Page 1/9

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: Nullifire SC902 B
· MSDS code: W-N-SC902B
· 1.2 Relevant identified uses of the substance or mixture and uses advised against -
· Application of the substance / the mixture Coating compound/ Surface coating/ paint
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
tremco illbruck Coatings Ltd
Coupland Road, Hindley Green, WIGAN, WN2 4HT
Tel: +44 (0) 1942251400, Fax: +44 (0) 1942251410
msds@tremco-illbruck.com
· Further information obtainable from:
Nullifire
Torrington Avenue, Coventry, CV4 9TJ
T: +44 (0) 2476855000, F: +44 (0) 2476469547
www.nullifire.com, protect@nullifire.com
· 1.4 Emergency telephone number:
During office hours tel.: +44 (0) 2476855000. At all other times please contact your national poisoning
centre.

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 3 H226 Flammable liquid and vapour.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Dam. 1 H318 Causes serious eye damage.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant
R36: Irritating to eyes.
R10: Flammable.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

Trade name: Nullifire SC902 B

(Contd. of page 1)
· Hazard pictograms

GHS02 GHS05

· Signal word Danger

· Contains:
3-(trimethoxysilyl)propylamine
· Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H318 Causes serious eye damage.
· Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P280 Wear protective gloves / eye protection / face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
· 2.3 Other hazards No further relevant information available.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Mixtures
· Description: Mixture of substances listed below with non-hazardous additions.
· Dangerous components:
CAS: 1330-20-7 xylene (mix) 5- <10%
EINECS: 215-535-7 Xn R20/21; Xi R38
Reg.nr.: 01-2119488216-32-xxxx R10
Flam. Liq. 3, H226; Acute Tox. 4, H312; Acute Tox. 4,
H332; Skin Irrit. 2, H315
CAS: 13822-56-5 3-(trimethoxysilyl)propylamine 5- <10%
EINECS: 237-511-5 Xi R38-41
Reg.nr.: 01-2119510159-45-xxxx Eye Dam. 1, H318; Skin Irrit. 2, H315
CAS: 100-41-4 ethylbenzene 1- <5%
EINECS: 202-849-4 Xn R20; F R11
Reg.nr.: 01-2119489370-35-xxxx Flam. Liq. 2, H225; Acute Tox. 4, H332
· Additional information:
While curing the following substances are formed and released by a reaction with atmospheric
humidity:
Methanol (CAS 67-56-1)
For the wording of the listed risk phrases refer to section 16.
GB
(Contd. on page 3)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

Trade name: Nullifire SC902 B

(Contd. of page 2)

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information: Take affected persons out of danger area and lay down.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
Irritant to skin and mucous membranes.
Risk of serious damage to eyes.
· Information for doctor: No further relevant information available.
· Hazards No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
GB
(Contd. on page 4)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

Trade name: Nullifire SC902 B

(Contd. of page 3)

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Avoid contact with the eyes and skin.
· Information about fire - and explosion protection:
Flammable liquid and vapour.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in unopened original receptacles.
Provide ventilation for receptacles.
· Information about storage in one common storage facility: Protect from heat and direct sunlight.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Storage temperature: +5 °C to +25 °C
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
1330-20-7 xylene (mix)
WEL Short-term value: 441 mg/m³, 100 ppm
Long-term value: 220 mg/m³, 50 ppm
Sk; BMGV
100-41-4 ethylbenzene
WEL Short-term value: 552 mg/m³, 125 ppm
Long-term value: 441 mg/m³, 100 ppm
Sk
· Ingredients with biological limit values:
1330-20-7 xylene (mix)
BMGV 650 mmol/mol creatinine
Medium: urine
Sampling time: post shift
Parameter: methyl hippuric acid
· Additional information:
The lists valid during the making were used as basis.
EH40/2005 Workplace Exposure Limits (2nd edition, 2011)
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Do not breathe spray.
Do not eat, drink, smoke or sniff while working.
Avoid contact with the eyes and skin.
(Contd. on page 5)
GB

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

Trade name: Nullifire SC902 B

(Contd. of page 4)
· Respiratory protection:
Use only in well-ventilated areas.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
Filter A/P2
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
· Material of gloves
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
PVA gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection:

Tightly sealed goggles

· Body protection: Protective work clothing

* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Viscous
Colour: According to product specification
· Odour: Characteristic
· Boiling point/Boiling range: > 100 °C
· Flash point: 51 °C
· Danger of explosion: Product is not explosive. However, formation of explosive air/vapour
mixtures are possible.
· Density at 20 °C: 1 g/cm³
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

Trade name: Nullifire SC902 B

(Contd. of page 5)
· Solvent content:
VOC (EC) 112 g/l
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity Stable
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions Reacts with acids, alkalis and oxidising agents.
· 10.4 Conditions to avoid
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
methanol
Nitrogen oxides
Carbon monoxide and carbon dioxide

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity
· LD/LC50 values relevant for classification:
1330-20-7 xylene (mix)
Oral LD50 4300 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
· Primary irritant effect:
· Skin corrosion/irritation Causes skin irritation.
· Serious eye damage/irritation Risk of serious damage to eyes.
· Respiratory or skin sensitisation No sensitising effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
Repeated exposure may cause skin dryness or cracking.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
1330-20-7 xylene (mix)
EC50/48 h 7.4 mg/L (daphnia magna)
EC50/72 h 10 mg/L (skelettonema costatum)
LC50/96 h 3.77 mg/L (fish)
· 12.2 Persistence and degradability No further relevant information available.
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

Trade name: Nullifire SC902 B

(Contd. of page 6)
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Overall evaluation
Avoid transfer into the environment.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
Disposal must be made according to official regulations.
· Waste disposal key: UK : H3B
· European waste catalogue
08 01 11* waste paint and varnish containing organic solvents or other dangerous substances
· Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
Packagings that may not be cleansed are to be disposed of in the same manner as the product.
Non contaminated packagings may be recycled.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, ADN, IMDG, IATA Void
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA Void
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

Trade name: Nullifire SC902 B

(Contd. of page 7)
· Transport/Additional information:
· ADR 2.2.3.1.1 (note 1)
2.2.3.1.5
· IMDG 2.3.1.2 + 2.3.1.3
2.3.2.5
· IATA 3.3.1.2 + 3.3.1.3
· UN "Model Regulation": UN-, -

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Directive 1999/45/EC.
"CLP" Regulation (EC) No 1272/2008 (OJ L 353, 31.12.2008, p.1).
"CHIP" SI 2009 No.716.
"REACH" Regulation (EC) No 1907/2006 (OJ L 396, 30.12.2006, p.1, with subsequent amendments).
· National regulations:
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57 Not applicable.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
R10 Flammable.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
(Contd. on page 9)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 14.05.2015 Version number 5 Revision: 14.05.2015

Trade name: Nullifire SC902 B

(Contd. of page 8)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Flam. Liq. 3: Flammable liquids, Hazard Category 3
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
· * Data compared to the previous version altered.
GB

40.3.4