Solved Exercise Mass
Solved Exercise Mass
Solved Exercise Mass
Air containing SO2 at partial pressure of 0.01 atm passes through a device filled with a liquid
solution (50 cm3 in volume) that absorbs SO2, as shown below. The interface area is 10 cm2. The
feed air flow rate is Q= 50 cm3/s. The device is operated at 1 atm and 25oC. Both air and liquid
are well stirred. The mass transfer coefficients for the liquid and gas phase are respectively: k L =
2.0x10-4 cm/s, kG = 4.0x10-3 mmol/cm2.s.atm. The Henry constant for SO2 in these two-phase
system is H=0.1 atm.cm3/mmol. The gas constant R=82.06 cm3 atm/mol.K.
Liquid solution
(a). If the initial SO2 concentration in the liquid solution is 0, calculate time required for the
SO2 concentration in the solution to reach 0.08 mmol/cm3. You can assume a quasi-
steady state in the gas phase, i.e., the term dCg/dt=0, where Cg is the SO2 concentration in
the gas phase in the device.
(b). Draw quantitatively the SO2 concentration profile from the liquid phase to the gas phase.
Solution
Q Q
Pin Pout
N
Mass balance for the liquid phase: C,P
d (CV )
AN (1)
dt
N K g ( Pout HC ); Pout HC
1
K g 1 H
1.23x10 3 mol / cm 2 atm
K G K L
dC AK G
Equation (1) ( Po HC)
dt V
At t = 0 C, P = 0
Pin P dC g
Q AN Q out 0
RT RT dt
P P
Q in AK G ( Pout HC ) Q out 0
RT RT
AK G RT
Pin HC
Q 0.01 0.6C
Pout atm
AK G RT 7
1
Q
dC 10 x1.23x10 3
(1.43x10 3 0.0143C )
dt 50
0.08x10 3 t
dC
0
3
1.43x10 0.0143C
0.246 x10 3 dt
0
t 3.107 min