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Mohammad Rameez

    Mohammad Rameez

    In the third generation photovoltaic cells, DSSCs are the most promising due to their unique features such as cost effectiveness, flexibility and high efficiency in converting solar energy and they show wide range applicability. The use... more
    In the third generation photovoltaic cells, DSSCs are the most promising due to their unique features such as cost effectiveness, flexibility and high efficiency in converting solar energy and they show wide range applicability. The use of highly expensive Pt as counter electrode is a major hindrance in large scale commercialization of DSSCs. In this paper, an inexpensive Ni-Co (2.5 wt. % each) decorated CNFs counter electrode was prepared by electrospinning technique followed by a simple in-situ polyol reduction method. First, the CNFs were prepared by electrospinning of poly acrylonitrile (PAN) followed by its carbonization at 1400°C with the heating rate of 2°C/min. The prepared CNFs were dispersed in ethylene glycol through ultrasonication and then the precursors of Ni and Co were added in it. The reductions of Ni and Co were achieved under reflux condition at the temperature of 80°C. The structural morphology of Ni-Co decorated CNFs was characterized by using XRD, Raman spectro...
    Counter electrode (CE) plays an important role in dye-sensitized solar cells (DSSCs). Electron transfer from external circuit to redox couple is mediated and facilitated by it to complete the DSSC circuit. Platinum (Pt) is widely employed... more
    Counter electrode (CE) plays an important role in dye-sensitized solar cells (DSSCs). Electron transfer from external circuit to redox couple is mediated and facilitated by it to complete the DSSC circuit. Platinum (Pt) is widely employed as CE in DSSCs. However, due to its high cost and scarcity, efforts are being made to replace Pt. In this study, a bimetal (Ni–Co) nanoparticles-incorporated carbon nanofibers (CNFs) are prepared by electrospinning technique and used as CE material for DSSC applications. The morphology of prepared CNFs is characterized by field emission scanning electron microscope and transmission electron microscope studies. The structural properties are confirmed by X-ray diffraction and Raman spectroscopy studies. The electrochemical characterization of Ni–Co nanoparticles-incorporated CNFs is carried out using cyclic voltammetry, electrochemical impedance and Tafel polarization studies and compared with CNFs and std. Pt. The photo-conversion efficiency (PCE) of DSSC assembled with Ni–Co nanoparticles-incorporated CNFs as CE is very nearer to that of the same assembled with std. Pt as CE. Hence, Ni–Co nanoparticles-incorporated CNFs can be used as a cost-effective alternative CE for DSSCs.
    Research Interests:
    Conducting polymers (CPs) have been widely investigated and applied in various applications such as sensors, supercapacitors, energy storage devices, dye-sensitized solar cells (DSSCs) and others. They are pseudo-capacitive materials and... more
    Conducting polymers (CPs) have been widely investigated and applied in various applications
    such as sensors, supercapacitors, energy storage devices, dye-sensitized solar cells
    (DSSCs) and others. They are pseudo-capacitive materials and can undergo fast redox reactions.
    Counter electrode (CE) is an important component in DSSCs. The counter electrode
    function as an electron transfer agent as well as the regenerator of redox couple. So far various
    methods and materials are used to prepare different counter electrodes. This paper
    reviews the conducting polymers and their composites as counter electrodes which offer
    a valuable insight to find out the appropriate alternative to costly platinum (Pt) counter
    electrode for DSSCs. Furthermore, it also outlines the desirable properties for good counter
    electrode materials and their evaluation methods such as cyclic voltammetry (CV), electrochemical
    impedance spectroscopy (EIS), Tafel polarization and chronoamperometry with
    photovoltaic performance studies for DSSCs.