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Cooling Curve of A Two Component System

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COOLING CURVE OF A

TWO COMPONENT
SYSTEM
GROUP 2
A N TA Z O , F R A N C E S C A V I C TO R I A
DIONISIO, EUNICE ANNE B.
G U T I E R R E Z , M A . E L L A H PAT R I C I A
M.
INTRODUCTION
COOLING CURVE
A graph that shows how the temperature changes with
time as a substance is cooled down.
It has a horizontal flat parts, or the plateau, where the
phase modifies from liquid to solid or from gas to liquid.
The slope in the graph is due to the temperature difference
between the substance and the surroundings as the
substance cools.
INTRODUCTION
It is related to the heat capacity, the external temperature,
and thermal conductivity.
The more heat is required to alter the substance’s
temperature, the slower it cools, thus the gradient of the
curve is smaller.
Heat is transferred faster when the thermal conductivity is
higher making the substance cool rapidly.
Figure 1. Cooling of a Two-component System from Figure 2. Cooling Curve
Liquid to Solid

The temperature will decrease at a rate that is determined by the composition of


the sample as the sample cools from point A. As the temperature reaches point B,
formation of some solid compound B occurs that will slow the cooling because of
the exothermic reaction of the formation.
INTRODUCTION
The composition of the solution will also change making it
abundant with compound A as compound B is removed from
the liquid phase during the solidification.

This process will proceed until the liquid attains the


composition where the temperature will no longer decrease--
this is the eutectic point.
INTRODUCTION
When temperature reaches the eutectic point, both
compounds will solidify and the composition of the liquid
phase will become constant.
Eutectic halt happens when the temperature stops changing.
When it stops, the cooling will still continue at a rate that is
determined by the heat capacities of the two components.
A phase diagram can be made through measuring the cooling
curves of the samples.
OBJECTIVES
To generate a cooling curve of a two component system.

To explain the effect of mole fraction in relation to the


cooling curve.

To determine the eutectic point of the two component


system.
METHODOLOGY
preparation of α- dissolve the solidify the mixture
naphthol and p-toluidine
mixture
mixture

• Prepare • Remove the test


• Heat the tube from the
mixture of α- mixture in water bath, allow
naphthol and 80°C water it to cool, and get
p-toluidine the temperature
bath until every 15 seconds
with varying
amounts in 7 the interval until the
mixture mixture is
different test completely
tubes. dissolves. solidified again.
RESULT AND DISSCUSION
CONCLUSION

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