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Halo Alkanes

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OBJECTIVES

After studying this unit, STUDENTS will be able to


• Name haloalkanes and haloarenes according to the IUPAC
system of nomenclature from their given structures;
• Describe the reactions involved in the preparation of
haloalkanes and haloarenes and understand various
reactions that they undergo;
• Correlate the structures of haloalkanes and haloarenes with
various types of reactions;
• Use stereochemistry as a tool for understanding the reaction
mechanism;
• Appreciate the applications of organo-metallic compound;
• Highlight the environmental effects of polyhalogen
compounds.
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OUTLINE

1. INTRODUCTION,CLASSIFICATION,
NOMENCLATURE
2. PHYSICAL PROPERTIES OF HALO
ALKANES & HALO ARENES
3. METHODS OF PREPARATION
4. CHEMICAL PROPERTIES
5. OPTICAL ISOMERISM
6. SN1 & SN2 REACTIONS
7. POLY HALOGEN COMPOUNDS

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What is meaning of haloalkane?

Organic compounds formed by replacement of one or


more hydrogen atom/s by halogen atom/s. from
Hydrocarbon
Ex: chloromethane, Dichloromethane etc.

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Examples for haloalkanes

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What is meaning of haloarene?
If one or more hydrogen is displaced by
halogen atom/s in aromatic ring ,
product is called as Haloarenes

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Importance of Halogen
derivative.

Haloderivative Organic compounds have


many importance for Mankind:
1.As solvents for non-polar
compounds.

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2.Chloramphenicol
(medicine) to treat typhoid
fever.

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3.Chloroquine
(medicine) used
to treat
malaria.

4. Some fluorinated
compounds are being
developed as blood substitute
in surgery.

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5.Halothane is used as anaesthatic during
surgery.

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6.THYROXINE is used in the treatment of
Goitre disease

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7. As starting materials for synthesis of
many compounds.

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Classification of Haloderivatives
Based on Based on the hybridisation of C−atom
Number of of C−X bond of
Halogen atoms monohalocompounds

Monohalogen Compounds containing


sp3 C−X bond (X = F,
Cl, Br, I).
Dihalogen

Compounds containing
sp2 C−X bond
Polyhalogen

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Monohalo derivatives

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Dihalo derivatives

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Dihalo derivatives

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Trihalo derivatives

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Compounds containing sp3
C−X bond (X = F, Cl, Br, I).

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