of 2p-orbital in terms of h/2 units.

BY SHIVAM SIR (C16)

7. Given in hydrogenic atom rn, Vn, E, Kn stand for radius, potential energy, total energy and
kinetic energy in nth orbit. Find the value of U,v,x,y. [JEE 2006]
Vn
(A) U= (P) 1
Kn
1
(B)  Ex (Q) –2
rn
(C) rn  Zy (R) –1
(Z = Atomic number)
(D) v = (Orbital angular momentum of electron (S) 0
in its lowest energy )
8. Match the entries in Column I with the correctly related quantum number(s) in Column II.
Indicate your answer by darkening the appropriate bubbles of the 4 × 4 matrix given in the
ORS. [JEE 2008]
Column I Column II
(A) Orbital angular momentum of the (P) Principal quantum number
electron in a hydrogen-like atomic orbital
(B) A hydrogen-like one-electron wave (Q) Azimuthal quantum number
function obeying Pauli principle
(C) Shape, size and orientation of hydrogen (R) Magnetic quantum number
like atomic orbitals
(D) Probability density of electron at the nucleus (S) Electron spin quantum
number in hydrogen-like
atom
Paragraph for questions 14 to 16
The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node.
Upon absorbing light the ion undergoes transition to a state S2. The state S2 has one radial node
and its energy is equal to the ground state energy of the hydrogen atom. [JEE 2010]
9. The state S1 is :-
(A) 1s (B) 2s (C) 2p (D) 3s
10. Energy of the state S1 in units of the hydrogen atom ground state energy is :-
(A) 0.75 (B) 1.50 (C) 2.25 (D) 4.50
11. The orbital angular momentum quantum number of the state S2 is :-
(A) 0 (B) 1 (C) 2 (D) 3

BY SHIVAM SIR (C16)

12. The maximum number of electrons that can have principal quantum number, n=3, and spin
quantum number, ms = – 1/2, is [JEE 2011]
13. The work function () of some metals is listed below. The number of metals which will show
photoelectric effect when light of 300 nm wavelength falls on the metal is : – [JEE 2011]
Metal Li Na K Mg Cu Ag Fe Pt W

2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

14. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is
[a0 is Bohr radius] [JEE 2012]
h2 h2 h2 h2
(A) (B) (C) (D)
42 ma 02 162 ma 02 322 ma 02 322 ma 02

15. The atomic masses of He and Ne are 4 and 20 a.m.u. respectively. The value of the de Broglie
wavelength of He gas at –73 ºC is "M" times that of the de Broglie wavelength of Ne at 727 ºC.
M is. [JEE 2013]
1
16. In an atom, the total number of electrons having quantum numbers n = 4, |m| = 1 and ms = –
2
is [JEE 2014]
17. P is the probability of finding the 1s electron of hydrogen atom in a spherical shell of
infinitesimal thickness, dr, at a distance r from the nucleus. The volume of this shell is 4r2dr.
The qualitative sketch of the dependence of P on r is - [JEE 2016]
P P

(A) (B)

O r O r
P P

(C) (D)

O r O r

BY SHIVAM SIR (C16)

 Answer 18, 19 and 20 by appropriately matching the information given in the three
columns of the following table.
The wave function n,l.m1 is a mathematical functions whose value depends upon spherical

polar coordinates (r,q,f) of the electron and characterized by the quantum number n,l and m1.
Here r is distance from nucleus, is colatitude and  is azimuth . In the mathematical functions
given in the Table, Z is atomic number and a0 is Bohr radius.

Column 1 Column 2 Column 3

3
 Zr 
 Z   
2
(I) 1s orbital (i) n,l .m1   e  a0  (P)
 a0 

r / a0

(II) 2s orbital (ii) One radial node (Q) Probability density at

1
nucleus 
a 30
5
 Zr 
 Z  2  
(III) 2pz orbital (iii) n,l ,m1    re  2a0  cos  (R) Probability density is
 a0 
maximum at nucleus

(IV) 3d 2z orbital (iv) xy-plane is a nodal plane (S)Energy needed to excite electron
from n = 2 state to n = 4 state is
27
times the energy needed to
32
excite electron from n = 2 state to
n = 6 state
[JEE Adv. 2017]

18. For the given orbital in Column 1, the only CORRECT combination for any hydrogen- like
species is
(A) (IV) (iv) (R) (B) (II) (ii) (P) (C) (III) (iii) (P) (D) (I) (ii) (S)

BY SHIVAM SIR (C16)

19. For He+ ion, the only INCORRECT combination is
(A) (II) (ii) (Q)v (B) (I) (i) (S) (C) (I) (i) (R) (D) (I) (iii) (R)
20. For hydrogen atom, the only CORRECT combination is
(A) (I) (iv) (R) (B) (I) (i) (P) (C) (II) (i) (Q) (D) (I) (i) (S)

21. The ground state energy of hydrogen atom is –13.6 eV. Consider an electronic state  of He+

whose energy; azimuthal quantum number and magnetic quantum number are –3.4 eV, 2 and 0,

respectively. Which of the following statement(s) is(are) true for the state ? [JEE Adv. 2019]

(1) It has 2 angular nodes

(2) It has 3 radial nodes
(3) The nuclear charge experienced by the electron in this state is less than 2e, where e is the
magnitude of the electronic charge
(4) It is a 4d state.
22. Answer the following by appropriately matching the lists based on the information given
in the paragraph
Consider the Bohr‟s model of a one electron atom where the electron moves around the
nucleus, In the following, List-I contains some quantities for the nth orbit of the atom and List-II
contains showing how they depend on n. [JEE Adv. 2019]
List-I List-II

(I) Radius of the nth orbit (P) n–2

(II) Angular momentum of the electron in the nth orbit (Q)  n–1

(III) Kinetic energy of the electron in the nth orbit (R)  n0

(IV) Potential energy of the electron in the nth orbit (S)  n1

(T)  n2

(U)  n1/2

Which of the following options has the correct combination considering List-I and List-II?
(1) (I), (T) (2) (II), (Q) (3) (I), (P) (4) (II), (R)

BY SHIVAM SIR (C16)

 ANSWER KEY

(JEE-MAIN)
1. 1 2. 3 3. 1 4. 3 5. 1 6. 2 7. 3
8. 3 9. 4 10. 1 11. 3 12. 2 13. 4 14. 1
15. 4 16. 1 17. 3 18. 1 19. 2 20. 3 21. 2
22. 1 23. 3 24. 3 25. 1 26. 1 27. 2 28. 1
29. 3 30. 1 31. 1 32. 4 33. 4 34. 2 35. 2
36. 2 37. 4 38. 1 39. 1 40. 2 41. 2 42. 2
43. 3 44. 2 45. 3 46. 3 47. 2

(JEE-ADVANCE)
1. D 2. D 3. C 4. D 5. (a) r0 = 2a0 (b) 6.626 × 10–25 Å
h
6. (a) 2.197 × 106 m/s (b) 3.31 Å (c) 2. 7. (A) Q, (B) P, (C) R, (D) S
2
8. (A) Q,R); (B) (P,Q,R,S) ; (C) (P,Q,R) ; (D) (P,Q)
9. B 10. C 11. B 12. 9 13. 4 14. C 15. 5
16. 6 17. B 18. D 19. D 20. 1,4 21. 1 22. 2

BY SHIVAM SIR (C16)