Chapter 2

Structure of Atom
1. Calculate the wavelength (in nanometer) associated 6. The electrons identified by quantum numbers n
with a proton moving at 1.0 × 103 ms–1 and l
(Mass of proton = 1.67 × 10–27 kg and h = 6.63 × (a) n = 4, l = 1 (b) n = 4, l = 0
10–34 Js) [AIEEE-2009] (c) n = 3, l = 2 (d) n = 3, l = 1
(1) 0.40 nm (2) 2.5 nm can be placed in order of increasing energy as
(3) 14.0 nm (4) 0.032 nm [AIEEE-2012]

2. In an atom, an electron is moving with a speed of (1) (d) < (b) < (c) < (a)
600 m/s with an accuracy of 0.005%. Certainty with (2) (b) < (d) < (a) < (c)
which the position of the electron can be located is
(3) (a) < (c) < (b) < (d)
(h = 6.6 × 10–34 kg m2s–1, mass of electron, em = 9.1
× 10–31 kg) [AIEEE-2009] (4) (c) < (d) < (b) < (a)

(1) 5.10 × 10–3 m (2) 1.92 × 10–3 m 7. Energy of an electron is given by

(3) 3.84 × 10–3 m (4) 1.52 × 10–4 m § Z2 ·

E = -2.178×10 -18 J ¨ 2 ¸. W avelength of light
¨n ¸
3. The energy required to break one mole of Cl – Cl © ¹
bonds in Cl 2 is 242 kJ mol –1 . The longest required to excite an electron in an hydrogen atom
wavelength of light capable of breaking a single form level n = 1 to n = 2 will be
Cl – Cl bond is
(h = 6.62 × 10–34 Js and c = 3.0 × 108 ms–1)
(c = 3 × 108 ms–1 and NA = 6.02 × 1023 mol–1) [JEE (Main)-2013]
[AIEEE-2010]
(1) 1.214 × 10–7 m (2) 2.816 × 10–7 m
(1) 494 nm (2) 594 nm
(3) 6.500 × 10–7 m (4) 8.500 × 10–7 m
(3) 640 nm (4) 700 nm
8. The first ionisation potential of Na is 5.1 eV. The
4. Ionisation energy of He+
is 19.6 × 10–18 atom–1. value of electron gain enthalpy of Na+ will be
The energy of the first stationary state (n = 1) of [JEE (Main)-2013]
Li2+ is [AIEEE-2010] (1) –2.55 eV (2) –5.1 eV
(1) 8.82 × 10–17 J atom–1 (3) –10.2 eV (4) +2.55 eV
(2) 4.41 × 10–16 J atom–1 9. The correct set of four quantum numbers for the
(3) –4.41 × 10–17 J atom–1 valence electrons of rubidium atom (Z = 37) is
[JEE (Main)-2014]
(4) –2.2 × 10–15 J atom–1
5. The frequency of light emitted for the transition 1 1
(1) 5, 0, 0, + (2) 5,1, 0, +
n = 4 to n = 2 of He + is equal to the transition in 2 2
H atom corresponding to which of the following
[AIEEE-2011] 1 1
(3) 5,1,1, + (4) 5, 0,1, +
2 2
(1) n = 4 to n = 3
10. Which of the following is the energy of a possible
(2) n = 3 to n = 1
excited state of hydrogen? [JEE (Main)-2015]
(3) n = 2 to n = 1
(1) +13.6 eV (2) –6.8 eV
(4) n = 3 to n = 2
(3) –3.4 eV (4) +6.8 eV
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11. A stream of electrons from a heated filament was towards higher r value. [JEE (Main)-2019]
passed between two charged plates kept at a
(1) (a), (d) (2) (b), (c)
potential difference V esu. If e and m are charge
and mass of an electron, respectively, then the (3) (a), (c) (4) (a), (b)
h 15. W hich of the graphs shown below does not
value of (where O is wavelength associated with
O represent the relationship between incident light and
electron wave) is given by [JEE (Main)-2016] the electron ejected from metal surface?
(1) 2meV [JEE (Main)-2019]
(2) meV
(3) 2meV K.E.
of e s
(4) meV
12. The radius of the second Bohr orbit for hydrogen
atom is (1)
0
(Planck's Const. h = 6.6262 × 10–34 Js; Energy of
Light
mass of electron = 9.1091 × 10–31 kg;
charge of electron e = 1.60210 × 10–19 C;
Number
permittivity of vacuum
of e s
H0 = 8.854185 × 10–12 kg–1 m–3 A2)
[JEE (Main)-2017]
(2)
(1) 0.529 Å (2) 2.12 Å
0 Frequency of
(3) 1.65 Å (4) 4.76 Å Light
13. For emission line of atomic hydrogen from ni = 8
G
to nf = n, the plot of wave number ( Q ) against
K.E.
§ 1· of e s
¨ 2 ¸ will be (The Rydberg constant, RH is in wave
©n ¹
number unit) [JEE (Main)-2019] (3)
(1) Linear with slope RH 0 Intensity of
LIght
(2) Linear with intercept –RH
(3) Non-linear
(4) Linear with slope –RH K.E.
of e s
14. Which of the following combination of statements
is true regarding the interpretation of the atomic
orbitals? (4)

(a) An electron in an orbital of high angular 0 Frequency of

momentum stays away from the nucleus than Light
an electron in the orbital of lower angular 16. The ground state energy of hydrogen atom is
momentum –13.6 eV. The energy of second excited state of
(b) For a given value of the principal quantum He+ ion in eV is [JEE (Main)-2019]
number, the size of the orbit is inversely (1) –27.2 (2) –6.04
proportional to the azimuthal quantum number.
(3) –54.4 (4) –3.4
(c) According to wave mechanics, the ground
17. Heat treatment of muscular pain involves radiation of
h
state angular momentum is equal to wavelength of about 900 nm. Which spectral line of
2S
H-atom is suitable for this purpose?
(d) The plot of \ Vs r for various azimuthul
quantum numbers, shows peak shifting [RH= 1 × 105 cm, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1]

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 [JEE (Main)-2019] 22. If p is the momentum of the fastest electron
ejected from a metal surface after the irradiation of
(1) Balmer, fo 2 (2) Lyman, fo 1
light having wavelength O, then for 1.5 p momentum
(3) Paschen, 5 o 3 (4) Paschen, fo 3 of the photoelectron, the wavelength of the light
18. The de Broglie wavelength (O) associated with a should be
photoelectron varies with the frequency (Q) of the (Assume kinetic energy of ejected photoelectron to be
incident radiation as, [Q0 is threshold frequency] very high in comparison to work function):
[JEE (Main)-2019] [JEE (Main)-2019]

1 1 3 4
(1) O v (2) O v 1 (1) O (2) O
Q  Q0 4 9
Q  Q0 4
2 1
1 1 (3) O (4) O
(3) O v 1
(4) O v 3
3 2
Q  Q0 2 Q  Q0 2 23. For any given series of spectral lines of atomic
19. What is the work function of the metal if the light hydrogen, let 'Q Qmax  Qmin be the difference in
of wavelength 4000 Å generates photoelectrons of maximum and minimum frequencies in cm–1. The
velocity 6 × 105 ms–1 from it? ratio 'QLyman / 'QBalmer is [JEE (Main)-2019]
(Mass of electron = 9 × 10–31 kg
(1) 9 : 4 (2) 27 : 5
Velocity of light = 3 × 108 ms–1
(3) 4 : 1 (4) 5 : 4
Planck’s constant = 6.626 × 10–34 Js
24. Which one of the following about an electron
Charge of electron = 1.6 × 10–19 JeV–1) occupying the 1s orbital in a hydrogen atom is
[JEE (Main)-2019] incorrect? (The Bohr radius is represented by a0)

(1) 4.0 eV (2) 2.1 eV [JEE (Main)-2019]

(3) 3.1 eV (4) 0.9 eV (1) The probability density of finding the electron is
maximum at the nucleus
20. If the de Broglie wavelength of the electron in nth
Bohr orbit in a hydrogenic atom is equal to 1.5 Sa0 (2) The electron can be found at a distance 2a0
(a0 is Bohr radius), then the value of n/z is from the nucleus
(3) The magnitude of the potential energy is double
[JEE (Main)-2019]
that of its kinetic energy on an average
(1) 0.40 (2) 1.50
(4) The total energy of the electron is maximum
(3) 0.75 (4) 1.0 when it is at a distance a0 from the nucleus
21. The quantum number of four electrons are given 25. The graph between |\|2 and r(radial distance) is
below shown below. This represents [JEE (Main)-2019]
1
(I) n = 4, l = 2, ml = –2, ms = –
2
|\|2
1
(II) n = 3, l = 2, ml = 1, ms = +
2
1 r
(III) n = 4, l = 1, ml = 0, ms = + (1) 1s orbital (2) 2s orbital
2
1 (3) 2p orbital (4) 3s orbital
(IV) n = 3, l = 1, ml = 1, ms = –
2 26. The ratio of the shortest wavelength of two spectral
The correct order of their increasing energies will series of hydrogen spectrum is found to be about
be [JEE (Main)-2019] 9. The spectral series are [JEE (Main)-2019]

(1) IV < II < III < I (2) I < III < II < IV (1) Paschen and Pfund (2) Brackett and Pfund

(3) IV < III < II < I (4) I < II < III < IV (3) Lyman and Paschen (4) Balmer and Brackett

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27. The electrons are more likely to be found 32. The de Broglie wavelength of an electron in the 4th
Bohr orbit is [JEE (Main)-2020]
[JEE (Main)-2019]
(1) 4Sa0 (2) 6Sa0
(3) 8Sa0 (4) 2Sa0
a < (x)
33. The figure that is not a direct manifestation of the
b x quantum nature of atoms is [JEE (Main)-2020]
–x o Increasing wavelength
c
(1)

(1) In the region a and c (2) Only in the region c

Absorption spectrum
(3) Only in the region a (4) In the region a and b
28. Among the following, the energy of 2s orbital is Internal
energy
lowest in [JEE (Main)-2019] of
(2)
Ar 300 400 500 600
(1) Li (2) K
(3) H (4) Na Temperature (K)

29. The number of orbitals associated with quantum T2 > T1

Intensity
1
numbers n = 5, ms =  is [JEE (Main)-2020] (3) of radiation
black body
2 T1

(1) 15 (2) 50 Wavelength

(3) 25 (4) 11 Rb K
Na
30. For the Balmer series in the spectrum of H atom, Kinetic
energy of
(4) photoelectrons
°­ 1 1 °½
Q =RH ® 2 – 2 ¾, the correct statements among (I) Frequency of incident
¯° n1 n2 ¿° radiation
to (VI) are 34. The number of subshells associated with n = 4 and
m = –2 quantum numbers is [JEE (Main)-2020]
(I) As wavelength decreases, the lines in the
series converge (1) 2 (2) 8
(3) 4 (4) 16
(II) The integer n1 is equal to 2
35. The region in the electromagnetic spectrum where
(III) The lines of longest wavelength corresponds to the Balmar series lines appear is
n2 = 3
[JEE (Main)-2020]
(IV) The ionization energy of hydrogen can be (1) Microwave (2) Ultraviolet
calculated from wave number of these lines
(3) Visible (4) Infrared
[JEE (Main)-2020] 36. The shortest wavelength of H atom in the Lyman
(1) (I), (II), (III) (2) (II), (III), (IV) series is O1. The longest wavelength in the Balmar
series of He+ is [JEE (Main)-2020]
(3) (I), (III), (IV) (4) (I), (II), (IV)
5O1 36O1
31. The radius of the second Bohr orbit, in terms of the (1) (2)
9 5
Bohr radius, a0, in Li2+ is [JEE (Main)-2020]
27O1 9O1
4a0 4a0 (3) (4)
5 5
(1) (2)
3 9 37. The difference between radii of 3rd and 4th orbits of
Li2+ is 'R1. The difference between the radii of 3rd
2a0 2a0
(3) (4) and 4 th orbits of He + is 'R 2 . Ratio
3 9 'R1 : 'R2 is [JEE (Main)-2020]

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 (1) 3 : 2 (2) 8 : 3 42. The plots of radial distribution functions for various
(3) 2 : 3 (4) 3 : 8 orbitals of hydrogen atom against ‘r’ are given below

38. The correct statement about probability density

8
(except at infinite distance from nucleus) is

4Sr R2n, l (r)

[JEE (Main)-2020] (A) 4

2
(1) It can never be zero for 2s orbital
0 10
(2) It can be zero for 3p orbital 5
r(Å)
(3) It can be zero for 1s orbital
(4) It can be negative for 2p orbital
3

4Sr Rn, l (r)

39. The work function of sodium metal is 2
4.41 × 10–19 J. If photons of wavelength 300 nm (B)

2
1

2
are incident on the metal, the kinetic energy of the
ejected electrons will be (h = 6.63 × 10–34 J s; 0
5 10
c = 3 × 108 m/s) ________ × 10–21 J. r(Å)
[JEE (Main)-2020]
40. A proton and a Li3+
nucleus are accelerated by the
3
same potential. If OLi and Op denote the de Broglie

4Sr Rn, l (r)

2
wavelengths of Li3+ and proton respectively, then (C)

2
1

2
O Li
the value of O is x × 10–1. 0
p 5 10
r(Å)
The value of x is _____. (Rounded off to the
nearest integer)
2.0
[Mass of Li3+ = 8.3 mass of proton]
4S r Rn, l (r)

1.5
[JEE (Main)-2021] (D)
2

1.0
2

41. According to Bohr’s atomic theory: 0.5

0
5 10
2 r(Å)
Z
(A) Kinetic energy of electron is v
n2
The correct plot for 3s orbital is
(B) The product of velocity (v) of electron and
principal quantum number (n), ‘vn’ v Z2 (1) (C) (2) (D)

(C) Frequency of revolution of electron in an (3) (B) (4) (A)

Z3 [JEE (Main)-2021]
orbit is v
n 3 43. Electromagnetic radiation of wavelength
663 nm is just sufficient to ionise the atom of metal
(D) Coulombic force of attraction on the
A. The ionization energy of metal A in
Z3 kJ mol –1 is ____. (Rounded-off to the nearest
electron is v integer)
n4
[h = 6.63 × 10 –34 Js, c = 3.00 × 10 8 ms –1 ,
Choose the most appropriate answer from the
options given below: [JEE (Main)-2021] NA = 6.02 × 1023 mol–1] [JEE (Main)-2021]

(1) (A) only 44. The orbital having two radial as well as two
angular nodes is : [JEE (Main)-2021]
(2) (A) and (D) only
(1) 3p (2) 4d
(3) (C) only
(3) 5d (4) 4f
(4) (A), (C) and (D) only

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45. A ball weighing 10 g is moving with a velocity of 90 52. The Azimuthal quantum number for the valence
ms–1. If the uncertainty in its velocity is 5%, then the electrons of Ga+ ion is _______.
uncertainty in its position is ___________ × 10–33
(Atomic number of Ga = 31) [JEE (Main)-2021]
m. (Rounded off to the nearest integer)
53. The wavelength of electrons accelerated from rest
[Given : h = 6.63 × 10–34 Js] [JEE (Main)-2021]
through a potential difference of 40 kV is x × 10–2 m.
46. When light of wavelength 248 nm falls on a metal of The value of x is _______. (Nearest integer)
threshold energy 3.0 eV, the de-Broglie wavelength
of emitted electrons is ____ Å. (Round off to the Given: Mass of electron = 9.1 × 10–31 kg
Nearest Integer). Charge on an electron = 1.6 × 10–19 C
[Use : 3 = 1.73, h = 6.63 ×10-34 Js Planck’s constant = 6.63 × 10–34 Js
me = 9.1 × 10–31 kg; c = 3.0 × 108 ms–1 ; 1eV = [JEE (Main)-2021]
1.6 × 10–19J] [JEE (Main)-2021]
54. Number of electrons that Vanadium (Z = 23) has in
47. The number of orbitals with n = 5, m A = +2 is p-orbitals is equal to _______. [JEE (Main)-2021]
______.
55. A source of monochromatic radiation of wavelength
(Round off to the Nearest Integer). 400 nm provides 1000 J of energy in 10 seconds.
[JEE (Main)-2021] When this radiation falls on the surface of sodium,
x × 1020 electrons are ejected per second. Assume
48. A certain orbital has n = 4 and mL = –3. The number that wavelength 400 nm is sufficient for ejection of
of radial nodes in this orbital is __________. electron from the surface of sodium metal. The value
(Round off to the Nearest Integer). of x is _______. (Nearest integer)
[JEE (Main)-2021] (h = 6.626 × 10–34 Js) [JEE (Main)-2021]
49. In the ground state of atomic Fe(Z = 26), the 56. An accelerated electron has a speed of 5 × 10 6
spin-only magnetic moment is ______ × 10–1 BM. ms–1 with an uncertainty of 0.02%. The uncertainty
(Round off to the Nearest Integer). in finding its location while in motion is x × 10–9 m.
The value of x is _________. [JEE (Main)-2021]
[Given : 3 = 1.73, 2 = 1.41]
[Use mass of electron = 9.1 × 10–31 kg, h = 6.63
[JEE (Main)-2021] × 10–34 Js, S = 3.14]
50. Given below are two statements : 57. Given below are two statements :
Statement I : Bohr’s theory accounts for the Statement I : Rutherford’s gold foil experiment
stability and line spectrum of Li+ ion. cannot explain the line spectrum of
Statement II : Bohr’s theory was unable to explain hydrogen atom.
the splitting of spectral lines in the presence of a
Statement II : Bohr’s model of hydrogen atom
magnetic field.
contradicts Heisenberg’s
In the light of the above statements, choose the uncertainty principle.
most appropriate answer from the options given
In the light of the above statement, choose the
below. [JEE (Main)-2021]
most appropriate answer from the options given
(1) Both statement I and statement II are true below: [JEE (Main)-2021]
(2) Statement I is false but statement II is true (1) Both statement I and statement II are false.
(3) Both statement I and statement II are false (2) Statement I is true but statement II is false.
(4) Statement I is true but statement II is false
(3) Statement I is false but statement II is true.
51. A certain orbital has no angular nodes and two
(4) Both statement I and statement II are true.
radial nodes. The orbital is [JEE (Main)-2021]
58. If the Thompson model of the atom was correct, then
(1) 2p (2) 3p
the result of Rutherford’s gold foil experiment would
(3) 3s (4) 2s have been : [JEE (Main)-2021]

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 (1) All D-particles get bounced back by 180° 63. Ge (Z = 32) in its ground state electronic
(2) D-particles pass through the gold foil deflected configuration has x completely filled orbitals with
by small angles and with reduced speed ml = 0. The value of x is _____.

(3) D-particles are deflected over a wide range of [JEE (Main)-2021]

angles 64. A 50 watt bulb emits monochromatic red light of
(4) All of the D-particles pass through the gold foil wavelength of 795 nm. The number of photons
without decrease in speed emitted per second by the bulb is x × 10 20. The
value of x is ______. (Nearest integer)
59. Given below are two statements :
[Given : h = 6.63 × 10–34 Js and c = 3.0 × 108 ms–1]
Statement I : According to Bohr’s model of an
atom, qualitatively the magnitude of velocity of [JEE (Main)-2021]
electron increases with decrease in positive 65. Consider the following pairs of electrons
charges on the nucleus as there is no strong hold
on the electron by the nucleus. [JEE (Main)-2022]

Statement II : According to Bohr’s model of an 1

atom, qualitatively the magnitude of velocity of A (a) n 3, l 1, mA 1, ms 
2
electron increases with decrease in principal
quantum number. 1
(b) n 3, l 2, mA 1, ms 
In the light of the above statements, choose the 2
most appropriate answer from the options given
below : [JEE (Main)-2021] 1
B (a) n 3, l 2, mA 2, ms 
(1) Both Statement I and Statement II are false 2

(2) Statement I is false but Statement II is true

1
(b) n 3, l 2, mA 1, ms 
(3) Both Statement I and Statement II are true 2
(4) Statement I is true but Statement II is false
1
60. A metal surface is exposed to 500 nm radiation. The C (a) n 4, l 2, mA 2, ms 
2
threshold frequency of the metal for photoelectric
current is 4.3 × 1014 Hz. The velocity of ejected
1
electron is _____ × 105 ms–1. (Nearest integer) (b) n 3, l 2, mA 2, ms 
2
[Use : h = 6.63 × 10–34 Js, me = 9.0 × 10–31 kg]
The pairs of electrons present in degenerate orbitals
[JEE (Main)-2021] is /are:
61. The kinetic energy of an electron in the second Bohr (1) Only (A) (2) Only (B)
(3) Only (C) (4) (B) and (C)
h2
orbit of a hydrogen atom is equal to . The 66. The energy of one mole of photons of radiation of
x ma02
wavelength 300 nm is (Given h = 6.63 × 10–34Js, NA
value of 10x is ______. (a0 is radius of Bohr’s orbit) = 6.02 × 1023 mol–1, c = 3 × 108 ms–1)
(Nearest integer)
[JEE (Main)-2022]
[Given : S = 3.14] [JEE (Main)-2021]
(1) 235 kJ mol –1
(2) 325 kJ mol–1
62. The number of photons emitted by a monochromatic
(3) 399 kJ mol–1 (4) 435 kJ mol–1
(single frequency) infrared range finder of power 1
mW and wavelength of 1000 nm, in 0.1 second is x 67. The pair, in which ions are isoelectronic with Al3+ is:
× 1013. The value of x is _____. (Nearest integer) [JEE (Main)-2022]
(h = 6.63 × 10–34 Js, c = 3.00 × 108 ms–1) (1) Br– and Be2+ (2) Cl– and Li+
[JEE (Main)-2021] (3) S2– and K+ (4) O2– and Mg2+

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68. The longest wavelength of light that can be used for 74. Consider the following statements :
the ionisation of lithium atom (Li) in its ground state
[JEE (Main)-2022]
is x × 10–8 m. The value of x is ______. (Nearest
Integer) (A) The principal quantum number ‘n’ is a positive
(Given : Energy of the electron in the first shell of integer with values of ‘n’ = 1, 2, 3, ….
the hydrogen atom is –2.2 x 10 –18 J; (B) The azimuthal quantum number ‘l’ for a given
h = 6.63 × 10– 34 Js and c = 3 × 108 ms–1) ‘n’ (principal quantum number) can have
[JEE (Main)-2022] values as ‘l’ = 0, 1, 2, …n
69. The minimum energy that must be possessed by (C) Magnetic orbital quantum number ‘ml’ for a
photons in order to produce the photoelectric effect particular ‘l’ (azimuthal quantum number) has
with platinum metal is (2l + 1) values.
[Given The threshold frequency of platinum is 1.3 × (D) ±1/2 are the two possible orientations of
1015 s–1 and h = 6.6 × 10–34 Js.] electron spin.
[JEE (Main)-2022] (E) For l = 5, there will be a total of 9 orbital
(1) 3.21 × 10 –14
J (2) 6.24 × 10–16 J Which of the above statements are correct?
(3) 8.58 × 10–19 J (4) 8.58 × 10–19 J (1) (A), (B) and (C)
70. If the radius of the 3rd Bohr’s
orbit of hydrogen atom (2) (A), (C), (D) and (E)
is r3 and the radius of 4th Bohr’s orbit is r4. Then :
(3) (A), (C) and (D)
[JEE (Main)-2022]
(4) (A), (B), (C) and (D)
9 16
(1) r4 r3 (2) r4 r3 75. Which of the following statements are correct?
16 9
[JEE (Main)-2022]
3 4 (A) The electronic configuration of Cr is [Ar]
(3) r4 r3 (4) r4 r3
4 3 3d54s1.
71. The number of radial and angular nodes in 4d orbital (B) The magnetic quantum number may have a
are, respectively negative value.
[JEE (Main)-2022] (C) In the ground state of an atom, the orbitals
are filled in order of their increasing energies.
(1) 1 and 2 (2) 3 and 2
(D) The total number of nodes are given by n – 2.
(3) 1 and 0 (4) 2 and 1
Choose the most appropriate answer from the
72. If the uncertainty in velocity and position of a minute options given below :
particle in space are, 2.4 × 10–26 (m s–1) and 10–7 (1) (A), (C) and (D) only
(m) respectively. The mass of the particle in g is (2) (A) and (B) only
_____. (Nearest integer) (3) (A) and (C) only
(Given : h = 6.626 × 10–34 Js) (4) (A), (B) and (C) only
[JEE (Main)-2022] 76. Which of the following is the correct plot for the
73. Consider the following set of quantum numbers. probability density \2 r as a function of distance
‘r’ of the electron from the nucleus for 2s orbital?
n l ml
[JEE (Main)-2022]
A. 3 3 –3

B. 3 2 –2

C. 2 1 +1

D. 2 2 +2 (1)
The number of correct sets of quantum numbers is
_____. [JEE (Main)-2022]

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 48 3 
80. Consider an imaginary ion 22 X . The nucleus
contains ‘a’% more neutrons than the number of
electrons in the ion. The value of ‘a’ is ________.
(2) [nearest integer] [JEE (Main)-2022]

81. Given below are two statements. One is labelled

as Assertion A and the other is labelled as
Reason R.

Assertion A: Energy of 2s orbital of hydrogen atom

is greater than that of 2s orbital of lithium.
(3)
Reason R : Energies of the orbitals in the same
subshell decrease with increase in the atomic number.

In the light of the above statements, choose the

correct answer from the options given below.
[JEE (Main)-2022]

(4) (1) Both A and R are true and R is the correct

explanation of A.
(2) Both A and R are true but R is NOT the
correct explanation of A.
77. Which of the following sets of quantum numbers
(3) A is true but R is false.
is not allowed?
(4) A is false but R is true.
[JEE (Main)-2022]
82. The correct decreasing order of energy for the
1
(1) n 3, l 2, ml 0, s  orbitals having, following set of quantum numbers:
2

1 (A) n = 3, l = 0, m = 0 (B) n = 4, l = 0, m = 0
(2) n 3, l 2, ml 2, s 
2 (C) n = 3, l = 1, m = 0 (D) n = 3, l = 2, m = 1
1 [JEE (Main)-2022]
(3) n 3, l 3, ml 3, s 
2
(1) (D) > (B) > (C) > (A) (2) (B) > (D) > (C) > (A)
1 (3) (C) > (B) > (D) > (A) (4) (B) > (C) > (D) > (A)
(4) n 3, l 0, ml 0, s 
2
83. Identify the incorrect statement from the following.
78. When the excited electron of a H atom from n =
5 drops to the ground state, the maximum number [JEE (Main)-2022]
of emission lines observed are ____. (1) A circular path around the nucleus in which
an electron moves is proposed as Bohr’s
[JEE (Main)-2022]
orbit.
79. The wavelength of an electron and a neutron will (2) An orbital is the one electron wave function
become equal when the velocity of the electron is (<) in an atom.
x times the velocity of neutron. The value of x is (3) The existence of Bohr’s orbits is supported
______. (Nearest integer) by hydrogen spectrum.
(4) Atomic orbital is characterised by the
(Mass of electron is 9.1 × 10–31 kg and mass of
quantum numbers n and l only.
neutron is 1.6 × 10–27 kg) [JEE (Main)-2022]
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84. If the wavelength for an electron emitted from B. n = 4, l = 1, ml = 0, ms = +1/2
H-atom is 3.3 × 10–10 m, then energy absorbed by
C. n = 4, l = 2, ml = –2, ms = –1/2
the electron in its ground state compared to
minimum energy required for its escape from the D. n = 3, l = 1, ml = –1, ms- = +1/2
atom, is ______ times. (Nearest integer) The correct order of increasing energy is

[Given : h = 6.626 × 10–34 J s] [JEE (Main)-2022]

[Mass of electron = 9.1 × 10–31 kg] (1) D < B < A < C (2) D < A < B < C
[JEE (Main)-2022] (3) B < D < A < C (4) B < D < C < A
85. The minimum uncertainty in the speed of an
87. lf the work function of a metal is 6.63 × 10–19 J, the
electron in one dimensional region of length 2a0
(Where a0 = Bohr radius 52.9 pm) is ___ km s–1. maximum wavelength of the photon required to

(Given : Mass of electron = 9.1 × 10–31 kg, Planck’s remove a photoelectron from the metal is ______
constant h = 6.63 × 10 –34
Js) [JEE (Main)-2022]
nm. (Nearest integer)
86. Given below are the quantum numbers for 4
[Given : h = 6.63 × 10–34 J s, and c = 3 × 108 m s–1]
electrons.
[JEE (Main)-2022]
A. n = 3, l = 2, ml = 1, ms = +1/2

‰‰‰

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Chapter 2

Structure of Atom
1. Answer (1) 5. Answer (3)
h h
O= 1 ª1 1º
p mv RHZ2 « 2 – 2 »
O ¬« n1 n2 ¼»
6.63 u 10 34
or O = 0.4 nm
1.67 u 10 27 u 103
2. Answer (2) ª1 1º ª 1 1 º
? (1)2 « 2 – 2 » (2)2 « 2 – »
«¬ n1 n2 »¼ ¬ (2) (4)2 ¼
h
' p ˜ 'x t
4S
1 1 3
h – 2
'x n12 n2 4
4 S ˜ m 'V
Ÿ n1 = 1, n2 = 2
6.6 u 1034 u 100
= 6. Answer (1)
4 u 3.14 u 9.1u 1031 u 600 u 0.005
= 1.92 × 10–3 m 7. Answer (1)

3. Answer (1) E1 2.178 u1018 J

hc
E
O § 1·
E2 2.178 u1018 ¨ ¸ J
©4¹
242 u103
E J / atom
6.023 u1023
hc 3
E2  E1 2.178 u u10 18
242 u10 3
6.6 u10 34 8
u 3 u10 O 4
?
6.023 u1023 O
6.62 u10 34 u 3 u108 u 4
19.8 u10 26 u 6.023 u1023 O 1.214 u10 7 m
O 0.494 u10 6 2.178 u 3 u10 18
242 u103
8. Answer (2)
= 494 nm
4. Answer (3) Na(g) oNa  (g)  e, 'HIE 5.1 eV
2
EHe ZHe 

2 Na  (g)  e oNa(g), 'Heg 5.1 eV

ELi2 ZLi2

19.6 u10 18 4 9. Answer (1)

ELi2 9 37 o 1s22s22p63s23p63d104s24p65s1

9 So last electron enters 5s orbital

ELi2 u19.6 u10 18
4
1
= 4.41 × 10–17 J/atom Hence n = 5, l = 0, ml = 0, ms r
2
? Energy of orbit of Li+2 is –4.41 × 10–17 J/atom
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10. Answer (3) (d) As l increases , the peak of \ vs r shifts
towards higher ‘r’ value.
Energy of excited state is negative and correspond
to n > 1. 3s Node
3p 3d Node
–13.6 –13.6
n= = = 4 =2
Eexcited state –3.4 0

11. Answer (3) 5 a0 10 a0 15 a0

r
Kinetic energy of electron is = e × V 15. Answer (4)
As per de-Broglie's equation
hQincident hQ th  KE

h h KE is independent of intensity and number of

O photoelectrons does not depend on frequency of
2mEk 2meV
light.

h Ÿ KE = hQincident – hQ th
? 2meV
O 16. Answer (2)
12. Answer (2) Energy in nth state as per Bohr’s model

Z2
n2 = 13.6 u eV
r = a0 = 0.529 ×4 = 2.12 Å n2
Z
? 2nd excited state
Ÿ n=3
13. Answer (4)
22
? E3 ,He 13.6 u eV
§ 1 1· 32
Q RH ¨ 2 – 2 ¸ Z2 Z 1
¨n ¸
© 1 n2 ¹ –6.04 eV
17. Answer (4)
§ 1 1 ·
Q RH ¨ 2  2 ¸ 1 § 1 1·
©n 8 ¹ R¨ 2  2 ¸
O © n1 n2 ¹
RH RH n1 3, n2 f
Q 
n2 64
1 § 1· 9 9
R¨ ¸ Ÿ O 9 u 10 5 cm
y = mx + c O ©9¹ R 105
= 900 nm
1
x= , m = –RH (slope) 18. Answer (3)
n2
According to de-Broglie wavelength equation
14. Answer (1)
h 1
O Ÿ Ov
nh mv v
(a) Angular momentum (L) =
2S From photoelectric effect.

So, as n increases, L increases. 1

hQ– hQ0 = mv 2
2
n2
(b) r v v v (Q – Q0)1/2
Z
1
h ? Ov 1/2
(c) For n = 1, L =
2S
Q  Q0

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19. Answer (2) 23. Answer (1)

12400 Q v 'E
Ephoton 3.1 eV
4000
For H-atom,
1 1
KE e mv 2 u 9 u 10 31 u 36 u 1010 J
2 2 ª1 1º
Q R« 2  2 »
1.62 × 10–19 J  1 eV «¬ n1 n2 »¼
? Work function 3.1 – 1 2.1 eV
For Lyman series,
20. Answer (3)
nO = 2Sr § 1·
Q (max) v 13.6 ¨ 1  ¸
© f¹
n2
r a0
z
§ 1·
Q (min) v 13.6 ¨ 1  ¸
2Sa0n2 © 4¹
nO
z
§ 1·
2Sa0n2 ? Qmax  Qmin v 13.6 ¨ ¸
O ©4¹
z
For Balmer series,
n
1.5Sa0 2Sa0
2
§1 1·
Q (max) v 13.6 ¨  ¸
n 3 ©4 f¹
0.75
z 4
21. Answer (1) § 1 1·
Q (min) v 13.6 ¨  ¸
n+l ©4 9¹

(I) n = 4 l=2 4d 6
§ 1·
(II) n = 3 l=2 3d 5 ? Q min  Q min v 13.6 ¨ ¸
©9¹
(III) n = 4 l=1 4p 5
(IV) n = 3 l=1 3p 4 Q Lyman 9
more is n + l value, more is energy Q Balmer 4
3p < 3d < 4p < 4d
24. Answer (4)
22. Answer (2)
The total energy of the electron is minimum when it
In photoelectric effect, is at a distance a0 from the nucleus for 1s orbital.

hc 25. Answer (2)

= w + KE of electron
O The given probability density curve is for 2s orbital
It is given that KE of ejected electron is very high in because it has only one radial node. Among other
comparison to w. given orbitals, 1s and 2p do not have any radial node
and 3s has two radial nodes.
hc hc P2
KE Ÿ radial node
O O 2m
New wavelength < 2

hc (1.5P)2 4
Ÿ Oc O r
O1 2m 9

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26. Answer (3) 32. Answer (3)

Shortest wavelength means n2 = f According to Bohr’s model

n2
1 1 rn ua0 (a 0 1st Bohr radius)
Lyman series QL 1312 u u 12 Z
OL 12
' 2Sr nO (using de-Broglie relation)

Paschen series QP
1
1312 u
1
u 12 42
Ÿ 2S u ua0 4O
OP 3 2
1
Ÿ O 8Sa 0
QL OP
9
QP OL 33. Answer (2)
Explanation of variation of internal energy of Ar with
27. Answer (1) temperature (Straight line and U v T) is not a direct
Probability of finding an electron is given by 4Sr2dr manifestation of the quantum nature of atoms.
< 2 and it will have maximum value at both ‘a’ While explanation of absorption spectrum, nature of
and ‘c’. emission of radiation from hot bodies (black body
28. Answer (2) radiation) and photoelectric effect are direct
manifestation of the quantum nature of atoms.
As the value of Z (atomic number) increases, energy
34. Answer (1)
of orbitals decreases (becomes more –ve value)
2 subshells are associated with n = 4 and
? order of energy of 2s orbital is m = –2.
H > Li > Na > K 35. Answer (3)
29. Answer (3) In the hydrogen spectrum,

The number of orbitals possible in a shell with Balmer series lies in visible region.
principal quantum number ‘n’ is ‘n2’. 36. Answer (4)

30. Answer (1) Shortest wavelength o Max energy (f o 1) (Lyman

series)
In Balmer series of H-atom, the electronic
1 ª1 º
transitions take place from higher orbits to 2nd orbit R H (1) 2 « – 0»
O1 ¬1 ¼
and the longest wavelength will correspond to
transition from 3rd orbit to 2nd orbit. 1 1
RH Ÿ RH
? n1 = 2 and n2 = 3 for longest wavelength. O1 O1
As wavelength decreases the lines in the Balmer For Balmer series,
series converge. The correct statements are (I), (II)
1 ª 1 1 º 1 §94·
and (III). = R H (2) 2 « – » Ÿ = R H (4) ¨ ¸
O ¬2 2 2
3 ¼ O © 36 ¹
31. Answer (1)
1 5R H 9 9O 1
= Ÿ O=
n2 O 9 5R H 5
r 0.529 Å
Z
37. Answer (3)
Bohr’s radius for hydrogen atom (a0) = 0.529 Å
n2
Bohr’s radius of Li+2 ion for n = 2 rn a0
Z
n2
a0 n2
Z rn v
Z
4a 0
'R 1 Z 2
3 He 
? 'R 2 Z 3
Li 2 

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38. Answer (2) V
Frequency of revolution v
2
r
\ (probability density) can be zero for 3p orbital
ZuZ
other than infinite distance. It has one radial node. v
n u n2
39. Answer (222)
Z2
w, work function of sodium metal v
n3
= 4.41 × 10–19 J
mV 2
O, wavelength of incident light = 300 nm Force of attraction
r
= 3 × 10–7 m
V2
According to photoelectric effect Force of attraction v
r
hc
w  KE Z2 u z
O v
n2 u n2
34
6.63 u 10 u 3 u 10 8
4.41u 10 19  KE
3 u 107 Z3
v
6.63 × 10–19 = 4.41 × 10–19 + KE n4

KE = 2.22 × 10–19 J = 222 × 10–21 J Correct statements : (A) and (D).

40. Answer (2) 42. Answer (2)

3s orbital has 2 radial nodes
h h
de-Broglie wavelength (O) = mV Number of radial nodes = n – (l + 1)
2m(K.E.)
? Graph (A) can be for 1s
When a charge particle is accelerated by potential Graph (B) can be for 2s
difference (V) then increase in
K.E. = q.V Graph (C) can be for 2p
Graph (D) can be for 3s
h
OLi
2 u mp u 8.3 u 3 u V 43. Answer (181)
Ionisation energy of an atom of metal
h A = Quantum energy of radiation of wavelength 663
Op
2 u mp u 1u V nm

OLi h 2 u mp u V 1 6.63 u 10 34 u 3 u 108

? u  J 3 u 10 19 J
Op 2 u 24.9 u mp u V h 5 663 u 10 9
= 2 × 10–1 Ionisation energy per mol
41. Answer (2) = 3 × 10–19 × 10–3 × 6.02 × 1023
In Bohr’s atomic theory:
= 180.6 kJ mol–1 
181
Z2 44. Answer (3)
K.E. v
n2
Number of radial nodes = (n – l – 1)
Z
Velocity (v) v Number of angular nodes = l
n
? V.n v Z for 5d; n = 5, l = 2
5d orbital has two radial nodes and two angular
V
Frequency of revolution nodes
2 Sr
So, the correct option should be (3)
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45. Answer (1) 49. Answer (49)
According to Heisenberg uncertainty principle Fe(Z = 26)
Electronic configuration : 4s23d6
h
'x'p t
4S

h
'x ( 'P m'V)
4Sm'V n=4

?P 4 42 24 BM
6.63 u 10 34 Js
4 u 3.14 u 10 u 10 3 kg u 90 ms 1 u 0.05 = 4.89
| 49 × 10–1 BM
= 1.173 × 10–33 m
50. Answer (2)
= 1 × 10–33 m
Bohr’s theory is applicable for unielectronic species
46. Answer (9)
only
Incident energy of Work function of  K.E. of Li+ has two electrons
photon metal photoelectron
Bohr’s theory could not explain the splitting of
hQ = hQ0 + KE spectral lines in the presence of external magnetic
field (Zeeman effect)
6.63 u 10 34 Js u 3 u 108 ms 1 Statement I – false
3.0  K. E.
248 u 10 9 m u 1.6 u 10 19 J eV 1
Statement II – true
K. E. = 2.0 eV 51. Answer (3)
3s has no angular node two radial nodes.
h 6.63 u 1034
O 52. Answer (0)
2m K. E. 2 u 9.1u 1031 u 2 u 1019 u 1.6
Ga – 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p1
= 8.68 × 10–10 m | 9 Å Ga+ – 1s2 2s2 2p6 3s2 3p6 4s2 3d10
47. Answer (03) 4s2 are the valence electrons, so l = 0.
n=5 53. Answer (6)
Possible values of A = 4, 3, 2, 1, 0 Wavelength of electron is given by
mA = 2 is possible for A = 4, 3 & 2
h
O
as mA takes values from (– A to A) 2mqV
? Possible orbitals (n, A, mA) : (5, 4, 2) (5, 3, 2)
Here q = charge on electron, V = potential
(5, 2, 2)
difference
48. Answer (0)
6.63 u 10 –34
The orbital having n = 4 and mL = –3 is 4f. O
2 u 9.1u 10 –31 u 1.6 u 10 –19 u 40 u 103
The number of radial nodes is an orbital is given by
Number of radial nodes = n – mL –1
6.63 u 10 –34
6.144 u 10 –12 | 6 × 10–12
=4–3–1
1164.8 u 10 –47
=0
x=6

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54. Answer (12) 59. Answer (2)
Vanadium (Z = 23)
Z
vn 2.18 u 106 u m/s
V = 1s2 2s2 2p6 3s2 3p6 3d3 4s2 n
Number of electrons in p-orbital are 12 Qualitatively the magnitude of velocity of electron
55. Answer (2) increases with increase of positive charge on the
nucleus and decreases with increase of principal
E = nhQ
quantum number.

n u 6.626 u 10–34 u 3 u 108 60. Answer (5)

1000 –9
400 u 10
1
hQ hQ 0  me v 2
n = 20.122 × 1020 photons incidented on metal 2
surface in 10 seconds
6.63 u 10 34 u 3 u 108
n = 2.0122 × 1020 photon incidented on metal
surface in 1 second 500 u 10 9

Number of electrons ejected equal to number of

34 1
photon incidented.
14
= 6.63 u 10 u 4.3 u 10  u 9 u 10 31 u v 2
2
56. Answer (58)
v | 5 u 105 ms1
0.02
Uncertainty in speed of electron = u 5 u 106 61. Answer (3155)
100

= 103 ms–1 Kinetic energy of an electron in nth orbit of Bohr

2
h 1 mv n2 h2
m'v × 'x = mv 2
atom 2 2m
4S 2 4S2 mr 2

For 2nd orbit of H-atom

6.63 u 10 –34
'x =
4 u 3.14 u 9.1 u 10 –31 u 103 n = 2 and r = 4a0

h2 h2
5.80 u 10 –8 m = 58.00 × 10–9 m ? KE
8 S 2m × 4a02 315.5 ma02
57. Answer (4)
? x = 315.5; 10x = 3155
One of the drawback of Rutherford model is that,
it says nothing about the electronic structure of 62. Answer (50)
atom. It cannot explain the line spectra of hydrogen Power = 1 mW
atom.
= 10–3 J in 1 sec.
Since uncertainty principle rules out existence of
= 10–4 J in 0.1 sec.
definite paths or trajectories of electrons and other
similar particles. So Bohr’s model contradicts nhc
H.U.P. ? Energy =
O
58. Answer (2)
According to thompson model of atom, the mass n u 6.63 u 10 34 u 3 u 108
104
of each gold atom is uniformly distributed. And as 1000 u 10 9
the D-particles had enough energy to pass directly
n = 50.2 × 1013
through such mass, it slowed down with small
changes in its directions. ? x | 50

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63. Answer (7) hc
' E
Ge (32) = 1s2 2s2 2p6 3s2 3p6 O
4s2 3d10 4p2
9 6.63 u 1034 u 3 u 108
2.2 u 10 18 u
ml = 0 1s, 2s, 2pz, 3s, 3pz, 4s, 3d
z2
4 O

64. Answer (2) O 4 u 10 8 m

E = nhQ 69. Answer (3)
50 watt bulb emits 50 J energy per second. The minimum energy possessed by photons will be
equal to the work function of the metal.
n u 6.63 u 1034 u 3 u 108
50
795 u 10 9 Hence,

w0 = hQ0
50 u 795 u 10 9
n
6.63 u 1034 u 3 u 108 = 6.6 × 10–34 × 1.3 × 1015

= 8.58 × 10–19 J
n | 2 u 1020
70. Answer (2)
65. Answer (2)
For degenerate orbitals, only the value of m must be n2
rn r0
Z
different. The value of ‘n’ and ‘l’ must be the same.

Hence, the pair of electrons with quantum numbers 42

r4 r0 u
given in (B) are degenerate. 1

66. Answer (3) 32

and r3 r0 u
1
Wavelength of radiation = 300 nm
r4 42 16
hc Therefore Ÿ r4 r3
Photon energy = r3 32 9
O
71. Answer (1)
34 8
6.63 u 10 u 3 u 10 n 4d n=4 l=2
=
300 u 109
Radial nodes =n–l–1
= 6.63 × 10–19 J
=4–2–1
Energy of 1 mole of photons
=1
= 6.63 × 10–19 × 6.02 × 1023 × 10–3
Angular nodes = l
= 399 kJ
=2
67. Answer (4)
72. Answer (22)
O2–, Mg2+ and Al3+ are isoelectronic. All have 10
electrons. 'v 2.4 u 1026 m s1
68. Answer (4)
'x 10 7 m
Energy required for ionisation of Li atom
h
? mt
9 4S( 'x)( 'v)
= 2.2 × 10–18 × J [Assume this formule is
4
6.626 u 1034
True for Li atom] t
4 u 3.14 u (10 7 )(2.4) u 10 26

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 79. Answer (1758)
6.626 u 101
t
4 u 2.4 u 3.14 h h
Oe , ON
me u Ve mN u VN
t 0.02198 kg
? Mass of the particle  22 g Oe ON When Ve xVN
73. Answer (2) 1 1
me Ve mN u VN
The correct sets of Quantum numbers are, (02)
mN Ve
n=3 l=2 ml = –2 x
me VN
and n = 2 l=1 ml = +1
1.6 u 10 –27
x = 0.17582 × 104
I can have values from 0 to (n – 1) and m can have 9.1u 10 –31

values from –l..... 0 ......+l (2l + 1)  1758

74. Answer (3) 80. Answer (4)

Possible values of l for a given ‘n’ = 0,1,2 …(n – 1) 48 3 

Number of electrons in 22 X is 25.

For l = 5, total orbitals = 2l + 1 Number of neutrons = 48 – 22 = 26.

% increase in the number of neutrons over
= 2(5) + 1 = 11 orbital
electrons
Hence A, C and D are correct statements § 26  25 ·
= ¨ ¸ 100 4%
75. Answer (4) © 25 ¹
Cr = (Ar)3d54s1 ? a=4
M = +l to –l 81. Answer (1)

As per Aufbau principle, orbitals are filled in As the atomic number increases then the potential

increasing order of energy. energy of electrons present in same shell becomes

more and more negative. And therefore total energy
Total number of nodes = (n – 1)
also becomes more negative.
76. Answer (2)
Z2
2s Etotal 13.6 eV
n2
radial node = n – l – 1 ? Energies of the orbitals in the same subshell
decreases with increase in atomic number.
=2–0–1
82. Answer (1)
=1
Energy of an orbital is directly proportional to the
It will have one radial node (n + l) value
77. Answer (3)
(n + l)
If n = 3, then possible values of l = 0, 1, 2
(A) n = 3, l=0 3
But in option (3), the value of l is given ‘3’, this is
not possible. (B) n = 4, l=0 4
78. Answer (4)
(C) n = 3, l=1 4
Since there is a single hydrogen atom, so only
(D) n = 3, l=2 5
5 o 4, 4 o 3, 3 o 2, 2 o 1 lines are obtained.

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 If n + l value is same then the orbital with lower 85. Answer (548)
value of ‘n’ will have lower energy.
h
'x.'v t
? correct order of energy 4Sm
D>B>C>A
'x = 2 × 52.9 × 10–12 m
83. Answer (4)

Atomic orbital is characterised by the quantum 6.63 u 10 –34

'v t
numbers n, l and m. 4 u 3.14 u 9.1u 10 –31 u 2 u 52.9 u 10 –12
Hence option D is incorrect.
'v t 5.48 u 10 –4 u 109 m/s

84. Answer (2)

'v t 548 km/s (Rounded off to the nearest
h integer)
O=
mv
86. Answer (2)

34 m2 Energy of the sub-shell is given by, (n + l) rule.

h 6.626 u 10 kg u sec
Ÿ mv = = sec 2
O
3.3 u 10 10 m (n + l)

For, A 5
6.626 u 1024
mv = 2 u 1024 kg m sec 1
3.3 B 5

1 C 6
Kinetic energy = mv 2
2
D 4
2
mv Hence, the correct order of increasing energy is
=
2m D <A< B < C

2 87. Answer (300)

2 u 10 24
=
2 u 9.1u 10 31 kg hc
' E
O
= 2.18 × 10–18 J

= 21.8 × 10–19 J
6.63 u 10 34 u 3 u 108
Total energy = Ionization + Kinetic 6.63 u 1019
O
absorbed energy energy

= (21.76 + 21.8) × 10–19 O 3 u 10 7 m

= 300 × 10–9 m
= 43.56 × 10–19 J
= 300 nm
| 2 times of 21.76 × 10–19 J

‰‰‰

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