Riverpollution PDF
Riverpollution PDF
Riverpollution PDF
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Abstract: The present investigation is an attempt to study the effect of sewage discharge into River Ganges and
to record the qualitative change in water. Physiochemical properties of River Ganges at Mirzapur were studied
at five different sites, viz., Site Ist-Shivpur (Up stream of Ganges river), Site IInd-Choubey ghat (Khandwa Nala),
Site IIIrd-Baba ghat (After Khandwa Nala), Site IVth-Ghore Shaheed (After Badshahi Nala) and Site Vth-
Bisunderpur (Mirzapur Downstream). The physio-chemical characteristics were studied and analyzed during
February to May-2011. The range of observations are as under; temperature ranges from 22.100C to 300C, pH
of river water ranges between 7.59 to 8.42, Electrical conductivity from 440 to 573 µS/cm, TDS from 272 to 382
mg/L, TSS from 30 to 65 mg/L, DO from 6 to 9.10 mg/L, BOD from 2.30 to 5.80 mg/L, COD from 10.20 to
28.30 mg/L, Alkalinity from 180 to 276 mg/L, Cl- from 28 to 66 mg/L and TC ranges from 2.7 x 103 to 1.5 x 104
MPN/100 m/L.
Keywords: River Ganges, Physico-chemical Parameter, Sewage.
I. Introduction
The Ganges rises in the Garhwal Himalayas (30055N, 7907E) under the name of Bhagirathi. The total
length of Ganges river is about 2525 Km. The River Ganges is a part and parcel of everyday life in the city and
it is one of the most sacred river in India, yet it is being polluted by many sources. The main townships of
Uttarakhand and Uttarpradesh falling at bank of Ganges river are Rishikesh, Haridwar, Garhmukteshwar,
Narora, Kannauj, Kanpur, Dalmau, Allahabad, Mirzapur, Varanasi, Ghazipur, Ballia and goes up to the Bay of
Bengal in the Indian Ocean [1]. Today, over 29 cities, 70 towns, and thousands of villages extend along the
Ganga banks. Nearly all of their sewage - over 1.3 billion litres per day - goes directly into the river, along with
thousands of animal carcasses, mainly cattle [2]. Due to rapid population growth, agricultural and industrial
developments, the quality of water in rivers is being degraded continuously making it unsuitable for various
uses. An accurate and rational assessment for river water quality is required for determining the extent of
usefulness of water bodies for various uses. Untreated wastewater may contain different range of pathogens
including bacteria, parasites, and viruses, toxic chemicals such as heavy metals and organic chemicals from
agriculture, industrial and domestic sources [3, 4]. The present investigation is concerned in Nagar block of
Mirzapur district of Uttar Pradesh. The study of different water parameter is very important for understanding of
the metabolic events in aquatic system. The parameters influence each other, therefore it has become obligatory
to analyze important water parameters time to time which can indicate the favourable or unfavourable changes
occurring in the ecosystem.
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Physiochemical analysis of River Ganges at Mirzapur in Uttar Pradesh, India
following physicochemical and biological parameters viz. Temperature, pH, EC, TSS, TDS, DO (wrinkle`s
method), BOD (5 days at 200C), COD (by dichromate method), alkalinity, Chloride (Argentometric method)
and Total coliform (by MPN method). All the experiment was done within 24 hours of sampling.
1. Temperature
The mean Temperature of the Ganges River increase with distance but found similar among all sites
(F=0.17, p=0.951). Temperature was recorded to ±0.1°C accuracy using a mercury thermometer, immediately
after collecting the water samples from different sites. The fluctuation in river water temperature usually
depends on the season, geographic location, sampling time and temperature of effluents entering the stream [6].
Water temperature is recorded lower (22.1oC) on 01st Feb at Ghore Shaheed due to winter and higher (30.0oC)
on 30th April at Ghore Shaheed during summer. Higher temperature during summers was due to greater heating.
In polluted water, temperature can have profound effect on Dissolved oxygen (DO) and Biological Oxygen
Demand (BOD). Similar trends are also showed by Yadav & Srivastava (2011).
2. pH
In contrast, mean pH decrease with distance and differed significantly among the sites (F=3.79,
p=0.010). The pH at Site 4 is lower as compared to Site 1. pH is an important parameter which plays an
important role in the evaluation of acid-base balance of water. The pH of water mainly depends upon carbonic
acid and interaction between carbonate and bicarbonates (V. Mathivanan, 2005). The maximum mean pH value
8.08 was recorded at Shivpur (Upstream), however the minimum mean pH value 7.83 was recorded at Ghore
Shaheed. The maximum pH value (8.42) was recorded at Shivpur in the sixth sampling and minimum pH value
(7.59) recorded at Ghore Shaheed in seventh sampling. The decreased in pH values of water recorded from
upstream to downstream is indicates increasing of pollution load from upstream to downstream .The pH value
of water at sewage discharge points were usually lower than that of the river water [8, 9].
3. Electrical Conductivity
Conversely, mean EC increase with distance but not differed significantly among the sites (F=1.25,
p=0.303). The maximum mean EC value 507.70 µS/cm was recorded at Ghore Shaheed which carried about 15-
20 % city raw sewage and treated sewage from Mirzapur STP, however minimum mean EC value 483.40 µS/cm
was observed at Shivpur (Upstream). The maximum EC value (573.0µS/cm) was recorded at Ghore Shaheed
and minimum EC value (440.0µS/cm) was recorded at Upstream. EC is significantly increasing at all sites to
downstream, similar observation were also reported by Srivastava and Sinha at Allahabad [7]. The increased in
EC values of water indicates that there is a source of dissolved ions in the vicinity. Higher the value of dissolved
solids, greater the amount of ions in water [10]. Increasing levels of conductivity and cations are the products of
decomposition and mineralization of organic materials [11].
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Physiochemical analysis of River Ganges at Mirzapur in Uttar Pradesh, India
9. Alkalinity
Conversely, though mean Alkalinity increase with distance but not differed significantly among the
sites (F=0.26, p=0.903). The maximum mean Alkalinity value 228.5 recorded at Ghore Shaheed, however the
minimum mean Alkalinity value 217.5 was observed at Shivpur (Upstream). The maximum Alkalinity value
(276.0) recorded on fourth sample at Ghore Shaheed and minimum Alkalinity value (180.0) was recorded on
fifth sample at Choubey ghat. Graph shows about increasing trends on all sites as we go towards downstream,
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Physiochemical analysis of River Ganges at Mirzapur in Uttar Pradesh, India
except Bisunderpur site. The high value of alkalinity indicates the presence of weak and strong base as
carbonates, Bicarbonates and hydroxides in the water body (Abassi et al., 1999; Jain et al., 1997). The high
values of alkalinity may also be due to increase in free carbon dioxide in the River Ganges which ultimately
results in the increase in alkalinity at site 3 & site 4 [21, 22].
References
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Physiochemical analysis of River Ganges at Mirzapur in Uttar Pradesh, India
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Table 1: Physico-chemical parameter levels (Mean ± SD, n=10) at different sites of the Ganga River at
Mirzapur city
F value p
Parameter Site 1 Site 2 Site 3 Site 4 Site 5 (4, 45 DF) value
Temp (0C) 25.57 ± 2.28 25.69 ± 2.26 25.90 ± 2.39 26.21 ± 2.56 26.28 ± 2.34 0.17 0.951
pH 8.08 ± 0.16 8.03 ± 0.13 7.98 ± 0.13 7.83 ± 0.17 7.91 ± 0.18 3.79 0.010
EC (μS/cm) 483.40 ± 25.53 488.70 ± 26.52 491.80 ± 27.37 507.70 ± 28.89 499.60 ± 26.33 1.25 0.303
TDS (mg/L) 324.30 ± 28.28 328.50 ± 28.60 335.60 ± 28.49 348.60 ± 29.53 342.70 ± 27.48 1.22 0.314
TSS (mg/L) 37.90 ± 5.63 40.60 ± 6.80 45.20 ± 6.20 54.00 ± 7.41 49.30 ± 5.27 10.58 <0.001
DO (mg/L) 8.25 ± 0.59 7.99 ± 0.61 7.83 ± 0.74 6.81 ± 0.62 7.21 ± 0.67 8.31 <0.001
BOD (mg/L) 3.00 ± 0.45 3.31 ± 0.52 3.39 ± 0.52 4.61 ± 0.69 4.11 ± 0.77 11.98 <0.001
COD (mg/L) 15.18 ± 2.73 15.88 ± 3.02 16.43 ± 3.06 21.94 ± 4.06 19.36 ± 3.69 7.13 <0.001
Alk (mg/L) 217.50 ± 30.56 218.20 ± 30.99 223.50 ± 31.20 228.50 ± 31.48 226.90 ± 30.29 0.26 0.903
-
Cl (mg/L) 40.50 ± 6.57 42.90 ± 6.52 45.50 ± 6.35 55.30 ± 7.33 49.10 ± 6.19 7.68 <0.001
T. Coliform
MPN/100ml 3520.00 ± 875.34 4310.00 ± 952.72 5760.00 ± 877.12 12080.00 ± 2444.40 8110.00 ± 1507.33 55.69 <0.001
Table 2: Significance (p value) of mean difference in physico-chemical parameters between sites by Tukey
test
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Physiochemical analysis of River Ganges at Mirzapur in Uttar Pradesh, India
Temp of the Ganges River at Mirzapur city pH of the Ganges River at Mirzapur city
Temp (0C) pH
30.00 8.30
29.00 8.20
28.00 8.10
Mean ± SD
Mean ± SD
27.00 8.00
26.00 7.90
25.00 7.80
24.00 7.70
23.00 7.60
Site 1 Site 2 Site 3 Site 4 Site 5 Site 1 Site 2 Site 3 Site 4 Site 5
Locations Locations
EC of the Ganges River at Mirzapur city TDS of the Ganges River at Mirzapur city
EC (μmhos/cm) TDS (mg/l)
550.00 390.00
540.00 380.00
530.00 370.00
520.00 360.00
Mean ± SD
Mean ± SD
510.00 350.00
500.00 340.00
490.00 330.00
480.00 320.00
470.00 310.00
460.00 300.00
450.00 290.00
Site 1 Site 2 Site 3 Site 4 Site 5 Site 1 Site 2 Site 3 Site 4 Site 5
Locations Locations
TSS of the Ganges River at Mirzapur city DO of the Ganges River at Mirzapur city
TSS (mg/l) DO (mg/l)
70.00 10.00
60.00
8.00
50.00
Mean ± SD
Mean ± SD
40.00 6.00
30.00
4.00
20.00
10.00 2.00
0.00
0.00
Site 1 Site 2 Site 3 Site 4 Site 5
Site 1 Site 2 Site 3 Site 4 Site 5
Locations
Locations
BOD of the Ganges River at Mirzapur city. COD of the Ganges River at Mirzapur city.
BOD (mg/l) COD (mg/l)
6.00 30.00
5.00 25.00
Mean ± SD
Mean ± SD
4.00 20.00
3.00 15.00
2.00 10.00
1.00 5.00
0.00 0.00
Site 1 Site 2 Site 3 Site 4 Site 5 Site 1 Site 2 Site 3 Site 4 Site 5
Locations Locations
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Physiochemical analysis of River Ganges at Mirzapur in Uttar Pradesh, India
Alkalinity of the Ganges River at Mirzapur Chloride of the Ganges River at Mirzapur
city. city.
Alk (mg/l) Cl (mg/l)
270.00 70.00
260.00 60.00
250.00 50.00
Mean ± SD
Mean ± SD
240.00
40.00
230.00
30.00
220.00
210.00 20.00
200.00 10.00
190.00 0.00
Site 1 Site 2 Site 3 Site 4 Site 5 Site 1 Site 2 Site 3 Site 4 Site 5
Locations Locations
16000.00
14000.00
12000.00
Mean ± SD
10000.00
8000.00
6000.00
4000.00
2000.00
0.00
Site 1 Site 2 Site 3 Site 4 Site 5
Locations
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