Chapter 2

Structure of Atom
1. Calculate the wavelength (in nanometer) associated 6. The electrons identified by quantum numbers n
with a proton moving at 1.0 × 103 ms–1 and l
(Mass of proton = 1.67 × 10–27 kg and h = 6.63 × (a) n = 4, l = 1 (b) n = 4, l = 0
10–34 Js) [AIEEE-2009] (c) n = 3, l = 2 (d) n = 3, l = 1
(1) 0.40 nm (2) 2.5 nm can be placed in order of increasing energy as
(3) 14.0 nm (4) 0.032 nm [AIEEE-2012]

2. In an atom, an electron is moving with a speed of (1) (d) < (b) < (c) < (a)
600 m/s with an accuracy of 0.005%. Certainty with (2) (b) < (d) < (a) < (c)
which the position of the electron can be located is
(3) (a) < (c) < (b) < (d)
(h = 6.6 × 10–34 kg m2s–1, mass of electron, em = 9.1
× 10–31 kg) [AIEEE-2009] (4) (c) < (d) < (b) < (a)

(1) 5.10 × 10–3 m (2) 1.92 × 10–3 m 7. Energy of an electron is given by

(3) 3.84 × 10–3 m (4) 1.52 × 10–4 m § Z2 ·

E = -2.178×10 -18 J ¨ 2 ¸. W avelength of light
¨n ¸
3. The energy required to break one mole of Cl – Cl © ¹
bonds in Cl 2 is 242 kJ mol –1 . The longest required to excite an electron in an hydrogen atom
wavelength of light capable of breaking a single form level n = 1 to n = 2 will be
Cl – Cl bond is
(h = 6.62 × 10–34 Js and c = 3.0 × 108 ms–1)
(c = 3 × 108 ms–1 and NA = 6.02 × 1023 mol–1) [JEE (Main)-2013]
[AIEEE-2010]
(1) 1.214 × 10–7 m (2) 2.816 × 10–7 m
(1) 494 nm (2) 594 nm
(3) 6.500 × 10–7 m (4) 8.500 × 10–7 m
(3) 640 nm (4) 700 nm
8. The first ionisation potential of Na is 5.1 eV. The
4. Ionisation energy of He+ is 19.6 × 10–18 atom–1. value of electron gain enthalpy of Na+ will be
The energy of the first stationary state (n = 1) of [JEE (Main)-2013]
Li2+ is [AIEEE-2010] (1) –2.55 eV (2) –5.1 eV
(1) 8.82 × 10–17 J atom–1 (3) –10.2 eV (4) +2.55 eV
(2) 4.41 × 10–16 J atom–1 9. The correct set of four quantum numbers for the
(3) –4.41 × 10–17 J atom–1 valence electrons of rubidium atom (Z = 37) is
[JEE (Main)-2014]
(4) –2.2 × 10–15 J atom–1
5. The frequency of light emitted for the transition 1 1
(1) 5, 0, 0, + (2) 5,1, 0, +
n = 4 to n = 2 of He + is equal to the transition in 2 2
H atom corresponding to which of the following
[AIEEE-2011] 1 1
(3) 5,1,1, + (4) 5, 0,1, +
2 2
(1) n = 4 to n = 3
10. Which of the following is the energy of a possible
(2) n = 3 to n = 1
excited state of hydrogen? [JEE (Main)-2015]
(3) n = 2 to n = 1
(1) +13.6 eV (2) –6.8 eV
(4) n = 3 to n = 2
(3) –3.4 eV (4) +6.8 eV
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11. A stream of electrons from a heated filament was towards higher r value. [JEE (Main)-2019]
passed between two charged plates kept at a
(1) (a), (d) (2) (b), (c)
potential difference V esu. If e and m are charge
and mass of an electron, respectively, then the (3) (a), (c) (4) (a), (b)
h 15. W hich of the graphs shown below does not
value of (where O is wavelength associated with
O represent the relationship between incident light and
electron wave) is given by [JEE (Main)-2016] the electron ejected from metal surface?
(1) 2meV [JEE (Main)-2019]
(2) meV
(3) 2meV K.E.
of e s
(4) meV
12. The radius of the second Bohr orbit for hydrogen
atom is (1)
0
(Planck's Const. h = 6.6262 × 10–34 Js; Energy of
Light
mass of electron = 9.1091 × 10–31 kg;
charge of electron e = 1.60210 × 10–19 C;
Number
permittivity of vacuum
of e s
H0 = 8.854185 × 10–12 kg–1 m–3 A2)
[JEE (Main)-2017]
(2)
(1) 0.529 Å (2) 2.12 Å
0 Frequency of
(3) 1.65 Å (4) 4.76 Å Light
13. For emission line of atomic hydrogen from ni = 8
G
to nf = n, the plot of wave number ( Q ) against
K.E.
§ 1· of e s
¨ 2 ¸ will be (The Rydberg constant, RH is in wave
©n ¹
number unit) [JEE (Main)-2019] (3)
(1) Linear with slope RH 0 Intensity of
LIght
(2) Linear with intercept –RH
(3) Non-linear
(4) Linear with slope –RH K.E.
of e s
14. Which of the following combination of statements
is true regarding the interpretation of the atomic
orbitals? (4)

(a) An electron in an orbital of high angular 0 Frequency of

momentum stays away from the nucleus than Light
an electron in the orbital of lower angular 16. The ground state energy of hydrogen atom is
momentum –13.6 eV. The energy of second excited state of
(b) For a given value of the principal quantum He+ ion in eV is [JEE (Main)-2019]
number, the size of the orbit is inversely (1) –27.2 (2) –6.04
proportional to the azimuthal quantum number.
(3) –54.4 (4) –3.4
(c) According to wave mechanics, the ground
17. Heat treatment of muscular pain involves radiation of
h
state angular momentum is equal to wavelength of about 900 nm. Which spectral line of
2S
H-atom is suitable for this purpose?
(d) The plot of \ Vs r for various azimuthul
quantum numbers, shows peak shifting [RH= 1 × 105 cm, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1]

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[JEE (Main)-2019] 22. If p is the momentum of the fastest electron

ejected from a metal surface after the irradiation of
(1) Balmer, fo 2 (2) Lyman, fo 1
light having wavelength O, then for 1.5 p momentum
(3) Paschen, 5 o 3 (4) Paschen, fo 3 of the photoelectron, the wavelength of the light
18. The de Broglie wavelength (O) associated with a should be
photoelectron varies with the frequency (Q) of the (Assume kinetic energy of ejected photoelectron to be
incident radiation as, [Q0 is threshold frequency] very high in comparison to work function):
[JEE (Main)-2019] [JEE (Main)-2019]

1 1 3 4
(1) O v (2) O v (1) O (2) O
 Q  Q0  Q
1

 Q0 4
4 9

2 1
1 1 (3) O (4) O
(3) O v 1
(4) O v 3
3 2
 Q  Q0  2  Q  Q0  2 23. For any given series of spectral lines of atomic
19. What is the work function of the metal if the light hydrogen, let 'Q Qmax  Qmin be the difference in
of wavelength 4000 Å generates photoelectrons of maximum and minimum frequencies in cm–1. The
velocity 6 × 105 ms–1 from it? ratio 'QLyman / 'QBalmer is [JEE (Main)-2019]
(Mass of electron = 9 × 10–31 kg
(1) 9 : 4 (2) 27 : 5
Velocity of light = 3 × 108 ms–1
(3) 4 : 1 (4) 5 : 4
Planck’s constant = 6.626 × 10–34 Js
24. Which one of the following about an electron
Charge of electron = 1.6 × 10–19 JeV–1) occupying the 1s orbital in a hydrogen atom is
[JEE (Main)-2019] incorrect? (The Bohr radius is represented by a0)

(1) 4.0 eV (2) 2.1 eV [JEE (Main)-2019]

(3) 3.1 eV (4) 0.9 eV (1) The probability density of finding the electron is
maximum at the nucleus
20. If the de Broglie wavelength of the electron in nth
Bohr orbit in a hydrogenic atom is equal to 1.5 Sa0 (2) The electron can be found at a distance 2a0
(a0 is Bohr radius), then the value of n/z is from the nucleus
(3) The magnitude of the potential energy is double
[JEE (Main)-2019]
that of its kinetic energy on an average
(1) 0.40 (2) 1.50
(4) The total energy of the electron is maximum
(3) 0.75 (4) 1.0 when it is at a distance a0 from the nucleus
21. The quantum number of four electrons are given 25. The graph between |\|2 and r(radial distance) is
below shown below. This represents [JEE (Main)-2019]
1
(I) n = 4, l = 2, ml = –2, ms = –
2
|\|2
1
(II) n = 3, l = 2, ml = 1, ms = +
2
1 r
(III) n = 4, l = 1, ml = 0, ms = + (1) 1s orbital (2) 2s orbital
2
1 (3) 2p orbital (4) 3s orbital
(IV) n = 3, l = 1, ml = 1, ms = –
2 26. The ratio of the shortest wavelength of two spectral
The correct order of their increasing energies will series of hydrogen spectrum is found to be about
be [JEE (Main)-2019] 9. The spectral series are [JEE (Main)-2019]

(1) IV < II < III < I (2) I < III < II < IV (1) Paschen and Pfund (2) Brackett and Pfund

(3) IV < III < II < I (4) I < II < III < IV (3) Lyman and Paschen (4) Balmer and Brackett

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27. The electrons are more likely to be found 32. The de Broglie wavelength of an electron in the 4th
Bohr orbit is [JEE (Main)-2020]
[JEE (Main)-2019]
(1) 4Sa0 (2) 6Sa0
(3) 8Sa0 (4) 2Sa0
a < (x)
33. The figure that is not a direct manifestation of the
b x quantum nature of atoms is [JEE (Main)-2020]
–x o Increasing wavelength
c
(1)

(1) In the region a and c (2) Only in the region c

Absorption spectrum
(3) Only in the region a (4) In the region a and b
28. Among the following, the energy of 2s orbital is Internal
energy
lowest in [JEE (Main)-2019] of
(2)
Ar 300 400 500 600
(1) Li (2) K
(3) H (4) Na Temperature (K)

29. The number of orbitals associated with quantum T2 > T1

Intensity
1
numbers n = 5, ms =  is [JEE (Main)-2020] (3) of radiation
black body
2 T1

(1) 15 (2) 50 Wavelength

(3) 25 (4) 11 Rb K
Na
30. For the Balmer series in the spectrum of H atom, Kinetic
energy of
(4) photoelectrons
­° 1 1 ½°
Q =RH ® 2 – 2 ¾, the correct statements among (I) Frequency of incident
°¯ n1 n2 °¿ radiation
to (VI) are 34. The number of subshells associated with n = 4 and
m = –2 quantum numbers is [JEE (Main)-2020]
(I) As wavelength decreases, the lines in the
series converge (1) 2 (2) 8
(3) 4 (4) 16
(II) The integer n1 is equal to 2
35. The region in the electromagnetic spectrum where
(III) The lines of longest wavelength corresponds to the Balmar series lines appear is
n2 = 3
[JEE (Main)-2020]
(IV) The ionization energy of hydrogen can be (1) Microwave (2) Ultraviolet
calculated from wave number of these lines
(3) Visible (4) Infrared
[JEE (Main)-2020] 36. The shortest wavelength of H atom in the Lyman
(1) (I), (II), (III) (2) (II), (III), (IV) series is O1. The longest wavelength in the Balmar
series of He+ is [JEE (Main)-2020]
(3) (I), (III), (IV) (4) (I), (II), (IV)
5O1 36O1
31. The radius of the second Bohr orbit, in terms of the (1) (2)
9 5
Bohr radius, a0, in Li2+ is [JEE (Main)-2020]
27O1 9O1
4a0 4a0 (3) (4)
5 5
(1) (2)
3 9 37. The difference between radii of 3rd and 4th orbits of
Li2+ is 'R1. The difference between the radii of 3rd
2a0 2a0
(3) (4) and 4 th orbits of He + is 'R 2 . Ratio
3 9 'R1 : 'R2 is [JEE (Main)-2020]

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(1) 3 : 2 (2) 8 : 3 42. The plots of radial distribution functions for various
(3) 2 : 3 (4) 3 : 8 orbitals of hydrogen atom against ‘r’ are given below

38. The correct statement about probability density

8
(except at infinite distance from nucleus) is

4Sr R2n, l (r)

[JEE (Main)-2020] (A) 4

2
(1) It can never be zero for 2s orbital
0 10
(2) It can be zero for 3p orbital 5
r(Å)
(3) It can be zero for 1s orbital
(4) It can be negative for 2p orbital
3

4Sr Rn, l (r)

39. The work function of sodium metal is 2
4.41 × 10–19 J. If photons of wavelength 300 nm (B)

2
1

2
are incident on the metal, the kinetic energy of the
ejected electrons will be (h = 6.63 × 10–34 J s; 0
5 10
c = 3 × 108 m/s) ________ × 10–21 J. r(Å)
[JEE (Main)-2020]
40. A proton and a Li3+
nucleus are accelerated by the
3
same potential. If OLi and Op denote the de Broglie

4Sr Rn, l (r)

2
wavelengths of Li3+ and proton respectively, then (C)

2
1

2
O Li
the value of O is x × 10–1. 0
p 5 10
r(Å)
The value of x is _____. (Rounded off to the
nearest integer)
2.0
[Mass of Li3+ = 8.3 mass of proton]
4S r Rn, l (r)

1.5
[JEE (Main)-2021] (D)
2

1.0
2

41. According to Bohr’s atomic theory: 0.5

0
5 10
2 r(Å)
Z
(A) Kinetic energy of electron is v
n2
The correct plot for 3s orbital is
(B) The product of velocity (v) of electron and
principal quantum number (n), ‘vn’ v Z2 (1) (C) (2) (D)

(C) Frequency of revolution of electron in an (3) (B) (4) (A)

Z3 [JEE (Main)-2021]
orbit is v
n3 43. Electromagnetic radiation of wavelength
663 nm is just sufficient to ionise the atom of metal
(D) Coulombic force of attraction on the
A. The ionization energy of metal A in
Z3 kJ mol –1 is ____. (Rounded-off to the nearest
electron is v integer)
n4
[h = 6.63 × 10 –34 Js, c = 3.00 × 10 8 ms –1 ,
Choose the most appropriate answer from the
options given below: [JEE (Main)-2021] NA = 6.02 × 1023 mol–1] [JEE (Main)-2021]

(1) (A) only 44. The orbital having two radial as well as two
angular nodes is : [JEE (Main)-2021]
(2) (A) and (D) only
(1) 3p (2) 4d
(3) (C) only
(3) 5d (4) 4f
(4) (A), (C) and (D) only

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45. A ball weighing 10 g is moving with a velocity of 90 52. The Azimuthal quantum number for the valence
ms–1. If the uncertainty in its velocity is 5%, then the electrons of Ga+ ion is _______.
uncertainty in its position is ___________ × 10–33
(Atomic number of Ga = 31) [JEE (Main)-2021]
m. (Rounded off to the nearest integer)
53. The wavelength of electrons accelerated from rest
[Given : h = 6.63 × 10–34 Js] [JEE (Main)-2021]
through a potential difference of 40 kV is x × 10–2 m.
46. When light of wavelength 248 nm falls on a metal of The value of x is _______. (Nearest integer)
threshold energy 3.0 eV, the de-Broglie wavelength
of emitted electrons is ____ Å. (Round off to the Given: Mass of electron = 9.1 × 10–31 kg
Nearest Integer). Charge on an electron = 1.6 × 10–19 C
[Use : 3 = 1.73, h = 6.63 ×10-34 Js Planck’s constant = 6.63 × 10–34 Js
me = 9.1 × 10–31 kg; c = 3.0 × 108 ms–1 ; 1eV = [JEE (Main)-2021]
1.6 × 10–19J] [JEE (Main)-2021]
54. Number of electrons that Vanadium (Z = 23) has in
47. The number of orbitals with n = 5, m A = +2 is p-orbitals is equal to _______. [JEE (Main)-2021]
______.
55. A source of monochromatic radiation of wavelength
(Round off to the Nearest Integer). 400 nm provides 1000 J of energy in 10 seconds.
[JEE (Main)-2021] When this radiation falls on the surface of sodium,
x × 1020 electrons are ejected per second. Assume
48. A certain orbital has n = 4 and mL = –3. The number that wavelength 400 nm is sufficient for ejection of
of radial nodes in this orbital is __________. electron from the surface of sodium metal. The value
(Round off to the Nearest Integer). of x is _______. (Nearest integer)
[JEE (Main)-2021] (h = 6.626 × 10–34 Js) [JEE (Main)-2021]
49. In the ground state of atomic Fe(Z = 26), the 56. An accelerated electron has a speed of 5 × 10 6
spin-only magnetic moment is ______ × 10–1 BM. ms–1 with an uncertainty of 0.02%. The uncertainty
(Round off to the Nearest Integer). in finding its location while in motion is x × 10–9 m.
The value of x is _________. [JEE (Main)-2021]
[Given : 3 = 1.73, 2 = 1.41]
[Use mass of electron = 9.1 × 10–31 kg, h = 6.63
[JEE (Main)-2021] × 10–34 Js, S = 3.14]
50. Given below are two statements : 57. Given below are two statements :
Statement I : Bohr’s theory accounts for the Statement I : Rutherford’s gold foil experiment
stability and line spectrum of Li+ ion. cannot explain the line spectrum of
Statement II : Bohr’s theory was unable to explain hydrogen atom.
the splitting of spectral lines in the presence of a
Statement II : Bohr’s model of hydrogen atom
magnetic field.
contradicts Heisenberg’s
In the light of the above statements, choose the uncertainty principle.
most appropriate answer from the options given
In the light of the above statement, choose the
below. [JEE (Main)-2021]
most appropriate answer from the options given
(1) Both statement I and statement II are true below: [JEE (Main)-2021]
(2) Statement I is false but statement II is true (1) Both statement I and statement II are false.
(3) Both statement I and statement II are false (2) Statement I is true but statement II is false.
(4) Statement I is true but statement II is false
(3) Statement I is false but statement II is true.
51. A certain orbital has no angular nodes and two
(4) Both statement I and statement II are true.
radial nodes. The orbital is [JEE (Main)-2021]
58. If the Thompson model of the atom was correct, then
(1) 2p (2) 3p
the result of Rutherford’s gold foil experiment would
(3) 3s (4) 2s have been : [JEE (Main)-2021]

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(1) All D-particles get bounced back by 180° 63. Ge (Z = 32) in its ground state electronic
(2) D-particles pass through the gold foil deflected configuration has x completely filled orbitals with
by small angles and with reduced speed ml = 0. The value of x is _____.

(3) D-particles are deflected over a wide range of [JEE (Main)-2021]

angles 64. A 50 watt bulb emits monochromatic red light of
(4) All of the D-particles pass through the gold foil wavelength of 795 nm. The number of photons
without decrease in speed emitted per second by the bulb is x × 10 20. The
value of x is ______. (Nearest integer)
59. Given below are two statements :
[Given : h = 6.63 × 10–34 Js and c = 3.0 × 108 ms–1]
Statement I : According to Bohr’s model of an
atom, qualitatively the magnitude of velocity of [JEE (Main)-2021]
electron increases with decrease in positive 65. Consider the following pairs of electrons
charges on the nucleus as there is no strong hold
on the electron by the nucleus. [JEE (Main)-2022]

Statement II : According to Bohr’s model of an 1

atom, qualitatively the magnitude of velocity of A (a) n 3, l 1, mA 1, ms 
2
electron increases with decrease in principal
quantum number. 1
(b) n 3, l 2, mA 1, ms 
In the light of the above statements, choose the 2
most appropriate answer from the options given
below : [JEE (Main)-2021] 1
B (a) n 3, l 2, mA 2, ms 
(1) Both Statement I and Statement II are false 2

(2) Statement I is false but Statement II is true

1
(b) n 3, l 2, mA 1, ms 
(3) Both Statement I and Statement II are true 2
(4) Statement I is true but Statement II is false
1
60. A metal surface is exposed to 500 nm radiation. The C (a) n 4, l 2, mA 2, ms 
2
threshold frequency of the metal for photoelectric
current is 4.3 × 1014 Hz. The velocity of ejected
1
electron is _____ × 105 ms–1. (Nearest integer) (b) n 3, l 2, mA 2, ms 
2
[Use : h = 6.63 × 10–34 Js, me = 9.0 × 10–31 kg]
The pairs of electrons present in degenerate orbitals
[JEE (Main)-2021] is /are:
61. The kinetic energy of an electron in the second Bohr (1) Only (A) (2) Only (B)
(3) Only (C) (4) (B) and (C)
h2
orbit of a hydrogen atom is equal to . The 66. The energy of one mole of photons of radiation of
x ma02
wavelength 300 nm is (Given h = 6.63 × 10–34Js, NA
value of 10x is ______. (a0 is radius of Bohr’s orbit) = 6.02 × 1023 mol–1, c = 3 × 108 ms–1)
(Nearest integer)
[JEE (Main)-2022]
[Given : S = 3.14] [JEE (Main)-2021]
(1) 235 kJ mol–1 (2) 325 kJ mol–1
62. The number of photons emitted by a monochromatic
(3) 399 kJ mol–1 (4) 435 kJ mol–1
(single frequency) infrared range finder of power 1
mW and wavelength of 1000 nm, in 0.1 second is x 67. The pair, in which ions are isoelectronic with Al3+ is:
× 1013. The value of x is _____. (Nearest integer) [JEE (Main)-2022]
(h = 6.63 × 10–34 Js, c = 3.00 × 108 ms–1) (1) Br– and Be2+ (2) Cl– and Li+
[JEE (Main)-2021] (3) S2– and K+ (4) O2– and Mg2+

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68. The longest wavelength of light that can be used for 74. Consider the following statements :
the ionisation of lithium atom (Li) in its ground state
[JEE (Main)-2022]
is x × 10–8 m. The value of x is ______. (Nearest
Integer) (A) The principal quantum number ‘n’ is a positive
(Given : Energy of the electron in the first shell of integer with values of ‘n’ = 1, 2, 3, ….
the hydrogen atom is –2.2 x 10 –18 J; (B) The azimuthal quantum number ‘l’ for a given
h = 6.63 × 10– 34 Js and c = 3 × 108 ms–1) ‘n’ (principal quantum number) can have
[JEE (Main)-2022] values as ‘l’ = 0, 1, 2, …n
69. The minimum energy that must be possessed by (C) Magnetic orbital quantum number ‘ml’ for a
photons in order to produce the photoelectric effect particular ‘l’ (azimuthal quantum number) has
with platinum metal is (2l + 1) values.
[Given The threshold frequency of platinum is 1.3 × (D) ±1/2 are the two possible orientations of
1015 s–1 and h = 6.6 × 10–34 Js.] electron spin.
[JEE (Main)-2022] (E) For l = 5, there will be a total of 9 orbital
(1) 3.21 × 10 –14
J (2) 6.24 × 10–16 J Which of the above statements are correct?
(3) 8.58 × 10–19 J (4) 8.58 × 10–19 J (1) (A), (B) and (C)
70. If the radius of the 3rd Bohr’s orbit of hydrogen atom (2) (A), (C), (D) and (E)
is r3 and the radius of 4th Bohr’s orbit is r4. Then :
(3) (A), (C) and (D)
[JEE (Main)-2022]
(4) (A), (B), (C) and (D)
9 16
(1) r4 r3 (2) r4 r3 75. Which of the following statements are correct?
16 9
[JEE (Main)-2022]
3 4 (A) The electronic configuration of Cr is [Ar]
(3) r4 r3 (4) r4 r3
4 3 3d54s1.
71. The number of radial and angular nodes in 4d orbital (B) The magnetic quantum number may have a
are, respectively negative value.
[JEE (Main)-2022] (C) In the ground state of an atom, the orbitals
are filled in order of their increasing energies.
(1) 1 and 2 (2) 3 and 2
(D) The total number of nodes are given by n – 2.
(3) 1 and 0 (4) 2 and 1
Choose the most appropriate answer from the
72. If the uncertainty in velocity and position of a minute options given below :
particle in space are, 2.4 × 10–26 (m s–1) and 10–7 (1) (A), (C) and (D) only
(m) respectively. The mass of the particle in g is (2) (A) and (B) only
_____. (Nearest integer) (3) (A) and (C) only
(Given : h = 6.626 × 10–34 Js) (4) (A), (B) and (C) only
[JEE (Main)-2022] 76. Which of the following is the correct plot for the
73. Consider the following set of quantum numbers. probability density \2  r  as a function of distance
‘r’ of the electron from the nucleus for 2s orbital?
n l ml
[JEE (Main)-2022]
A. 3 3 –3

B. 3 2 –2

C. 2 1 +1

D. 2 2 +2 (1)
The number of correct sets of quantum numbers is
_____. [JEE (Main)-2022]

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48 3 
80. Consider an imaginary ion 22 X . The nucleus
contains ‘a’% more neutrons than the number of
electrons in the ion. The value of ‘a’ is ________.
(2) [nearest integer] [JEE (Main)-2022]

81. Given below are two statements. One is labelled

as Assertion A and the other is labelled as
Reason R.

Assertion A: Energy of 2s orbital of hydrogen atom

is greater than that of 2s orbital of lithium.
(3)
Reason R : Energies of the orbitals in the same
subshell decrease with increase in the atomic number.

In the light of the above statements, choose the

correct answer from the options given below.
[JEE (Main)-2022]

(4) (1) Both A and R are true and R is the correct

explanation of A.
(2) Both A and R are true but R is NOT the
correct explanation of A.
77. Which of the following sets of quantum numbers
(3) A is true but R is false.
is not allowed?
(4) A is false but R is true.
[JEE (Main)-2022]
82. The correct decreasing order of energy for the
1
(1) n 3, l 2, ml 0, s  orbitals having, following set of quantum numbers:
2

1 (A) n = 3, l = 0, m = 0 (B) n = 4, l = 0, m = 0
(2) n 3, l 2, ml 2, s 
2 (C) n = 3, l = 1, m = 0 (D) n = 3, l = 2, m = 1
1 [JEE (Main)-2022]
(3) n 3, l 3, ml 3, s 
2
(1) (D) > (B) > (C) > (A) (2) (B) > (D) > (C) > (A)
1 (3) (C) > (B) > (D) > (A) (4) (B) > (C) > (D) > (A)
(4) n 3, l 0, ml 0, s 
2
83. Identify the incorrect statement from the following.
78. When the excited electron of a H atom from n =
5 drops to the ground state, the maximum number [JEE (Main)-2022]
of emission lines observed are ____. (1) A circular path around the nucleus in which
an electron moves is proposed as Bohr’s
[JEE (Main)-2022]
orbit.
79. The wavelength of an electron and a neutron will (2) An orbital is the one electron wave function
become equal when the velocity of the electron is (<) in an atom.
x times the velocity of neutron. The value of x is (3) The existence of Bohr’s orbits is supported
______. (Nearest integer) by hydrogen spectrum.
(4) Atomic orbital is characterised by the
(Mass of electron is 9.1 × 10–31 kg and mass of
quantum numbers n and l only.
neutron is 1.6 × 10–27 kg) [JEE (Main)-2022]
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CHEMISTRY ARCHIVE - JEE (Main)

84. If the wavelength for an electron emitted from B. n = 4, l = 1, ml = 0, ms = +1/2

H-atom is 3.3 × 10–10 m, then energy absorbed by
C. n = 4, l = 2, ml = –2, ms = –1/2
the electron in its ground state compared to
minimum energy required for its escape from the D. n = 3, l = 1, ml = –1, ms- = +1/2
atom, is ______ times. (Nearest integer) The correct order of increasing energy is

[Given : h = 6.626 × 10–34 J s] [JEE (Main)-2022]

[Mass of electron = 9.1 × 10–31 kg] (1) D < B < A < C (2) D < A < B < C
[JEE (Main)-2022] (3) B < D < A < C (4) B < D < C < A
85. The minimum uncertainty in the speed of an
87. lf the work function of a metal is 6.63 × 10–19 J, the
electron in one dimensional region of length 2a0
(Where a0 = Bohr radius 52.9 pm) is ___ km s–1. maximum wavelength of the photon required to

(Given : Mass of electron = 9.1 × 10–31 kg, Planck’s remove a photoelectron from the metal is ______
constant h = 6.63 × 10–34 Js) [JEE (Main)-2022]
nm. (Nearest integer)
86. Given below are the quantum numbers for 4
[Given : h = 6.63 × 10–34 J s, and c = 3 × 108 m s–1]
electrons.
[JEE (Main)-2022]
A. n = 3, l = 2, ml = 1, ms = +1/2

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Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456