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    1. A double-threaded dimer bearing a long alkyl chain and large stopper group was prepared. 2. The dimer showed a conformational change when solvent polarity was increased. 3. The document is a 2007 article from Organic Letters that describes contraction of a supramolecular double-threaded dimer formed by α-cyclodextrin.

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    1. A double-threaded dimer bearing a long alkyl chain and large stopper group was prepared. 2. The dimer showed a conformational change when solvent polarity was increased. 3. The document is a 2007 article from Organic Letters that describes contraction of a supramolecular double-threaded dimer formed by α-cyclodextrin.

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    1. A double-threaded dimer bearing a long alkyl chain and large stopper group was prepared. 2. The dimer showed a conformational change when solvent polarity was increased. 3. The document is a 2007 article from Organic Letters that describes contraction of a supramolecular double-threaded dimer formed by α-cyclodextrin.

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    36 views1 page

    去Boc保护

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    angle6321
    1. A double-threaded dimer bearing a long alkyl chain and large stopper group was prepared. 2. The dimer showed a conformational change when solvent polarity was increased. 3. The document is a 2007 article from Organic Letters that describes contraction of a supramolecular double-threaded dimer formed by α-cyclodextrin.

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    of 1

    M ULT IPAGE 1 .

    1 R:F 3CC O2H, S:H 2O, 30 min, 0°C


    IMAGE
    934473- 90-2 1 .2 R:NH3, S:H 2O, rt, neutralized

    O O

    H 2 N CH 2 C H 2 (C H 2 ) 4 N H C NH ( CH 2 ) 6 NH C NH
    O

    CH CH C NH CH 2

    OH OH
    HO O OH
    CH 2 O H
    O
    O O O
    HO HO CH2 OH
    O
    HO CH 2
    O
    HO CH2 OH OH
    O O O
    O

    HO O OH
    HO CH 2 OH OH
    41 %

    NO TE: Rea ct an ts : 1 , R ea ge nts : 2, S ol ve nt s: 1,


    Ste ps : 1, S t age s: 2

    Organic Letters, 9(6), 1053-1055; 2007

    Bibliographic Information

    Contraction of Supramolecular Double-Threaded Dimer Formed by  -Cyclodextrin with a


    Long Alkyl Chain. Tsukagoshi, Shouichi; Miyawaki, Atsuhisa; Takashima, Yoshinori;
    Yamaguchi, Hiroyasu; Harada, Akira. Department of Macromolecular Science, Graduate School
    of Science, Osaka University, Toyonaka, Osaka, Japan. Organic Letters (2007), 9(6), 1053-
    1055. Publisher: American Chemical Society, CODEN: ORLEF7 ISSN: 1523-7060. Journal
    written in English. CAN 146:441990 AN 2007:196807 CAPLUS

    Abstract
    A double-threaded dimer bearing a long substituent part and a large stopper group has been
    prepd. and showed a conformational change with increased solvent polarity.

    http://pubs.acs.org/cgi-bin/article.cgi/orlef7/2007/9/i06/pdf/ol063078e.pdf

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