Dielectric Properties of Solids
Dielectric Properties of Solids
Dielectric Properties of Solids
Dielectric Constant
Faraday discovered that the capacitance of the condenser increases when the region
between the plates is filled with dielectric. If C0 is the capacitance of the capacitor without
dielectric and C is the capacitance of the capacitor with dielectric then the ratio C / C0 gives εr
called relative permittivity or Dielectric constant. Also for a given isotropic material the electric flux
density is related to the applied field strength by the equation D= ε E, Where ε is Absolute
permittivity. In SI system of units the relative permittivity is given by the ratio of absolute
permittivity to permittivity of free space.
ε = ε0 εr
ε0 is permittivity of free space.
εr is relative permittivity or dielectric constant.
For an isotropic material, under static field conditions, the relative permittivity is called
static dielectric constant. It depends on the structure of the atom of which the material is
composed.
Polarization of dielectrics:
dielectrics -
“The displacement of charged particles in atoms or molecules of dielectric material so
that net dipole moment is developed in the material along the applied field direction is called
polarization of dielectric.” Polarization is measured as dipole moment per unit volume and is a
vector quantity.
r r
P=N µ
r
Where µ is average dipole moment per molecule and N is number of molecules per unit volume.
r r
Also µ =α E where α is a constant of proportionality called polarizability.
In Polar dielectric materials, When the external electric field is applied all dipoles tend to
align in the field direction and hence net dipole moment develops cross dielectric material. This is
the polarization of polar dielectric materials.
materials
In non polar dielectric materials dipoles are induced due to the applied electric field which
results in the net dipole moment in the dielectric material in the direction of the applied field. This
is the polarization of non-
non-polar dielectric materials.
materials
As the polarization measures the additional flux density arising from the presence of the
material as compared to free space it has the same unit as D and is related to it as
D =ε 0 E + P
Since D = ε 0ε r E
ε 0ε r E = ε 0 E + P
∴P = ε 0 (ε r − 1) E
Also
p
= (ε r − 1) = χ
ε0 E
Where χ is Electric susceptibility
The electrical polarization takes place through four different mechanisms. They are
1. Electronic polarization.
2. Ionic polarization.
3. Orientation polarization.
4. Space charge polarization.
The net polarization of the material is due to the contribution of all four polarization
mechanisms.
P = Pe + Pi + Po + Ps
1) Electronic polarization:
polarization - This occurs through out the dielectric material and is due to the
separation of effective centers of positive charges from the effective center of negative charges in
atoms or molecules of dielectric material due to applied electric field. Hence dipoles are induced
within the material. This leads to the development of net dipole moment in the material and is the
vector sum of dipole moments of individual dipoles.
E<0 E>0
2) Ionic polarization:
polarization - This occurs in ionic solids such as sodium chloride etc. Ionic solids
possess net dipole moment even in the absence of external electric field. But when the external
electric field is applied the separation between the ions further increases. Hence the net dipole
moment of the material also increases.
+ - + + - +
- + - - + -
+ - + + - +
E = 0. E > 0.
It is found that the ionic dipole moment also proportional to the applied field strength.
hence µi = α i E
where α i is ionic polarisability.
3) Orientation Polarization:
Polarization - This occurs in polar dielectric material, which possesses permanent
electric dipoles. In polar dielectrics the dipoles are randomly oriented due thermal agitation.
Therefore net dipole moment of the material is zero. But when the external electric field is applied
all dipoles tend to align in the field direction. There fore dipole moment develops across the
material. This is referred to as orientation polarization (P
Po). Orientation polarization depends on
temperature. Higher the temperature more the randomness in dipole orientation smaller will be
the dipole moment.
E = 0. E > 0.
µ2
α0 = Where ‘k
k’ is Boltzman constant, T is absolute temperature and µ is permanent
3k T
dipole moment.
Expression for Internal field in case of Solids and Liquids (One dimensional ): Consider a dipole
with charges ‘+q ‘and ‘–q’ separated by a small distance ‘dx’ as shown in fig. The dipole moment
is given by µ = q dx. Consider a point ‘P’ at a distance ‘r’ from the center of dipole.
E
Er
r
Eθ
P
θ
-q +q
dx
The electric field ‘E’ at ‘P’ can be resolved into two components.
1) The Radial Component along the line joining the dipole and the point. It is given by
r 2 µ Cosθ
Er =
4 π ε0 r 3
2) The Tangential component or Transverse component perpendicular to the Radial
r
component is given by E =
µ Sin θ
θ
4 π ε0 r 3
Where ‘θ’ is the angle between the dipole and the line joining the dipole with the point ’P’, ‘ε0’
is permitivity of free space and ‘r’ is the distance between the point and dipole.
Consider a dielectric material placed in external electric field of strength ‘E’. Consider an array
of equidistant dipoles within the dielectric material, which are aligned in the field direction as
shown in the figure.
E C A X B D F
a a a a a a
2a 2a
3a 3a
Let us find the local field at ‘X’ due all dipoles in the Array.
The field at ‘X’ due to dipole ‘A’ is given by EXA = Er + Eθ
Here r = a and θ = 0 o
2 µ Cos0 o
Hence Er = , E θ = 0.
4 π ε 0 a3
µ
⇒ EXA =
2 π ε 0 a3
The field at ‘X’ due to dipole ‘B’ is given by E = E + E
XB r θ
Here r = −a and θ = 180o
2 µ Cos180o
Hence Er = 3
, Eθ = 0.
4 π ε 0 (− a)
µ
⇒ EXB =
2 π ε 0 a3
Hence the Total field at ‘X’ due to equidistant dipoles ‘A’ and ‘B’ is given by
E1 = EXA + EXB
µ µ
E1 = 3
+
2 π ε0 a 2 π ε 0 a3
µ
⇒ E1 =
π ε 0 a3
Similarly, the total field at ‘X’ due to equidistant dipoles ‘C’ and ‘E’ is given by
E2 = E XC + E XD
µ µ
E2 = +
2 π ε 0 (2a)3 2 π ε 0 (2a)3
µ
⇒ E2 = (Q r = 2a)
π ε 0 (2a)3
Similarly, the total field at ‘X’ due to equidistant dipoles ‘D’ and ‘F’ is given by
E3 = EXE + EXF
µ µ
E3 = 3
+
2 π ε0 (3a) 2 π ε0 (3a)3
µ
⇒ E3 = (Q r = 3a)
π ε0 (3a)3
The net field at ‘X’ due to all dipoles in the array is given by
E| = E1 + E2 + E3 + E4 + L L L
µ µ µ
E| = 3
+ 3
+ + LLL
π ε0 a π ε 0 (2a) π ε 0 (3a)3
µ 1 1
= 1 + 23 + 33 + L L L
π ε 0 a3
µ ∞
1
= ∑
π ε 0 a3 n =1 n3
∞
1
but ∑n
n=1
3
≅ 1.2
1 .2 µ
∴ E| =
π ε 0 a3
For Three-Dimension the above equation can be generalized by replacing 1/a3 by ‘N’ (where ‘N’ the
number of atoms per unit volume), and 1.2/π by γ called Internal Field Constant.
γNαE
∴ Ei = E +
ε0
γ P
but polarization P = NαE ∴ Ei = E +
ε0
Since γ, Ρ and ε0 are positive quantities Ei > E. For a Cubic Lattice γ = 1/3 and the Local field is called
Lorentz field. It is given by
P
EL = E +
3ε 0
Clausius
Clausius-
usius-Mosot
Mosott
otti Relation:
Relation:
Consider an Elemental solid dielectric material. Since they don’t posses permanent,
dipoles, for such materials, the ionic and orientation polarizabilities are zero. Hence the
polarization P is given by
P = Nα e E L Where E L is Lorentz Field
P
= N α e E +
3ε 0
P
P = Nα e E + Nα e
3ε 0
Nα e
P 1 − = Nα e E
3ε 0
Nα e E
∴P = ...............eqn(1)
Nα e
1 −
3ε 0
Where ‘N’ is the no. of dipoles per unit volume, αe is electronic polarizability ε0 is permittivity of
free space, and E is the Electric field strength.
Nα e E Nα e
= 1−
ε 0 (ε r − 1) E 3ε 0
Nα e E Nα e
+ =1
ε 0 (ε r − 1) E 3ε 0
Nα e 3
+ 1 = 1
3ε 0 (ε r − 1)
Nα e ε r − 1
∴ =
3ε 0 εr + 2
The above equation is called Clausius – Mosotti relation. Using the above relation if the value of
dielectric constant of the material is known then the electronic polarizability can be determined.
Piezoelectric Materials:
Materials Certain dielectric materials are electrically polarized when their surfaces
are stressed. This phenomenon is called piezoelectric effect and the materials are called
piezoelectric materials. The charges produced on the surface due to stressing are proportional to
the applied force which is utilized in the conversion of mechanical energy into electrical energy.
When crystals like Tourmaline, Rochelle salt and Quartz are sliced in a particular fashion they
exhibit piezoelectric effect. In the crystal the distribution of the ionic charges about their lattice
sites is symmetrical. Thus the net internal field is zero. But when the crystal is stressed the
symmetry is altered due to the displacement of charges which results in non zero internal field.
Piezoelectric strains are very small. Hence the corresponding electric fields are very high. For
quartz for a strain of the order 10-7 the corresponding electric field is 1000v/cm. The inverse of
Piezoelectricity is called electrostriction. Electrostriction is a phenomenon of straining a crystal by
applying an electric field. Hence the piezoelectric materials are also called electro-strictive
materials. The piezoelectric crystals are used in electro-mechanical transducers, as Oscillators to
generate highly stable frequency and measurement of velocity of ultrasonics in solids and liquids.
Space Charge
Polarization
Orientation
Ionic
Electronic
Frequency
Under alternating field conditions of high frequency (Greater than 1MHz) the oscillations of
dipoles lag behind those of field. If the frequency is increased further they are completely unable
to follow the alternations in the field and hence the molecular process Orientation polarization
ceases due to dielectric relaxation. This occurs in the frequency range 106 Hz to 1011Hz.As the
frequency is increased further other polarizing mechanisms start to cease one after another. The
ionic polarization ceases in the frequency range 1011 Hz to 1014Hz. Finally only electronic
polarization remains. Hence as the frequency of the field increases the polarization decreases
and hence the dielectric constant decreases. This is known as Anomalous Dielectric Dispersion.
Dispersion
Dielectric Loss:
Loss - In the alternating field conditions during the rotation of dipoles they have to
overcome some sort of internal friction, which is dissipated as heat by the material. This is called
as dielectric loss.
Important applications of Dielectric Materials: Dielectric materials find a wide range of applications
as insulating materials.
1) Plastic and Rubber dielectric are used for the insulations of electrical conductors
2) Ceramic beads are used for the prevention of electric short circuiting and also for the
purpose of insulation.
3) Mica and Asbestos insulation is provided in electric Iron in order to prevent the flow of
electric current to outer body.
4) Varnished cotton is used insulators in transformers.
5) Dielectric materials are used in the energy storage capacitors.
6) Piezoelectric crystals are used in oscillators and vibrators.
Diamagnetic Materials:
Materials Diamagnetic materials are the substances which become weakly
magnetized in the direction opposite to that of the applied field. They do not posse’s permanent
magnetic dipoles. The magnetic dipole moment of the atoms of the material is zero. Bismuth,
Gold, Water are the few examples for diamagnetic materials. When diamagnetic materials are
placed in the magnetic field they expel the flux lines. A perfect diamagnet expels all the flux lines
from the interior of the material.
Langevin’
Langevin’s theory of Diamagnetic Materials:
Materials Langevin, in 1905, explained diamagnetism from the
electron theory of matter. The atoms in diamagnetic materials contain even number of electrons.
The electrons in such atoms are paired. The electrons in each pair have orbital motion as well as
spin motions in opposite sense. The resultant magnetic moment of the atom is thus zero.
When diamagnetic materials are placed in the magnetic field, does not tend to align the
atoms (dipoles) of the substance. But the field is able to modify the motions of the electrons in
orbits which are equivalent to tiny current loops. The Lenz’s law acts in the atomic scale. The
electron moving in a direction so as to produce a magnetic field in the same direction as the
external field is slowed down, while the other accelerated. Hence atom acquires an effective
magnetic moment which is opposite to the applied magnetic field. It is not affected by thermal
agitations and hence independent of temperature. Diamagnetism is present in all magnetic
materials and is outweighed in case of the Diamagnetic materials. Hence it is universal property
of matter.
Langevin was able to derive an expression for the diamagnetic susceptibility and is given by
− µo n e2 ∑r
i
i
2
χ=
6m
Here χ is diamagnetic Susceptibility µo is permeability of free space, e is electronic charge, m is
the mass of the electron and ri is the radius of the ith orbit.
Paramagnetic Materials:
Materials Paramagnetic materials posse’s permanent magnetic dipoles. When
such materials are placed in the magnetic field they get weakly magnetized in the direction of the
applied magnetic field. Platinum, Aluminium, Manganese are the few examples of paramagnetic
materials. In paramagnetic materials the interaction between the neighboring dipoles is extremely
week.
Langevin’s theory
theory of Paramagnetism:
Paramagnetism Langevin explained paramagnetism on the basis of, atoms
or molecules of a paramagnetic material have a net intrinsic paramagnet magnetic moment due
to the spin and orbital motions of electrons in it. In the absence of the external magnetic field all
dipoles tend to orient in random directions due to thermal agitation and hence the net magnetic
moment of the material is zero.
When paramagnetic materials are placed in the magnetic field, the dipoles experience
torque and they tend to align in the applied field direction. Due to thermal agitation of the
molecules the average alignment produced give rise to the net magnetic moment of the material
in the direction of the applied field.
The paramagnetism is a function of temperature. Higher the temperatures more will the
randomness in the orientations of the dipoles due to thermal agitations. Hence the net dipole
moment decreases with temperature. The expression for paramagnetic susceptibility as derived
by Langevin is
µ0 n pm2
χm =
3k T
Weiss molecular
molecular field theory of Ferromagnetism:
Ferromagnetism In the year 1907 Weiss proposed a theory for
susceptibility of ferromagnetic materials. The Weiss theory is based on the following
assumptions.
1) The neighboring dipoles in ferromagnetic materials interact and they group together to
form ferromagnetic domains. Each domain is magnetized to saturation. In the absence of
Based on the above assumptions Weiss was able to derive an expression for ferromagnetic
susceptibility as a function of excess of temperature which is given by
Nµ 2 C
χ= =
3k (T − θ ) T − θ
Here χ is Ferromagnetic Susceptibility, C is Curie constant, T is the temperature above
ferromagnetic curie temperature (Tc), θ is a temperature very close to Tc.
o f H
d
S B M Jain College of Engineering K.S. Mahesh Lohith
Centre for Emerging Technologies Asst. Prof
Dielectric and Magnetic Properties of Solids 1
The origin O represents the initially unmagnetised specimen and zero magnetic intensity.
As H is increased B also increases and saturation (Bs) is reached (curve oa). At saturation all
domains are oriented in the same direction as the applied field. If H is reduced the domains tend
to reorient to their original direction and B decreases. But when H reduces to a value zero, B
does not reduce to Zero and curve ab is traced. The flux density corresponding to H=0 is called
remnant induction or remnant flux density (Br=ob). When the magnetizing force is removed the
magnetic flux retained by the specimen is measured as retentivity.
retentivity Now H is reversed in direction
and increased. For an applied reversed field of magnitude Hc (oc) the material is completely
demagnetized and B=0(Curve bc). The corresponding field Hc is called Coercive field. The
measure of magnetic intensity required to completely demagnetize the material is called
Coercivity
Coercivity.
ivity If further H is increased the curve cd is traced and the reverse saturation is achieved.
When H is varied from its negative maximum value, through zero, to its original positive
maximum value then a similar curve defa is traced. Further the complete variation of H from +H
to –H and back from –H to +H will trace a closed hysteresis curve abcdef. The area enclosed by
the curve abcdef gives the energy loss per cycle per unit volume of the material. This is called as
Hysteresis Loss.
Properties:
Properties -
1. They posses high permeability H
2. They posses high susceptibility
3. They posses low coercivity
Applications:
Applications -
1. They are used in electromagnets
2. They are used in A C current machinery
3. They are used in Communication equipments
4. They are used in audio and video transformers