MATERIAL SAFETY DATA SHEET

COMPANY DETAILS
Name : Address : Telephone: Buckman Laboratories (Pty) Ltd P. O. Box 591, Hammarsdale, 3700 (031) 736 8800 Emergency Telephone No: 0800 7368800 Fax: (031) 736 1593

1 Product Identification
Product: Chemical Family: Chemical Name: UN No:

BUBREAK 4019
Hydrocarbons Esters of Aliphatic acids extended in Oil Not Regulated Hazchem Code: 2 Z

Chemical Abstract Number:

Mixture

NIOSH No:

Not Listed

2 Composition
Hazardous Components Hydrocarbon Oil CAS No 64742-52-5 Concentration < 90 % TLV 10 mg/m3 EEC Classification 265-155-0

Risk Phrases:

R36/38

3 Hazards Identification
Main Hazard: Flammability: Chemical Hazard: Biological Hazard: Reproduction Hazard: Eye Effects - eyes: Health Effects - skin: Irritant. Not flammable Irritant No data available Not listed. Irritating to the eyes Irritating to the skin

Health Effects - ingestion:

Not expected to be hazardous by ingestion.

Health Effects - inhalation:

Not expected to be hazardous by inhalation.

Carcinogenicity: Mutagenicity: Neurotoxicity :

Refer Section 11 : Toxicological Information Refer Section 11 : Toxicological Information Refer Section 9 : Physical and Chemical Properties

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Revision No : MSDS - 05

06-Mar-2006

MATERIAL SAFETY DATA SHEET 4 First Aid Measures

Product in the eye:

BUBREAK 4019

Flush immediately with copious amounts of tap water or normal saline solution for a minimum of 15 minutes. Take exposed individual to a physician, preferably an opthalmologist, for further evaluation. Wash exposed area with plenty of water. Repeat washing. Remove contaminated clothing and wash thoroughly before re-use. If irritation persists, consult a physician.

Product on the skin:

Product ingested:

DO NOT INDUCE VOMITING. Rinse with copious amounts of water or milk first. Irrigate the oesophagus and dilute stomach contents by slowly giving one (1) or two (2) glasses of water or milk. Avoid giving alcohol or alcohol related products. In cases where the individual is semicomatose, comatose or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In case of intentional ingestion of the product, seek medical assistance immediately; take individual to nearest medical facility.

Inhalation:

Not applicable

NOTE TO PHYSICIAN:

No product specific antidote is known. Probable mucosal damage may contraindicate the use of gastric lavage. Treat symptoms. For specialist medical advice in the event of an emergency contact 0800 7368800

5 Fire Fighting Measures

Extinguishing Media: Special Hazards: Water fog, foam, carbon dioxide or dry chemical powder. None known.

Protective clothing:

standard fire-fighting body-protective clothing is recommended.

6 Accidental Release Measures

Personal Precautions: Generally, defoamers are non-toxic and non-hazardous, however, it is advisable to follow the normal handling procedures. Rubber gloves and safety glasses or goggles required. Eye wash fountains in the work place are strongly recommended. Body-protective clothing and shoes are recommended.

Environmental Precaution: Spills

Do not discharge concentrated, undiluted product into lakes, streams, ponds, estuaries, oceans and other waters. Liquids:Dam area to prevent spill from spreading. Clay, soil or commercially available absorbents may be used to recover any material that cannot be recovered as pure product. Liquids/Solids/Powder: Minimise adverse effects on the environment. Recover as much as possible of the pure product into appropriate containers. Later, determine if this recovered product can be used for its intended purpose. Dispose in accordance with local / national regulations governing the disposal of waste material.

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Revision No : MSDS - 05

06-Mar-2006

MATERIAL SAFETY DATA SHEET 7 Handling and Storage

Suitable Material:

BUBREAK 4019

Penton, Stainless Steel, Polypropylene, Polyethylene, Moulded Nylon

Handling/Storage Precautions:

The handling precautions for this product are based on the characteristics of the neat product unless otherwise specified. Store in a cool dry place. Rubber gloves and safety goggles are required. Body-protective clothing and safety shoes are required. Eye-wash fountains in the work place are strongly recommended.

8 Exposure Controls/Personal Protection

Occupational Exposure limits: Engineering Control Measures: None No special measures required

Personal Protection - respiratory:

Not applicable

Personal Protection - hand Personal Protection - eye Personal Protection-skin: Other Protection:

Rubber gloves Safety goggles are required. Body-protective clothing and safety shoes are recommended. Where splashing can occur, a protective face-shield is required. Eye wash fountain in the workplace is strongly recommended

9 Physical and Chemical Properties

Appearance: Odour: pH: Boiling point: Melting Point: Flash Point: Flammability: Autoflammability: Explosive properties: Oxidizing properties: Vapour Pressure: Density: Solubility in Water: Solubility-solvent Solubility Coefficient Neurotoxicity Opaque liquid Bland 6-8 >100C Not available >100C Not flammable Not applicable Not applicable Not available Not available 0.86 - 0.88 g/ml Emulsifiable in water Not available Not available No data available. None expected.

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Revision No : MSDS - 05

06-Mar-2006

MATERIAL SAFETY DATA SHEET 10 Stability and Reactivity

Conditions to avoid: Stable under normal conditions of use and storage.

BUBREAK 4019

Incompatible materials:

None

Hazardous decomposition products:

None known

11 Toxicological Information
Acute Toxicity: Not expected to be toxic by ingestion

Skin and Eye Contact:

Irritating to the eyes and skin

Chronic Toxicity:

The effects of chronic exposure have not been evaluated.

Carcinogenicity:

Not listed.

Mutagenicity: Reproduction Hazard:

Not listed. Not listed.

12 Ecological Information
Aquatic Toxicity - fish: No data available

Aquatic Toxicity:

48 Hr. LC50 : Daphnia Pulex = 1.9 ppm; 48 Hr. LC0:Daphnia Pulex = 0.01 ppm

Aquatic Toxicity - algae: Avian Toxicity:

No data available No data available

Biodegradability: Bio - Accumulation: Mobility: German wgk:

Not tested by Buckman Laboratories Not tested by Buckman Laboratories Not tested by Buckman Laboratories 1 = Low water hazard

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Revision No : MSDS - 05

06-Mar-2006

MATERIAL SAFETY DATA SHEET 13 Disposal Conditions

Disposal Method:

BUBREAK 4019

Dispose in accordance with local/national regulations governing the disposal of waste materials.

Disposal of Packaging:

Disposal of packaging material must be undertaken through a registered waste disposal company in an approved landfill.

14 Transport Information
UN No. : Substance Identity No: Dot Class ADR/RID Class: ADR/RID Item Number: ADR/RID Hazard Identity Number: IMDG - Shipping Name: IMDG - Page: IMDG - Class: IMDG - Packaging Group: IMDG - Marine Pollutant: EMS No. : MFAG Table No. : IATA - Shipping Name: IATA - Class: IATA - subsidiary risk(s): ADNR - Class: UK - Description: UK - Emergency Action Class: UK - Classification: Not Regulated Not Regulated Not Regulated Not Regulated Not Applicable Not Applicable Not Applicable Not Applicable Not Regulated III No Not Applicable Not Applicable Not Applicable Not Regulated Not Applicable Not Regulated Not Applicable Not Regulated Not Regulated

15 Regulatory Information
EEC - Hazard Classification: Risk Phrases: Safety Phrases: National Legislation: FDA Approvals: Not Listed R36/38 S26; S27/28 None known. FDA regulations governing food additives for human consumption. Sub-part D173.340 - defoaming agents.;Sub-part (1) 172.878 - mineral oil.

16 Other Information

The information on this Material Safety Data Sheet reflects the latest information and data that we have on hazards, properties, and handling of this product under the recommended conditions of use. Any use of this product or method of application which is not described in the Product Data Sheet is the responsibility of the user.

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Revision No : MSDS - 05

06-Mar-2006

TRANSPORT EMERGENCY CARD (Road)

LOAD : BUBREAK 4019 Name of Substance(s): Ester Based Defoamer

Class : Not Regulated

NATURE OF DANGER Irritant. PERSONAL PROTECTION Rubber gloves, safety goggles, body-protective clothing and safety shoes are recommended. Where splashing can occur, a protective face shield is required. Where misting can occur, a self-contained breathing apparatus is recommended. GENERAL ACTIONS BY THE DRIVER Stop the engine. Mark roads and warn other road users. Keep public away from the danger area. ADDITIONAL AND/OR SPECIAL ACTIONS BY THE DRIVER Shut off leaks, if possible without risk. Contain the spill to avoid any potential routes to sewers, streams, dams, etc. Clay, soil or commercially available absorbents may be used to contain the spill. If the product has entered a water course, or sewer, notify the police or emergency response department. FIRE (INFORMATION FOR DRIVER IN CASE OF FIRE) Do Not attempt to deal with any fire involving the load.

FIRST AID Eyes Flush with clean water for 15 minutes. Seek medical attention immediately. Skin Wash immediately with plenty of water. Remove contaminated clothing and wash thoroughly before re-use. Seek medical attention if irritation persists. Inhalation Immediately move the individual to fresh air. Seek medical attention. Ingestion DO NOT INDUCE VOMITING. Dilute by drinking 1 - 2 glasses of water or milk. Seek medical attention immediately. NOTE TO PHYSICIAN Probable mucosal damage may contraindicate gastric lavage. SUPPLEMENTARY INFORMATION FOR EMERGENCY SERVICES Water fog, foam, carbon dioxide or dry chemical powder. - standard fire-fighting bodyprotective clothing is recommended.

Additional information provided by: Emergency Telephone Number 0800 7368800 Buckman Laboratories (Pty) Ltd UN No : Not Regulated P.O.Box 591 Hammarsdale, 3700 Telephone: 031 - 736 8800 APPLIES ONLY DURING ROAD TRANSPORT