Chem12 C03 L2 Lo

3.
2 Units of Measurement >
Chapter 3
Scientific Measurement
3.1 Using and Expressing
Measurements
3.2 Units of Measurement

3.3 Solving Conversion Problems
1 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

3.2 Units of Measurement > CHEMISTRY & YOU
What’s the forecast for tomorrow—hot

or cold?
Will the high

temperature tomorrow
be 28°C, which is very
warm? Or 28°F, which
is very cold? Without
the correct units, you
can’t be sure.

3.2 Units of Measurement > Using SI Units
Using SI Units
What makes metric units easy to use?

• The standards of measurement used in

science are those of the metric system.
All metric units are based on multiples

of 10. As a result, you can convert
between units easily.

• The metric system was originally

established in France in 1795.
• The International System of Units

(abbreviated SI after the French name, Le
Système International d’Unités) is a
revised version of the metric system.
• The SI was adopted by international

agreement in 1960.

• There are seven SI base

SI Base Units
units.
Quantity SI base Symbol
unit
• From these base units, all
Length meter m
other SI units of
measurement can be Mass kilogram kg
derived. Temperature kelvin K
Time second s
• Derived units are used Amount of
mole mol
for measurements substance
such as volume, Luminous
candela cd
density, and pressure. intensity
Electric
ampere A
current

Units of Length
• In SI, the basic unit of length, or linear
measure, is the meter (m).
• All measurements of length can be

expressed in meters.
• For very large and very small lengths,

however, it may be more convenient to use
a unit of length that has a prefix.

Units of Length
The table below lists the prefixes in common use.
Commonly Used Metric Prefixes

Prefix Symbol Meaning Factor
mega M 1 million times larger than the unit it precedes 106
kilo k 1000 times larger than the unit it precedes 103
deci d 10 times smaller than the unit it precedes 10-1
centi c 100 times smaller than the unit it precedes 10-2
milli m 1000 times smaller than the unit it precedes 10-3
micro μ 1 million times smaller than the unit it precedes 10-6
nano n 1 billion times smaller than the unit it precedes 10-9
pico p 1 trillion times smaller than the unit it precedes 10-12

Units of Length
• For example, the prefix milli- means 1/1000
(one-thousandth), so a millimeter (mm) is
1/1000 of a meter, or 0.001 m.
• A hyphen (-) measures about 1 mm.
• For large distances, it is most appropriate to

express measurements in kilometers (km).
• The prefix kilo- means 1000, so 1 km

equals 1000 m.
Units of Volume
• The space occupied by any sample of
matter is called its volume.
• You calculate the volume of any cubic or

rectangular solid by multiplying its length
by its width by its height.
• The unit for volume is thus derived from

the units of length.

Units of Volume
• The SI unit of volume is the amount of space
occupied by a cube that is 1 m along each
edge.
• This volume is a cubic meter (m3).
• A more convenient unit of volume for everyday

use is the liter, a non-SI unit.
• A liter (L) is the volume of a cube that is 10

centimeters (10 cm) along each edge (10
cm x 10 cm x 10 cm = 1000 cm3 = 1 L).
Units of Volume
• A smaller, non-SI unit of volume is the
milliliter (mL); 1 mL is 1/1000 of a liter.
• Thus, there are 1000 mL in 1 L.
• Because 1 L is defined as 1000 cm3, 1 mL

and 1 cm3 are the same volume.
• The units milliliter and cubic centimeter are

thus used interchangeably.

Units of Volume
These figures give you some idea of
the relative sizes of a liter and a
milliliter.
1L
1 mL

Units of Volume
• There are many devices for measuring liquid
volumes, including graduated cylinders,
pipets, burets, volumetric flasks, and
syringes.
• The volume of substances will change with

temperature, so accurate volume-measuring
devices are calibrated at a given temperature
—usually 20 degrees Celsius (20°C), which
is about normal room temperature.

Units of Volume
The relationships among common metric units of volume
are shown in the table below.
Metric Units of Volume

Unit Symbol Relationship Example
Liter L base unit quart of milk ≈ 1 L
Milliliter mL 103 mL = 1 L 20 drops of water ≈ 1 mL
Cubic centimeter cm3 1 cm3 = 1 mL cube of sugar ≈ 1 cm3
Microliter μL 103 μL = 1 L crystal of table salt ≈ 1 μL

Units of Mass
• The mass of an object is measured in comparison to
a standard mass of 1 kilogram (kg), which is the
basic SI unit of mass.
• A kilogram was originally defined as the mass of 1 L

of liquid water at 4°C.
• A cube of water at 4°C measuring 10 cm on each
edge would have a volume of 1 L and a mass of
1000 grams (g), or 1 kg.
• A gram (g) is 1/1000 of a kilogram; the mass of 1

cm3 of water at 4°C is 1 g.

Units of Mass
The relationships among units of mass are shown in the
table below.
Metric Units of Mass

Unit Symbol Relationship Example
Kilogram
kg 1 kg = 103 g small textbook ≈ 1 kg
(base unit)
Gram g 1 g = 10-3 kg dollar bill ≈ 1 g
Milligram mg 103 mg = 1 g ten grains of salt ≈ 1 mg
Microgram μg 106 μg = 1 g particle of baking powder ≈ 1 μg

Units of Mass
• Weight is a force that measures the pull on a
given mass by gravity.
• Weight, a measure of force, is different from

mass, which is a measure of the quantity of
matter.
• The weight of an object can change with its

location.
• An astronaut in orbit is weightless, but not

massless.
Units of Energy
• The capacity to do work or to produce heat is
called energy.
• The SI unit of energy is the joule (J), named

after the English physicist James Prescott
Joule (1818–1889).
• A common non-SI unit of energy is the calorie.
• One calorie (cal) is the quantity of heat that

raises the temperature of 1 g of pure water
by 1°C.
Units of Energy
• Conversions between joules and calories can
be carried out using the following
relationships.
• 1 J = 0.2390 cal
• 1 cal = 4.184 J
• A kilojoule is 1000 joules; a kilocalorie is

1000 calories.

3.2 Units of Measurement >
What is the SI unit of volume?

What is the SI unit of volume?
The SI unit of volume is the cubic meter (m3). A

liter (L) can be converted to the SI unit of
volume, because a liter is defined as 1000 cm3.

3.2 Units of Measurement > Temperature Scales
Temperature Scales
What temperature units do scientists

commonly use?

• Temperature is a measure of how hot or

cold an object is.
• An object’s temperature determines the

direction of heat transfer.
• When two objects at different

temperatures are in contact, heat moves
from the object at the higher
temperature to the object at the lower
temperature.
• Almost all substances expand with an

increase in temperature and contract as
the temperature decreases.
• A very important exception is water.
• These properties are the basis for the

common bulb thermometer.

The liquid in a thermometer expands and

contracts more than the volume of the glass,
producing changes in the column height of
liquid.

Scientists commonly use two equivalent

units of temperature, the degree Celsius
and the kelvin.

• The Celsius scale sets the freezing point of

water at 0°C and the boiling point of water at
100°C.
• The distance between these two fixed

points is divided into 100 equal intervals, or
degrees Celsius (°C).

• Another temperature scale used in the

physical sciences is the Kelvin, or absolute,
scale.
• This scale is named for Lord Kelvin (1824–
1907), a Scottish physicist.
• On the Kelvin scale, the freezing point of

water is 273.15 kelvins (K), and the boiling
point is 373.15 (K).
• Note that with the Kelvin scale, the degree
sign is not used.
• The figure below compares the Celsius and Kelvin

scales.
• The zero point on the Kelvin scale, 0 K, or absolute

zero, is equal to –273.15°C.
Celsius 100
divisions
0°C 100°C
Freezing point Boiling point
of water of water
273.15 K 373.15 K
100
Kelvin divisions

• Because one degree on the Celsius scale

is equivalent to one kelvin on the Kelvin
scale, converting from one temperature to
another is easy.
• You simply add or subtract 273, as shown

in the following equations.
K = °C + 273
°C = K – 273

In a few countries, such as the United

States, metric units are not commonly
used in everyday measurements. What
temperature units are used for a typical
weather forecast in the United States?
What about for a country that uses the
metric system, such as Australia or
Japan?

In a few countries, such as the United

States, metric units are not commonly
used in everyday measurements. What
temperature units are used for a typical
weather forecast in the United States?
What about for a country that uses the
metric system, such as Australia or
Japan?
In the United States, temperatures are usually given
in degrees Fahrenheit. Countries that use the metric
system forecast the weather in degrees Celsius.

3.2 Units of Measurement > Sample Problem 3.7
Converting Between Temperature Scales

Normal human body temperature is
37°C. What is this temperature in
kelvins?

1 Analyze List the known and the unknown.

Use the known value and the equation K = °C +
273 to calculate the temperature in kelvins.
KNOWN
Temperature in °C = 37°C
UNKNOWN
Temperature in K = ? K

2 Calculate Solve for the unknown.

Substitute the known value for the Celsius
temperature into the equation and solve.
K = °C + 273 = 37 + 273 = 310 K

3 Evaluate Does the result make sense?

You should expect a temperature in this range,
since the freezing point of water is 273 K and
the boiling point of water is 373 K; normal body
temperature is between these two values.

Is the change of one degree on the Celsius

scale equivalent to one kelvin on the Kelvin
scale?

Is the change of one degree on the Celsius

scale equivalent to one kelvin on the Kelvin
scale?
Yes, a change of one degree on the Celsius

scale is equivalent to a change of one kelvin on
the Kelvin scale.

3.2 Units of Measurement > Density
Density
What determines the density of a

substance?

• The relationship between an object’s mass

and its volume tells you whether it will float
or sink.
• This relationship is called density.
• Density is the ratio of the mass of an

object to its volume.
Density = mass
volume

• When mass is measured in grams, and

volume in cubic centimeters, density has
units of grams per cubic centimeter
(g/cm3).
• The SI unit of density is kilograms per

cubic meter (kg/m3).

This figure compares the density of four

substances: lithium, water, aluminum, and lead.
Increasing density (mass per unit volume)
10 g 10 g 10 g 10 g
19 cm3 10 cm3 3.7 cm3 0.88 cm3
0.53 g/cm3 1.0 g/cm3 2.7 g/cm3 0.88 g/cm3

Density is an intensive property that

depends only on the composition of a
substance, not the size of the sample.

• Because of differences in
density, liquids separate into
layers.
Corn oil
• As shown at right, corn oil Water
floats on top of water
because it is less dense.
Corn syrup
• Corn syrup sinks below
water because it is more
dense.

3.2 Units of Measurement > Interpret Data
Densities of Some Common Materials

Solids and Liquids Gases
Density at Density at
Material Material
20°C (g/cm3) 20°C (g/L)
Gold 19.3 Chlorine 2.95
Mercury 13.6 Carbon dioxide 1.83
Lead 11.3 Argon 1.66
Aluminum 2.70 Oxygen 1.33
Table sugar 1.59 Air 1.20
Corn syrup 1.35–1.38 Nitrogen 1.17
Water (4°C) 1.000 Neon 0.84
Corn oil 0.922 Ammonia 0.718
Ice (0°C) 0.917 Methane 0.665
Ethanol 0.789 Helium 0.166
Gasoline 0.66–0.69 Hydrogen 0.084
What happens to the density of a substance as its

temperature increases?
• The volume of most substances increases as the

temperature increases, while the mass remains the
same.
• Since density is the ratio of an object’s mass to its

volume, the density of a substance generally
decreases as its temperature increases.
• Water is an important exception.

Calculating Density
A copper penny has a mass of 3.1 g
and a volume of 0.35 cm3. What is
the density of copper?

1 Analyze List the knowns and the unknown.

Use the known values and the equation for density
to solve the problem.
KNOWNS
mass = 3.1 g
volume = 0.35 cm3
UKNOWN
density = ? g/cm3

Start with the equation for density.
mass
Density =
volume


Substitute the known values for mass and volume and then
calculate.
31 g
Density = = 8.8571 g/cm 3
= 8.9 g/cm 3
0.35 cm3
The calculated answer must be

rounded to two significant figures.

3 Evaluate Does the result make sense?

A piece of copper with a volume of about 0.3
cm3 has a mass of about 3 grams. About three
times that volume of copper, 1 cm3, should have
a mass three times larger, about 9 grams. This
estimate is close to the calculated result.

Can you assume that something with a low

weight will float in water?

Can you assume that something with a low

weight will float in water?
No, it is the relationship between an object’s

mass and its volume, its density, that tells you
whether it will float or sink.

3.2 Units of Measurement > Key Concepts
All metric units are based on multiples of

10. As a result, you can convert between
units easily.
Scientists commonly use two equivalent

units of temperature, the degree Celsius
and the kelvin.
Density is an intensive property that

depends only on the composition of a
substance.
3.2 Units of Measurement > Key Equations
K = °C + 273
°C = K – 273
Density = mass
volume

3.2 Units of Measurement > Glossary Terms
• International System of Units (SI): the revised version of

the metric system, adopted by international agreement in
1960
• meter (m): the base unit of length in SI
• liter (L): the volume of a cube measuring 10 centimeters

on each edge (1000 cm3); it is the common unprefixed unit
of volume in the metric system
• kilogram (kg): the mass of 1 L of water at 4°C; it is the

base unit of mass in SI
• gram (g): a metric mass unit equal to the mass of 1 cm3 of

water at 4°C
• weight: a force that measures the pull of gravity on a

given mass
• energy: the capacity for doing work or producing heat
• Joule (J): the SI unit of energy; 4.184 J equals one

calorie
• calorie (cal): the quantity of heat needed to raise the

temperature of 1 g of pure water 1°C
• temperature: a measure of the average kinetic energy of

particles in matter; temperature determines the direction
of heat transfer
• Celsius scale: the temperature scale in which the

freezing point of water is 0°C and the boiling point is
100°C
• Kelvin scale: the temperature scale in which the freezing

point of water is 273 K and the boiling point is 373 K; 0 K
is absolute zero
• absolute zero: the zero point on the Kelvin temperature

scale, equivalent to –273.15°C
• density: the ratio of the mass of an object to its volume

END OF 3.2

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3.

2 Units of Measurement >

3.2 Units of Measurement

1 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

What’s the forecast for tomorrow—hot

Will the high

2 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

What makes metric units easy to use?

3 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• The standards of measurement used in

All metric units are based on multiples

4 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• The metric system was originally

• The International System of Units

• The SI was adopted by international

5 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• There are seven SI base

6 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• All measurements of length can be

• For very large and very small lengths,

7 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Commonly Used Metric Prefixes

8 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• A hyphen (-) measures about 1 mm.

• For large distances, it is most appropriate to

• The prefix kilo- means 1000, so 1 km

• You calculate the volume of any cubic or

• The unit for volume is thus derived from

10 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• This volume is a cubic meter (m3).

• A more convenient unit of volume for everyday

• A liter (L) is the volume of a cube that is 10

• Thus, there are 1000 mL in 1 L.

• Because 1 L is defined as 1000 cm3, 1 mL

• The units milliliter and cubic centimeter are

12 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

13 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• The volume of substances will change with

14 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Metric Units of Volume

15 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• A kilogram was originally defined as the mass of 1 L

• A gram (g) is 1/1000 of a kilogram; the mass of 1

16 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Metric Units of Mass

17 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

• Weight, a measure of force, is different from

• The weight of an object can change with its

• An astronaut in orbit is weightless, but not

• The SI unit of energy is the joule (J), named

• A common non-SI unit of energy is the calorie.

• One calorie (cal) is the quantity of heat that

• A kilojoule is 1000 joules; a kilocalorie is

20 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

What is the SI unit of volume?

21 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

What is the SI unit of volume?

The SI unit of volume is the cubic meter (m3). A

22 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.