Petrology
Petrology
Petrology
WHAT IS PETROLOGY???
WHAT IS PETROLOGY???
Study of rocks (petros) igneous & metamorphic chiey in the lithosphere
WHAT IS PETROLOGY???
Study of rocks (petros) igneous & metamorphic chiey in the lithosphere We will be dealing with hot rocks tell us about composition & history of lithosphere origin of rocks involves: transfer of heat (energy) movement of material
WHAT IS PETROLOGY???
Study of rocks (petros) igneous & metamorphic chiey in the lithosphere We will be dealing with hot rocks tell us about composition & history of lithosphere origin of rocks involves: transfer of heat (energy) movement of material
LITHOSPHERE
what criteria do we use to distinguish rocks? what do we want to know? how do we answer these questions?
eld methods & sample study (observation) theory, experiment & modeling (analytical)
THINGS TO CONSIDER
THINGS TO CONSIDER
materials of earth
THINGS TO CONSIDER
materials of earth physical conditions energy pressure temperature & heat
THINGS TO CONSIDER
materials of earth physical conditions energy pressure temperature & heat relationship to tectonics
THINGS TO CONSIDER
materials of earth physical conditions energy pressure temperature & heat relationship to tectonics
EgyPT
EARTH INTERIOR
Si-rich Fe-rich
EARTH INTERIOR
Si-rich Fe-rich
Structure of Earth:
EARTH INTERIOR
Si-rich Fe-rich
EARTH INTERIOR
Si-rich Fe-rich
Structure of Earth: chemical divisions core, mantle & crust mechanical divisions mesosphere, asthenosphere & lithosphere
EARTH INTERIOR
Si-rich Fe-rich
EARTH INTERIOR
Si-rich Fe-rich
Core:
EARTH INTERIOR
Si-rich
outer core is liquid (no S-waves) inner core is solid
Fe-rich
EARTH INTERIOR
Si-rich
outer core is liquid (no S-waves) inner core is solid differentiation at work! compositional separation within the planet (fractionation)
Fe-rich
EARTH INTERIOR
Si-rich Fe-rich
EARTH INTERIOR
Si-rich Fe-rich
Mantle:
EARTH INTERIOR
peridotite (ultramac) greatest V, m & E (moves & carries heat)
Fe-rich
Si-rich
Mantle:
EARTH INTERIOR
peridotite (ultramac) greatest V, m & E (moves & carries heat) upper layer to 410 km (olivine to spinel) contains low velocity layer 60-220 km
Fe-rich
Si-rich
Mantle:
EARTH INTERIOR
peridotite (ultramac) greatest V, m & E (moves & carries heat) upper layer to 410 km (olivine to spinel) contains low velocity layer 60-220 km transition zone between 410-660 km (spinel to perovskite) SiIV to SiVI
Fe-rich
Si-rich
Mantle:
EARTH INTERIOR
peridotite (ultramac) greatest V, m & E (moves & carries heat) upper layer to 410 km (olivine to spinel) contains low velocity layer 60-220 km transition zone between 410-660 km (spinel to perovskite) SiIV to SiVI lower mantle has more gradual velocity increase
Fe-rich
Si-rich
Mantle:
EARTH INTERIOR
Si-rich Fe-rich
EARTH INTERIOR
Crust:
Fe-rich
Si-rich
EARTH INTERIOR
Crust: mac (magnesium + ferric) to felsic (feldspar + silica) rich in Si, Al, K, Na, Ca
Fe-rich
Si-rich
EARTH INTERIOR
Crust: mac (magnesium + ferric) to felsic (feldspar + silica) rich in Si, Al, K, Na, Ca two main types: oceanic continental + transitional
Fe-rich
Si-rich
EARTH INTERIOR
EARTH INTERIOR
Oceanic crust:
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average dense: avg = 3.0 g/cm3
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average dense: avg = 3.0 g/cm3 relatively uniform stratigraphy (= ophiolite suite)
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average dense: avg = 3.0 g/cm3 relatively uniform stratigraphy (= ophiolite suite) sediments
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average dense: avg = 3.0 g/cm3 relatively uniform stratigraphy (= ophiolite suite) sediments pillow basalt
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average dense: avg = 3.0 g/cm3 relatively uniform stratigraphy (= ophiolite suite) sediments pillow basalt sheeted dikes
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average dense: avg = 3.0 g/cm3 relatively uniform stratigraphy (= ophiolite suite) sediments pillow basalt sheeted dikes massive gabbro
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average dense: avg = 3.0 g/cm3 relatively uniform stratigraphy (= ophiolite suite) sediments pillow basalt sheeted dikes massive gabbro ultramac rocks (mantle)
EARTH INTERIOR
Oceanic crust: thin: ~10 km on average dense: avg = 3.0 g/cm3 relatively uniform stratigraphy (= ophiolite suite) sediments pillow basalt sheeted dikes massive gabbro ultramac rocks (mantle)
mafic rocks
CONTINENTAL
OCEANIC
EARTH INTERIOR
EARTH INTERIOR
Continental crust: thicker: 20-90 km (avg = 35 km) less dense: avg = 2.7 g/cm3 highly variable composition average = granodiorite
CHEMICAL DIVISIONS
CHEMICAL DIVISIONS
divisions separate Earth into Si-rich and Fe-rich spheres, largely a result of early chemical differentiation based on a redistribution of matter, prior to major solidication, by density
CHEMICAL DIVISIONS
divisions separate Earth into Si-rich and Fe-rich spheres, largely a result of early chemical differentiation based on a redistribution of matter, prior to major solidication, by density later, continued differentiation was (and is) mostly a result of melting and igneous process
CHEMICAL DIVISIONS
divisions separate Earth into Si-rich and Fe-rich spheres, largely a result of early chemical differentiation based on a redistribution of matter, prior to major solidication, by density later, continued differentiation was (and is) mostly a result of melting and igneous process how do we know these things???
CHEMICAL DIVISIONS
divisions separate Earth into Si-rich and Fe-rich spheres, largely a result of early chemical differentiation based on a redistribution of matter, prior to major solidication, by density later, continued differentiation was (and is) mostly a result of melting and igneous process how do we know these things??? seismic velocity structure
CHEMICAL DIVISIONS
divisions separate Earth into Si-rich and Fe-rich spheres, largely a result of early chemical differentiation based on a redistribution of matter, prior to major solidication, by density later, continued differentiation was (and is) mostly a result of melting and igneous process how do we know these things??? seismic velocity structure meteorites
CHEMICAL DIVISIONS
divisions separate Earth into Si-rich and Fe-rich spheres, largely a result of early chemical differentiation based on a redistribution of matter, prior to major solidication, by density later, continued differentiation was (and is) mostly a result of melting and igneous process how do we know these things??? seismic velocity structure meteorites xenoliths in volcanics
CHEMICAL DIVISIONS
divisions separate Earth into Si-rich and Fe-rich spheres, largely a result of early chemical differentiation based on a redistribution of matter, prior to major solidication, by density later, continued differentiation was (and is) mostly a result of melting and igneous process how do we know these things??? seismic velocity structure meteorites xenoliths in volcanics experimental petrology
MECHANICAL DIVISIONS
Figure 1-3.Variation in P and S wave velocities with depth. Compositional subdivisions of the Earth are on the left, rheological subdivisions on the right. After Kearey and Vine (1990), Global Tectonics. Blackwell Scientic. Oxford.
MECHANICAL DIVISIONS
Velocity structure (v)
Figure 1-3.Variation in P and S wave velocities with depth. Compositional subdivisions of the Earth are on the left, rheological subdivisions on the right. After Kearey and Vine (1990), Global Tectonics. Blackwell Scientic. Oxford.
MECHANICAL DIVISIONS
Velocity structure (v)
v increases with density () v = f ()
Figure 1-3.Variation in P and S wave velocities with depth. Compositional subdivisions of the Earth are on the left, rheological subdivisions on the right. After Kearey and Vine (1990), Global Tectonics. Blackwell Scientic. Oxford.
MECHANICAL DIVISIONS
Velocity structure (v)
v increases with density () v = f () dependent on physical properties & compositions = f (X, T)
Figure 1-3.Variation in P and S wave velocities with depth. Compositional subdivisions of the Earth are on the left, rheological subdivisions on the right. After Kearey and Vine (1990), Global Tectonics. Blackwell Scientic. Oxford.
MECHANICAL DIVISIONS
Velocity structure (v)
v increases with density () v = f () dependent on physical properties & compositions = f (X, T) v increases with depth (z) mostly!
Figure 1-3.Variation in P and S wave velocities with depth. Compositional subdivisions of the Earth are on the left, rheological subdivisions on the right. After Kearey and Vine (1990), Global Tectonics. Blackwell Scientic. Oxford.
MECHANICAL DIVISIONS
Velocity structure (v)
v increases with density () v = f () dependent on physical properties & compositions = f (X, T) v increases with depth (z) mostly! v discontinuities indicate a change in material composition properties Figure 1-3.Variation in P and S wave velocities with depth. Compositional subdivisions of the Earth are on the left,
rheological subdivisions on the right. After Kearey and Vine (1990), Global Tectonics. Blackwell Scientic. Oxford.
MECHANICAL DIVISIONS
composition property LVZ
CMB
OC-IC
MECHANICAL DIVISIONS
composition
Velocity boundaries
property LVZ
CMB
OC-IC
MECHANICAL DIVISIONS
composition
Velocity boundaries
source of LVZ?
property LVZ
CMB
OC-IC
MECHANICAL DIVISIONS
composition
Velocity boundaries
source of LVZ? warmer? liquid?
property LVZ
CMB
OC-IC
MECHANICAL DIVISIONS
composition
Velocity boundaries
source of LVZ? warmer? liquid? source of CMB?
property LVZ
CMB
OC-IC
MECHANICAL DIVISIONS
composition
Velocity boundaries
source of LVZ? warmer? liquid? source of CMB? change in composition
property LVZ
CMB
OC-IC
MECHANICAL DIVISIONS
composition
Velocity boundaries
source of LVZ? warmer? liquid? source of CMB? change in composition source of OC-IC?
property LVZ
CMB
OC-IC
MECHANICAL DIVISIONS
composition
Velocity boundaries
source of LVZ? warmer? liquid? source of CMB? change in composition source of OC-IC? phase change (S to L)
property LVZ
CMB
OC-IC
MECHANICAL DIVISIONS
composition
Velocity boundaries
source of LVZ? warmer? liquid? source of CMB? change in composition source of OC-IC? phase change (S to L)
property
OC-IC
Depth
~410 km ~660 km
Density low
high
LO
HI
LO
LO
HI
HI
LO
LO
HI
HI
MG-SILICATES
VARIATION IN SEISMIC VELOCITY, DENSITY & MINERAL STRUCTURE
LO
LO
T S A
O N HE
T.Z.
. H SP
HI
HI
O S E
H P S
E R E
MG-SILICATES
VARIATION IN SEISMIC VELOCITY, DENSITY & MINERAL STRUCTURE
properties?
properties? connections?
MANTLE GEOTHERM
MANTLE GEOTHERM
MANTLE GEOTHERM
MANTLE GEOTHERM
compare continental, oceanic & ridge typical continental geotherm = 25 C/km T @ 100 km = 1000 C (enough to melt rocks!)
MANTLE GEOTHERM
compare continental, oceanic & ridge typical continental geotherm = 25 C/km T @ 100 km = 1000 C (enough to melt rocks!) are they molten? P too high? where?
compare geotherm to petrologic solidus for mantle rocks (peridotite) if dry conditions, no melting possible (geotherm below solidus) solid lherzolite is stable at T above geotherm
LITHOSPHERE
LITHOSPHERE
LITHOSPHERE
lithosphere includes crust + upper mantle
LITHOSPHERE
lithosphere includes crust + upper mantle can be oceanic, continental, or both
LITHOSPHERE
lithosphere includes crust + upper mantle can be oceanic, continental, or both typical lithosphere is 100 km (70-125 km)
LITHOSPHERE
lithosphere includes crust + upper mantle can be oceanic, continental, or both typical lithosphere is 100 km (70-125 km) largely solid material (silicates)
LITHOSPHERE
lithosphere includes crust + upper mantle can be oceanic, continental, or both typical lithosphere is 100 km (70-125 km) largely solid material (silicates) lowest densities (2.7-3.0 g/cm3)
LITHOSPHERE
lithosphere includes crust + upper mantle can be oceanic, continental, or both typical lithosphere is 100 km (70-125 km) largely solid material (silicates) lowest densities (2.7-3.0 g/cm3) slowest seismic velocities (6-8 km/sec)
LITHOSPHERE
lithosphere includes crust + upper mantle can be oceanic, continental, or both typical lithosphere is 100 km (70-125 km) largely solid material (silicates) lowest densities (2.7-3.0 g/cm3) slowest seismic velocities (6-8 km/sec) internal boundary is the Moho (density boundary)
LITHOSPHERE
lithosphere includes crust + upper mantle can be oceanic, continental, or both typical lithosphere is 100 km (70-125 km) largely solid material (silicates) lowest densities (2.7-3.0 g/cm3) slowest seismic velocities (6-8 km/sec) internal boundary is the Moho (density boundary) base of lithosphere is the low-velocity zone (LVZ)
LITHOSPHERE
lithosphere = plate
lithosphere includes crust + upper mantle can be oceanic, continental, or both typical lithosphere is 100 km (70-125 km) largely solid material (silicates) lowest densities (2.7-3.0 g/cm3) slowest seismic velocities (6-8 km/sec) internal boundary is the Moho (density boundary) base of lithosphere is the low-velocity zone (LVZ)
EgyPT
Physical conditions of Earth necessary to understand petrologic process: 1. pressure 2. temperature 3. energy & heat
PRESSURE GRADIENT
Figure 1-8. Pressure variation with depth. From Dziewonski and Anderson (1981). Phys. Earth Planet. Int., 25, 297-356. Elsevier Science.
PRESSURE GRADIENT
P = gh
Figure 1-8. Pressure variation with depth. From Dziewonski and Anderson (1981). Phys. Earth Planet. Int., 25, 297-356. Elsevier Science.
PRESSURE GRADIENT
P = gh P increases with depth
Figure 1-8. Pressure variation with depth. From Dziewonski and Anderson (1981). Phys. Earth Planet. Int., 25, 297-356. Elsevier Science.
PRESSURE GRADIENT
P = gh P increases with depth
Figure 1-8. Pressure variation with depth. From Dziewonski and Anderson (1981). Phys. Earth Planet. Int., 25, 297-356. Elsevier Science.
PRESSURE GRADIENT
P = gh P increases with depth Mantle: nearly linear through mantle ~ 30 MPa/km 1 GPa at base of avg crust
Figure 1-8. Pressure variation with depth. From Dziewonski and Anderson (1981). Phys. Earth Planet. Int., 25, 297-356. Elsevier Science.
PRESSURE GRADIENT
P = gh P increases with depth Mantle: nearly linear through mantle ~ 30 MPa/km 1 GPa at base of avg crust slope (P/z) depends on density (composition & compressibility) of material
Figure 1-8. Pressure variation with depth. From Dziewonski and Anderson (1981). Phys. Earth Planet. Int., 25, 297-356. Elsevier Science.
PRESSURE GRADIENT
H IG H DE
LOW
P = gh P increases with depth Mantle: nearly linear through mantle ~ 30 MPa/km 1 GPa at base of avg crust slope (P/z) depends on density (composition & compressibility) of material
N S IT Y
DEN Y SIT
Figure 1-8. Pressure variation with depth. From Dziewonski and Anderson (1981). Phys. Earth Planet. Int., 25, 297-356. Elsevier Science.
PRESSURE GRADIENT
P = gh P increases with depth Core: increases more rapidly since alloy is more dense smaller increase in P with depth suggests inner core is more uniform, solid, and has decreasing compressibility
Figure 1-8. Pressure variation with depth. From Dziewonski and Anderson (1981). Phys. Earth Planet. Int., 25, 297-356. Elsevier Science.
gh
gh
ENERGY
ENERGY
Energy is the capacity to do work (subatomic, to mountain, to mantle scale)
ENERGY
Energy is the capacity to do work (subatomic, to mountain, to mantle scale) 1. kinetic energy: EK = 1/2mv2
motion of a body
ENERGY
Energy is the capacity to do work (subatomic, to mountain, to mantle scale) 1. kinetic energy: EK = 1/2mv2
motion of a body
ENERGY
Energy is the capacity to do work (subatomic, to mountain, to mantle scale) 1. kinetic energy: EK = 1/2mv2
motion of a body
3. thermal energy: ET = EK + EP motions & attractions in a body (subatomic and larger) ET heat (transferred energy)
original heat of early core separation (PV work of compression) still slowly reaching surface as geotherm decays
original heat of early core separation (PV work of compression) still slowly reaching surface as geotherm decays
original heat of early core separation (PV work of compression) still slowly reaching surface as geotherm decays
continues today!
HEAT PRODUCTION
Rock Abundance of radioactive element U Granite Basalt Peridotite 4 0.5 0.02 Th 13 2 0.06 K 4 1.5 0.02
(joules/kg/yr)
HEAT PRODUCTION
Rock Abundance of radioactive element U Granite Basalt 4 0.5 Th 13 2 K 4 1.5
(joules/kg/yr)
Peridotite
0.0001
HEAT PRODUCTION
Crustal Ts are lower because of: 1. less of it compared to mantle 2. continental crust is a good insulator 3. its thicker 4. it suffers from surface cooling
HEAT TRANSFER
1. radiation
conversion of IR energy from hot body; travels as a wave efcient in a vacuum or transparent material; not efcient in rocks!
HEAT TRANSFER
2. conduction
transfer of EK by vibration & contact, one molecule to another does not occur in a vacuum greatest transfer with greatest T (thermal gradient) conduction increases with increasing surface area depends on thermal conductivity (k) of material, given by: q = kT/z
HEAT TRANSFER
3. convection
movement of material with contrasting T, which changes density gravity acts on , in which less dense material (ie, hotter) rises movement of solid can occur in viscous mantle rocks, including rise of plumes
HEAT TRANSFER
4. advection
heat carried by owing liquids or viscous bodies (e.g., water, magma) to cooler surroundings
LAVA FLOW
MAGMA
GEOTHERMAL GRADIENT
Figure 1-9. Estimated ranges of oceanic and continental steadystate geotherms to a depth of 100 km using upper and lower limits based on heat ows measured near the surface. After Sclater et al. (1980), Earth. Rev. Geophys. Space Sci., 18, 269-311.
GEOTHERMAL GRADIENT
T/z is the slope of T variation
with depth
Figure 1-9. Estimated ranges of oceanic and continental steadystate geotherms to a depth of 100 km using upper and lower limits based on heat ows measured near the surface. After Sclater et al. (1980), Earth. Rev. Geophys. Space Sci., 18, 269-311.
GEOTHERMAL GRADIENT
T/z is the slope of T variation
with depth
Figure 1-9. Estimated ranges of oceanic and continental steadystate geotherms to a depth of 100 km using upper and lower limits based on heat ows measured near the surface. After Sclater et al. (1980), Earth. Rev. Geophys. Space Sci., 18, 269-311.
GEOTHERMAL GRADIENT
T/z is the slope of T variation
with depth
gradient drives conductive cooling toward the surface why steeper curve at depth?
Figure 1-9. Estimated ranges of oceanic and continental steadystate geotherms to a depth of 100 km using upper and lower limits based on heat ows measured near the surface. After Sclater et al. (1980), Earth. Rev. Geophys. Space Sci., 18, 269-311.
GEOTHERMAL GRADIENT
T/z is the slope of T variation
with depth
gradient drives conductive cooling toward the surface why steeper curve at depth? more heat production in crust
Figure 1-9. Estimated ranges of oceanic and continental steadystate geotherms to a depth of 100 km using upper and lower limits based on heat ows measured near the surface. After Sclater et al. (1980), Earth. Rev. Geophys. Space Sci., 18, 269-311.
GEOTHERMAL GRADIENT
T/z is the slope of T variation
with depth
gradient drives conductive cooling toward the surface why steeper curve at depth? more heat production in crust more efcient convective mixing of heat in the mantle
Figure 1-9. Estimated ranges of oceanic and continental steadystate geotherms to a depth of 100 km using upper and lower limits based on heat ows measured near the surface. After Sclater et al. (1980), Earth. Rev. Geophys. Space Sci., 18, 269-311.
IGNEOUS ROCKS