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Extraction of Aluminium

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EXTRACTION OF

METAL FROM ITS


ORE
Prepared by
Nor Dahlia Zamani
Nurul Nadiah Bt Kamal
 Aluminium is extracted by electrolysis.
 The aluminium oxide is dissolve in molten
cryolite and then reduced to the pure
metal.
 The first stage is the removal of the
impurities, sand and some iron oxide.
 The pure aluminium oxide left is called
alumina.
 Electricity is passed tgrough the alumina
solution via electrodes.
 The electrode that is connected to the
positive terminal is called the anode.
 The negative electrode is called the
cathode.
 Both these electrodes are made of
graphite.
 The reaction at the cathode — the
negative terminal is
Al3+ + 3 e− → Al
 At the positive electrode (anode), oxygen
is formed:
2 O2− → O2 + 4 e−
 the whole process requires a great deal
of electricity, which makes it very
expensive.
Electrolysis of pure alumina (Hall-Heroult process)

fig 8.3 - Hall's cell


Refining of aluminium (Hoopes process)
 The metal obtained in the above step is about
99% pure and for most purposes it is taken as
pure metal.
 However, further purification of aluminium can
be carried out by Hoopes process. The cell
consists of an iron tank lined with carbon at the
bottom.
 A molten alloy of copper, crude aluminium and
silicon is used as the anode. It forms the lower
most layer in the cell.
 The middle layer consists of molten mixture of
fluorides, of sodium aluminium and barium
(cryolite + BaF2). The upper most layer consists
of molten aluminium. A set if graphite rods
dipping in molten aluminium serve as cathode.
Uses Properties

Overhead electric cables Low density, light


Resistant to corrosion (protected
by aluminium oxide)
Good electrical conductivity
Food containers Non-toxic
Resistant to corrosion
Good conductor of heat

Low density, light


Aircraft body High tensile strength
Resistant to corrosion
 We mine iron ore from iron mines. Iron
ore (haematite) is iron (iii) oxide, Fe2O3.
 Carbon, C is the main reducing agent in the
metal extraction process.
 The extraction is carried out in a blast
furnace. The metal ore is mixed with coke
and limestone, CaCO3 .
 Hot water is pumped into the blast
furnace to burn the carbon and produce
carbon monoxide, CO.
 2C + O2 → 2CO

 Fe2O3 + 3CO → 2Fe + 3CO2


2Fe2O3 + 3C → 4Fe +3CO2

Limestone or calcium carbonate, CaCO3


reacts with impurities such as silica in the
metal ores. Slag is formed.
CaCO3 + SiO2 → CaSiO3 + CO2
 Slag floats on top of the molten metal
and is removed. The molten metal is
collected at the bottom part of the
blast furnace.
Extracting iron in industry
• Making useful steel for construction,
automobiles, and other forms of
transportation such as trucks, trains and
train tracks.
• Powdered iron: used in metallurgy
products, magnets, high-frequency cores,
auto parts, catalyst.
• Radioactive iron (iron 59): in medicine,
tracer element in biochemical and
metallurgical research.
-THE END-

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