Chemistry SPM State Trial Papers-Form5chap2
Chemistry SPM State Trial Papers-Form5chap2
Chemistry SPM State Trial Papers-Form5chap2
Diagram 2 / Rajah 2
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Suggested Answer:
(a) Alkene
(b)
(c) Hydration
(d)
Diagram 6 / Rajah 6
(e) Isomerism is the phenomenon where a compound has the same molecular fonnula but
different structural formula. Butene has three isomers. Draw all the isomers of butene.
Isomerism ialah fenomena di mana suatu sebatian mempunya formula molekul yang sama
tetapi formula struktur yang berbeza. Butena mempunyai tiga isomer. Lukis semua isomer bagi
butena. [3 marks]
Suggested Answer:
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Rajah 6 menunjukkan carta alir penukaran propanol kepada propena kepada propana melalui
Proses I dan II.
Diagram 6 / Rajah 6
(b) Complete the chemical equation for Process 1 by drawing the structural formula of the product
formed.
Lengkapkan persamaan kimia bagi Proses 1 dengan melukis formula struktur hasil yang
terbentuk. [1 mark]
(i) Write the chemical equation for combustion of propene in excess oxygen.
Tuliskan persamaan kimia bagi pembakaran propena di dalam oksigen berlebihan. [1 mark]
(ii) Compare the sootiness for the combustion of propene and propane. Explain your answer.
[Given the relative molar mass of propene = 42 gmol-1 and propane = 44 gmol-1]
Bandingkan jelaga yang terhasil semasa pembakaran propena dan propana. Terangkan
jawapan anda.
[Diberi jisim molar bagi propena = 42 gmol-1 dan propana = 44 gmol-1] [3 marks]
(d) Propene decolorised the purple colour of potassium manganate (VII) solution but propane
does not change the purple colour of potassium manganate (VII) solution. Give a reason.
Propena menyahwarnakan warna ungu larutan kalium manganate (VII) tetapi propana tidak
mengubah warna ungu larutan kalium manganat (VII). Berikan satu sebab. [1 mark]
(e) Draw a labelled diagram to show how Process 1 can be carried out.
Lukiskan gambarajah berlabel yang menunjukkan bagaimana Proses 1 boleh dijalankan.
[3 marks]
Suggested Answer:
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(ii) Propene produce more soot
% of C in propene is higher than that in propane
% of C in propene:
3 X 12 X 100 = 85.71%
42
% of C in propane:
3 X 12 X 100 = 81.82%
44
(d) Propene is an unsaturated hydrocarbon but propane is saturated hydrocarbon // Propene
has double bond but propane has single bond.
(e)
(a) State the substance required for the fermentation process of pineapple juice.
Nyatakan bahan yang diperlukan untuk proses penapaian jus nenas. [1 mark]
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(d) Substance P is a very good fuel.
Bahan P adalah merupakan bahan api yang sangat baik.
(ii) Write a balanced chemical equation when substance P is burnt completely in excess
oxygen.
Tulis persamaan kimia seimbang apabila bahan P terbakar lengkap dalam oksigen
berlebihan. [2 marks]
Suggested Answer:
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(a) Name process X.
Namakan proses X. [1 mark]
(c) 28g of but-2-ene is completely burnt in oxygen. The chemical equation below shows the
combustion of but-2-ene.
[Relative atomic mass: C = 12, O = 16, H = 1; Molar volume of gas = 24 dm3mol 1 at room
conditions]
28g but-2-ena terbakar dengan lengkap dalam oksigen. Persamaan kimia di bawah
menunjukkan pembakaran but-2-ena.
[Jisim atom relalif: C = 12, O = 16, H = 1; Isi padu molar gas = 24 dm3mol 1 pada keadaan bilik]
(e) Diagram 6.2 shows two types of rubbers, rubber type A and rubber type B.
Rajah 6.2 menunjukkan dua jenis getah, getah jenis A dan getah jenis B.
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(i) Identify the type of rubbers A and B.
Kenal pasti jenis getah A dan B. [2 marks]
Suggested Answer:
(a) Hydrogenation
(b) C4 H8 H 2 C4 H10
(c) 2.8
(i) Mole of but-2-ene 0.05mol
56
(ii) 1. 1 mole of butene burns in oxygen gas produces 4 moles of carbon dioxide gas.
Therefore 0.05 mole of butene burns in oxygen gas produces 0.2 mole of carbon
dioxide gas//
2. Volume of CO2 0.2 24 4.8dm
3
(d) 1. 2 cm3 of but-2-ene and 2 cm3 of butane gas are filled in two different test tubes.
2. 2-3 drops of acidified potassium manganate(VII) solution is added to both test tubes.
3. But-2-ene decolourises purple acidified KMnO4 . Purple acidified KMnO4 in butane
remains unchange.
Or
1. 2 cm3 of but-2-ene and 2 cm3 of butane gas are filled in two different test tubes.
2. 2-3 drops of bromine water is added to both lest tubes.
3. But-2-ene decolourises brown bromine water. Brown bromine water in butane remains
unchange.
(e) (i) A: Unvulcanised rubber B: Vulcanised rubber
(ii) Rubber type B / Vulcanised rubber is more elastic than rubber type A / unvulcanised
rubber.
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R
(a) (i) Compare and contrast the sootiness of compound P and compound Q when burnt in excess
of oxygen. Explain your answer.
[Relative atomic mass: C=12, H=l]
Bandingkan dan bezakan kejelagaan sebatian P dan sebatian Q apabila terbakar dalam
oksigen berlebihan. Terangkan jawapan anda.
[Jisim atom relatif: C=12, H=l] [4 marks]
(b) 2.3g of compound R is burnt completely in excess oxygen to produce carbon dioxide gas and
water. Write the chemical equation for the reaction and determine the volume of carbon
dioxide gas produced.
[Molar mass of R=46, molar volume at room condition= 24 dm3 mol-1]
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2.3g sebatian R terbakar dengan lengkap dalam oksigen berlebihan untuk menghasilkan gas
karbon dioksida dan air. Tuliskan persamaan kimia bagi tindak balas tersebut dan tentukan
isipadu gas karbon dioksida yang terhasil.
[Jisim molar R =46, isipadu molar gas pada keadaan bilik 24 dm3 mol-1] [5 marks]
Diagram 8 / Rajah 8
(i) State two compounds from Table 8.1 that react to produce ester. Name and draw the
structural formula of the ester formed.
Nyatakan dua sebatian daripada Jadual 8.1 yang bertindak balas untuk menghasilkan
ester. Namakan dan lukiskan formula struktur bagi ester yang terbentuk. [4 marks]
(ii) Acid T is used as catalyst during esterification reaction. When concentrated acid T spills
on marble floor bubbles are formed. Name acid T and write the ionic equation for the
reaction.
Asid T digunakan sebagai mangkin semasa tindak balas pengesteran. Apabila asid T
yang pekat tumpah ke atas lantai marmar gelembung gas terbentuk. Namakan asid T
dan tuliskan persamaan ion bagi tindak balas tersebut. [3 marks]
Suggested Answer:
(a) Percentage of C in P
(i) = 36 X 100%
44
= 81.81%
Percentage of C in Q
= 36 X 100%
42
= 85.7%
Q produce more soot because percentage of carbon by mass of Q more than P.
(ii) Test I
1. P is saturated hydrocarbon / P has single bond between carbon atoms
2. Do not undergo addition reaction //do not react with bromine
Test II
3. Q is unsaturated hydrocarbon / Q has double bond between carbon atom
4. Undergoes addition reaction react with bromine
(b) C2H5OH + 3O2 2CO2 + 3H2O
1. Correct formula and reactant
2. Correct balancing
2 .3
3. No of mole of ethanol = // 0.05 mol
46
4. 1 mole of ethanol produce 2 mole of carbon dioxide // 0.05 mole of ethanol produce 0.1
mole of carbon dioxide
5. Volume = 0.1 x 24 dm3 // 2.4 dm3
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(c) 1. R
(i) 2. S
3. Ethyl butanone
4.
(a) Draw the structural formula and state the name of compounds X, Y and Z.
Lukiskan formula struktur dan nyatakan nama sebatian X, Y dan Z. [6 marks]
(b) State the type of Reaction I and explain a chemical test to identify compound X.
Nyatakan jenis Tindak balas I dan terangkan ujian kimia untuk mengenal pasti sebatian X.
[3 marks]
(c) Compound X can be converted into propan-1-ol. Write the chemical equation and state the
conditions needed for the reaction.
Sebatian X boleh ditukarkan kepada propan-1-ol. Tuliskan persamaaan kimia dan nyatakan
keadaan diperlukan untuk tindak balas itu. [3 marks]
(d) In Reaction III, describe the method of preparing compound Z in the laboratory.
Dalam Tindak balas III, huraikan kaedah penyediaan sebatian Z di makmal. [4 marks]
(e) When calcium carbonate is added to compound Y, carbon dioxide gas is liberated.
State the name of the functional group of compound Y.
Write the general formula of compound Y.
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Write the chemical equation of the reaction.
Apabila kalsium karbonat ditambahkan kepada sebatian Y, gas karbon diaksida dibebaskan.
Nyatakan nama kimpulan berfungsi sebatian Y.
Tuliskan fornula am bagi xebatian Y
Tuliskan persamaan kimia bagi tindak balas itu. [4 marks]
Suggested Answer:
(a)
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QUESTION 8 2014 KEDAH MODUL 1 QUESTION 10
Alcohol is an example of an organic compound with various uses. The general formula of alcohol
is CnH2n+1 OH.
Alkohol adalah satu contoh sebatian organik dengan pelbagai kegunaan. Formula am alkohol
adalah CnH2n+1 OH.
(a) An alcohol contains 64.9% of carbon. 13.5% of hydrogen and 21.6% of oxygen. Determine the
molecular formula of the alcohol and state the name of the alcohol.
Sejenis alcohol mengandungi 64.9% karbon, 13.5% hidrogen and 21.6% oksigen. Tentukan
formula molekul alkohol tersebut dan nyatakan nama alkohol tersebut. [3 marks]
(b) Diagram 10 shows the flow chart on how ethanol can be prepared in the school laboratory and
industry using glucose and ethene respectively.
Rajah 10 menunjukkan carta alir bagaimana etanol dapat disediakan di makmal sekolah dan
industri menggunakan glukosa dan etena masing-masing.
Diagram 10 / Rajah 10
(c) Alcohols react with carboxylic acids to form esters and water. By using one named example of
an alcohol and one named example of a carboxylic acid, describe the preparation of an ester in
the laboratory.
Alkohol bertindak balas dengan asid karboksilik untuk menghasilkan ester dan air. Dengan
menggunakan satu alkohol yang dinamakan dan satu asid karboksilik yang dinamakan,
huraikan penyediaan ester di dalam makmal. [6 marks]
Suggested Answer:
(a) Elements: C : H : O
Mass/g: 64.9 : 13.5 : 21.6
No of mole: 5.4 : 13.5 : 1.35
Ratio: 4 : 10 : 1
C4H 9OH
Butanol
(b) From glucose:
Process
Fermentation
Steps
50cm3 glucose solution is added with yeast into a conical flask
Left for 30 days
The product is then purified by fractional distillation
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Chemical equation
C6H12O6 2C2H5OH + 2CO2
From ethane:
Process
Hydration // addition reaction
Steps
A mixture of ethene and water vapour / steam are passed over phosphoric acid as the
catalyst
At temperature of 300 C and pressure of 60 atm
Chemical equation
C2H4 + H2O C2H5OH
(c) - Name any suitable alcohol
- Name any suitable carboxylic
- Mix alcohol and carboxylic acid (same volume)
- In round bottom flask
- Add a few drops of sulphuric acid concentrated
- Heat the mixture in bath under reflux
(a) Propanol burns completely in excess oxygen gas to produce gas X and water.
Write a balance chemical equation to show the reaction.
Calculate the volume of gas X produced if 0.3 mol of oxygen gas is used in this reaction.
[Molar volume at room conditions = 24.0 dm3mol 1 ]
Propanol terbakar dengan lengkap dalam oksigen berlebihan menghasilkan gas X dan air.
Tuliskan persamaan kimia seimbang bagi tindak balas tersebut.
Hitungkan isi padu gas X yang terhasil jika 0.3 mol gas oksigen digunakan dalam tindak
balas ini.
[Isipadu molar pada keadaan bilik = 24.0 dm3mol 1 ] [4 marks]
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(b) Propanol reacts with propanoic acid to produce ester Y. Draw the structural formula and name
of the ester Y formed. Compare propanol and ester Y in terms of:
Functional group
Solubility in water
Propanol bertindak balas dengan asid propanoik untuk menghasilkan ester Y. Lukiskan
formula struktur dan namakan ester yang terbentuk. Bandingkan propanol dan ester Y dari
segi:
Kumpulan berfungsi
Keterlarutan dalam air [6 marks]
(c) Diagram 10.2 shows two reagent bottles P and Q. One of the bottles contains hexane while
another contains hexene.
Rajah 10.2 menunjukkan dua botol reagen P dan Q. Satu daripada botol tersebut
mengandungi heksana dan satu lagi mengandungi heksena.
Suggested Answer:
(a) 9
Chemical equation: C3 H 7OH O2 3CO2 4 H 2O //
2
Chemical equation: 2C3 H 7OH 9O2 6CO2 8H 2O
Volume of gas X:
1. Based on equation;
9
mol O2 : 3 mol CO2
2
0.3 mol O2 : 0.2 mol CO2
2. Volume of CO2 0.2 24 4.8dm3 // 4800cm3
(b) Structural formula of ester Y
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Name: propyl propanoate
Propanol Ester Y
Functional group Hydroxyl / - OH Carboxylate/ - COO
Solubility in water Soluble in water Insoluble in water
.
(c) Apparatus: Test tubes, dropper
Materials: Bromine water // acidified potassium manganate (VII) solution, hexane, hexane
Procedure:
1. [2 - 5] cm 3 of liquid in bottle P is poured into a test tube.
2. 2 cm 3 / A few drop of bromine water // acidified potassium manganate(VII) solution is
added to the test tube.
3. The mixture is shaken.
4. Any changes is observed and recorded.
5. Steps 1 to 4 are repeated by using the liquid in bottle Q to replace the liquid in bottle P.
Observation:
Set Observation
Liquid in bottle P Brown bromine water decolourised // purple acidified
potassium manganate(VII) solution decolourised.
Liquid in bottle Q No change.
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