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The Mechanical Testing of Polymers

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The Mechanical Testing of

Polymers
and their Composites
By
Gordon Williams
Introduction
Standard methods are vital in ensuring
reliable data
True in all fields Thus ASTM & ISO
If a property is to be claimed it must be
backed by 1) a method and 2) statistical
analysis ( means ,SD)
For materials science ;materials
development must be supported by proper
results.
Introduction
e.g. Toughened polymers (PA,PE),
Filled polymers; glass filled ;particle filled
Nano Composites
Recent confusion in Nano field is often a
result of poor data.
Test Types
A range from direct product testing to
basic properties ,e.g. Drop tests to
Youngs Modulus.
Intermediate type, Testing special plaques
or bowls.
Basic Tests measure material properties
independent of size and method.
Test Types

Two Main Types


Deformation behaviour; to find Youngs
Modulus ,Yield stress ,Poissons Ratio
,Elongation*,Strength*.
Fracture Behaviour; to find
Toughness,K1c,Izod*, Charpy*.
All use Tension, Compression or Bending
Tests.
* See later; not usually a good idea.
Testing Machines
A long history e.g. 1880
Originally to test steel, e.g. Harbour Bridge
Machines in Civil Eng. Dept. from 1908
All work in a similar way
Load applied via a screw ( Instron) or
hydraulic rams (Servo Hydraulic)
Load measured by load cells (must
calibrate)
Test machine Instron 4302
Test machine Instron 1195
Test machine MTS 810
Testing Machines
Deformations; Cross head ,Gauge length?
Extensometers, videos.
Modern machines are speed controlled,
i.e. constant or exponential.
Polymers are rate dependent, i.e. are
visco-elastic.
Deformation Properties
Measured in; Tension ,compression or
bending.
Tension; simplest but; end effects (dog
bones) ,gripping (slipping) ,accurate
strains difficult.
Compression; no gripping problems
However ,friction .
Necessary for some yield stress tests.
Definition of Deformation
Stress,

y F

E
0 2% y F
Strain,
Illustrations of Deformation
Tension:

b
W

= /l =F/bW E= /=(F/)(l/bW)
Illustrations of Deformation

Compression:
Illustrations of Deformation

Bending:

F

b

E= /=(F/)(l/bW)(l 2/4W2)
Deformation Properties
Bending
Good for Modulus (magnification)
However; variable strain , inhomogeniety
(flexural modulus)
Interpretation of curves.
Youngs Modulus; elastic property
,polymers are visco-elastic ,rate
dependent ,unloading and hysterysis
.Usually non- linear.
Deformation Behaviour
Yield Stress; onset of permanent
deformation, hard to define. 2% offset
,maximum stress.
Correct or definable ?
Fracture stress/strain ,strength .Variable
(surface finish) .A property?
Fracture Mechanics!! See next week.

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