In this work, we demonstrate doping graphene oxide (GO) films using a low power atmospheric pressure plasma jet (APPJ) with subsequent tuning of the work function.
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The novel thiourea-functionalized silicon nanoparticles (SiNPs) have been successfully synthesized using allylamine and sulforaphane, an important anticancer drug, followed by a hydrosilylation reaction on the surface of hydrogen... more
The novel thiourea-functionalized silicon nanoparticles (SiNPs) have been successfully synthesized using allylamine and sulforaphane, an important anticancer drug, followed by a hydrosilylation reaction on the surface of hydrogen terminated SiNPs. Their physiochemical properties have been investigated by photoluminescence emission, FTIR and elemental analysis. MTT assay has been employed to evaluate in vitro toxicity in colorectal cancer cells (Caco-2) and primary normal cells (CCD). The results show significant toxicity of thiourea SiNPs after 72 h incubation in the cancer cell line and the toxicity is concentration dependent and saturated for concentrations above 100 µg/mL. Confocal microscopy images have demon-strated the internalization of thiourea-functionalized SiNPs inside the cells. Flow cytometry data has confirmed receptor-mediated targeting in cancer cells. This nanocomposite takes advantage of the EGFR active targeting of the ligand in addi-tion to the photoluminescence ...
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Electroactive biofilms are capable of extracellular electron transfer to insoluble metal oxides and electrodes; such biofilms are relevant to biogeochemistry, bioremediation, and bioelectricity production. We investigated the... more
Electroactive biofilms are capable of extracellular electron transfer to insoluble metal oxides and electrodes; such biofilms are relevant to biogeochemistry, bioremediation, and bioelectricity production. We investigated the extracellular electron transfer mechanisms in Shewanella loihica PV-4 viable biofilms grown at indium tin oxide (ITO) and graphite electrodes in potentiostat-controlled electrochemical cells poised at 0.2 V vs. Ag/AgCl. Chronoamperometry and confocal microscopy showed higher biofilm growth at graphite compared to the ITO electrode. Cyclic voltammetry, differential pulse voltammetry, along with fluorescence spectroscopy showed that direct electron transfer through outer membrane c type cytochromes (Omcs) prevailed at the biofilm/ITO interface, while biofilms formed at graphite electrode reduced the electrode also via secreted redox mediators, such as flavins and quinones. The biofilm age does not affect the prevalent transfer mechanism at ITO electrodes. On the ...
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... Arrow indicates the non substitutional Mn in 20% Mn doped GaN 4 Conclusions In conclusion we used XES and XAS to study the local electronic structure around Mn and N in GaMnN. ... PRTLI programme. JMD Coey is supported by Science... more
... Arrow indicates the non substitutional Mn in 20% Mn doped GaN 4 Conclusions In conclusion we used XES and XAS to study the local electronic structure around Mn and N in GaMnN. ... PRTLI programme. JMD Coey is supported by Science Founda-tion Ireland. ...