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Reaction of Silver Group

Reagent Formula Color and Nature


HCL AgCl white curdy ppt to gray ppt when exposed to light
S a) boiling water   insoluble
I b) Excess
Ag(NH3)2+ or Ag(NH3)2 Cl colorless solution
NH4OH
L NH4OH AgOH white ppt
V a) excess Ag(NH3)2+ or Ag(NH3)2 OH soluble- colorless solution
NaOH AgOH to Ag2O white to brown ppt
E a) excess   insoluble
R K2CrO4 Ag2CrO4 brownish red ppt
Ag+ a) NaOH   insouble
KI AgI canary yellow ppt
a) excess   insoluble

Reagent Formula Color and Nature


HCL PbCl2 white crystal ppt
a) boiling water Aqueous Solution of PbCl2 soluble- colorless solution
L b) Excess
insoluble
NH4OH
E NH4OH Pb(OH)2 white ppt
A a) excess insoluble
NaOH Pb(OH)2 white amorphous ppt
D a) excess Pb(OH)42- or Na2PbO2 soluble-colorless solution
Pb2+ K2CrO4 PbCrO4 yellow ppt
a) NaOH Na2PbO2 soluble- yellow solution
KI PbI2 yellow ppt
a) excess insoluble

Reagent Formula Color and Nature


M HCL Hg2Cl2 white curdy ppt
a) boiling water insoluble
E b) Excess
Hg2NH2 and HgO white and black ppt
R NH4OH
NH4OH HgO.HgNH2NO3 and HgO white and black ppt
C a) excess insoluble
U NaOH Hg2O black ppt
R a) excess insoluble
K2CrO4 Hg2CrO4 orange red ppt but brownish red on boiling
Y a) NaOH insoluble
Hg22+
KI Hg2I2 greenish yellow or green ppt
a) excess Hg2I4- and HgO / K2HgI and HgO colorless solution with black ppt

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