Model Answer Key For Grade 11

Model Answer Key For Grade 11
VOLUMETRIC ANALYSIS
AIM:
To find molarity and strength of the given NaOH Solution. You are provided
with M/10 solution of HCl.Also determine the percentage purity of the
given NaOH, 4.5g of which is dissolved per litre.
APPARATUS: measuring flask, glass funnel, burette, pipette, burette
stand.
CHEMICALS: NaOH, HCl, phenolphthalein.
THEORY:
It is possible to find the molarity or volume of the unknown solution using
molarity equation:
M1V1 = M2V2
n1
n2
Where M=Molarity, V=Volume , n=no of moles

The reaction that occurs can be represented as
NaOH + HCl NaCl + H2O
PROCEDURE:
1
2
3
4
Solution in the burette

Solution in the pipette
INDICATOR
End point
HCl
NaOH
Phenolpthalein
Pink to colorless.
5
6
Molar mass of NaOH

Molar mass of HCl
40g/mol
36.5g/mol
Observation Table
Sr No
Volume of
NaOH
used
Initial
Burette
reading
(x)
Final
Burette
reading(y
)
Volume of
HCl
used(final
initial)
Concorda
nt reading
(y-x)
1
2
3
4
10
10
10
10
ml
ml
ml
ml
Calculations:
1.Molarity of the NaOH Solution
According to the equation, one mole of NaOH reacts with one mole of HCl
VNaOH x MNaOH
VHCl
nNaOH
x MHCl
nHCl
MNaOH
___________M
VHCl
x MHCl
x nNaOH
VNaOH x nHCl
2. Calculation of strength of NaOH in g/L.
Strength / litre = Molarity x Molar mass = ____ x 40 = __(x)___g/L
3.To calculate percentage purity.
4.5g of impure sample of NaOH contain = x g of NaOH
1g of impure sanmple of NaOH contain = x g of NaOH
4.5
Percentage Purity = x x 100 = _____%
4.5
RESULT:
(a)
Molarity of the given NaOH solution = ___________M
(b)
The strength of the given NaOH solution =
______g/L
(c) Percentage Purity = _____ %
PRECAUTIONS:
1. Since the lower meniscus of HCl is visible, read the

lower meniscus.
2. Rinse the burette and pipette before use.
SALT ANALYSIS Model Answer Sheet for BaCl2, Barium

Chloride
Aim: To analyze the given salt and identify the anion and cation
present in it.
S.N
O
EXPERIMENT
OBSERVATION
INFERENCE
White
Absence of copper,
cobalt,iron,nickel,
manganese.
Absence of
carbonate
Preliminary Test
1.
2.
3.
4.
5.
6.
COLOUR
The Colour of given
salt is noted.
APPEARANCE
The appearance of the
given salt is noted
SOLUBILITY IN WATER
A little of the given salt
is dissolved in distilled
water in a test tube
ODOUR
ANION ANALYSIS
ACTION OF
DIL.SULPHURIC ACID
To a little of the substance
taken in a test tube a few
drops of dil. Sulphuric acid
is added .
ACTION OF
CONC.SULPHURIC ACID
To a little of the substance
Crystalline
Soluble
No
characteristic
odour
Absence
ofCarbonate
Absence of
ammonium salts.
No
characteristic
reaction
Absence of
Carbonate,sulphite,n
itrite and sulphide.
A colourless
pungentsmellin
g gas is evolved
May be chloride
taken in a test tube a few

drops of conc. Sulphuric acid
is added and warmed.
7.
8.
9.
10
11.
12.
13.
CHROMYL CHLORIDE
TEST
To a small amount of the
given salt conc. H2SO4 and
K2Cr2O7are added and
Warmed.
Pass red vapours through
sodium hydroxide solution.
To yellow solution add acetic
acid and lead acetate .
SILVER NITRATE TEST
To salt solution add dil nitric
acid and silver nitrate
solution.
CATION ANALYSIS
Original solution s prepared
by dissolving the salt in
water
ZEROGROUP(AMMONIUM)
To a little of the salt sodium
hydroxide solution is added
and heated
I GROUP (LEAD)
To a little of the original
solution dil. HCI is added.
II GROUP (COPPER)
solution dil. HCI and
Hydrogen sulphide are
added.
III GROUP (ALUMINIUM,
IRON)
solution ammonium chloride
and ammonium hydroxide
are added.
IV GROUP (ZINC,
givingdense
white fumes
with glass rod
dipped in
ammonium
hydroxide
Chloride is
confirmed
Reddish brown
vapourswhich
turn sodium
hydroxide
solution yellow.
Yellow ppt is
formed.
A curdy white
Chloride is
precipitate
confirmed
soluble inNH4OH
is obtained
No
characteristic
reaction
Absence of
ammonium
salts
No
characteristic
reaction
Absence of I group
No
characteristic
reaction
Absence of II group
No
characteristic
reaction
Absence of III group
14.
15.
16.
MANGANESE, NICKEL,
COBALT)
solution ammonium chloride,
ammonium hydroxide and
hydrogen sulphidesolution
are added
V GROUP(CALCIUM,
BARIUM , STRONTIUM)
solution ammonium chloride,
ammonium hydroxide and
ammonium carbonate are
added
CONFIRMATORY TEST
solution acetic acid and
potassium chromate solution
are added
FLAME TEST
The paste of the given salt
with Conc. HCl is introduced
into the nonluminous part of
theflame and the colour
isnoted.
No
characteristic
reaction
Absence of IVgroup
White
precipitate is
formed.
Presence of V Group.
Yellow
precipitate is
formed.
Presence of barium
confirmed
Presence of barium
confirmed
Pale green
coloured flame
Result: The anion present in the given salt is Chloride (Cl--) and cation is
Barium Ba+2. The salt is Barium Chloride BaCl2

Model Answer Key For Grade 11

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Model Answer Key For Grade 11

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Model Answer Key For Grade 11

Where M=Molarity, V=Volume , n=no of moles

Solution in the burette

Molar mass of NaOH

1. Since the lower meniscus of HCl is visible, read the

SALT ANALYSIS Model Answer Sheet for BaCl2, Barium

taken in a test tube a few

Absence of III group

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