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Msds-Ammonia Solution - Cas 1336-21-6

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Safety data sheet


according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

SECTION 1: Identification of the substance/mixture and of the company/undertaking


· 1.1 Product identifier
· Trade name: Ammonia solution 25-30%.
· SDS number: CH5255
· Application of the substance / the mixture Chemicals products for laboratory
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
CARLO ERBA REAGENTS
Chaussée du Vexin
Parc d'Affaires des Portes - BP616
27106 VAL DE REUIL Cedex
Téléphone: +33 (0)2 32 09 20 00
Télécopie: +33 (0)2 32 09 20 20
· Further information obtainable from:
Q.A / Normative
email: MSDS_CER-SDS@cer.dgroup.it
· 1.4 Emergency telephone number:
Ireland - Tel : 00 353 1 8092568 - 00 353 1 8379964 (24h/24)
EU Tel : 112
National Poisons Information Centre: +353 (1) 809 2166 (8.00 a.m. to 10.00 p.m. 7 days a week)
Healthcare Professionals: +353 (1) 809 2566 (24 hour service)
Members of the public seeking specific information on poisons should contact:
In England and Wales: NHS 111 - dial 111
In Scotland: NHS 24 - dial 111

* SECTION 2: Hazards identification


· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.

environment

Aquatic Acute 1 H400 Very toxic to aquatic life.

STOT SE 3 H335 May cause respiratory irritation.


· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the GB CLP regulation.
(Contd. on page 2)
GB

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 1)
· Hazard pictograms

GHS05 GHS07 GHS09

· Signal word Danger


· Hazard-determining components of labelling:
ammonia, aqueous solution
· Hazard statements
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
· Precautionary statements
P280 Wear protective gloves / eye protection / face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients


· 3.2 Chemical characterisation: Mixtures
· Description:
Mixture made by the following substances:
CAS: 7732-18-5 water, distilled, conductivity or of similarpurity ≤100%
EINECS: 231-791-2
RTECS: ZC 0110000
· Dangerous components:
CAS: 1336-21-6 ammonia, aqueous solution 25-<30%
EINECS: 215-647-6 Skin Corr. 1B, H314; Aquatic Acute 1, H400; STOT SE
Index number: 007-001-01-2 3, H335
Reg.nr.: 01-2119488876-14

SECTION 4: First aid measures


· 4.1 Description of first aid measures
· General information:
Remove immediately any clothing soiled by the product and wash with plenty of water. The rescuer has to be
equipped with individual protection
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
(Contd. on page 3)
GB

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 2)
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly. Wash contaminated clothing before reuse.
Seek immediate medical advice.
If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Drink plenty of water and provide fresh air.
Do not induce vomiting; call for medical help immediately.
Call for a doctor immediately.
Rinse out mouth and then drink plenty of water.
· Information for doctor: Show the doctor this Material Safety Data Sheet.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures


· 5.1 Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· For safety reasons unsuitable extinguishing agents: Water with full jet.
· 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released:
· 5.3 Advice for firefighters
· Protective equipment: Do not inhale gases in case or fire or combustion.
· Additional information Keep receptacles cool with water spray.

SECTION 6: Accidental release measures


· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Ensure adequate ventilation
· 6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to penetrate the ground/soil.
Dilute with plenty of water after collecting the liquid.
Do not allow to enter sewers/ surface or ground water.
In case of seepage into the ground inform responsible authorities.
· 6.3 Methods and material for containment and cleaning up:
Collect the liquid with vacuum in a suitable container and absorb the remainder with a porous material
(diatomite, acid binders, universal binders, etc).
Ensure adequate ventilation.
Use neutralising agent.
Dispose contaminated material as waste according to section 13.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
GB
(Contd. on page 4)

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 3)

SECTION 7: Handling and storage


· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
When diluting always pour product into water and not vice versa.
· Information about fire - and explosion protection: The product is not flammable.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a well-ventilated place. Keep container tightly closed.
Unsuitable material for receptacle: aluminium.
Provide alkali-resistant floor.
Provide floor trough without outlet.
Prevent any seepage into the ground.
Use only receptacles specifically permitted for this substance/product.
· Information about storage in one common storage facility: Do not keep in contact with acids.
· Further information about storage conditions: None.
· 7.3 Specific end use(s) No further relevant information available.

* SECTION 8: Exposure controls/personal protection


· 8.1 Control parameters
· Additional information about design of technical facilities: No further data; see section 7.
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Do not inhale dust / smoke / mist.
Avoid contact with the eyes and skin.
· Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed.

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or
longer exposure use self-contained respiratory protective device.

Suitable respiratory protective device recommended in case of leakages or handling in open devices.
Use suitable respiratory protective device in case of insufficient ventilation.
(Contd. on page 5)
GB

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 4)
· Protection of hands:
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation

Protective gloves

Rubber gloves
Avoid direct contact with the chemical/ the product/ the preparation by organisational measures.
· Material of gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
Fluorocarbon rubber (Viton)
Recommended thickness of the material:  0.4 mm
Chloroprene rubber, CR
Recommended thickness of the material:  0.5 mm
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Recommended thickness of the material:  0.5 mm
· Not suitable are gloves made of the following materials:
Nitrile rubber, NBR
Natural rubber, NR
PVC gloves
· Eye protection:

Tightly sealed goggles

· Body protection:
Protective work clothing
In case of pouring big amounts or disconnecting pipes.
Alkaline resistant protective clothing
Apron
· Limitation and supervision of exposure into the environment
The product must not be released into the environment.
In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Risk management measures Keep good industrial hygiene.

SECTION 9: Physical and chemical properties


· 9.1 Information on basic physical and chemical properties
· Molecular weight
· Appearance:
Form: Fluid
(Contd. on page 6)
GB

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 5)

Colour: Colourless
· Odour: Like ammoniac
· Odour threshold: Not determined.
· pH-value at 20 °C: >12
· Change in condition
Melting point/freezing point: <-69.2 °C
Initial boiling point and boiling range: <25 °C
· Flash point: Not applicable.
· Flammability (solid, gas): Not applicable.
· Decomposition temperature: Not determined.
· Ignition temperature: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard.
· Explosion limits:
Lower: 15 Vol %
Upper: 28 Vol %
· Vapour pressure at 20 °C: 635 hPa
· Density at 20 °C: 0.898 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Fully miscible.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent separation test:
Water: 70.1 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity


· 10.1 Reactivity See 10.3
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions
Reacts with strong acids.
Strong exothermic reaction with acids.
With iodine in solution gives a precipitate of NJ3, explosive when dry.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials:
Strong acids.
Zinc
Aluminium
· 10.6 Hazardous decomposition products:
No decomposition products known, more dangerous than the product as such.
GB
(Contd. on page 7)

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 6)

* SECTION 11: Toxicological information


· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
CAS: 1336-21-6 ammonia, aqueous solution
Oral LD50 350 mg/kg (rat)
Inhalative LC50 13,770 mg/m³ (rat) (1h)
· Primary irritant effect:
· Skin corrosion/irritation
Stronghly basic product: irritant by the degreasing properties.
Causes severe skin burns and eye damage.
· Serious eye damage/irritation
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Causes serious eye damage.
· Inhalation:
Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract.
Harmful if inhaled. May cause respiratory tract irritation.
May cause respiratory irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Other information (about experimental toxicology): No further relevant information available.
· Target organ information
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause respiratory irritation.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


· 12.1 Toxicity
· Aquatic toxicity:
CAS: 1336-21-6 ammonia, aqueous solution
EC50/48h 24 mg/l (Daphnia)
EC50 2 mg/L (bacteria (Photobacterium phosphoreum)) (5 mn)
24 mg/L (Daphnia)
LC50/96h 0.53 mg/l (fishes)
· 12.2 Persistence and degradability No further relevant information available.
· Method
· Ecological information Not available
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark:
Local effects: may change the environmental pH endangering the aquatic life.
Very toxic for fish
(Contd. on page 8)
GB

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 7)
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralised.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high
pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably reduced, so
that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations


· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Reutilise if possible or contact a waste processors for recycling or safe disposal.
· Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
Packagings that may not be cleansed are to be disposed of in the same manner as the product.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.

SECTION 14: Transport information


· 14.1 UN-Number
· ADR/RID, IMDG, IATA UN2672
· 14.2 UN proper shipping name
· ADR/RID 2672 AMMONIA SOLUTION, ENVIRONMENTALLY
HAZARDOUS
· IMDG AMMONIA SOLUTION, MARINE POLLUTANT
· IATA Ammonia solution
· 14.3 Transport hazard class(es)
· ADR/RID

· Class 8 (C5) Corrosive substances.


· Label 8
(Contd. on page 9)
GB

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according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 8)

· IMDG

· Class 8 Corrosive substances.


· Label 8
· IATA

· Class 8 Corrosive substances.


· Label 8
· 14.4 Packing group
· ADR/RID, IMDG, IATA III
· 14.5 Environmental hazards: Product contains environmentally hazardous substances:
ammonia, aqueous solution
· Marine pollutant: Yes
Symbol (fish and tree)
· Special marking (ADR/RID): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Corrosive substances.
· Hazard identification number (Kemler code): 80
· EMS Number: F-A,S-B
· Segregation groups (SGG18) Alkalis
· Stowage Category A
· Stowage Code SW2 Clear of living quarters.
SW5 If under deck, stow in a mechanically ventilated
space.
· Segregation Code SG35 Stow "separated from" SGG1-acids
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR/RID
· Excepted quantities (EQ): E1
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category 3
· Tunnel restriction code E
· IMDG
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
(Contd. on page 10)
GB

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 9)

· UN "Model Regulation": UN 2672 AMMONIA SOLUTION, 8, III,


ENVIRONMENTALLY HAZARDOUS

* SECTION 15: Regulatory information


· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· SARA Section 355 (extremely hazardous substances)
None of the ingredients is listed.
· SARA Section 313 (specific toxic chemical listings)
CAS: 1336-21-6 ammonia, aqueous solution
· Prop 65 - Chemicals known to cause cancer
None of the ingredients is listed.
· Poisons Act
· Regulated explosives precursors
None of the ingredients is listed.
· Regulated poisons
None of the ingredients is listed.
· Reportable explosives precursors
None of the ingredients is listed.
· Reportable poisons
CAS: 1336-21-6 ammonia, aqueous solution 10%
· Chemical safety assessment
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category E1 Hazardous to the Aquatic Environment
· Qualifying quantity (tonnes) for the application of lower-tier requirements 100 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· National regulations:
· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

* SECTION 16: Other information


This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
· Department issuing SDS: Q.A./Normative
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
RCR : Risk Characterisation Ratio
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
(Contd. on page 11)
GB

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Safety data sheet
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Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 10)


EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
ATE: Acute toxicity estimate values
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
· Sources
Globally Harmonized System, GHS
ADR/RID, IMDG, IATA
PubChem : an open chemistry database at the National Institutes of Health (NIH)
ECHA : European CHemicals Agency
· * Data compared to the previous version altered. .
GB
(Contd. on page 12)

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Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 11)

Annex: Exposure scenario 1


· Short title of the exposure scenario Formulation or re-packing
· Sector of Use Industrial use.
· Process category
PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with
equivalent containment conditions.
PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure
or processes with equivalent containment conditions
PROC5 Mixing or blending in batch processes
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including weighing)
PROC15 Use as laboratory reagent
· Environmental release category ERC2 Formulation into mixture
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use Customary application according to section 1.
· Duration and frequency 5 workdays/week.
· Physical parameters
The data on the physical - chemical properties in the Exposure Scenario is based on the properties of the
preparation.
· Physical state Fluid
· Concentration of the substance in the mixture The substance is main component.
· Other operational conditions Observe the general safety regulations when handling chemicals.
· Other operational conditions affecting environmental exposure Use only on hard ground.
· Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
· Risk management measures
· Worker protection
· Organisational protective measures
Keep good industrial hygiene.
Ensure that activities are executed by specialists or authorised personnel only.
Persons, who tend to skin diseases or other hypersensitivity reactions of the skin, should not handle the
product.
Provide sufficient washing facilities.
· Technical protective measures Ensure good ventilation/exhaustion at the workplace.
· Personal protective measures
Avoid contact with the skin.
Avoid contact with the eyes.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Protective gloves
Rubber gloves
Avoid direct contact with the chemical/ the product/ the preparation by organisational measures.
Tightly sealed goggles
The usual precautionary measures are to be adhered to when handling chemicals.
Detailed measures on hand protection according to Safety Data Sheet, section 8.
Use suitable respiratory protective device only when aerosol or mist is formed.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Use suitable respiratory protective device in case of insufficient ventilation.
(Contd. on page 13)
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Trade name: Ammonia solution 25-30%.

(Contd. of page 12)


Protective work clothing
Apron
· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Water
Generally, prior to the introduction of wastewater into wastewater treatment plants a neutralisation is
required.
Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures Ensure that waste is collected and contained.
· Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (dermal)
The exposure estimation was carried out in accordance with ECETOC TRA.
RCR 0.202
· Worker (inhalation)
The exposure estimation was carried out in accordance with ECETOC TRA.
RCR <0.98
· Environment
The estimation of environmental exposure was carried out in accordance with EUSES.
RCR 0.045
· Guidance for downstream users
Whether the downstream user acts within the scope of the Exposure Scenario can be verified based on the
information in sections 1 to 8.
GB
(Contd. on page 14)

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Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 13)

Annex: Exposure scenario 2


· Short title of the exposure scenario Chemicals products for laboratory
· Sector of Use Industrial use.
· Process category
PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with
equivalent containment conditions.
PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure
or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC5 Mixing or blending in batch processes
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including weighing)
PROC13 Treatment of articles by dipping and pouring
PROC15 Use as laboratory reagent
PROC20 Use of functional fluids in small devices
· Environmental release category
ERC8b Widespread use of reactive processing aid (no inclusion into or onto article, indoor)
ERC8e Widespread use of reactive processing aid (no inclusion into or onto article, outdoor)
ERC8f Widespread use leading to inclusion into/onto article (outdoor)
ERC9a Widespread use of functional fluid (indoor)
ERC9b Widespread use of functional fluid (outdoor)
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use Customary application according to section 1.
· Duration and frequency 5 workdays/week.
· Physical parameters
The data on the physical - chemical properties in the Exposure Scenario is based on the properties of the
preparation.
· Physical state Fluid
· Concentration of the substance in the mixture The substance is main component.
· Other operational conditions Observe the general safety regulations when handling chemicals.
· Other operational conditions affecting environmental exposure Use only on hard ground.
· Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
· Risk management measures
· Worker protection
· Organisational protective measures
Keep good industrial hygiene.
Ensure that activities are executed by specialists or authorised personnel only.
Persons, who tend to skin diseases or other hypersensitivity reactions of the skin, should not handle the
product.
Provide sufficient washing facilities.
· Technical protective measures Ensure good ventilation/exhaustion at the workplace.
· Personal protective measures
Avoid contact with the skin.
Avoid contact with the eyes.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Protective gloves
Rubber gloves
(Contd. on page 15)
GB

58.1.5
Page 15/17
Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 14)


Avoid direct contact with the chemical/ the product/ the preparation by organisational measures.
Tightly sealed goggles
The usual precautionary measures are to be adhered to when handling chemicals.
Detailed measures on hand protection according to Safety Data Sheet, section 8.
Use suitable respiratory protective device only when aerosol or mist is formed.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Use suitable respiratory protective device in case of insufficient ventilation.
Protective work clothing
Apron
· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Water
Generally, prior to the introduction of wastewater into wastewater treatment plants a neutralisation is
required.
Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures Ensure that waste is collected and contained.
· Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (dermal)
The exposure estimation was carried out in accordance with ECETOC TRA.
RCR 0.202
· Worker (inhalation)
The exposure estimation was carried out in accordance with ECETOC TRA.
RCR <0.98
· Guidance for downstream users
Whether the downstream user acts within the scope of the Exposure Scenario can be verified based on the
information in sections 1 to 8.
Whether the downstream user uses the substance / the mixture within the scope of the Exposure Scenario can
be determined by means of a technical assessment.
GB
(Contd. on page 16)

58.1.5
Page 16/17
Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 15)

Annex: Exposure scenario 3


· Short title of the exposure scenario
· Sector of Use Industrial use.
· Process category
PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with
equivalent containment conditions.
PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure
or processes with equivalent containment conditions
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC15 Use as laboratory reagent
· Environmental release category ERC1 Manufacture of the substance
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use Customary application according to section 1.
· Duration and frequency 5 workdays/week.
· Physical parameters
The data on the physical - chemical properties in the Exposure Scenario is based on the properties of the
preparation.
· Physical state Fluid
· Concentration of the substance in the mixture The substance is main component.
· Other operational conditions Observe the general safety regulations when handling chemicals.
· Other operational conditions affecting environmental exposure Use only on hard ground.
· Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
Respiratory protection is required in work areas with inadequate ventilation and during spraying application.
· Risk management measures
· Worker protection
· Organisational protective measures
Keep good industrial hygiene.
Ensure that activities are executed by specialists or authorised personnel only.
Persons, who tend to skin diseases or other hypersensitivity reactions of the skin, should not handle the
product.
Provide sufficient washing facilities.
Ensure good ventilation. This can be achieved by using a local exhaustion or general exhaust system. If these
measures are insufficient to keep the solvent vapour concentration below the workplace limit, wear an
adequate respiratory protective device.
· Technical protective measures Ensure good ventilation/exhaustion at the workplace.
· Personal protective measures
Avoid contact with the skin.
Avoid contact with the eyes.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Protective gloves
Rubber gloves
Avoid direct contact with the chemical/ the product/ the preparation by organisational measures.
Tightly sealed goggles
The usual precautionary measures are to be adhered to when handling chemicals.
Detailed measures on hand protection according to Safety Data Sheet, section 8.
Use suitable respiratory protective device only when aerosol or mist is formed.
Suitable respiratory protective device recommended in case of leakages or handling in open devices.
Protective work clothing
In case of pouring big amounts or disconnecting pipes.
Apron
(Contd. on page 17)
GB

58.1.5
Page 17/17
Safety data sheet
according to Regulation (EC) No 1907/2006, Article 31
Printing date 08.05.2024 Version number 4 Revision: 01.05.2024

Trade name: Ammonia solution 25-30%.

(Contd. of page 16)


· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Water
Generally, prior to the introduction of wastewater into wastewater treatment plants a neutralisation is
required.
Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures Ensure that waste is collected and contained.
· Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (dermal)
The exposure estimation was carried out in accordance with ECETOC TRA.
RCR 0.202
· Worker (inhalation)
The exposure estimation was carried out in accordance with ECETOC TRA.
RCR <0.98
· Environment
The estimation of environmental exposure was carried out in accordance with EUSES.
RCR 0.121
· Guidance for downstream users
Whether the downstream user acts within the scope of the Exposure Scenario can be verified based on the
information in sections 1 to 8.
GB

58.1.5

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