The document provides information on piping elements, specifications, codes and standards for piping design. It discusses the main piping elements including pipes, flanges, fittings, valves and specialties. It also describes the selection and design considerations for piping elements based on material strength properties and design conditions. Finally, it outlines the key American and international codes and standards used for piping design, materials specification and construction, such as ASME, ASTM, ANSI and API standards.
The document provides information on piping elements, specifications, codes and standards for piping design. It discusses the main piping elements including pipes, flanges, fittings, valves and specialties. It also describes the selection and design considerations for piping elements based on material strength properties and design conditions. Finally, it outlines the key American and international codes and standards used for piping design, materials specification and construction, such as ASME, ASTM, ANSI and API standards.
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 1 CONTENTS Page 0.0 Cover Sheet 1 1.0 Piping Elements and Specification 2 2.0 Piping Elements 3 3.0 Selection and Design 3 5 4.0 Codes and Standards 5 16 Applicable Revision: R1 Prepared: NNG Date: 15.01.2001 Checked: AKB Date: Approved: RUD Date: First Edition: R0 Prepared: DNL Date: 13.09.2000 Checked: AKB Date: 20.09.2000 Approved: RUD Date: 31.10.2000 File Name: C-5 Server: PUNE: KUMUS 207 VKO: KUMUS 209 Directory: PUNE: Refer \ Pi \Training Manual VKO: Refer \ Training Manual TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 2 1.0 PIPING ELEMENTS & SPECIFICATION: The Piping System involves pipes, pipe fittings, valves and specialities. These are collectively termed as Piping elements. Main items are as under : Pipes Flanges Fittings Gaskets Bolting Valves Specialities Piping Specification is a document specifying each of the elements. Different material specifications are segregated in different Piping Classes. Identification of Piping Classes depends on each designer. The basic material of construction is specified by Process Licenser / Process Engineer for all process fluids depending upon, Corrosion Properties of fluid.
Pressure Temperature Conditions of Process. Nature of Service. The Piping design criteria originates from medium list (process line list), which gives normal and design conditions with respect to pressure and temperature, pipe size and material. TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 3 2.0 PIPING ELEMENTS: CLASSIFICATION BASED ON MATERIAL OF CONSTRUCTION METALLIC NON-METALLIC LINED MSGL MS MS MS MS MS Ferrous Non-Ferrous PTFE PP Cement Lead Ceramic Materials Material MSRL Lined Lined Lined Lined Lined
FRP PP Lined Copper Aluminium. Nickel Lead +Copper +Aluminium. + Nickel Alloys Alloys Alloys Cast Carbon Alloy Stainless PVC PP HDPE FRP GLASS Iron Steel Carbon Steel Steel 3.0 SELECTION AND DESIGN: The selection or design of the elements is based on : Yield Strength.
The Ultimate Strength Percentage elongation Impact Strength The Fatigue Endurance Strength The following are to be considered for strength calculation Design Pressure as 10% higher than anticipated maximum operating pressure.
Design Temperature as 25 C above the maximum anticipated operating temperature. When operating temperature is 15 C and below, the design temperature is minimum anticipated operating temperature. TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 4 The design should meet the requirements of relevant piping design standards of ANSI / ASME or BSI. The material used shall be in accordance with latest revisions of standards. If ASTM materials are suggested, materials adapted by ASME / ANSI are preferred. Carbon Steel shall be used upto 425 C.
Low temperature Steel shall be used below 20 C.
Alloy carbon steel shall be used above 425 C
For corrosive fluids recommendation from Process Engineer to be followed. PIPE: The pipes are designated by nominal bore. Corresponding outside diameters are as per Table. ANSI standard have no metric pipe sizes and equivalent metric sizes are widely followed. PIPE SIZE NB (INCH). EQ. METRIC PIPE SIZE OUTSIDE DIA. (INCH) OUTSIDE DIA. (MM) 1/8 6 0.405 10.3 1/4 8 0.540 13.7 3/8 10 0.675 17.1 1/2 15 0.840 21.3 3/4 20 1.050 26.7 1 25 1.315 33.4 1 1/4 * 32 1.660 42.2 1 1/2 40 1.900 48.3 2 50 2.375 60.3 2 1/2 * 65 2.875 73.0 3 80 3.500 88.9 3 1/2 * 90 4.000 101.6 4 100 4.500 114.3 5 * 125 5.563 141.3 6 150 6.625 168.3 8 200 8.625 219.1 10 250 10.750 273.0 12 300 12.750 323.8 14 350 14.000 355.6 16 400 16.000 406.4 The outside Dia of pipes 14 NB and above are same as nominal bore. * Non - preferred sizes. The Dimensional Standard will be as per ASME B 36.10. TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 5 Standard thickness of pipes are specified by schedule numbers. Stainless steel pipe schedules as per ASME B 36. 19 are 5 S, 10 S, 40 S, 80 S. Carbon steel pipe schedules a per ASME B 36.10 are 10, 20, 30, 40, 60, 80, 100,120, 140, 160. Carbon steel pipes are specified as STD, XS and XXS. Normally the thickness of Carbon Steel and Stainless Steel pipes for same schedule number matches except as under : 10 SCH80 / SCH80S 12 SCH40 / SCH40S 12 SCH80 / SCH80S 14 SCH10 / SCH10S 16 SCH10 / SCH10S 18 SCH10 / SCH10S 20 SCH10 / SCH10S 22 SCH10 / SCH10S The pipes are normally available in standard length of 20 ft.( 6 m ). Type of Pipe based on Pipe Ends Bevelled Ends. Plain Ends Screwed Ends. Flanged Ends. Spigot / Socket Ends ( lead cock joint ). Type of Pipes Based on Manufacture Seamless Welded. Electric Resistance Welded ( ERW). Electric Fusion Welded ( EFW ). Spiral Welded. Furnace Butt Welded. Double Submerged Arc Welded. Forged and Bored. 4.0 CODES AND STANDARDS: For scientific design of the piping systems, selection of proper material of construction and to detail out the material specification, knowledge of codes and standards are essential. Each country has its own codes and standards. On global basis, American National Standards is undoubtedly the most widely used code and compliance with its requirements is accepted all over. Other than the American Standards, British Standards and Indian Standards are also used for the design and selection of piping system. TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 6 In American National Standard, material standards are covered under ASTM (American Society of Testing Materials) and dimensional standard under ANSI (American National Standard Institute). Most of these Standards are adapted by ASME (American Society of Mechanical Engineers) and are specified alongwith. The American Standards referred by Piping Engineers are mainly the standards given below: American Petroleum Institute ( API ). The American Iron and Steel Institute ( AISI ). The American National Standard Institute ( ANSI ). The American Society of Testing Materials ( ASTM ). The American Welding Institute ( AWS ). The American Water Works Association ( AWWA ). The Manufacturers Standardization Society of Valves and Fitting Industry - Standard Practices MSS - SP ) The American Society of Mechanical Engineer (ASME) 4.1 API STANDARDS : The generally referred API Standard by the Piping Engineers are : API 5L - Specification for line pipe. API 6D - Pipe line valves, end closures, connectors and swivels. API 6F - Recommended practice for fire test for valves. API 598 - Valves inspection and test. API 600 - Steel Gate Valves. API 602 - Compact Design Carbon Steel Gate Valves for Refinery use. API 607 - Fire test for soft seated ball valves. API 609 - Butterfly valves API 1104 - Standard for welding pipe line and related facilities. 4.2 AISI STANDARDS : The American Iron and Steel Institute Standards specifies the material by its chemical and physical properties. When specific model of manufacture of the element is not to be specified, then the material can be identified by the AISI standards. The most commonly used ANSI specifications are: AISI 410 - 13 % Chromium Alloy Steel AISI 304 - 18 / 8 Austenitic Stainless Steel. AISI 316 - 18 / 8 /3 Austenitic Stainless Steel. R1 TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 7 4.3 ASME STANDARDS: The ASME Code for Pressure Piping, B 31 are as follows: ASME B 31.1 - Power Piping. ASME B 31.2 - Fuel Gas Piping ASME B 31.3 - Process Piping. ASME B 31.4 - Pipeline Transportation Systems for Liquid Hydrocarbons and other Liquids. ASME B 31.5 - Refrigeration Piping. ASME B 31.8 - Gas Transmission and Distributor Piping System. ASME B 31.9 - Building Services Piping. ASME B 31.11 - Slurry Transportation Piping System. Of the above, the most commonly used code is B 31.3. All Process Plants viz. Refineries Chemical and Petrochemical Plants are designed based on the same. All power plants are designed as per ASME B 31.1. Other major ASME Standards referred for the piping elements are : ASME B 16.1 - Cast iron pipe flanges and flanged fittings. ASME B 16.3 - Malleable iron threaded fittings. ASME B 16.4 - Cast iron threaded fittings. ASME B 16.5 - Steel pipe flanges and flanged fittings. ASME B 16.9 - Steel butt weldings fittings. ASME B 16.10 - Face to face and end to end dimensions of ferrous valves. ASME B 16.11 - Forged steel socket welding and threaded fittings. ASME B 16.20 - Ring joint gaskets and grooves for pipe flanges. ASME B 16.21 - Non metallic gasket for pipe flanges. ASME B 16.25 - Butt welding ends. ASME B 16.28 - Short radius elbows and 180 Degree returns ASME B 16.47 - Large Diameter steel Flanges ASME B 16.34 - Steel valves, flanged and butt welding ends. ASME B 18.2 - Square and hexagonal head bolts and nuts. R1 TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 8 ASME B 36.10 - Welded and seamless wrought steel pipes. ASME B 36.19 - Welded and seamless Austenitic stainless steel pipes. 4.4 ASTM STANDARDS The materials of construction and testing are referred under ASTM Standard. Most of the ASTM Standards are adapted by ASME and are specified in ASME section II. The section has three parts. Part-A - For Ferrous materials Part-B - For Non-ferrous metals and Part-C - For welding materials. In Part - II, the material are listed in the Index based on the available forms such as plates, castings, tubes, etc. and also on the numerical index. The selection of ASTM specification depends upon the required manufacturer, form of material, its mechanical strength and the corrosion properties. The specification number is given on Alphabetical prefix, A for ferrous materials and B for non-ferrous materials. STANDARD PIPE MATERIAL SPECIFICATION: The following ASTM Standards are widely used ASTM A53 Welded and Seamless Pipe. ASTM A106 Seamless CS Pipe for High Temp. Services ATM A120 Black and Hot Dipped, Zinc Coated (Galvanized), Welded and Seamless Pipe for ordinary use. ATM A134 Electric Fusion Welded Steel Plate Pipe (Sizes > 16 NB). ATM A135 Electric Resistance Welded Pipe ASTM A139 Electric Fusion Welded Steel Plate Pipe ( Size > 4 NB). ASTM A155 Electric Fusion Welded Steel Pipe for High Pressure Service. ASTM A211 Spiral Welded Steel Pipe. ATM A312 Seamless and Welded Austenitic Stainless Steel Pipes. ASTM A333 Seamless and Welded Steel Pipe for Low Temperature Service. ASTM A335 Seamless Ferritic Alloy Steel Pipe for High Temperature Service. TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 9 ASTM A358 Electric Fusion Welded Austenitic Chrome-Nickel Alloy Steel Pipe for High Temperature Service ASTM A369 Carbon and Ferritic Alloy Steel Forged and Bored Pipe for High Temperature Service. ASTM A376 Seamless Austenitic Steel Pipe for High Temperature Central Station Service. ASTM A381 Metal Arc Welded Steel Pipe for High Pressure Transmission Systems. ASTM A405 Seamless Ferritic Alloy Steel Pipe Specially heat treated for high temperature service. ASTM A409 Welded Large Diameter Austenitic Steel Pipe for Corrosive or High temperature service. ASTM A424 Seamless Carbon Steel Pipe for Process Piping. ASTM A426 Centrifugally Cast Ferritic Alloy Steel Pipe for High temperature service. ASTM A430 Austenitic Steel Forged And Bored Pipe for high temperature service. ASTM A451 Centrifugally Cast Austenitic Steel Pipe for High temperature service. ATM A452 Centrifugally Cast Austenitic Steel Wrought Pipe for High temperature service. ASTM A524 Seamless Carbon Steel Pipe for Atmospheric and low temperature service. ASTM A587 Electric Welded Low Centrifugally Cast Carbon Steel Pipe for high temperature service. ( Sizes 4 NB ). ASTM A660 Centrifugally Cast Carbon Steel Pipe for High temperature service ASTM A671 Electric Fusion Welded Steel Pipe for Atmospheric and low temperatures ( Sizes 16 NB ). ASTM A672 Electric Fusion Welded Steel Pipe for High pressure service at moderate temperatures ( Sizes 16 NB ). ASTM A691 Carbon and Alloy Steel Pipe, Electric Fusion Welded for High pressure service at High temperatures. ( Sizes 16 NB ). ASTM A731 Seamless and Welded Ferritic Stainless Steel Pipe. ASTM A780 Seamless and Welded Ferritic / Austenitic Stainless Steel Pipe. ASTM A813 Single or Double Welded Austenitic Stainless Steel Pipe. TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 10 ASTM A814 Cold Worked Welded Austenitic Stainless Steel Pipe. STANDARD PIPE FITTINGS: END CONNECTIONS SOCKET WELD SCREWED BUTT WELD FLANGED SPIGOT/SOCKET
TYPES CLASSIFICATION BASED ON END CONNECTIONS: Socket Welded/ Screwed Fitting Classification based on the maximum cold non-shock working pressure. 2000 # Class - only in 16.11 for SCRD fittings 3000 # Class 6000 # Class BENDS TEES CAPS REDUCERS STUB ENDS COUPLINGS SWAGE NIPPLE UNIONS SPECIAL FITTINGS ( Olets) EQUAL TEES REDUCING TEES 90 0 ELBOW 45 0 ELBOW SHORT STUB ENDS LONG STUB ENDS CONCENTRIC SWAGE NIPPLE ECCENTRIC SWAGE NIPPLE ECCENTRIC REDUCERS CONCENTRIC REDUCERS REDUCING COUPLINGS HALF COUPLINGS FULL COUPLINGS S.R.ELBOW L.R.ELBOW THREADOLET NIPPOLET SWEEPOLET SOCKOLET ELBOWLET WELDOLET LATROLET TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 11 SOCKET WELD / SCREWED AS PER STD. ASTM MATERIAL SPECIFICATIONS ASTM A105 Carbon steel forgings for piping Components ASTM A181 Carbon Steel forgings for general Purpose ASTM A182 Alloy Steel forgings for High Temperature Services ASTM A234 Wrought carbon steel and alloy steel pipe fittings for moderate and elevated temperatures. ASTM A350 Carbon steel and low alloy steel forgings for pipe components Bevelled Weld Fittings Classification is based on corresponding pipe thickness BW FITTING MATERIAL AS PER STANDARD ASTM SPECIFICATION. ASTM A234 Wrought carbon steel and alloy steel pipe fittings for moderate & elevated temperatures. ASTM A403 Wrought & Austenitic steel pipe fittings. ASTM A420 Pipe fittings carbon steel and alloy steel for low temperatures. Flanged Fittings Classification based on pressure temperature ratings, same as that of flanges. FLANGED FITTING MATERIAL AS PER STANDARD ASTM SPECIFICATIONS ASTM A216 Carbon Steel Castings ASTM A352 Ferritic & Martensitic Steel Casting for Low temperature services. Spigot Socket Fittings: Used mainly in cast iron piping. TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 12 TYPES OF FITTINGS: Elbow L.R. Elbows. S.R. Elbows. Pulled Bends. Fabricated Bends. Tee Forged Tees Fabricated Tees Stub Connections Minimum size standard reduction Tee / Reducer available is the lower size lower size of (Major Size / 2). Reducer Concentric Reducers Eccentric Reducers Stub End Long Stub Ends Short Stub Ends Fabricated Stub Ends Coupling Full Couplings Reducing Couplings Half Couplings Swage Nipple Concentric swage nipple Eccentric Swage Nipple TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 13 Special Fittings: As per manufactures standards Weldolet Sockolet Threadolet Elbowlet Sweepolet Latrolet Nippolet FLANGES: The Dimensional Standard from 1/2 inch to 24 inch NB is ASME B16.5. For higher sizes ASME B16.47 series B is used. CLASSIFICATION BASED ON ATTACHMENT TO PIPING. Slip on Socket Weld Screwed Lap Joint Welding Neck Blind Reducing 4.5 AWS STANDARD The American Welding Society (AWS) Standards Refer to the welding electrodes. Individual manufactures have given their own brand names for the various electrodes and are sold under these names. 4.6 AWWA STANDARDS The American Water Works association (AWWA) standards refer to the piping elements required for low pressure water services. These are less stringent than other standards. Valves, flanges, etc. required for large diameter water pipelines are covered under this standard and are referred rarely by piping engineers here. 4.7 MSS-SP STANDARDS In addition to the above standards and material codes, there are standards practices followed by manufactures. These are published as standards and are widely followed. The most common MSS-SP standards referred for piping are : MSS-SP-6 - Standard Finishes for Contact Surface for Flanges. MSS-SP-25 - Standard Marking System for Valves, Fittings and Flanges. R1 TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 14 MSS-SP-42 - Corrosion Resistant Gate, Globe and Check Valves. MSS-SP-43 - Stainless Steel Buttweld Fittings. MSS-SP-44 - Steel Pipe Flanges MSS-SP-45 - Bypass and Drain Connection MSS-SP-61 - Pressure Testing Of Valves. MSS-SP-67 - Butterfly Valves. MSS-SP-70 - Cast Iron Gate Valves. MSS-SP-71 - Cast Iron Check Valves. MSS-SP-72 - Ball Valves. MSS-SP-78 - Cast Iron Plug Valves. MSS-SP-80 - Bronze Gate, Globe and Check Valves. MSS-SP-83 - Pipe unions. MSS-SP-85 - Cast Iron Globe Valves. MSS-SP-88 - Diaphragm Valves. MSS-SP-89 - Pipe Hanger Supports. 4.8 BRITISH STANDARDS In many instance, it is possible to find a British standard which may be substituted for American Standards. For example, BS 3351 - British standards specification for piping system used for the design of piping system is similar to ASME B 31.3 There are certain British Standard referred by Indian manufactures for the construction of piping elements such as valves. The most commonly referred British standards in the piping industry are : BS 806 - pipes and fittings for boilers BS 916 - black bolts, nuts and screws BS 970 - steel for forgings etc. BS1414 - Gate valves for petroleum industry. BS1560 - Steel pipe Flanges. BS1600 - Dimensions of steel pipes. BS1640 - Butt welding fittings. BS1868 - Steel check valves for petroleum industry. TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 15 BS1873 - Steel globe valves for petroleum industry. BS2080 - Face to face / end to end dimensions of valves. BS2598 - Glass pipe lines and fittings. BS2995 - SW and screwed valves - 2 and smaller. BS3059 - Steel boiler and super heater tubes. BS3351 - Piping system for petroleum refineries. BS3381 - Metallic spiral wound gaskets. BS797 - SW / Screwed Fittings. BS4504 - Flanges. BS4146 - Inspection and testing of valves. BS5155 - Butterfly valves. BS5158 - GI plug valves. BS5351 - Steel ball valves. BS5352 - SW and screwed valves - 2 and smaller. BS5353 - Carbon Steel and Alloy Steel plug Valves 4.9 INDIAN STANDARDS Bureau of Indian Standards ( BIS ) have so far not developed an Indian Standard for the design of piping systems. Hence, ASME standards B 31.1/31.3 are widely referred for the design. These standards also accept materials covered in other standards as well. Unlike American Standard, Indian Standards cover dimensions and material specifications under the same standard number. There are no groupings also done based on the series/ Branch of engineering as well. Some of the most commonly referred Indian standards by the piping engineering are : IS - 210 - Gray Iron Castings. IS - 554 - Pipe Threads. IS - 778 - Specifications for G.M Valves. IS - 780 - Specification for sluice valves-up to 300 NB IS - 1239 - Part I & II specification for pipe and pipe fittings. IS - 1364 - Bolts and Nuts. IS - 1536 - Centrifugal Cast Iron pipes. IS - 1537 - Vertically Cast Iron pipes. IS - 1538 - Cast Iron fittings. R1 TRAINING MANUAL- PIPING PIPING ELEMENTS SPECIFICATION, CODES AND STANDARDS
Uhde India Limited DOC No. : 29040-PI-UFR-0005 Rev. : R1 Page : 16 IS - 1539 - Compressors of Indian and overseas standards. IS - 1978 - Line pipe. IS - 1979 - High test line pipe. IS- 2002 - Steel plates. IS - 2016 - Plain washers. IS- 2062 - Weldable structural steel. IS- 2379 - Colour code for pipelines. IS - 2712 - Compressed Asbestos joints. IS - 2825 - Unfired pressure Vessels. IS- 2906 - Specification for sluice valves( 350-1200 ) IS - 3076 - Specification for LDPE Pipes. IS - 3589 - Specification for ERW pipes. IS- 4038 - Foot valves for water works. IS - 4984 - Specification for HDPE pipes. IS - 4985 - Specification for PVC pipes. IS - 5312 - Specification for swing check valves. IS - 6392 - Steel pipe flanges. IS - 7240 - Code of practice for cold insulation. IS - 7413 - Code of practice for hot insulation. IS - 8008 - HDPE Fittings. There are certain other international standards also referred in the piping industry. They are the DIN standards of Germany and the JIS standards of Japan. DIN standards are more popular and equivalent British and Indian standards are also available for certain piping elements. Periodic review of the standards by the committee are held and these are revised to incorporate the modified features based on the results of research and feed back from the industry. Hence, it is necessary that the latest editions of the codes and standards are referred for the design and year of publication also to be indicated alongwith.
Oxy-Acetylene Welding and Cutting
Electric, Forge and Thermit Welding together with related methods and materials used in metal working and the oxygen process for removal of carbon
Oxy-Acetylene Welding and Cutting
Electric, Forge and Thermit Welding together with related methods and materials used in metal working and the oxygen process for removal of carbon