RoClean P112

SAFETY DATA SHEET

1. Company and Product Identification

1.1 Identification Product Name: RoClean P112
Other means of identification Organic and Inorganic Salts
1.2
Synonym: Mixture, none
Recommended Use Of The Chemical Membrane filtration or ultrafiltration process cleaner
1.3
and Restrictions On Use: Use only as directed on the label.
Name,, Address, And Telephone Number Of AVISTA TECHNOLOGIES
The Manufacturer, Or Other Responsible Party: 140 Bosstick Street
1.4 San Marcos, CA 92069
(760) 744-0536
Competent Person email address klindsey@avistatech.com
24 Hour Emergency No.: 1-800-424-9300
9300 (United States)
1.5
1-703 527-3887 (International Collect)

DRINKING WATER TREATMENT ADDITIVES CLASSIFIED

BY NSF INTERNATIONAL TO ANSI/NSF 60 AS STANDARD
DRINKING WATER TREATMENT CHEMICAL FOR USE OFFOFF-
LINE IN REVERSE OSMOSIS SYSTEMS

2. HAZARD
HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: This product is an odorless, white to cream colored solid. This product can irritate contaminated
skin, eyes, mucous membranes, and any other exposed tissues. This product is neither reactive nor flammable. Thermal
decomposition of this product produces irritating vapors and toxic gases (e.g., carbon oxides, phosphorus oxides, and sodium oxides).
Emergency responders must wear personal protective equipment (and have appropriate fire fire-extinguishing
extinguishing protection) suitable for the
situation to which they are responding.

Physical Hazards Summary This product is a moderate skin or eye irritant

Potential Health Hazards Summary Skin Corrosion/Irritation - Category 2
Serious Eye Damage
Eye Irritation - Category 2A
Acute toxicity oral, Category 3
Potential Ecological Effects Summary Acute Hazards to the aquatic environment Category 3

2.1 Classification Of Product

U.S. OSHA classification Corrosive, skin/eye irritant
Skin Corrosion/Irritation - Category 2
Classification as per EC 1272/2008 Serious Eye Damage
Eye Irritation - Category 2A
(CLP/GHS)
Acute toxicity oral, Category 3
Xi Irritant

RoClean P112 SDS PAGE 1 OF 11

 E, Corrosive
WHMIS classification
D2B - Poisonous and infectious material - Other effects Toxic

Health 2
Hazardous Materials Information Flammability 0
System (HMIS) Rating
Physical Hazard 0
Protective Equipment C
2.2 Label Elements OSHA/GHS

General Warnings P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use
P403 Store in a well-ventilated place.
P233 Keep container tightly closed
Signal Word WARNING

Hazard statements H 312 Harmful in contact with skin

H315 + H320 Causes skin or eye irritation
H319 Causes serious eye irritation
H314-H335 Causes severe skin burns and eye damage. May cause respiratory
irritation
H318 Causes serious eye damage
H402 Harmful to aquatic life
Precautionary statements P305 IF IN EYES, RINSE THOROUGHLY WITH RUNNING WATER
P338 Remove contact lenses if present and easy to do. Continue rinsing.
P261 Avoid breathing dust
P280 Wear protective gloves/protective clothing/eye protection/face
protection
P271 Use only outdoors or in a well-ventilated
ventilated area.
P312 IF SWALLOWED:
WALLOWED: Call a POISON CENTER or doctor/physician if
P302/P352 you feel unwell.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P404 Store in a closed container.
P273 Avoid release to the environment.
Hazard pictograms - GHS

Hazard pictograms - WHMIS

2.3 Unclassified Hazards None

2.4 Ingredients with unknown acute None
toxicity

RoClean P112 SDS PAGE 2 OF 11

 3.. COMPOSITION and INFORMATION ON INGREDIENTS
Chemical name % w/w US OSHA GHS/EU CLP WHMIS
CAS #
EINECS #
Silicate compound 60-70 Corrosive Corrosive, Category 1B Class E Corrosive
Proprietary H314-H335
Proprietary P261-P280-P305
P305 + P351 +
P338-P310

Citrate compound 15-20 Corrosive Irritant, Category 2 Class D2B: Toxic Material at
Proprietary H319 > 1%
Proprietary P305 + P351 + P338

Polyphosphate 10-15 Corrosive Acute Hazards to the aquatic E, Corrosive

Proprietary environment - Category 3
Proprietary Specific Target Organ
Toxicity Single Exposure -
Category 3
Skin Corrosion/Irritation -
Category 1B
Serious Eye Damage
Eye Irritation - Category 1
Surfactant 1-5 Corrosive, Combustible Skin sensitizer, Category 1 B3 Combustible
Proprietary liquid Acute toxicity, oral, Category 3 E Corrosive
Proprietary H317 May cause an allergic
skin reaction
Acute toxicity, oral, Category 3
H312 Harmful in contact with
skin
H332 Harmful if inhaled
H314 Causes severe skin burns
and eye damage
P280 Wear protective
gloves/protective clothing/eye
protection/face protection.
P305 IF IN EYES: rinse
extensively with large amounts
of water
P351 Rinse cautiouslyiously with
water for several minutes.
P338 Remove contact lenses, if
present and easy to do. Continue
rinsing.
P310 IF INGESTED or
INHALED Immediately call a
POISON CENTER or
doctor/physician.
PRODUCT CLASSIFICATION Corrosive, oxidizer, Skin Corrosion/Irritation - E, Corrosive
skin/eye irritant Category 2 D2B - Poisonous and
Serious Eye Damage infectious material - Other
Eye Irritation - Category 2A effects Toxic
Acute toxicity oral, Category 3
Acute Hazards to the aquatic
Environment, Category 3
NE = Not Established. C = Ceiling Limit. See Section 16 for Definitions of Terms Used
Used.

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 4. FIRST-AID MEASURES
4.1 Description of Necessary Measures
Skin exposure: If this product contaminates the skin, immediately begin decontamination with
running water. Remove exposed or contaminated clothing, taking care not to
contaminate eyes. Victim should seek immediate medical attention if any
adverse exposure symptoms develop.
Eye exposure: If this product enters the eyes, open victim's eyes while under gently running
water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum
flushing is for 15 minutes. Victim must seek medical attention.
Inhalation: If dusts of this product are inhaled, remove victim to fresh air. If necessary, use
artificial respiration to support vital functions. Remove or cover gross
contamination to avoid exposure to rescuers.
Ingestion: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL
CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE
VOMITING. Have victim rinse mouth with water, if conscious. Never induce
vomiting or give a diluent (e.g., water) to someone who is unconscious, having
convulsions, or unable to swallow. If contaminated individual is convulsing,
maintain an open airway and obtain immediate medical attention.
4.2 Most Important Symptoms/Effects: Immediate: Inhalation exposure may cause coughing or sneezing. Symptoms
of skin and eye contact may include redness and irritation. Ingestion may cause
stomach pains, cramps, and gastritis.
Delayed: Prolonged or repeated skin overexposure to this product may cause
dermatitis (dry, red skin). Symptoms may include tingling, redness, and visible
injury.
4.3 Indication Of Immediate Medical TARGET ORGANS: Acute: Skin, eyes. Chronic: Skin.
Attention And Special Treatment Needed,
If Necessary:
Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Rescuers should be taken for medical
attention if necessary. Take a copy of label and MSDS to physician or health professional with victim.

5. FIRE-FIGHTING MEASURES
Flammable properties Non-flammable solid NFPA
FLAMMABILITY
RATING

0
2 0
HEALTH REACTIVITY

OTHER
See Section 16 for
definitions of ratings

Flash Point oC: Not applicable.

Autoignition Temperature oC: Not applicable.

Flammable Limits (in air by volume, %):

Upper: Not applicable.
Lower: Not applicable.
5.1 Suitable And Unsuitable Extinguishing Use extinguishing material suitable to the surrounding fire.
Media: Water spray YES Carbon dioxide YES
Foam YES Dry chemical YES

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 Halon YES Other YES
5.2 Specific Hazards Arising From Chemical: When involved in a fire, this material may decompose and produce irritating
fumes and toxic gases (e.g., carbon monoxide, carbon dioxide, phosphorous
oxides, and nitrogen oxides).
Explosion Sensitivity to Mechanical Impact: Not applicable.
Explosion Sensitivity to Static Discharge: Not applicable.
5.3 Special Protective Equipment And Incipient fire responders should wear eye protection. Structural firefighters must
Precautions For Fire-Fighters: wear Self-Contained Breathing Apparatus and full protective equipment. Move
containers from fire area if it can be done without risk to personnel. If possible,
prevent runoff water from entering storm drains, bodies of water, or other
environmentally sensitive areas.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal Precautions Uncontrolled releases should be responded to by trained personnel using pre-
planned procedures. Proper protective equipment should be used. In case of a
spill, clear the affected area and protect people.
Protective equipment For small releases (< 20 kg), clean up spilled solid wearing gloves, goggles,
faceshield, and suitable body protection. The minimum Personal Protective
Equipment recommended for response to non-incidental releases (more than 20
kg) should be Level C: triple-gloves (neoprene gloves and nitrile gloves over
latex gloves), chemical resistant suit and boots, hard hat, and full-face respirator
with HEPA filter.
Emergency procedures Monitoring must indicate that exposure levels are below those provided in
Section 8 (Exposure Controls-Personal Protection) and that oxygen levels are
above 19.5% before anyone is permitted in the area without Self-Contained
Breathing Apparatus.
6.2 Methods and Materials for Containment and Moisten to suppress dust. Shovel up solids into plastic container for
Cleaning Up recovery/disposal. Neutralize residue with sodium bicarbonate or other
neutralizing agent for weak caustics. Decontaminate the area thoroughly. Test
area with litmus paper to ensure neutralization. Place all spill residues in a
suitable plastic container. Dispose of in accordance with applicable U.S.
Federal, State, or local procedures, or appropriate local standards (see Section
13, Disposal Considerations).

7. HANDLING and STORAGE

7.1 Precautions for Safe Handling All employees who handle this material should be trained to handle it safely. Open containers
carefully on a stable surface. Empty containers may contain residual solid; therefore, empty
containers should be handled with care.
As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly
after handling this product. Do not eat or drink while handling this material. Avoid
generating dust of this product. Remove contaminated clothing immediately.
During equipment maintenance follow practices indicated in Section 6 (Accidental Release
Measures) to decontaminate equipment or clean-up small spills. Make certain that application
equipment is locked and tagged-out safely if necessary. Collect all rinsates and dispose of
according to applicable U.S. Federal, State, or local procedures or appropriate local standards.
7.2 Conditions For Safe Storage Store at temperatures less than 45oC (113oF). Store containers in a cool, dry location, away
from direct sunlight, sources of intense heat, or where freezing is possible. Store away from
incompatible materials. Material should be stored in secondary containers, or in a diked area,
as appropriate. Storage and use areas should be covered with impervious materials. Keep
container tightly closed when not in use. Store in original shipping container. If appropriate,
post warning signs in storage and use areas. Inspect all incoming containers before storage, to
ensure containers are properly labeled and not damaged.
Incompatibilities Strong acids, oxidizers, caustics. It may react with metals to generate pressure.

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 8. EXPOSURE CONTROLS - PERSONAL PROTECTION
8.1 Control Parameters

CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR

ACGIH-TLVs OSHA-PELs OTHER
TWA STEL TWA STEL IDLH
mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3
Silicate compound Proprietary 60-70 NE NE NE NE NE NE
Citrate compound Proprietary NE NE NE NE NE NE
15-20
Polyphosphate Proprietary 10-15 NE NE NE NE NE NE
Surfactant Proprietary 1-5 NE NE NE NE NE NE
Water and other components which are present in Balance None of the other components contribute significant additional hazards at the concentration present
less than 1 percent concentration (0.1% in this product. All pertinent hazard information has been provided in this document, per the
concentration for potential carcinogens, requirements of the Federal Occupational Safety and Health Administration Standard (29 CFR
reproductive toxins, respiratory tract sensitizers 1910.1200), U.S. State equivalent Standards and Canadian Workplace Hazardous Materials
and mutagens). Identification System Standards (CPR 4).
8.2 Appropriate Engineering Controls. Use with adequate ventilation to ensure exposure levels are maintained below the
limits provided in this Section or as low as reasonably achievable. Ensure
eyewash/safety shower stations are available near areas where this product is used.
8.3 Personal Protective Equipment None needed under normal conditions of use. Use NIOSH approved respirators if
Respiratory protection: ventilation is inadequate to control mists or vapor. If respiratory protection is
needed, use only protection authorized in the U.S. Federal OSHA Standard (29
CFR 1910.134), applicable U.S. State regulations, or the applicable local standards.
Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres,
use of a full-face piece pressure/demand SCBA or a full-face piece, supplied air
respirator with auxiliary self-contained air supply is required under OSHAs
Respiratory Protection Standard (1910.134).
Eye protection: Use approved safety goggles or safety glasses, as described in OSHA 29 CFR
1910.133. Splash goggles with a faceshield may be needed if splash hazards exist.
Hand protection: Wear chemical impervious gloves (e.g., Solvex, Neoprene).
Body protection: If needed, use body protection appropriate for task (e.g., Tyvek suit, rubber apron)
to protect from splashes and sprays.

9. PHYSICAL and CHEMICAL PROPERTIES

Appearance This product is an odorless, white to cream colored solid.
Odor None Odor Threshold N/A
Melting Point oC NE pH (1% aqueous solution) 12.0-12.9
Initial Boiling Point oC NE Boiling Point Range oC N/A
Flammability Non-flammable Evaporation Rate (water = 1) N/A
Vapor Density (air = 1) N/A Vapor Pressure mm Hg @ 20C: N/A
Solubility (in water) Soluble Relative density (water = 1) NE
Viscosity Flowing solid Oil-Water Partition Coefficient N/A
Decomposition Temperature NE
How To Detect This Substance Litmus paper will turn blue when in contact with solutions of this product.
(Warning Properties):

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 10. STABILITY and REACTIVITY
10.1 Reactivity Not considered reactive.
10.2 Chemical Stability Stable
10.3 Possibility of hazardous reactions Hazardous polymerization will not occur.
10.4 Conditions to avoid Avoid mixing with incompatible materials.
10.5 Incompatible Materials Strong acids, oxidizers, caustics. It may react with metals to generate pressure.
10.6 Hazardous Decomposition Products Thermal decomposition of this product may generate carbon monoxide, carbon
dioxide, phosphorous oxides and nitrogen oxides.

11. TOXICOLOGICAL INFORMATION

Oral LD50 mg/kg Dermal LD50 mg/kg Inhalation LD50 mg/kg

Toxicity data for hazardous ingredients
Silicate compound LD50 (Oral, rat) 1153 N/A N/A
Skin irritation (24 hr) severe
Citrate compound LD50 (Oral-Rat) 3 g/kg
LD50 (Oral-Mouse) 5040 mg/kg
LD50 (Intraperitoneal-Rat) 883
mg/kg
LD50 (Intraperitoneal-Mouse) 903
mg/kg
LD50 (Subcutaneous-Rat) 5500
mg/kg
LD50 (Subcutaneous-Mouse) LD50 (dermal, rabbit) > 2000
N/A
2700 mg/kg mg/kg
LD50 (Intraperitoneal-Mouse
LD50: 903 mg/kg
LD50 (Intravenous-Rabbit, adult)
330 mg/kg
LD50 (Intravenous-Mouse) 42
mg/kg
LDLo (Oral-Rabbit, adult) 7000
mg/kg
Standard Draize Test (Skin-Rabbit, adult) 500 mg/24 hours: Moderate
irritation effects
Standard Draize Test (Eye-Rabbit, adult) 750 mg/24 hours: Severe
irritation effects
Polyphosphate LD50 (oral, rat) > 7400 mg/kg
LDLo (Intravenous-Rabbit, adult)
1580 mg/kg LDLo (skin, rabbit) > 300 mg/kg N/A

Sex Chromosome Loss and Nondisjunction (Oral-Drosophila

melanogaster) 11 pph
Standard Draize Test (Skin-rabbit) > 300 mg/kg

Surfactant N/A N/A N/A

RoClean P112 SDS PAGE 7 OF 11

 12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.

12.1 Ecotoxicity LC50, mg/L EC50, mg/L

Silicate compound
Aquatic LC50 (Mosquitofish) = 530 mg/L NE
LC50 (Waterflea) 48 hours = 113 mg/L
LC50 (Scud) 96 hours = 160 mg/L
LC50 (Polycheate) 28 days = 210-250 g/L
TLm (Mosquitofish) 96 hours = 2320 ppm (fresh
water)
Terrestrial NE NE
Citrate compound
Aquatic Water Solubility = 59.2% (20 C); 84% (100 C) EC50 (daphnia/48h) = 5.6-10 g/L
Biological Oxygen Demand (BOD): 40%, 5 days; EC50 (chlorella vulgaris/5d) = >18-32 g/L
60%, 10-20 days. EC10 (pseudomonas putita/16h) = EC50/8h ps.
Food Chain Concentration Potential: Very Low fluorescens : >1.800-3.2 g/L
Experimental Log P = -1.64
Persistence: Can ferment on standing. Biodegrades
quite rapidly. It is dangerous to aquatic life in high
concentrations. Lowers pH in water but does not
dissociate to any great extent.
LC50 fish/96h : 18-32 g/L
Terrestrial NE NE
Polyphosphate
Aquatic LC50 28.5 (Gambusia affinis (Western mosquito fish, NE
adult female)
Terrestrial NE NE
Surfactant
Aquatic NE NE
Terrestrial NE NE

12.3 Bioaccumulative Potential Most components of this product are not expected to bioaccumulate. There is limited information available on
the environmental fate and effects of the silicate salt, if released to the environment. This salt has exhibited
moderate to high toxicity to aquatic organisms and moderate toxicity to terrestrial organisms. The salt will
persist in aquatic and terrestrial systems. Significant releases could have an adverse impact on the pH of an
aquatic system.
12.4 Mobility in Soil When spilled onto soil, this product will infiltrate downward, the rate being greater with lower concentration
because of reduced viscosity.
12.5 Other Adverse Ecological Effects This product may be harmful to aquatic life if large volumes of it are released into an aquatic environment.

13. DISPOSAL CONSIDERATIONS

Preparing Wastes of this Product for Waste disposal must be in accordance with appropriate U.S. Federal, State, and local
Disposal regulations or with local regulations. This product, if unaltered by the handling, may
be disposed of by treatment at a permitted facility or as advised by your local waste
regulatory authority.
Disposal of Contaminated Packaging Cleaned containers can be recycled or disposed of as non-contaminated waste, if
authorized by your local authorities. Dispose of containers as required by local
regulations.
U.S. EPA Waste Number This product is not a hazardous waste as shipped. If spilled, the spill residue may
exhibit the D002 hazardous waste characteristic.

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 14. TRANSPORT INFORMATION
THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.

14.1 UN Number UN3262

14.2 UN Proper Shipping Name Corrosive solid, basic, inorganic, n.o.s. (Sodium metasilicate, sodium triphosphate)
14.3 Transport Hazard Class(es) 8 (Corrosive)
Transport label(s) required Corrosive Class 8
14.4 Packing Group II
14.5 Marine Pollutant Not applicable
NA Emergency Response Guide 154
Number (2012)
14.6 Transport in Bulk (Annex II of Not applicable
MARPOL 73/78 and IBC Code)
14.7 Special Transport Precautions Not applicable
National Motor Freight #70
Classification

International Air Transport Association

14.8 UN Number UN3262
UN Proper Shipping Name Corrosive solid, basic, inorganic, n.o.s. (Sodium metasilicate, sodium triphosphate)
Transport Hazard Class(es) 8 (Corrosive)
Transport label(s) required Corrosive Class 8
Packing Group II
Packaging Instructions 822

International Maritime Organization

14.9 UN Number UN3262

UN Proper Shipping Name Corrosive solid, basic, inorganic, n.o.s. (Sodium metasilicate, sodium triphosphate)
Transport Hazard Class(es) 8 (Corrosive)
Transport label(s) required Corrosive Class 8
Packing Group II
Marine Pollutant Not applicable
NA Emergency Response Guide 154
Number (2012
Transport in Bulk (Annex II of Not applicable
MARPOL 73/78 and IBC Code)

15. SAFETY, HEALTH and ENVIRONMENTAL REGULATIONS

SPECIFIC FOR THE PRODUCT
Citrate
Silicate
PROGRAM compound Polyphosphate Surfactant
compound
US EPA PROGRAMS
Clean Air Act Hazardous
NO NO NO NO
Air Pollutants
Safe Drinking Water Act NO NO NO NO
RCRA F, K, P, U or
NO D001 NO NO
D-lists
SARA 302 RQ NO NO NO NO
SARA 302 TPQ NO NO NO NO
SARA 313 LISTED NO NO NO NO
SARA CHEMICAL CATEGORIES
SARA 311/312 ACUTE YES YES NO YES

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 SARA 311/312
YES YES NO NO
CHRONIC
SARA 311/312 FIRE NO NO NO NO
SARA 311/312
NO NO NO NO
PRESSURE
SARA 311/312
NO YES NO NO
REACTIVITY
EPA EXTREMELY
HAZARDOUS NO NO NO NO
SUBSTANCE
CALIFORNIA SAFE DRINKING WATER ACT (Proposition 65)
This product does not contain any chemical listed on the California Safe Drinking Water Act list (Proposition
65)
US OSHA PROGRAMS
PEL NO NO NO NO
PSM NO NO NO NO
CHEMICAL SECURITY PROGRAMS
DHS CFATS NO NO NO NO
CHEMICAL WEAPONS CONVENTION
NO NO NO NO
US DRUG ENFORCEMENT ADMINISTRATION
DEA Controlled
NO NO NO
Substances
CHEMICAL INVENTORY PROGRAMS
WHMIS E C, D2B D2B B3, E
DSL YES YES YES YES
NDSL N/A N/A N/A N/A
REACH Pre-registered
YES YES YES YES
List
TSCA YES YES YES YES
European Inventory of
Existing Commercial
YES YES YES YES
Chemical Substances
(EINECS)
EU No-Longer Polymers
N/A N/A N/A N/A
List (NLP)
EEC Classification
Packaging, and Labeling
Xi NO Xi NO
of Dangerous
Substances(Annex 1)
Philippines YES YES YES YES
Japan YES YES YES YES
Australia YES YES YES YES
Korea YES YES YES YES
China YES YES YES YES
New Zealand Inventory of
YES YES YES YES
Chemicals

16. OTHER INFORMATION

16.1 Original Preparation January 5, 2009
16.2 Revision History GHS 11 Dec 2013
16.3 Prepared by ADVANCED CHEMICAL SAFETY, Inc.
PO Box 152329
San Diego, CA 92195
(858)-874-5577
16.4 Date of Printing April 22, 2015

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 DEFINITIONS OF TERMS
16.5 A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:
Section 2 GHS: Global Harmonization System
OSHA: U.S. Occupational Safety and Health Administration.
CLP: Classification and Packaging
WHMIS: Workplace Hazardous Materials Information System
STOT: Specific Target Organ Toxicity
Section 3 CAS #: Chemical Abstract Service index number
EINECS #: European Chemical Substances Information System index number
Section 5 NFPA: Nation Fire Protection Association
Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible
materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that
on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3
(materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short
exposure could cause death or major residual injury). Flammability Hazard
Reactivity Hazard: Refer to definitions for Hazardous Materials Identification System.

Flash Point: Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air.
Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition.
LEL: The lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL: The
highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source.
Section 8 ACGIH - American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure
limits.
TLV - Threshold Limit Value - an airborne concentration of a substance which represents conditions under which it is generally
believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including
the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level
(C). Skin absorption effects must also be considered
PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TLV, except that it is enforceable by
OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule
(Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase,
Vacated 1989 PEL, is placed next to the PEL which was vacated by Court Order.
IDLH - Immediately Dangerous to Life and Health - This level represents a concentration from which one can escape within
30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germanys
Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which
is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH issues exposure guidelines
called Recommended Exposure Levels (RELs). When no exposure guidelines are established, an entry of NE (Not
Established) is made for reference.
Section 11 LD50 : Lethal Dose (solids & liquids) which kills 50% of the exposed animals;
LC50 : Lethal Concentration (gases) which kills 50% of the exposed animals;
ppm: Concentration expressed in parts of material per million parts of air or water;
mg/m3 : Concentration expressed in weight of substance per volume of air;
mg/kg: Quantity of material, by weight, administered to a test subject, based on their body weight in kg
IARC - the International Agency for Research on Cancer;
NTP - the National Toxicology Program,
RTECS - the Registry of Toxic Effects of Chemical Substances,
OSHA and CAL/OSHA.
IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings
(2A, 2B, etc.) are also used.
TDLo, the lowest dose to cause a symptom and
TCLo the lowest concentration to cause a symptom;
TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects.
BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens
collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to
the TLV.
Section 12 LC50: The lowest concentration in water which kills 50% of the test subjects.
EC50: The Effect Concentration in water at which 50% of the test species if affected.
Section 13 US EPA Hazardous Waste Codes: refer to 40 CFR 261.20
Section 14 DOT: US Department of Transportation
IATA: International Air Transport Association
IMO: International Maritime Organization
MARPOL: International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978
IBC Code : Merchant Shipping Code
Section 15 RCRA: US Resource Conservation and Recovery Act
SARA: US Superfund Amendments and Reauthorization Act
PSM: US OSHA Process Safety Management
CFATS: US Department of Homeland Security Chemical Facility Anti-terrorism Standard
DSL: Canadian Domestic Substances List
NDSL: Canadian Non-Domestic Substances List
REACH: European Registration, Evaluation, Authorization and Restriction of Chemicals list
TSCA: US Toxic Substances Control Act

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