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    Dyeing and Printing Assignment 1 Topic: To Study The Mercerizing Process

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    This document summarizes the mercerization process. It begins by defining mercerization as the treatment of cellulosic material with a higher concentrated alkali solution for a short period at a lower temperature. The objectives of mercerization are then listed as improving luster, strength, dyeability, dimensional stability, and elasticity of cotton materials. The document goes on to describe the chemical and physical changes that occur during mercerization, such as swelling of fibers, rearranging of cellulosic chains, and changes to the fiber cross-section and structure. Parameters that affect mercerization like alkali concentration, time, tension, and temperature are also discussed. Finally, the document briefly summarizes different mercerization

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    Dyeing and Printing Assignment 1 Topic: To Study The Mercerizing Process

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    This document summarizes the mercerization process. It begins by defining mercerization as the treatment of cellulosic material with a higher concentrated alkali solution for a short period at a lower temperature. The objectives of mercerization are then listed as improving luster, strength, dyeability, dimensional stability, and elasticity of cotton materials. The document goes on to describe the chemical and physical changes that occur during mercerization, such as swelling of fibers, rearranging of cellulosic chains, and changes to the fiber cross-section and structure. Parameters that affect mercerization like alkali concentration, time, tension, and temperature are also discussed. Finally, the document briefly summarizes different mercerization

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    This document summarizes the mercerization process. It begins by defining mercerization as the treatment of cellulosic material with a higher concentrated alkali solution for a short period at a lower temperature. The objectives of mercerization are then listed as improving luster, strength, dyeability, dimensional stability, and elasticity of cotton materials. The document goes on to describe the chemical and physical changes that occur during mercerization, such as swelling of fibers, rearranging of cellulosic chains, and changes to the fiber cross-section and structure. Parameters that affect mercerization like alkali concentration, time, tension, and temperature are also discussed. Finally, the document briefly summarizes different mercerization

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    61 views27 pages

    Dyeing and Printing Assignment 1 Topic: To Study The Mercerizing Process

    Uploaded by

    nidhisanjeet
    This document summarizes the mercerization process. It begins by defining mercerization as the treatment of cellulosic material with a higher concentrated alkali solution for a short period at a lower temperature. The objectives of mercerization are then listed as improving luster, strength, dyeability, dimensional stability, and elasticity of cotton materials. The document goes on to describe the chemical and physical changes that occur during mercerization, such as swelling of fibers, rearranging of cellulosic chains, and changes to the fiber cross-section and structure. Parameters that affect mercerization like alkali concentration, time, tension, and temperature are also discussed. Finally, the document briefly summarizes different mercerization

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 27

    Dyeing and Printing

    Assignment 1
    Topic: To study the mercerizing process

    Submitted to:

    Submitted By :

    Prof. Pranav Vora DEEPSH KUMAR TOLAMBIA


    CC MFTech DINESH MAKWANA
    NIFT Gandhinagar

    SHASHIKANT SOLANKI
    SANJAY BELWAL
    NADEEM PATHAN

    Course Name: M.Ftech


    Semester: 2nd
    Session: 2012 - 2014
    Submission Date: 1st February , 2013

    mercerisation
    Definition :
    Treatment of cellulosic material with higher
    concentrated Alkali for short period at lower
    temperature.

    OBJECTIVES
    To improve lustre of cotton materials.
    To improve strength and mechanical properties.
    To improve dyeability and moisture absorbency.
    To improve dimensional stability of materials.
    Improving elasticity.

    Action of alkali
    Cotton have resistance to alkali solution.

    Mild alkali like sodium carbonate have no action


    on cotton.

    Strong alkalis with higher concentration induce


    structural and physical changes in cotton fibre.

    Penetration of alkali
    For small concentration of alkali , less than 5 %
    no penetration.

    As the concentration of alkali increases ,


    penetration increase than automatically fibre
    swells.

    What happen to cotton


    during mercerization
    Swelling of the fibre takes place.
    Cellulosic chain gets rearranged an become
    parallel.
    De-convolution.
    Convolution bean shape to circular shape.

    When mercerising can be


    carried out ?
    At grey stage.
    After desizing.
    After scouring.
    After scouring and bleaching.

    Physical changes
    Improvement in strength.
    Improvement in luster.
    Change in cross-section from bean shape to
    almost circular.
    Change in longitudinal view convoluted to
    cylindrical.

    Chemical changes
    Formation of cellulose second .

    Improvement in moisture regain (more hydroxyl


    group).

    Improvement in due uptake.

    Structural changes

    conditions
    Application of caustic soda solution around at a
    room temperature.
    A dwell period of 55 sec. of an average.
    Tension at both direction.
    Finally , washing-off of alkali from the treated
    fabric or yarn.

    What are the parameters


    Concentration of NaoH .
    Time of treatment.
    Tension applied.
    Temperature.
    Impurities of NaoH.

    MERCERISATION
    MACHINE
    Tension mercerisation. (treatment under tension / control).
    Slack mercerisation . (treatment without tension /
    control).
    Yarn mercerisation.
    Fabric mercerisation.

    Fabric mersarisation machine:


    Paid chain type
    Paid chainless type
    Paidless chainless type.

    Hot mercerisation drawback


    with cold mercerisation
    Penetration of grey cotton become more difficult.
    (high viscosity)

    Swelling in only at surface . (heavy fabric)

    Poor mercerisation at the core and lack of


    uniformity.

    Recipe
    NaoH = 26 30 %
    WETTING AGENT = 1 %
    TEMP = 60 centigrades
    TIME = 20 TO 60 sec.

    Advantage of hot
    mercerisation
    Rapid alkali penetration.
    Improved core mercerisation.
    More uniform treatment.
    Dwell time can be reduced from 50 sec. to 20
    30 sec.

    Disadvantage of hot
    mercerisation
    Less lustre. (lower swelling)

    Higher energy consumption.

    Costlier.

    Liquid ammonia
    mercerisation
    treatment of cotton fibre with liquid ammonia
    produces similar effect that of mercerisation.

    It is widely accepted for sewing threads ,and


    special fabric like denim, pillow material, linen
    etc.

    Advantage of ammonia
    mercerisation
    Less pollution
    Higher productivity.
    Jute and linen can be mercerised.
    Evenness and uniformity is better.

    disadvantage
    Very costly equipment.
    Ammonia recovery problem ,leakages will do
    grate harm to the personnel working .

    References..
    1. Ian Holme, International Dyer, 188(5), 7, (2003).
    2. Verschuren J.,Kiekens P., New Cloth Market, 18(4),
    35, (2004).
    3. Rouette Hans-Karl, Encyclopedia of Textile Finishing,
    Springer-Verlag, Berlin, vol no 2, 1613,(2002).
    4. Ramachandran T., Karthik T., and Shetty Guruprasad
    S., The Indian TextileJournal,114(9), 23,(2004).
    5. Ume vohrer, New Cloth Market, 15(7), 13, (2001).
    6. Zaisheng Cai, Hwang Yoon Joon, Park Yoon-Chewl,
    Zhang Chuyang, Mccord Marian, Qui Yiping,

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